硅钢资料

对西昌钢钒炼钢厂200 t BOF(顶底复吹)-RH-CC工艺生产50PRW800无取向硅钢RH精炼过程中主要成份进行了分析。找出了目前工艺中影响钢液质量的主要因素是钢水脱氧处理不彻底,造成加入的部分硅元素烧损。操作工艺改为铝的脱氧即合金化操作一步完成,保证了钢水中氧处于一个较低的范围,从而减少对硅元素的烧损,提高合金收得率。 The factors of BOF-RH-CC process affecting the compositions of liquid steel were systematically investigated and studied of Xichang Steel and Vanadium Company. The main factors affecting the steel cleanliness were picked out. All results showed that the loss of silicon elements resulting from the deoxidization of liquid steel was not completely. It was suggested that the addition of aluminum for deoxidizing and alloying of molten steel was executed as one step in order to lower the oxygen potent... 

【机构】 中国金属学会电工钢分会； ...

利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1～2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,... 

针对某厂DMS森吉米尔轧机生产无取向硅钢表面麻面缺陷的问题，根据生产实际，对其形成原因从乳化液及工作辊两方面因素进行了分析。结果表明：乳化液对麻面缺陷的产生有一定影响，但不是主要因素，主要原因是由于二十辊森吉米尔轧机工作辊辊径较小，轧制相同长度带钢轧辊运转周期较大，容易产生疲劳失效而导致。为此，提出通过调整冷轧工序成品轧制道次的压下率以减小轧制力，从而减小工作辊的磨损疲劳；通过对轧制乳化液浓度、温度的合理控制，以改善润滑效果、提高轧制速度，而进一步缓解轧辊疲劳的改进措施，使该钢厂无取向硅钢麻面缺陷发生率由原来的18%降至0.8%,带钢表面质量明显改善。 For the problem of surface pockmarks of non-oriented silicon steel strip produced by a DMS Sendzimir mill, based on the production practice, the formation causes were analyzed from two aspects of emulsion and working roll. The results show that the emulsion has a certain effect on the formation of surface pockmarks defects, but it is not the main factor. The main reason is that the working roll diameter of the 20-high Sendzimir mill is small, and the running period of the roll rolling the same l... 

对取向硅钢在不同气氛下的高温退火工艺进行实验室模拟，利用X射线衍射仪（XRD）分析了硅钢退火至900℃和1170℃时的样品表面氧化层和底层的物相组成，采用场发射扫描电镜（SEM）观察了样品表面氧化层和底层在截面方向上的微观形貌特征，并计算了高温退火一次升温阶段氧化反应的吉布斯自由能以及900℃时退火气氛的氧分压。结果表明：当退火气氛的露点温度保持一定时，较高的氢气含量有利于生成完整连续的底层；当退火气氛的水氢分压比保持一定时，在露点温度与氢气含量两者较低的条件下，底层附着性不佳易脱落，较高条件下，底层中夹杂着较多的铁单质；当氧化层中无FeO时，底层完整连续但易脱落，当FeO层较薄时，底层下方存在部分未反应的SiO₂,当FeO层较厚时，底层不完整连续且有分层。 The high temperature annealing process of grain-oriented silicon steel in different atmospheres was simulated in the laboratory. X-ray diffractometer（XRD） was used to analyze the phase compositions of the surface oxide layer and forsterite film of the silicon steel annealed to 900 ℃ and 1170 ℃. Field-emission scanning electron microscopy（SEM） was used to observe the micro morphology characteristics of the surface oxide layer and forsterite film of the samples in the cross section direction. The ... 

高强无取向硅钢主要应用于高速电机，要求其具备高强度和优异磁性能，但目前无取向硅钢的磁性能和强度难以兼顾。因此，设计并制备了添加微量Cr的含Nb高强无取向硅钢，通过光学显微镜、EBSD、万能拉伸试验机、四探针测试仪和磁性能测量仪等研究了Cr对含Nb高强无取向硅钢微观组织、织构、力学性能及磁性能的影响。结果表明，添加质量分数为0.5%的Cr抑制了热轧组织的回复，使常化和退火组织再结晶减弱，常化和退火后有利织构面积分数增加，不利织构面积分数减小。添加质量分数为0.5%的Cr使含Nb无取向硅钢的屈服强度显著增大，磁感略升高，但对铁损几乎没有影响。Cr对屈服强度的影响一方面是由于Cr的固溶强化作用，另一方面Cr促进了Nb的析出而使Nb的析出强化效果增强；而Cr提高含Nb高强无取向硅钢的磁感主要是由于促进有利织构形成的同时抑制了不利织构的形成，使得织构因子增大；添加Cr使无取向硅钢的电阻率增加从而使铁损降低，同时Cr促进了Nb的析出，而这种富Nb析出相不仅抑制晶粒长大且会阻碍磁畴移动而使铁损增高，在两方面因素的综合作用下，添加质量分数为0.5%的Cr对含Nb高强无取向硅钢的铁损几乎没有影响。因此，... High strength non-oriented silicon steel is mainly used in high-speed motors, which requires good mechanical and magnetic properties. However, it is difficult for non-oriented silicon steel to obtain high strength and good magnetic properties at the same time. In this paper, the Cr-microalloyed Nb-containing high strength non-oriented silicon steel was designed and prepared. The effect of Cr on the microstructure, texture, mechanical properties and magnetic properties of Nb-containing high stren... 

通过对辉光放电发射光谱参数的优化,以铁元素为内标来消除基体效应,建立了测定硅钢薄板中微量硼元素的方法。优化的实验参数为:放电电压1200 V,放电电流50 mA,预溅射时间40 s,积分时间10 s。校准曲线硼元素含量范围0.0001%~0.022%,相关系数大于0.999,测量结果与认定值一致,相对标准偏差小于10%。完全能够满足日常分析测试的要求。 A glow discharge optical emission spectrometry(GD-OES) method for determining trace boron element in silicon steel sheets were established through optimization of instrumental parameters and using Fe element as an internal standard to eliminate the matrix effect.The optimized instrumental parameters included discharge voltage,discharge current,pre-sputtering time and integration time,which are 1200 V,50 mA,40 s,and 10 s,respectively.The content of boron element that can be determined from the ca... 

运用电子背散射衍射(EBSD)和X射线衍射(XRD)技术对硅钢热轧板的织构在板厚方向的分布进行了研究,并分析了两种织构测量方法的特点。EBSD技术能直观给出板厚方向的微观织构,XRD能得到钢板的宏观统计织构信息,结合两种技术的分析,能更直观更精确的研究不同织构在板厚方向的分布。 The texture distribution along the thickness of the silicon steel has been investigated by electron backscatter diffraction(EBSD) and X-ray diffraction(XRD) technique.The characteristics of two technique of texture analysis have been investigated.Combined the two techniques,the texture distribution along the thickness of the silicon steel could be realized distinctly and accurately. 

取向硅钢利用析出物作为抑制剂,抑制初次再结晶晶粒的长大,抑制剂是取向硅钢发生二次再结晶的基本条件之一。文中通过低温板坯加热技术制备取向硅钢,采用透射电镜(TEM)观察并研究了高温退火阶段抑制剂的演化过程。结果表明,渗氮后形成的非晶态Si3N4析出物不稳定,在700～750℃退火升温阶段转化为(Al,Si)N;(Al,Si)N颗粒在800℃发生团聚,随后长大并粗化;(Al,Si)N是低温取向硅钢主要抑制剂,随退火温度的升高,(Al,Si)N抑制力大幅下降。 Precipitates as inhibitor are used to inhibit the grain growth of primary recrystallization in grain-oriented silicon steel,and inhibitor is one of the basic conditions for occurring of secondary recrystallization.The grain-oriented silicon steel was produced by low temperature slab heating and nitriding technique.The evolution of inhibitor was observed by transmission electron microscopy.The results show that Si3N4 particles are precipitated after nitriding,and Si3N4 particles are amorphous and... 

选用Q235和Q345钢,在纯锌浴和含钛量分别为0.05%、0.10%、0.15%、0.20%(质量分数)的合金浴中浸镀0.5、1、3、5、8 min。利用扫描电子显微镜和能谱仪研究了钛对热浸镀锌组织和生长动力学的影响,并提出钛对含硅钢铁锌反应抑制作用的机理。结果表明:钛的加入缩短了Γ的孕育期,促进了合金层中δ的生长和ζ的消失,δ的生长依然受扩散控制,呈抛物线生长规律;Zn-0.05%Ti锌浴可以很好的抑制高硅钢的硅反应性;含硅钢热浸镀锌钛合金浴时,在锌浴中会形成锌铁钛三元T相,该相能吸收ζ晶界处富集的硅,从而抑制了铁锌反应。 Both Q235 and Q345 steels were immersed for 0.5 to 8 min in Zn bath with different amount of Ti,ranging from 0 to 0.20 mass%,for galvanization.The effect of Ti in Zn bath on microstructure and growth kinetics of hot-dip galvanizing coatings on the two steels were investigated by means of SEM and EDS analysis.Base on the experiment,the mechanism of Ti additions in controlling Fe-Zn reaction was proposed.The results show that addition of Ti in the zinc bath decreases the incubation time of Γ phase... 

对新能源汽车以及驱动电机的现有市场和未来市场规模进行梳理分析，通过自建计算公式推导出我国2021年1-11月份驱动电机用电工钢的总量，进而预测未来10年中国新能源汽车驱动电机用电工钢情况，为无取向电工钢的生产和在电机中的应用提供有价值的参考。 The current market and future market size of new energy vehicles and traction motors were analyzed,and the total amount of electrical steels used in traction motors in China from January to November 2021 was derived by using self-built calculation formulas,and then the situation in the next ten years of electrical steel used in traction motors of new energy vehicles in China was predicted.It will provide a valuable reference for the production of non-grain oriented electrical steel and its appli... 

硅钢连续退火线是无取向硅钢生产的成品线。由于受机组布置的影响,带钢经转向辊进出口活套后,当套量达到60%后就出现偏离生产线的情况,从而影响最终产品的质量及成材率,甚至损坏设备。针对某冷轧厂硅钢连续退火机组出口活套入口处带钢跑偏开展纠偏研究,利用Matlab对该纠偏系统进行动态仿真研究,分析系统的稳定性。 Silicon steel continuous annealing line is non oriented silicon steel production of finished product line.Due to the influence of unit layout,strip by roll Import & Export loop,when the set volume reached 60% after the emergence of deviation from the production line,thus affecting the quality of the final product and the rate of finished products,and even damage the equipment.For the export of continuous annealing line in cold rolling silicon steel strip deviation rectification loop at the e...