钢厂
无取向电工钢退火工艺研究现状
综述了退火温度、时间对无取向电工钢磁性的影响。退火温度主要影响无取向电工钢不同织构的占有率,退火时间主要影响晶粒尺寸的大小,晶粒尺寸的变化对织构的形成也有一定的影响。磁感最高点出现在纤维组织完全消失,(111)面织构组分较弱的组织状态。铁损的降低主要依赖于磁滞损耗的降低,织构的影响不大。 The effects of annealing temperature and time on the non-oriented electrical steel magnetic properties were reviewed.Annealing temperature and time mainly affects the different textures share and the grain sizes of non-oriented electrical steel respectively.Changes of the grain sizes also have a certain effect on textures formation.The highest point of the magnetic induction value in the fibrous tissue completely disappears and{111} plane texture has a lower state of the component content.Iron l...
取向硅钢中含铜抑制剂的固溶析出行为
含铜抑制剂作为取向硅钢的主抑制剂或辅助抑制剂不仅可以抑制初次晶粒的长大,促进二次再结晶,还可以降低铸坯的加热温度。取向硅钢中主要抑制剂为10~50 nm Cu2S,在钢的铸坯、热轧、冷轧、脱碳等工艺过程均可析出;(Cu,Mn)1.8S、Cu1.8S、ε-Cu等主要作为辅助抑制剂,尺寸一般为30~50 nm(或大于50 nm),主要在热轧阶段析出。总结了国内外有关取向硅钢中含铜抑制剂析出行为的研究进展,当前主要研究不同生产流程和工序中含铜抑制剂的析出行为和作用机理。 As main inhibitor or auxiliary inhibitor for grain-oriented silicon steel,the particles of inhibitor bearing copper not only inhibit the primary crystal growing and promote the secondary recrystallization,but also decrease the heat temperature of casting slab.The main inhibitor for grain-oriented silicon steel is 10~50 nm Cu2S,which precipitate in process and procedure including steel casting slab,hot rolling,cold rolling and decarburizing process,while the 30~50 nm or more than 50 nm...
制备{100}织构无取向电工钢方法综述
{100}织构因具有两个易磁化方向能够明显的提高磁性能,因此如何在表面获得具有{100}织构一直是无取向电工钢研究焦点。本文主要介绍了获得{100}织构的主要工艺方法及其基本原理,并结合实际生产过程对各工艺方法的优缺点进行了分析;一方面,优化无取向电工钢的成分,降低碳、锰元素含量以避免脱碳退火和真空退火,简化生产工艺;另一方面,调节升温速度、降温速度和退火气氛,使{100}晶面的表面能或弹性应变能最低,制备具有{100}织构柱状晶组织的无取向电工钢是今后的发展方向。 Because { 100} texture has two easy magnetization directions,which can significantly improve magnetization properfies,how to develop { 100} texture is a focus for researchers and manufactures. In the paper,main manufacturing processes and basic principle are introdued,and their advantages and disadvantages in practical production are analyzed. On the one hand,the production process can be simplified by optimizing chemical compositions,such as reducing the content of C and Mn,which can avoid deca...
水氯镁石制备硅钢级氧化镁
以水氯镁石为原料,采用氨法沉镁-煅烧-添加剂的方法制备硅钢级氧化镁。考察了反应温度、反应pH值、陈化时间对中间体氢氧化镁纯度及转化率的影响;研究了煅烧温度和煅烧时间对氧化镁水化率的影响及添加剂的量对氧化镁悬浮性能的影响。控制实验条件为:反应温度55℃,pH值为9.5,陈化时间2h,煅烧温度1050℃,煅烧时间2h,添加剂量为0.8%,制得氧化镁的纯度为98.99%、水化率为2.92%、悬浮性能为3mm/h,达到硅钢级氧化镁的要求。 Using bischofite as raw material,the preparation of magnesium oxide with silico-steel grade was studied.The effects of reaction temperature,reaction pH value and aging time on the intermediate magnesium hydroxide purity and conversion rate were studied.Calcinations temperature,calcinations time relationship to the hydration rate of MgO and amount of additive to the suspension performance of MgO were investigated.The results indicated that the optimum technological conditions were as follows:reac...
电工钢铸锭内析出相粒子特征及回溶行为
利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1~2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,...
无取向硅钢钢液增钛原因分析
对无取向硅钢炼钢全流程钢液增钛的原因进行了分析,认为铁水钛含量、转炉出钢温度、转炉下渣量、精炼渣TiO2含量、钢水罐及RH浸入管混钢种生产是影响钢液增钛的主要原因。通过采取低钛铁水冶炼,减少转炉下渣量,提高出钢温度,添加白灰改质精炼渣等措施,均能够降低钢液中的钛含量。 After analyzing the causes leading to increased content of titanium in molten nonoriented silicon steel during whole steelmaking process, it was concluded that such factors as content of titanium in hot metal, tapping temperature from converter, quantity of roughing slag entered into the ladle from converter, content of TiO2 in refining slag, molten steel ladle car,carrying out the steelmaking of different steel grades by the same ladle and same RH immersion tube were the main causes ...
高性能取向硅钢的工业化生产研究
采用光学显微镜、X射线衍射仪等分析了宁波钢铁有限公司生产的取向硅钢不同工序下的组织及织构演变规律。结果表明:铸坯经过热轧后,沿着厚度方向组织不均匀;一次冷轧并经脱碳退火后,组织由条状纤维状变成等轴状的初次再结晶晶粒,初次再结晶平均晶粒尺寸为18.17μm,织构主要以α织构和γ织构为主;在二次冷轧后,晶粒再次被压缩,转变为纤维状,织构主要为γ织构;经过高温退火后,发生二次再结晶,晶粒异常长大,晶粒尺寸达到厘米级,织构成分为单一且锋锐的Goss织构。 The microstructure and texture evolution of oriented silicon steel produced by Ningbo Iron and Steel Co.,Ltd.were analyzed by optical microscope and X-ray diffraction.The results showed that the microstructure of the slab was inhomogenous along the thickness direction after hot rolling.After first cold rolling and decarburizing annealing,the microstructure changed from strip fibrous to equiaxed primary recrystallized grains,and the average grain size of the primary recrystallization microstructu...
提高热轧硅钢凸度精度的工艺措施
以太钢热连轧厂的硅钢为研究对象,利用凸度仪测量热轧带钢出口凸度值,采用矩阵和失效模式的分析方法了解影响带钢凸度变化的主次因素。研究结果表明:通过有效控制轧制过程中的加热温度、时间及采用合理的辊型,硅钢凸度精度提高了4.34%左右。 In this paper,we take the hot-rolled silicon steelsheet of Taigang as the research symbol,exit profile was measured by convex instrument,the primary and secondary factors that affect the strip profile were measured by using matrix and failure mode analysis methed.The results indicate that convexity accuracy has significantly improved by nearly 4.34% through the effective control of the heating temperature,heating time and the use of correct roller type in the process of hot rolling.
无取向电工钢HW600高温变形抗力的研究
在Gleeble-3500热/力模拟试验机上对HW600钢进行高温压缩试验,研究在不同试验条件下的变形抗力。试验结果表明:变形温度对变形抗力的影响最为显著,在相同的变形速率下,随着变形温度的升高,变形抗力降低;在同一变形温度下,变形速率增大,变形抗力增加;在同一变形温度、变形速率下,随着变形程度的增加,变形抗力急剧增大,真应变达到0.1后,变形抗力增加趋势变缓。 The high-temperature compression test is done for HW600 steel with Gleeble-3500 thermal simulation testing machine to research its resistance to deformation under different test conditions.It is showed from result that deformation temperature has greatest effect on the resistance,and along with the temperature getting higher the resistance lowered under same deformation rate;the resistance increases along with deformation rate getting greater under same temperature;and under same deformation tem...
化学气相沉积法制备6.5%Si高硅钢的研究
采用化学气相沉积(CVD)渗硅处理工艺连续制备6.5%Si高硅钢,具有优质的软磁性能,通过理论研究化学反应并且用简单的试验设备做进一步的探讨。根据试验的结果对连续制备6.5%Si高硅钢的CVD工艺构造提出全面、有效的建议,实现制备6.5%Si高硅钢系统。 CVD method for continuously manufacturing 6.5%Si Steel Sheet has excellent soft magnetic.Carried out a theoretical study of related chemical reaction and performing basic research with a simple test apparatus.Based on the results,finally proposed an overall process configuration to realize such a production-CVD method for continuously manufacturing 6.5%Si Steel Sheet.
Cr对含Nb高强无取向硅钢组织、织构及性能的影响
高强无取向硅钢主要应用于高速电机,要求其具备高强度和优异磁性能,但目前无取向硅钢的磁性能和强度难以兼顾。因此,设计并制备了添加微量Cr的含Nb高强无取向硅钢,通过光学显微镜、EBSD、万能拉伸试验机、四探针测试仪和磁性能测量仪等研究了Cr对含Nb高强无取向硅钢微观组织、织构、力学性能及磁性能的影响。结果表明,添加质量分数为0.5%的Cr抑制了热轧组织的回复,使常化和退火组织再结晶减弱,常化和退火后有利织构面积分数增加,不利织构面积分数减小。添加质量分数为0.5%的Cr使含Nb无取向硅钢的屈服强度显著增大,磁感略升高,但对铁损几乎没有影响。Cr对屈服强度的影响一方面是由于Cr的固溶强化作用,另一方面Cr促进了Nb的析出而使Nb的析出强化效果增强;而Cr提高含Nb高强无取向硅钢的磁感主要是由于促进有利织构形成的同时抑制了不利织构的形成,使得织构因子增大;添加Cr使无取向硅钢的电阻率增加从而使铁损降低,同时Cr促进了Nb的析出,而这种富Nb析出相不仅抑制晶粒长大且会阻碍磁畴移动而使铁损增高,在两方面因素的综合作用下,添加质量分数为0.5%的Cr对含Nb高强无取向硅钢的铁损几乎没有影响。因此,... High strength non-oriented silicon steel is mainly used in high-speed motors, which requires good mechanical and magnetic properties. However, it is difficult for non-oriented silicon steel to obtain high strength and good magnetic properties at the same time. In this paper, the Cr-microalloyed Nb-containing high strength non-oriented silicon steel was designed and prepared. The effect of Cr on the microstructure, texture, mechanical properties and magnetic properties of Nb-containing high stren...

