硅钢资料

为了确保硅钢铬酸盐涂料的环保性,需要严格控制涂料的固化工艺,保证涂料固化过程中涂料中的六价铬充分转化为三价铬。对涂料及原料进行热重分析(TG)及差示扫描量热法分析(DSC)。结果表明,MgO与铬酐混合转化为MgCrO4,使六价铬稳定性增强,其中大部分Cr6+转变为Cr3+发生在620~700℃,在450~500℃高于铬酐发生大量失重,因此必须加入还原剂保证涂料中六价铬被充分还原;超过360℃后树脂会发生分解,因此实际板温不能超过360℃;加入了还原剂的整体涂料的失重温度区间主要在260~320℃,因此涂料固化时钢板的实际温度最佳区间为320~360℃。 Because of the silicon steel chromate coating’s environmental requirements,the paint curing process must be controlled strictly to ensure all Cr( Ⅵ) transforms to Cr( Ⅲ). The TG and DSC analyses of the paint are studied. The reaction of MgO and CrO3 would generate MgCrO4,enhancing the stability of Cr( Ⅵ). The most r( Ⅵ) in MgCrO4 changes to Cr( Ⅲ) at 620-700 ℃,while the CrO3 has a large weight loss at 450-500 ℃. The reductant must be added in the paint to make sure the Cr( Ⅵ) could transform suf... 

通过对35W300高牌号0.35 mm冷轧无取向电工钢卷(/%:0.002C、2.71Si、0.22Mn、0.015P、0.003S、0.0020N、0.55Als)头、中、尾组织、织构及对应的磁性能的试验研究,发现因热轧时12 MPa高压水连续冷却造成接触轧辊的钢卷头、中、尾在不同温度下轧制,卷取后钢卷头部处于卷心、温度略高而冷却速度略低于钢卷尾部,致使钢卷纵向组织、织构不同,成品卷头、尾各250 m内磁感逐渐增加,铁损逐渐降低,250 m外至钢卷中部磁性能稳定。通过将热轧辊的冷却方式改为周期冷却和卷取后的层流冷却改为钢卷70 m后开始冷却,至钢卷尾部70 m前停止冷却的方式使得钢卷纵向铁损差异明显减小,磁感差异略有改善。 According to the test research on structure and texture of head,meddle and end of 35W300 high grade 0.35 mm cold rolled non-oriented electrical steel strip coil(/%:0.002C,2.71Si,0.22Mn,0.015P,0.003S,0.002 0 N,0.55Als) and corresponding magnetic properties,It is found that due to 12 MPa high pressure water continuous cooling the roller in hot rolling process led to head,middle and tail of strip rolling at different temperature and after coiling the head of strip coil being in center of coil led t... 

研究了热轧卷取时间对无取向电工钢晶粒组织、织构演变、铁损和磁感的影响。结果表明,成品晶粒尺寸在120～140μm之间,随卷取时间的增加,成品晶粒尺寸增大。成品织构主要由γ纤维、а纤维和高斯织构等构成。随着保温时间的增加,{111}<110>和{112}<110>织构强度降低。随卷取时间的增加,成品P1.5降低。热轧板最佳的卷取工艺为550℃保温2～3 h,电工钢的综合磁性能优良。 The effects of hot-rolling coiling time on microstructure,texture,core loss and magnetic induction of a new cold-rolled non-oriented electrical steel containing copper were investigated.The test results showed that for final product the grain sizes are 120-140um,with the increase of coiling time,the grain size increase.For final product there are mainly γ-fibre,а-fibre,and {110}<001> texture,Coiling at 550℃ for hot rolled plate,the {111}<110>,{112}<110> texture was weaked with ... 

冷轧无取向硅钢是高技术含量、高附加值产品,工艺复杂,生产周期长,过程控制难度大,被誉为钢铁产品中的\"工艺品\"。热轧生产工艺又是无取向硅钢生产的重中之重,直接决定了硅钢的铁损和电磁性等多项指标。 Cold rolled non-oriented silicon steel is high technology content 、high added value product. Its process is complex, its production cycle is of length, and its process control is difficult, which is known as the iron and steel products \" Arts and crafts\". Hot rolling production process is the top priority of non-oriented silicon steel, which directly determines iron loss of the silicon steel and electromagnetic property,as well as other many index. 

通过测试取向硅钢不同工艺条件下的碳含量,探讨了CGO取向硅钢碳含量控制的最优处理条件,研究了脱碳温度和脱碳时间对相同初始碳含量取向硅钢的脱碳效果的影响。结果表明,在气氛为(15%~20%)H2+(75%~80%)N2,炉压差为10~20 Pa的条件下,CGO取向硅钢合适的脱碳温度为1 073 K~1 123 K,脱碳时间为10~20 min。在该处理条件下,能取得较好的脱碳效果。 By means of testing carbon content of oriented silicon steel below the distinct technical conditions,inquires the excellent handle terms of carbon content controlling for CGO oriented silicon steel,studies effects of decarburization annealing temperature and decarburization annealing time to the oriented silicon steel decarburization efficiency in same initial carbon content.The results show that,under the condition of atmosphere(15% ~ 20%) H2+(75% ~ 80%)N2 and furnace pressure difference 10 ~ 2... 

研究了硼酸对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响。用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同硼酸含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响,同时采用SEM对涂层的表面形貌进行了研究。结果表明,硼酸含量为9.7%时,涂层的耐盐雾性及电化学性能最好;硼酸含量过少或过多时,涂层的耐蚀性和电化学性能都较差。 Influence of boric acid on the performance of chromium-free non-oriented silicon steel insulating coating based on aluminum dihydrogen phosphate was investigated.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of boric acid content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.Surface morphologies of the coatings were tested by SEM.Result shows that when the boric ... 

本文中简要介绍了武汉钢铁有限公司采用薄板坯连铸连轧CSP(compact strip production, CSP)工艺生产中低牌号无取向硅钢的实践情况.CSP工艺生产的硅钢具有成品磁性均匀、板形好的优势，但是在利用该技术生产中低牌号无取向硅钢时，常存在成品板表面瓦楞状缺陷严重、连铸生产效率低等问题.通过优化炼钢成分、热轧等相关工艺，可消除热轧板厚度方向中心的粗大形变组织，从源头上避免了粗大{100}<011>纤维组织的出现，消除了瓦楞状缺陷；通过提升冶炼效率和控制钢中夹杂物总量，可优化隧道炉的加热温度与在炉时间，大幅度提升了连铸生产效率，实现了中低牌号无取向硅钢的批量稳定制造，使CSP产线成为中低牌号无取向硅钢热轧板原料的主要供给生产线.如何进一步提升钢水纯洁度、提高连铸生产效率、降低生产成本，以及挖掘该产线生产薄带钢的技术优点，是未来工作的重点. This paper briefly introduces the practice of producing medium and low grade non oriented silicon steel(NGO) with CSP(compact strip production, CSP)technology in Wuhan Iron and Steel Co., Ltd.. This technology has the inherent advantages of uniform magnetic properties and good shape for silicon steel finished strip. However, in the actual production process, there are serious corrugated defects on the surface of silicon steel finished strip, and production efficiency of continuous casting is low... 

采用自主研发的脉冲磁场退火装置，在取向硅钢脱碳退火过程中分别施加不同强度的磁场，并采用光学显微镜和X射线衍射仪研究了脉冲磁场脱碳退火后试样的显微组织和宏观织构。结果表明，脱碳退火过程中施加脉冲磁场后取向硅钢的平均晶粒尺寸均增加，当磁场强度为40 mT时，平均晶粒尺寸最大，为13.06μm。此外，取向硅钢试样的立方织构{001}<100>强度减弱，高斯织构{110}<001>和{111}<112>织构增强，有利于获得更好的成品织构和磁性能。 Self-developed pulsed magnetic field annealing device was used to apply magnetic field of different intensities during decarburization annealing of an oriented silicon steel, and microstructure and macro-texture of the specimens after decarburization annealing in a pulsed magnetic field were studied by using optical microscope and X-ray diffractometer. The results show that the average grain size of the oriented silicon steel increases with the application of pulsed magnetic field during decarbu... 

【作者】 彭志华； ...

研究稀土Ce的添加对含Sn高磁感无取向电工钢磁性能及夹杂物的影响。对比分析了两种成分钢的磁性能以及各过程工艺条件下夹杂物种类和分布情况。结果表明,在含Sn高磁感无取向电工钢中加入稀土元素Ce可以粗化夹杂物,提高成品晶粒的均匀性,有效降低铁损;同时Ce的添加不影响Sn元素提高磁感的效果,磁感保持不变。 Effect of Ce on magnetic properties and inclusion of Sn-bearing high permeability non-oriented electrical steel was investigated. A comparative analysis of the magnetic properties and the types and distributions of inclusion in the two sheets with different composition shows that the addition of Ce to the Sn-bearing high permeability non-oriented electrical steel can coarse the inclusion,improve the homogeneity of the finished grain and effectively decrease the core loss. Also,the addition of Ce... 

主要对硅钢退火炉耐材施工进行阐述,对一期工程与二期工程施工经验进行总结,包括设计、施工、耐材生产、人员素质等方面,指出了工程项目所所存在的不足,为同类型炉窑的施工提供借鉴。 This paper describes the construction of silicon steel annealing furnace refractories;and it was summarized the construction experience of phase-Ⅰ and phase-Ⅱ projects,including design,construction,refractory production,the quality of personnel etc,and pointed out the shortcomings of the project,which provided a reference for the construction of the same type of furnaces. 

研究了常化温度、常化时间及常化后冷却速度对Si的质量分数为1.6%的无取向电工钢成品磁性能的影响。结果表明:在850~1 050℃范围内,随着常化温度的升高,成品铁损先减小后增大,成品磁感应强度先增大后减小;当常化温度为1 000℃时,成品平均铁损最低,平均磁感应强度最高;常化时间从3min延长到7min时,成品铁损先减小后增大,成品磁感应强度则呈单调下降趋势;随着常化冷却速度的降低,成品铁损先减小后增大,成品磁感应强度则呈单调增大趋势;对于Si的质量分数为1.6%的无取向电工钢,最佳的常化制度为:在1 000℃进行常化,时间5min,常化后空冷。对热轧板进行常化后,热轧板发生了不同程度的再结晶和晶粒长大。提高常化温度、延长常化时间、降低冷却速度,都能使常化板晶粒粗化,进而粗化成品板晶粒,改善磁性能。通过扫描电镜观察发现,成品板中析出物主要为AlN和MnS的复合析出物,以及少量的单独析出的AlN和MnS,而常化工艺主要是通过粗化析出相,减少细小析出相数量,从而减少对晶界钉扎作用来改善成品磁性能。 The effects of normalizing temperature,normalizing time and cooling rate after normalizing on magnetic properties of non-oriented electrical steel with mass fraction of Si of 1.6% were investigated.The results show that core loss of product decreases first and then increases,while magnetic induction increases first and then decreases with the increase of normalizing temperature from 850 to 1 050℃.Average core loss of product is the lowest and average magnetic induction is the highest when normal...