硅钢资料

结合工业化生产的无取向硅钢,进行了RH精炼喂CaSi线去除钢中的非金属夹杂物试验研究。针对不同的钙处理条件,分析了CaS夹杂生成热力学,观察了夹杂物的形貌和尺寸分布,确定了夹杂物的类型、数量,探讨了钙处理后钢中夹杂物的变化规律。结果表明,本试验条件下,钙处理可以有效抑制MnS、AlN夹杂物的生成,有效促进钢中微细夹杂物的聚合、上浮、去除,钢质纯净度明显提高。经过合适的钙处理后,钢中的夹杂物以独立存在的CaO为主,同时有少量含CaO、SiO2、MgO的复合夹杂,没有发现CaS夹杂存在。这部分夹杂物的尺寸集中分布在2～20μm,数量约为1.8×105个/mm3。 Experimental study on removal of non-metallic inclusions in non-oriented silicon steel obtained from industrial production by CaSi wire feeding during RH refining process was carried out.The thermodynamics of CaS inclusion formation was analyzed,the morphology and the size distribution of inclusions were observed,and the numbers and types of inclusions were also determined for the steel specimens treated under different calcium treatment conditions.Furthermore,the variation of inclusion characte... 

利用OM、TEM与EDS技术,对Fe-3.2%Si低温取向硅钢热轧板进行不同常化冷却工艺处理后的显微组织、析出相及最终产品的磁性能进行分析,并与热轧板的组织和析出相进行对比。结果表明,常化板较热轧板的表层组织均匀,基体中再结晶比例增加,带状组织变窄;常化板中析出物的数量明显比热轧板的多,析出物主要有AlN、MnS及复合析出的(Cu,Mn)S等。在常化温度1120℃、保温3 min的条件下,采用二段式冷却较空冷、淬沸水、淬常温水的冷却工艺,常化板表层显微组织更均匀,沿板厚方向的显微组织的不均匀性显著,取向硅钢的磁性能最高;常化后采用二段式冷却工艺析出的细小析出物数量最多,且弥散分布在基体中,抑制剂的抑制效果最好,对成品获得高磁性最有利。 Microstructure, precipitate and magnetic characteristic of final products with different normalizing cooling processes for Fe-3.2%Si low-temperature hot-rolled grain-oriented silicon steel were analyzed and compared with the hot-rolled plate by optical microscopy(OM), transmission electron microscopy(TEM), and energy dispersive spectrometry(EDS). The results show that, the surface microstructure is uniform, the proportion of recrystallization in matrix increases, and the banding textures are nar... 

【作者】 康凌晨； 王丽娜； ...

取向硅钢热轧板中组织、织构梯度对发展完善的二次再结晶十分关键,通过对2种不同热轧工艺生产取向硅钢的组织、织构进行研究,结果表明:采用后道次大压下热轧工艺时热轧板表层再结区晶粒平均尺寸增加,再结晶区厚度增加,高温退火后二次晶粒尺寸减小;采用后道次大压下热轧工艺热轧时,热轧板中平均等效应变高,热轧板厚度心部{100}〈011〉和{100}〈001〉位向取向强度降低,({111}～{113})〈110〉位向取向强度提高,高温退火后{110}〈001〉位向偏离角降低,磁性能提高。 The texture and microstructure gradient in hot rolled grain oriented silicon steel strip was one of the essential factors to achieve a perfect secondary recrystallization.The texture and microstructure of grain oriented silicon steel strip as-rolled with two different hot rolling parameters was investigated.The results show that with big reduction at the end rolling process,the intensity of {100}〈011〉 and {100}〈001〉 orientation reduces with({111}-{113})〈110〉 orientation intensity enhanced in hot... 

利用场发射扫描电镜观察了以MnS为主要抑制剂的普通取向电工钢加工过程中第二相粒子的分布状态,统计了粒子面密度、平均尺寸以及相应的尺寸分布.结果显示,热轧加工造成了大量第二相粒子弥散、细小地析出,同时基体仍保持过饱和状态.冷轧变形会造成第二相粒子的回溶行为,而基体的过饱和状态会减弱回溶现象.中间退火与脱碳退火过程中会同时存在新粒子的形核及已析出粒子的粗化两个过程,而在最终二次再结晶升温阶段则以第二相粒子明显粗化为主. The distribution of second phase particles in conventional grain-oriented electrical steels during manufacturing processes with MnS as inhibitors was observed by field emission scanning electron microscopy,while the areal particle density,the average particle size and the corresponding size distribution were statistically determined.It is indicated that hot rolling leads to dispersive precipitation of a large amount of fine second phase particles and the matrix keeps a supersaturated state furth... 

硅钢是钢铁产品中的\"工艺品\",是高附加值产品,通过对我国主要硅钢生产厂家的工艺设备,市场情况分析,简要介绍了我国硅钢生产消费现状,未来生产能力预测及硅钢未来发展趋势。 Silicon steel is the \"crafts\" of steel products,also is high value-added product.By analyzing process equipment and market condition of major silicon steel-making plant of China,it briefly introduces our current production consumption status,future production capacity prediction and future development trend of silicon steel. 

本文研究了丙烯酸树脂含量对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同树脂含量对硅钢绝缘涂层的耐盐雾性能和电化学行为的影响,同时采用SEM对涂层的表面形貌和附着性进行研究.结果表明,树脂含量为19.9~29.4%时,涂层的耐蚀性和附着性最好;树脂含量过多时,涂层的耐蚀性和附着性均较差. This paper studies the influence of acrylic resin on the performance of insulating coating of aluminum dihydrogen phosphate on chromium-free non-oriented silicon steel.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of acrylic resin content on the salt spray resistance and electrochemical behavior of the insulation coating of nonoriented silicon steel.The surface morphologys and adhesion of coating were tested by SEM.... 

{100}织构因具有两个易磁化方向能够明显的提高磁性能,因此如何在表面获得具有{100}织构一直是无取向电工钢研究焦点。本文主要介绍了获得{100}织构的主要工艺方法及其基本原理,并结合实际生产过程对各工艺方法的优缺点进行了分析;一方面,优化无取向电工钢的成分,降低碳、锰元素含量以避免脱碳退火和真空退火,简化生产工艺;另一方面,调节升温速度、降温速度和退火气氛,使{100}晶面的表面能或弹性应变能最低,制备具有{100}织构柱状晶组织的无取向电工钢是今后的发展方向。 Because { 100} texture has two easy magnetization directions,which can significantly improve magnetization properfies,how to develop { 100} texture is a focus for researchers and manufactures. In the paper,main manufacturing processes and basic principle are introdued,and their advantages and disadvantages in practical production are analyzed. On the one hand,the production process can be simplified by optimizing chemical compositions,such as reducing the content of C and Mn,which can avoid deca... 

针对攀钢高硫铁水冶炼现状,结合不同生产工艺路线,论述了攀钢近年来为实现低硫电工钢的生产,在铁水预处理、转炉冶炼、钢水精炼过程中硫控制技术的开发与应用,形成了低硫洁净钢生产工艺技术,实现了低硫电工钢的生产。低硫电工钢RH脱硫率可达到20%左右,成品[S]控制在0.006%左右。 According to the smelting situations of hot metal with high sulphur content at Panzhihua Steel,combined with different produce processes,technologies for controlling the sulfur content during hot metal pretreatment,converter smelting,and second refining are developed. Technologies in low-sulfur clean steelmaking are formed. Low-sulfur electric steel are produced. As for the desulfurization rate of lowsulfur electric steel can reach about 20%,and the content of [S] in products is controlled to ab... 

研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%～100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters... 

【作者】 刘彤； ...

对取向硅钢熔融态钢液进行处理,对比研究了不同脉冲参数的作用效果。结果表明,电脉冲对钢锭晶粒组织具有明显的细化作用,凝固组织等轴晶比例大幅上升。在脉冲电容、频率、处理时间和电压中,影响等轴晶比例的最显著性因素为脉冲频率;最优正交实验参数为:电容1 200μF,脉冲频率1 Hz,处理时间5 s,脉冲电压800 V;随着输入能量的增大,等轴晶率先增大后减小,脉冲输入能量为某值时,等轴晶率最大,通过经典形核理论和热力学对这一现象进行了解释。 Research on the influence of the electric pulse on the solidification structure of oriented silicon steel was preformed.Electric pulses in different parameters were applied to molten steel and results were compared.The result shows that solidification structure of oriented silicon steel can be improved by the electric pulse,and the equiaxed crystal ratio increases obviously.Among the four parameter factors of electric capacity,frequency,applied time and voltage,the most effective factor is frequ...