硅钢资料

采用中、厚板坯生产技术对取向硅钢进行了研制和开发,对热轧及后工序样品进行了金相组织观察和EBSD分析,探讨了两种组织及织构的差异性,研究结果表明:除高温退火样品外,中板坯生产的取向硅钢各工序样品平均晶粒尺寸大;厚板坯生产的取向硅钢热轧和常化样品亚表层Goss织构强;中板坯和厚板坯的脱碳退火板织构没有明显区别。中板坯生产的取向硅钢成本低,产品磁性能和质量与厚板坯相当。 Grain oriented silicon steel was researched and developed by medium thickness slab and thick slab.Microstructures observation and EBSD analysis to the samples of hot rolling and following processes were carried out,respectively.The differences between the two kinds of microstructures and textures were discussed.The results show that the average grain sizes of every process samples are larger except that of high temperature annealing samples of grain oriented silicon steel produced by medium thic... 

【作者】 侯桂芹； 张颖； ...

针对新能源汽车的发展，制备了含Ni固溶强化、含Cu析出强化以及含Ni+Cu复合强化3%Si无取向硅钢，研究了强化方式对无取向硅钢组织、织构和性能的影响。结果表明：固溶强化型无取向硅钢热轧板中形成了粗大{221}<221>晶粒，冷轧过程中剪切变形明显并在退火后形成良好再结晶织构。析出强化型无取向硅钢热轧板中心层形成γ取向粗大晶粒，在后续的加工中γ织构逐渐增强并最终得到相对细小的再结晶晶粒。复合强化型无取向硅钢热轧板中保留了强λ取向带状组织，退火后形成了有益的Goss织构和λ织构。固溶强化型与复合强化型无取向硅钢磁感应强度B₅₀分别达到1.742、1.688 T,高于析出强化型无取向硅钢的1.645 T。同时，复合强化型无取向硅钢高频铁损最低，其P_1.0/400和P_{1.0/1 000}分别低至20.97、82.69 W/kg,这与其较小的晶粒尺寸和织构改善有关。强度计算结果表明：Ni元素固溶强化对强度的提高有限，屈服强度为468 MPa,纳米Cu析出可显著提高屈服强度（强度增量约200 MPa）,且主要来自于模量强... For the development of new energy vehicles, 3%Si non-oriented silicon steel were processed by solid solution strengthening with Ni, precipitation strengthening with Cu, and composite strengthening with Ni and Cu. The effects of different strengthening methods on the microstructure, texture and properties of high-strength non oriented silicon steel were studied.The results show that coarse {221}<221> grains are formed in the hot rolled sheet of solution strengthened non-oriented silicon ste... 

以青海盐湖氯化镁为初级原料,采用喷雾热解法制备原料氧化镁。原料氧化镁通过水化制备氢氧化镁。将氢氧化镁过滤、洗涤、烘干、粉碎、煅烧,制备硅钢级氧化镁。本文重点考察煅烧温度、煅烧时间、料层厚度等因素对氧化镁水化率的影响,采用均匀实验设计和DPS数据处理,确定最优煅烧实验条件为:煅烧温度1250℃,煅烧保温时间4小时,料层厚度0.5cm。在此条件下得到的硅钢级氧化镁完全满足硅钢及氧化镁的行业标准。 The magnesium oxide is prepared by Spray pyrolysis process,which magnesium chloride from Qinghai Salt Lake is used as primary raw material,and hydrated to magnesium hydroxide,then obtained silicon steel magnesia through filtering,washing,drying,crushing and calcinations.In this paper,influences of some factors on magnesia hydration rate are studied,such as calcination temperature,calcination time and material thickness.After average experimental design and DPS data processing,optimal calcination... 

无取向硅钢特别是中牌号以上的无取向硅钢,随着含硅量的提高,常温下塑性较差,冷轧过程中轧制力明显提高,如果存在原料质量问题,极易发生断带事故,影响硅钢冷轧过程的成材率和生产效率。通过优化冷轧工艺参数,可提高冷轧稳定性。生产中通过合理分配冷轧各道次压下量和轧制速度,保证了轧制过程的稳定,很大程度减少了冷轧断带事故的发生。 Non-oriented silicon steel, especially in the low and middle grade, with the increase of silicon content, plasticity is poor at room temperature, rolling force in cold rolling process significantly improved .If there is the quality defect of raw materials , easily sheet is rolling off. Affect finished product rate and production efficiency in process of cold-rolled silicon steel. Through optimization of cold rolled process parameter , improve the stability of cold-rolling process. Through reason... 

采用光学显微镜和X射线衍射仪研究了常化退火处理对无取向硅钢热轧板和成品退火板显微组织和织构的影响。结果表明:常化退火处理消除了热轧板中的变形组织,促使变形晶粒完成再结晶;常化退火处理使高斯织构和立方织构易通过再结晶在变形带内形核和长大,可显著降低成品退火板的{111}和{112}不利织构组分的占有率,提高{100}和{110}有利织构组分的占有率,从而有利于提高无取向硅钢成品板的磁性能。 The effect of normalizing annealing treatment on microstructure and texture of non-oriented silicon steel hot rolled plates and final products were investigated by means of optical microscope and X-ray diffractometer analysis.The results show that the deformed microstructure of the hot rolled plates transformed into recrystallized grain after normalizing annealing treatment.The grains of Goss texture and cubic texture crystallographic orientation were formed and grown by recrystallization in the... 

取向硅钢热轧板中织构梯度对发展完善的二次再结晶十分关键,通过添加铜可以显著降低取向硅钢板坯加热温度,从而影响热轧板织构分布。利用X射线衍射仪,分析了实验室模拟薄板坯连铸连轧(TSCR)工艺的3种不同铜含量的取向硅钢热轧板织构。结果表明:不同铜含量热轧板表面到厚度1/4处均为弱的热轧织构,热轧板心部主要为{100}面织构;铜含量约在0.4%时,热轧板次表层的{110}<001>织构比例最高,而热轧板心部的{100}<110>织构比例最低;铜含量对热轧织构中{114}<110>和{001}<100>织构发展有显著影响。 The texture gradient in hot rolled grain oriented silicon steel strip is one of the essential factors to achieve a perfect secondary recrystallization.The addition of copper can significantly reduce the slab reheating temperature of grain oriented silicon steel,so as to impact the texture distribution in the hot rolled strip.The texture of hot rolled grain oriented silicon steel strip as-rolled by thin slab casting and rolling process(TSCR) in laboratory with three different copper contents was ... 

近年来，在节能减排背景之下，国内外众多研究者对无取向电工钢磁性能的提升做了大量研究。为了探索无取向电工钢磁性能提升的方法，对锡或锑对无取向电工钢磁性能的作用机制(晶粒尺寸和晶体织构的控制)进行分析。基于该作用机制，介绍锡或锑的添加对无取向电工钢磁性能的影响。经研究发现，适量的锡或锑在晶界偏聚，不会阻碍晶界的移动并且致使晶粒尺寸降低；与此同时，锡或锑在晶界偏聚不仅抑制{111}织构在原始晶界处形核及生长，还降低(100)晶粒表面能，促进(100)晶粒生长。因此，适量添加锡或锑，可使无取向电工钢铁损下降、磁感提升。最后结合生产工艺，建议无取向电工钢的研究方向应为稀土含量对高牌号无取向硅钢夹杂物尺寸和数量分布的影响，锡或锑的添加量和常化工艺参数(常化时间、常化温度)对常化晶粒尺寸的影响。 In recent years, due to the background of energy saving and emission reduction, numerous researchers all around the world have done a lot of investigations on the improvement of magnetic properties for non-oriented electrical steel. In order to explore the method of improving the magnetic properties of non-oriented electrical steel, the mechanism of tin or antimony on the magnetic properties(the control of grain size and crystallographic texture) of non-oriented electrical steel is illuminated. ... 

无氧化炉具有加热效率高、投资与运营成本低、作业率高、表面质量及板型良好、NOx排放相对低等优势,在硅钢热处理领域应用前景广泛。本文阐述了确定无氧化炉(NOF)加热能力详细过程,涵盖炉温、炉断面尺寸、炉长、热平衡结算、加热能力计算等,为今后无氧化炉(NOF)在硅钢热处理应用时的设计提供了借鉴,同时也为今后明火直接加热的工业炉设计提供了参考。 Non-oxidation furnace has the advantage s of high heating efficiency, low investment and operation cost, high operation rate, good surface quality and plate shape, and relatively low NOxemission,and it still has wide application prospect in the field of silicon steel heat treatment. The detailed process of determining the heating capacity of a non-oxidizing furnace(NOF) is described, covering furnace temperature, furnace section size, furnace length, heat balance settlement, heating capacity cal... 

热轧轧制工艺对产品性能和轧制稳定性影响很大,对中低牌号无取向电工钢,当在两相区轧制时,热轧塑性明显降低,板形变坏,易出现边裂等情况。以50W1000为例,通过对其变形抗力进行研究,得出把两相区控制在F4与F5之间为最佳轧制工艺的结论。在此基础上制定了一套较为合理的热轧工艺制度。采用新的轧制工艺后,50W1000热轧精轧的稳定性明显改善,热轧产品合格率由开发初期的40%左右提高到95%以上。 The hot rolling process has great influence on product′s performance and rolling stability.For the low medium grade non-oriented electrical steel,when non-oriented electrical steel is rolled in tow phase region,the hot rolling plasticity reduces obviously,the shape of strip goes bad and easily to crack at the edge.The deformation resistance of 50W1000 steel was investigated.The results show that the optimal rolling process is to control the two phase region between F4 and F5.Based on the results... 

结合冶炼无取向硅钢的生产实际,对钢中硫的来源,以及炉渣性质、钢水温度、底吹强度对脱硫的影响进行了分析。研究表明,转炉钢中硫的主要来源为铁水、废钢、铁水渣及石灰带入;冶炼硅钢时,终渣碱度为3.0~3.5,w((FeO))≤20%,终点钢水温度大于等于1 680℃,加大底吹搅拌强度能提高转炉脱硫效果。硅钢平均出钢硫的质量分数为0.004 8%,能满足无取向硅钢对硫含量的要求。 With the actual production of non-oriented silicon steel,the source of sulphur and the effect of metallugic parameters like slag properties,temperature of molten steel and bottom stirring on desulphurizing ability were investigated.The results show that the main source of sulphur is molten metal,scrap,the remaining slag volume in hot metal and lime.The degree of desulphurization for smelting silicon steel can be increased through adopting the following measures,such as the basicity of finishing ... 

研究了硼酸对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响。用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同硼酸含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响,同时采用SEM对涂层的表面形貌进行了研究。结果表明,硼酸含量为9.7%时,涂层的耐盐雾性及电化学性能最好;硼酸含量过少或过多时,涂层的耐蚀性和电化学性能都较差。 Influence of boric acid on the performance of chromium-free non-oriented silicon steel insulating coating based on aluminum dihydrogen phosphate was investigated.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of boric acid content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.Surface morphologies of the coatings were tested by SEM.Result shows that when the boric ...