钢厂
碳化法制备硅钢氧化镁过程中杂质脱除研究
以轻烧氧化镁粉为原料,经消化、碳化制得重镁水,在热解反应前采用络合剂对重镁水中的杂质钙、铁进行络合掩蔽,再经热解得到碱式碳酸镁,碱式碳酸镁经煅烧可制得钙、铁杂质含量较低的氧化镁。在重镁水络合除杂过程中,考察了络合剂三乙醇胺、柠檬酸、草酸单独和复合使用的除铁、除钙效果。以三乙醇胺为络合剂时,在200 mL重镁水中加10 mL三乙醇胺(1∶1),氧化镁产品中w(氧化镁)=99.3%、w(氧化钙)=0.31%、w(氧化铁)=0.042%;使用草酸和柠檬酸作为复合络合剂时,在200 mL重镁水中加入1.0 g柠檬酸和2.0 g草酸,氧化镁产品中w(氧化镁)=98.2%、w(氧化钙)=0.24%、w(氧化铁)=0.030%。 Light-burned magnesia as a raw material was hydrated and carbonated to obtain magnesium bicarbonate liquor.Before the pyrolyzing of magnesium bicarbonate liquor,complexants were used to cover Fe and Ca impurities.Then the treated liquid was pyrolyzed to obtain basic magnesium carbonate which was calcined to magnesium oxide with low calcium and iron content.During the complexing purification of magnesium bicarbonate liquor,the Fe and Ca removing effects of single or compound complexing agents,suc...
热轧卷取时间对新型冷轧无取向电工钢组织和性能的影响
研究了热轧卷取时间对无取向电工钢晶粒组织、织构演变、铁损和磁感的影响。结果表明,成品晶粒尺寸在120~140μm之间,随卷取时间的增加,成品晶粒尺寸增大。成品织构主要由γ纤维、а纤维和高斯织构等构成。随着保温时间的增加,{111}<110>和{112}<110>织构强度降低。随卷取时间的增加,成品P1.5降低。热轧板最佳的卷取工艺为550℃保温2~3 h,电工钢的综合磁性能优良。 The effects of hot-rolling coiling time on microstructure,texture,core loss and magnetic induction of a new cold-rolled non-oriented electrical steel containing copper were investigated.The test results showed that for final product the grain sizes are 120-140um,with the increase of coiling time,the grain size increase.For final product there are mainly γ-fibre,а-fibre,and {110}<001> texture,Coiling at 550℃ for hot rolled plate,the {111}<110>,{112}<110> texture was weaked with ...
CN202110176053.9一种常化后免酸洗生产取向硅钢的方法
本发明涉及一种常化后免酸洗生产取向硅钢的方法,取向硅钢的生产工艺路线为:冶炼→连铸→热轧→常化退火→拉伸矫直→抛丸→冷轧→脱碳退火→渗氮→涂MgO→高温退火→热拉伸平整及涂绝缘膜;本发明在常化退火后通过物理方法去除带钢表面的氧化铁皮,且效率高、效果好、操作简单、易于控制;与常规工艺相比,省去了酸洗及后续废酸处理工作,排除了酸雾对环境的污染,消除了取向硅钢带因酸洗而产生的潜在缺陷,产品质量更加稳定可靠。
硅钢连续退火炉无氧化加热段辐射换热研究
以能量平衡和辐射换热理论为基础,通过合理假定,建立了硅钢无氧化加热炉数学模型。采用数值计算的方法,通过自编程序,完成对带钢加热过程温度场的仿真。结果显示:数学模型能够反映带钢在无氧化炉内的加热过程,其升温曲线能够与工艺曲线相吻合;现行炉温分布并非最优,数学模型能够为炉温分布的优化、炉段的设计提供理论依据。 Mathematical model of NOF Section of Continuous Annealing Furnace is established based on energy balance and radiation heat exchange. The temperature field of steel is simulated by mathematical computation. The simulating results show that the mathematical model can reflect the heating process of silicon steel in NOF section, and the heat-up curve is coincide with the processing curve. From the results,it is known that the current furnace temperature gradient is not the best, and the mathematica...
CN202111440570.9一种超高效变频空调压缩机用无取向硅钢薄带及其制造方法
本发明公开了一种超高效变频空调压缩机用无取向硅钢薄带及其制造方法,属于无取向硅钢技术领域。本发明包括以下重量百分比的组分:C≤0.003%,Si:2.0%~2.5%,Mn:0.15%~0.5%,Als:0.3%~0.7%,Sn:0.05%~0.11%,S≤0.003%,P≤0.03%,B:0.002%~0.004%,Ca:0.003%~0.005%,N≤0.003%,Ti≤0.003%,其余为Fe及不可避免的杂质,且Mn/S比控制在20~60范围内,B/N比控制在0.7~1.5,Ca/S的比例≥1。为解决现有技术中存在的问题,本发明通过添加合金元素以及偏析元素,配合连铸、热轧、常化和连续退火等热处理工艺,以及优良的冷轧板形控制技术,实现0.30~0.35mm厚度薄规格的高效无取向硅钢产品,具备优异的磁性能和高屈强比的力学性能,满足高效变频空调压缩机电机磁性能和关节式定子高速冲裁对力学性能和板形的高标准要求。
取向硅钢超大高斯晶粒取向偏离角的X射线衍射测量
介绍了一种适用于超大晶粒取向硅钢的高斯晶粒取向偏离角的X射线衍射测量方法,提出了将试探法和探测器扫描法相结合的方式进行测量。结果表明:该方法可以同时获得准确的实际衍射角度和取向偏离角度,试样制备方式简单,对设备的要求低且测量结果准确。 This paper introduces a X-ray diffraction measurement method of Gaussian grain orientation deviation angle for ultra-large grain oriented silicon steel, and puts forward a method of combining the test method with the detector scanning. The results show that this method can obtain accurate actual diffraction angle and orientation deviation angle at the same time. The sample preparation method is simple, the requirements for equipment are low, and the measurement results are accurate.
退火温度对3.1%Si无取向硅钢组织织构与磁性能的影响
研究了退火温度对3.1%Si无取向硅钢组织和磁性能的影响规律。结果表明:退火温度从940℃提高至1 000℃,平均晶粒尺寸由98μm增加到145μm,铁损P1.5/50从2.576 W/kg降低至2.408W/kg。随着退火温度的升高,γ不利织构组分强度逐渐降低,{111}〈112〉织构组分强度降低约16%,磁感B50逐渐升高,磁性能水平提高。 The effects of annealing temperature on microstructure and texture and magnetic properties of 3.1%Si non-oriented silicon steel were investigated in this paper.The results showed that,when the annealing temperature increased from 940℃ to 1 000℃,the average grain size of metallographic structure increased from 98μm to 145μm,the iron loss value P1.5/50 decreased from2.576 W/kg to 2.408 W/kg.And as the annealing temperature increased,the strength of the unfavorable texture componentγgrad...
CN202180018973.6电磁钢板的加工方法、马达以及马达铁芯的制造方法
本发明相对于板厚较薄的电磁钢板提供不会导致磁特性劣化的基于激光的加工方法。在对电磁钢板进行使用激光的熔断并将该电磁钢板加工成规定的形状的电磁钢板的加工方法中,使上述激光的扫描速度成为10000mm/min以上来进行上述熔断。
CN202111279129.7一种硅钢片自动切片设备
本发明涉及硅钢片切片领域,具体涉及一种硅钢片自动切片设备,包括下拉机构、推料机构、硅钢片输送机构、硅钢片推动机构、压片机构、导料壳、两个斜切机构、连接机构和三角切边机构,该硅钢片自动切片设备,通过移动连接机构,使得该设备能够进行两种硅钢片的切割加工,使得该设备能够满足多种硅钢片的加工,通过在移动三角切边机构和斜切机构的位置,使得该设备能够加工出各种硅钢片,且能够单一旋转加工那种硅钢片,并且一次加工出两张硅钢片,通过硅钢片输送机构带动推料机构进行同时运动,避免两个硅钢片之间叠起,当原料与推料机构的端部接触时,由于推料机构的拉动速度比硅钢片推动机构的速度快,避免原料上发生褶皱而影响切割的位置。
高牌号无取向硅钢CSP流程铸坯及热轧板的组织和夹杂物分析
2.9 mm热轧3%Si高牌号无取向硅钢板(/%:0.004 6C、3.04Si、0.32Mn、0.49Als、0.004S、0.013P、0.0042N)由CSP(Compact Strip Production紧凑式带材生产线)流程:120 t BOF-70 mm CC-热轧工艺生产。热轧终轧温度872℃,卷取温度683℃。铸坯及热轧板的组织和夹杂物的分析结果表明,铸坯组织为典型的贯穿柱状晶组织;热轧板边部为再结晶组织,中部为纤维组织带有少量再结晶晶粒;高牌号无取向硅钢的主要夹杂物为铸坯-Al2O3,AlN和Cu2S+MnS;热轧板-Al2O3,AlN,AIN+MnS和Cu2S+MnS。 The 2.9 mm hot rolled 3%Si high grade non-oriented silicon steel plate(/%:0.004 6C,3.04Si, 0.32Mn,0.49Als,0.004S,0.013P,0.004 2N) is produced by CSP(Compact Strip Production) flow sheet i.e.120 t BOF-70 mm CC-hot rolling process with end rolling at 872℃and coiling at 683℃.The analysis results on structure and inclusions in casting slab and hot rolled plate show that the structure of slab is typical trans-columnar crystal,the structure of hot rolled plate at edge is recrystallized grain and in ce...
电工钢铸锭内析出相粒子特征及回溶行为
利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1~2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,...
CN202111273676.4一种新能源汽车驱动电机用低铁损高强度无取向电工钢及其制造方法
本发明公开了一种新能源汽车驱动电机用低铁损高强度无取向电工钢及其制造方法,所述无取向电工钢的化学成分及重量百分比包括C:0.001‑0.005%、Si:2.4‑3.0%、Mn:0.25‑0.5%、Al:0.70‑1.10%、P:≤0.02%、S:≤0.005%、0.015%≤Ce+Sn≤0.035%,余量为铁和不可避免的杂质,本发明通过加入Ce和Sn,净化钢质、微合金化提高无取向电工钢强度和磁性能,不需要添加固溶金属元素,且避免了高Si体系下的轧制困难问题,且不需要高温退火,解决了退火温度过高使晶粒异常长大,晶粒尺寸均匀性降低的问题,生产出的无取向电工钢具有较高强度的同时,还具有优良的磁性能。

