硅钢资料

采用自主研发的脉冲磁场退火装置，在取向硅钢脱碳退火过程中分别施加不同强度的磁场，并采用光学显微镜和X射线衍射仪研究了脉冲磁场脱碳退火后试样的显微组织和宏观织构。结果表明，脱碳退火过程中施加脉冲磁场后取向硅钢的平均晶粒尺寸均增加，当磁场强度为40 mT时，平均晶粒尺寸最大，为13.06μm。此外，取向硅钢试样的立方织构{001}<100>强度减弱，高斯织构{110}<001>和{111}<112>织构增强，有利于获得更好的成品织构和磁性能。 Self-developed pulsed magnetic field annealing device was used to apply magnetic field of different intensities during decarburization annealing of an oriented silicon steel, and microstructure and macro-texture of the specimens after decarburization annealing in a pulsed magnetic field were studied by using optical microscope and X-ray diffractometer. The results show that the average grain size of the oriented silicon steel increases with the application of pulsed magnetic field during decarbu... 

研究稀土Ce的添加对含Sn高磁感无取向电工钢磁性能及夹杂物的影响。对比分析了两种成分钢的磁性能以及各过程工艺条件下夹杂物种类和分布情况。结果表明,在含Sn高磁感无取向电工钢中加入稀土元素Ce可以粗化夹杂物,提高成品晶粒的均匀性,有效降低铁损;同时Ce的添加不影响Sn元素提高磁感的效果,磁感保持不变。 Effect of Ce on magnetic properties and inclusion of Sn-bearing high permeability non-oriented electrical steel was investigated. A comparative analysis of the magnetic properties and the types and distributions of inclusion in the two sheets with different composition shows that the addition of Ce to the Sn-bearing high permeability non-oriented electrical steel can coarse the inclusion,improve the homogeneity of the finished grain and effectively decrease the core loss. Also,the addition of Ce... 

取向硅钢热轧板中织构梯度对发展完善的二次再结晶十分关键,通过添加铜可以显著降低取向硅钢板坯加热温度,从而影响热轧板织构分布。利用X射线衍射仪,分析了实验室模拟薄板坯连铸连轧(TSCR)工艺的3种不同铜含量的取向硅钢热轧板织构。结果表明:不同铜含量热轧板表面到厚度1/4处均为弱的热轧织构,热轧板心部主要为{100}面织构;铜含量约在0.4%时,热轧板次表层的{110}<001>织构比例最高,而热轧板心部的{100}<110>织构比例最低;铜含量对热轧织构中{114}<110>和{001}<100>织构发展有显著影响。 The texture gradient in hot rolled grain oriented silicon steel strip is one of the essential factors to achieve a perfect secondary recrystallization.The addition of copper can significantly reduce the slab reheating temperature of grain oriented silicon steel,so as to impact the texture distribution in the hot rolled strip.The texture of hot rolled grain oriented silicon steel strip as-rolled by thin slab casting and rolling process(TSCR) in laboratory with three different copper contents was ... 

通过热力学计算与模拟试验研究了含钒钛取向硅钢中氮化物析出相的析出规律与析出行为,并探讨了含钒钛元素的氮化物析出相作为薄板坯连铸连轧流程制备取向硅钢中辅助抑制剂的可行性.研究表明,在所冶炼的含钒钛取向硅钢的成分范围内,Ti N在钢液凝固末期便具备析出的热力学条件,而Al N与VN只可能在凝固后的α+γ或α+Fe3C两相区内析出.含钒钛取向硅钢中氮化物析出相以成分复杂的复合析出相为主,且随着钒钛加入量的增加,钢中抑制剂析出相总的分布密度由于含钒钛元素的氮化物析出相的增加而明显提高,使抑制剂抑制初次再结晶晶粒正常长大的能力得以加强,最终成品的磁感应强度值B8由1.857 T提升至1.898 T.同时,加入不高于0.007%的Ti与不高于0.005%的V不会影响中间脱碳退火工序的脱碳效果以及高温退火净化阶段硫、氮的脱除效果,其形成的含钒钛元素的纳米级氮化物析出相适合作为薄板坯连铸连轧流程制备取向硅钢的辅助抑制剂. The precipitation behavior of nitride precipitates in grain-oriented silicon steel containing vanadium and titanium elements produced by thin slab casting and rolling process was studied by thermodynamic calculation and simulation experiment. The feasibility of nitride precipitates containing V and Ti elements as auxiliary inhibitors was also investigated. It is found that Ti N is likely to precipitate at the final stage of solidification in the grain-oriented silicon steel,but VN and Al N can p... 

利用加热炉模拟、动态再结晶以及热模拟等试验方法以及扫描电镜、金相显微镜等分析观察手段对无取向硅钢边裂的成因进行了探讨。结果表明,长时间加热使得板坯边部晶粒异常长大,晶界氧化并脱碳,轧制过程中边部温度过低,动态再结晶过程变弱,使得板坯边部延伸性能变差,是导致硅钢边裂的主要原因。建议通过适当降低铸坯加热温度、缩短保温时间、提高终轧温度来改善硅钢边裂缺陷。 The behaviors of high temperature oxidation,dynamic recrystallization,and hot ductility,microstructure evolution were investigated on the non-oriented electrical steel sheets to discuss the formation of edge crack.The key causes of cracking was found to be the coarse as-cast microstructure,grain boundary oxidation and decarburization in reheating furnace,as well as reduced temperature at strip edge region during hot rolling process resulting in reduced hot ductility and lack of enough dynamic re... 

研究了退火温度对3.1%Si无取向硅钢组织和磁性能的影响规律。结果表明:退火温度从940℃提高至1 000℃,平均晶粒尺寸由98μm增加到145μm,铁损P_1.5/50从2.576 W/kg降低至2.408W/kg。随着退火温度的升高,γ不利织构组分强度逐渐降低,{111}〈112〉织构组分强度降低约16%,磁感B₅₀逐渐升高,磁性能水平提高。 The effects of annealing temperature on microstructure and texture and magnetic properties of 3.1%Si non-oriented silicon steel were investigated in this paper.The results showed that,when the annealing temperature increased from 940℃ to 1 000℃,the average grain size of metallographic structure increased from 98μm to 145μm,the iron loss value P_1.5/50 decreased from2.576 W/kg to 2.408 W/kg.And as the annealing temperature increased,the strength of the unfavorable texture componentγgrad... 

阐述了国内外高磁感取向硅钢的生产研究水平与发展趋势,包括通过提高高斯晶粒取向度、细化磁畴、涂覆张力涂层、减薄钢片厚度进一步降低铁损以及低温加热技术和短流程技术新工艺。分析高磁感取向硅钢在我国大型电力变压器上的应用情况,结果表明,发展更薄规格高磁感、低铁损、低磁致伸缩取向硅钢可为大型变压器的安全性、节能性及环保性提供有效保障。 The research progress and development trend of high magnetic induction grain-oriented silicon steel at home and abroad are summarized,including the technology of improving the Goss alignment,refining domain wall,adding stress coating,decreasing thickness of sheet,and the new technique of reducing heating temperature of casting slab and shortening operational.Moreover,the application of high magnetic induction grain-oriented silicon in power transformer is presented.Developing grain-oriented sili... 

取向硅钢因其高磁导率、低矫顽力和大电阻系数等特性，被广泛应用于大中型变压器和大型电动机铁芯的制造。因取向硅钢性能和成分控制严格，生产工艺复杂，故其产品代表了钢铁企业特殊钢生产的最高水平。本文介绍了新钢公司卷板厂1580热连轧线生产取向硅钢过程中出现的窄尺问题，研究了取向硅钢产品的特点，分析了热轧过程中的组织转变，并结合生产实际提出了改进措施。通过对加热炉钢坯加热模式、粗轧轧制策略、精轧轧制工艺、二级模型等方面的优化和改进，取向硅钢窄尺情况明显好转，提高了产品的成材率和市场口碑。 The oriented silicon steel is widely used in the iron core manufacture of large and mediumsized transformers and large motors because of its high permeability, low coercivity and large resistance coefficient. Due to the performance and composition control of oriented silicon steel is strict, the production process is complex,therefore, its products represent the highest level of special steel production in iron and steel enterprises. This paper introduces the problem of narrow gauge in the produ... 

采用RH精炼添加钙合金方式对硅钢进行钙处理,结果表明,钙合金添加量为0.67、1.00和1.67 kg/t钢时,钢中Ca含量分别为0、2×10-6和4×10-(6质量分数);随着钙合金添加量的增加,钢中夹杂物粒度逐渐由0～2μm向2～4μm、4～6μm偏移;不同钙处理条件下,钢中均存在粒径小于1μm和粒径为1～5μm的MnS、CuxS夹杂物,后者或单独存在,或与AlN、CaS夹杂复合;钢中粒径为5～10μm的夹杂物基本以Ca的氧化物和硫化物为主。与未经钙处理的炉次相比,钙合金添加量为0.67、1.00和1.67 kg/t钢时,粒径小于1.0μm的夹杂物减少幅度分别为68.06%、87.50%和94.94%。钙合金添加量为1.67 kg/t钢时,可以去除钢中绝大部分的微细夹杂物。 In order to improve the properties of final silicon steels,the calcium treatment was adopted by adding Ca alloys into the liquid steel during the RH refining process.Results show that when the addition of Ca alloys is 0.67 kg/t,1.00 kg/t and 1.67 kg/t,the corresponding Ca content in silicon steels is 0,2 × 10-6 and 4 × 10-6 respectively.With the increase of Ca alloy addition,the particle sizes of inclusions in steels become 2～4 μm and 4～6 μm,from 0～2 μm.Under different calcium treatments,there e... 

对低温加热工艺生产的以AlN为主抑制剂的高磁感取向硅钢高温退火过程进行中断实验,借助电子背散射衍射技术对高温退火过程中高斯晶粒的演变进行了研究.在升温过程中高斯晶粒平均尺寸先减小再增大.800℃时取向分布函数图出现高斯织构组分,但强度很弱,高斯晶粒偏离角在10°以上;900℃时高斯晶粒平均生长速率超过其他晶粒;950~1000℃时高斯晶粒异常长大,偏离角3°~6°;在1000℃之前高斯取向晶粒相比于其他晶粒没有尺寸优势. The high-temperature annealing process of high permeability grain-oriented silicon steel with AlN as an inhibitor was studied by interrupting test.The evolution of Goss texture in this process was analyzed by electron back-scattered diffraction.It is found that the Goss grain size first decreases and then increases with the rise of temperature.Goss texture appears in the orientation distribution function at 800 ℃,but the intensity is very weak and the deviation angle is more than 10°.The average... 

以市场上购买的取向硅钢成品板为原料，经不同压下率冷轧至0.23～0.08 mm不等。借助X射线衍射仪(XRD)检测了冷轧后样品中的织构组分及其含量，利用电子背散射技术(EBSD)测量了试样的取向因子分布情况。观察了孪晶的形貌与晶体学特征，分析了硅钢超薄带的塑性变形行为。结果发现，在平面压缩应力下，{112}<111>滑移系的取向因子较大。随冷轧压下率的增加，Goss织构的含量逐渐减少，{212}<141>织构组分的含量先增加后减少，{111}<112>织构组分的含量逐渐增加，织构组分以{110}<001>→{212}<141>→{111}<112>顺序演变。冷轧后样品中出现了孪晶，其晶体取向为{001}<110>,冷轧过程中孪晶取向没有发生变化。 The commercial finished oriented silicon steel plate as the raw material were rolled to 0.23-0.08 mm. With the X-ray diffractometer(XRD), the texture components and their volume fractions in the cold-rolled samples were detected. And the orientation factor distribution of the cross-section of the samples was measured by the electron backscattering technique(EBSD). The morphology and crystallographic characteristics of twins were observed, and the plastic deformation behaviors of the ultra-thin o... 

为开发高效电机用冷轧无取向电工钢,借助实验室薄板坯连铸连轧模拟设备及扫描电镜、透射电镜等检验手段研究了成分、组织、织构和析出物等对无取向电工钢磁性能的影响规律;结果表明:常化处理使组织均匀化并增加有利于磁性提高的织构组分;采用CSP流程开发的高效电机用无取向电工钢铁损平均值3.4 0 W/kg,磁感≥1.68 T。 In order to develop electrical steel for high efficiency motor,effect of components,microstructure,texture and precipitation on magnetic property of electrical steel are analyzed.From the result,normalizing treatment makes microstructure uniform and increases component of favorable texture.Iron loss of electrical steel developed by CSP line is 3.40W/kg and magnetic induction is more than 1.68T.