钢厂
稀土元素Ce含量对50W470无取向硅钢显微组织及性能的影响
利用光学显微镜（OM）和扫描电镜（SEM）研究了不同稀土Ce含量的50W470无取向硅钢的铸坯、热轧板和冷轧退火板的宏观和微观组织，并采用磁性能测试仪测定其磁性能。结果表明：当稀土Ce的加入量从0增加到66×10-6（质量分数）时，铸坯的柱状晶平均宽度从3.82 mm减小到3.24 mm,等轴晶率从43.1%增加到51.3%;热轧板的平均晶粒尺寸逐渐增加，从26.2μm增加到33.3μm,再结晶百分数从24%增加到37%;退火板的平均晶粒尺寸从36.2μm增加到39.3μm;磁性能测试表明，微观组织的变化有利于50W470无取向硅钢铁损降低和磁感提高。 Macro-structure and microstructure of as-cast plate, hot rolled plate and cold rolled annealed plate of 50 W470 non-oriented silicon steel with different rare earth Ce content was studied by optical microscope（OM） and scanning electron microscopy（SEM）, and their magnetic properties were measured by magnetic property tester. The results show that when the addition amount of rare earth Ce increases from 0 to 66×10-6（mass fraction）, the average width of columnar crystal of the as-cast pl...
Fe-3.15%Si低温取向硅钢不同常化工艺下的组织及析出相研究
利用OM,TEM,EDS与XRD技术,对Fe-3.15%Si低温取向硅钢热轧板不同常化处理后的显微组织、析出相及最终产品的磁性能进行了分析研究,并对热轧板和常化板经过冷轧后的冷轧板织构进行了对比分析.结果表明,采用1120℃保温3 min二段式冷却的常化处理工艺,常化板表层显微组织均匀,沿板厚方向的显微组织的不均匀性显著,对后续过程中形成高取向的Goss织构最有利,取向硅钢的磁性能最高;采用二段式冷却的常化冷却工艺最优,在此冷却工艺下析出的细小的析出物数量最多,且弥散分布在基体中,抑制剂的抑制效果最好,对成品获得高磁性最有利;热轧板、常化板经过冷轧后的冷轧板织构均主要由{111}〈110〉和{111}〈112〉织构组成,但常化板较热轧板冷轧后的冷轧板γ取向线织构密度明显增高,由此可以证实常化处理有助于取向硅钢最终获得高取向的Goss织构. The decreasing of slab heating temperature for grain-oriented silicon steel will reduce the amount of precipitates in hot rolled plate,and be disadvantage to the formation of ultimate Goss texture.The aim of normalizing is to control and adjust the amount,size and distribution of precipitates.Microstructures,precipitates and magnetic characteristics of finished products with different normalizing technologies for Fe-3.15%Si low temperature hot rolled grain-oriented silicon steel are researched,a...
EBSD技术在硅钢织构研究中的应用
运用电子背散射衍射(EBSD)和X射线衍射(XRD)技术对硅钢热轧板的织构在板厚方向的分布进行了研究,并分析了两种织构测量方法的特点。EBSD技术能直观给出板厚方向的微观织构,XRD能得到钢板的宏观统计织构信息,结合两种技术的分析,能更直观更精确的研究不同织构在板厚方向的分布。 The texture distribution along the thickness of the silicon steel has been investigated by electron backscatter diffraction(EBSD) and X-ray diffraction(XRD) technique.The characteristics of two technique of texture analysis have been investigated.Combined the two techniques,the texture distribution along the thickness of the silicon steel could be realized distinctly and accurately.
硅元素对Fe-(4.5～7.0)%Si高硅钢组织和性能的影响
通过Axio Imager金相显微镜考察4.5%~7.0%硅(质量分数)对高硅钢材料组织形貌的影响,并利用Fe-6.5%Si高硅钢薄板制备方法对其进行轧制,通过DDL50电子万能试验机对阶段产品进行力学性能测试。结果证明,硅含量为5.58%的高硅钢在实验硅含量区间内存在最大延伸率及最小铸态组织晶粒尺寸。 An investigation about the influence of 4.5%-7.0% Si on microstructure and mechanical properties of high-silicon steel was presented.SEM was adopted to take an observation towards microstructure during fabrication,and DDL50electronic universal testing machine was applied into the detection of tensile curves.The results show that silicon steel with 5.58% Si provides the maximum elongation and minimum grain size as cast.
热轧辊冷却对冷轧无取向电工钢卷纵向磁性的影响及工艺优化
通过对35W300高牌号0.35 mm冷轧无取向电工钢卷(/%:0.002C、2.71Si、0.22Mn、0.015P、0.003S、0.0020N、0.55Als)头、中、尾组织、织构及对应的磁性能的试验研究,发现因热轧时12 MPa高压水连续冷却造成接触轧辊的钢卷头、中、尾在不同温度下轧制,卷取后钢卷头部处于卷心、温度略高而冷却速度略低于钢卷尾部,致使钢卷纵向组织、织构不同,成品卷头、尾各250 m内磁感逐渐增加,铁损逐渐降低,250 m外至钢卷中部磁性能稳定。通过将热轧辊的冷却方式改为周期冷却和卷取后的层流冷却改为钢卷70 m后开始冷却,至钢卷尾部70 m前停止冷却的方式使得钢卷纵向铁损差异明显减小,磁感差异略有改善。 According to the test research on structure and texture of head,meddle and end of 35W300 high grade 0.35 mm cold rolled non-oriented electrical steel strip coil(/%:0.002C,2.71Si,0.22Mn,0.015P,0.003S,0.002 0 N,0.55Als) and corresponding magnetic properties,It is found that due to 12 MPa high pressure water continuous cooling the roller in hot rolling process led to head,middle and tail of strip rolling at different temperature and after coiling the head of strip coil being in center of coil led t...
取向硅钢用特种氧化镁的应用研究
采用XRD、SEM和激光粒度仪等手段,观察并研究了不同特性氧化镁在硅钢表面形成硅酸镁底层形貌特点,并结合热力学和差热-失重分析了MgO-SiO2的反应机理。研究结果表明:粒度小,活性值高的特种氧化镁在高温退火过程中与基体表面氧化物生成的硅酸镁底层,界面中硅酸镁底层嵌入基体较多,表面致密,颗粒细小,有利于形成附着性能优良的硅酸镁底层。 Surface microstructure of Mg2SiO4 coatings formed on the surface of oriented silicon steel coated with different kinds of MgO was investigated by XRD and SEM.The reaction mechanism between MgO and SiO2 was analyzed by TG-DSC and thermodynamic calculation.Results revealed that when the MgO with finer microstructure size and higher activity is employed,a dense Mg2SiO4 layer with finer microstructure and good binding to the steel substrate can be obtained.The results are very helpful for the prepar...
硅钢轧制过程中乳化液流量数学模型研究及应用
目前高磁感冷轧硅钢生产过程中，采用经验方法确定的乳化液流量设定值往往会造成硅钢产品的磁感性能达不到预期目标，针对此情况，基于轧机轧制机理研究了的乳化液流量数学模型，确定了乳化液流量设定值。实践表明，使用该数学模型输出的乳化液流量设定值，可提高轧制过程中乳化液流量控制精度，从而提高高磁感冷轧硅钢的轧制性能。 In view of the current production process of high magnetically inductive cold-rolled silicon steel, the mathematical model of emulsified fluid flow based on mill rolling mechanism is studied in view of the situation in which the magnetic sensing performance of silicon steel products is often not up to the expected target by using empirical method to determine the emulsified liquid flow setting. Practice shows that the emulsified fluid flow setting value output from this mathematical model improv...
电感耦合等离子体质谱法测定硅钢中痕量铝钼钒钛铌
研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c...
