硅钢资料

采用Nb对Fe-6.5%Si(质量分数)高硅钢进行微合金化处理,结果表明:Nb在高硅钢薄板制备过程中细晶效果明显.铸态、锻态和热轧态组织的晶粒分别细化了17.50%,24.51%和30.13%.铸态样品压缩强度由1365 MPa提高至1520 MPa,延伸率提高77.78%;温轧板试样室温拉伸强度由573 MPa提高至621 MPa,延伸率提高44.44%.利用XRD对厚度为0.30—1.68 mm的温轧板的板面织构演变过程进行跟踪测量,结果发现:初始织构以(011)〈100〉Goss织构为主,单道次变形量为26.2%的情况下,Goss织构完全转化为(100)〈011〉旋转立方织构,随后,在单道次变形为22.6%的情况下,旋转立方织构完全转化为{111}面织构,即纤维织构,并稳定保持至0.30 mm. Fe-6.5%Si（mass fraction） alloy possess perfect magnetic properties,though intermetallics of Fe₁₄Si₂ phase brought 6.5%Si leads to room temperature brittleness and hinder this significant materials industrialization.Nb was adopted into micro-alloying of Fe-6.5%Si high silicon steel. OM,thermal simulated test machine and XRD were employed to study the influence of Nb on high silicon steel in processing stages.Textures of warm-rolled high silicon steel strips were determined b... 

以CaO-CaF2复合渣系为脱硫剂,在RH精炼过程采用真空投入法进行高牌号无取向电工钢深脱硫工业试验,采用KTH模型计算分析了RH炉渣成分对硫容量CS的影响。研究结果表明,炉渣成分控制在w((CaO))/w((SiO2))为5~7,w((CaO))/w((Al2O3))为1.5~1.8,w((Al2O3))为25%~30%,w((FeO+MnO))<5%,脱硫剂加入量为6~8kg/t时,钢中硫质量分数从平均0.003 1%降低到0.001 8%,最高脱硫率达到47.1%,平均脱硫率为41.7%。 The industrial trials on deep desulphurization of high grade non-oriented electrical steel were finished through using CaO-CaF2complex based fluxes in RH process.Using the KTH model,the effect of refining slag composition on the sulfide capacities was analyzed.The results show that the chemical composition of refining slag(mass fraction,%)is w((CaO/SiO2))between 5to 7,w((CaO))/w((Al2O3))beween 1.5to 1.8,w((Al2O3)) between 25%to 30%,w((FeO+MnO))less than 5%,and the desulphurizer addition level of... 

常化快冷是生产高牌号无取向硅钢和高磁感取向硅钢不可缺少的一个工艺环节,气-雾冷却则是实现常化快冷的关键方式之一。介绍了国内自主设计建设的常化酸洗机组气雾冷却系统的技术特性,并对其特点进行了系统分析,最后给出该系统在设计、运行参数的选择上若干注意事项,对气-雾冷却系统设计和使用具有一定的指导作用。 The normalizing rapid cooling is a indispensable process to high grade non-oriented silicon steel and high magnetic induction oriented silicon steel’ s production. The fog cooling is a key ways of coming true the normalizing rapid cooling. This paper introduces the technical features of the fog cooling system in normalizing pickling line which is the domestic independent design and construction. Meanwhile,the fog cooling system’s characteristic is analyzed systematacially. In the end,this paper ... 

利用光学显微镜（OM）和扫描电镜（SEM）研究了不同稀土Ce含量的50W470无取向硅钢的铸坯、热轧板和冷轧退火板的宏观和微观组织，并采用磁性能测试仪测定其磁性能。结果表明：当稀土Ce的加入量从0增加到66×10^-6（质量分数）时，铸坯的柱状晶平均宽度从3.82 mm减小到3.24 mm,等轴晶率从43.1%增加到51.3%;热轧板的平均晶粒尺寸逐渐增加，从26.2μm增加到33.3μm,再结晶百分数从24%增加到37%;退火板的平均晶粒尺寸从36.2μm增加到39.3μm;磁性能测试表明，微观组织的变化有利于50W470无取向硅钢铁损降低和磁感提高。 Macro-structure and microstructure of as-cast plate, hot rolled plate and cold rolled annealed plate of 50 W470 non-oriented silicon steel with different rare earth Ce content was studied by optical microscope（OM） and scanning electron microscopy（SEM）, and their magnetic properties were measured by magnetic property tester. The results show that when the addition amount of rare earth Ce increases from 0 to 66×10^-6（mass fraction）, the average width of columnar crystal of the as-cast pl... 

研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c... 

【机构】 中国金属学会电工钢分会； ...

以水氯镁石为原料,采用氨法沉镁-煅烧-添加剂的方法制备硅钢级氧化镁。考察了反应温度、反应pH值、陈化时间对中间体氢氧化镁纯度及转化率的影响;研究了煅烧温度和煅烧时间对氧化镁水化率的影响及添加剂的量对氧化镁悬浮性能的影响。控制实验条件为:反应温度55℃,pH值为9.5,陈化时间2h,煅烧温度1050℃,煅烧时间2h,添加剂量为0.8%,制得氧化镁的纯度为98.99%、水化率为2.92%、悬浮性能为3mm/h,达到硅钢级氧化镁的要求。 Using bischofite as raw material,the preparation of magnesium oxide with silico-steel grade was studied.The effects of reaction temperature,reaction pH value and aging time on the intermediate magnesium hydroxide purity and conversion rate were studied.Calcinations temperature,calcinations time relationship to the hydration rate of MgO and amount of additive to the suspension performance of MgO were investigated.The results indicated that the optimum technological conditions were as follows:reac... 

为了确定普通冷轧取向硅钢最优的中间完全脱碳退火工艺,在其一次冷轧后进行5种不同工艺的脱碳退火处理,借助扫描电镜及电子背散射衍射技术研究了不同工艺脱碳退火后的组织、织构和脱碳效果。结果表明:经5种工艺脱碳退火处理后,初次再结晶的平均晶粒尺寸均约为19μm,且不随退火温度和时间的变化而变化;经840℃×10min工艺退火后的晶粒最均匀,高斯织构位向更准确,高斯织构面积分数最多,为3.1%,可将碳脱至0.003 5%。 In order to determine the optimal intermediate complete decarburizing annealing processes for common grain-oriented(CGO)silicon steel,five kinds of intermediate decarburizing annealing processes were conducted,the microstructure,texture and decarbonization after different decarburizing annealing processes were studied by scanning electron microscopy and electro back-scattered diffraction(EBSD)technology.The results show that the average grains sizes of primary recrystallization were about 19μm a... 

利用电子探针面分析、状态分析及电子背散射衍射相分析技术研究硅钢高温氧化铁皮的显微结构。电子探针面分析可以直观的看出元素的分布状态,初步判断氧化铁皮的结构,而状态分析可以准确表征常规氧化铁皮中铁元素的状态,对于合金元素富集区域则通过电子背散射衍射相分析技术来标定。结果表明,高温氧化铁皮的结构主要有4层,即最外层为厚度约为10μm的Fe2O3相,次外层为Fe3O4相,中间层为FeO相上分布有颗粒状的Fe3O4相,最内层为FeO相和Si元素富集的Fe2SiO4相。其中Fe2SiO4层的分布特征与加热温度密切相关:1 100℃时,Fe2SiO4相呈颗粒状,弥散分布在FeO层;1 200℃时,Fe2SiO4相呈液态,侵入基体和疏松的FeO层,且沿着FeO晶界呈网状分布。 The microstructure of high temperature oxide scale on silicon steel was characterized by electron probe microanalyzer(EPMA)mapping analysis,state analysis and electron backscatter diffraction(EBSD)phase analysis.The element distribution and the initial structure of the oxide scale could be detected by EPMA mapping analysis apparently.And the state of iron in the conventional oxide scales could be determined by state analysis.Meanwhile,the alloy-rich region could be identified by EBSD phase analy... 

通过热力学计算与模拟试验研究了含钒钛取向硅钢中氮化物析出相的析出规律与析出行为,并探讨了含钒钛元素的氮化物析出相作为薄板坯连铸连轧流程制备取向硅钢中辅助抑制剂的可行性.研究表明,在所冶炼的含钒钛取向硅钢的成分范围内,Ti N在钢液凝固末期便具备析出的热力学条件,而Al N与VN只可能在凝固后的α+γ或α+Fe3C两相区内析出.含钒钛取向硅钢中氮化物析出相以成分复杂的复合析出相为主,且随着钒钛加入量的增加,钢中抑制剂析出相总的分布密度由于含钒钛元素的氮化物析出相的增加而明显提高,使抑制剂抑制初次再结晶晶粒正常长大的能力得以加强,最终成品的磁感应强度值B8由1.857 T提升至1.898 T.同时,加入不高于0.007%的Ti与不高于0.005%的V不会影响中间脱碳退火工序的脱碳效果以及高温退火净化阶段硫、氮的脱除效果,其形成的含钒钛元素的纳米级氮化物析出相适合作为薄板坯连铸连轧流程制备取向硅钢的辅助抑制剂. The precipitation behavior of nitride precipitates in grain-oriented silicon steel containing vanadium and titanium elements produced by thin slab casting and rolling process was studied by thermodynamic calculation and simulation experiment. The feasibility of nitride precipitates containing V and Ti elements as auxiliary inhibitors was also investigated. It is found that Ti N is likely to precipitate at the final stage of solidification in the grain-oriented silicon steel,but VN and Al N can p... 

阐述了国内外高磁感取向硅钢的生产研究水平与发展趋势,包括通过提高高斯晶粒取向度、细化磁畴、涂覆张力涂层、减薄钢片厚度进一步降低铁损以及低温加热技术和短流程技术新工艺。分析高磁感取向硅钢在我国大型电力变压器上的应用情况,结果表明,发展更薄规格高磁感、低铁损、低磁致伸缩取向硅钢可为大型变压器的安全性、节能性及环保性提供有效保障。 The research progress and development trend of high magnetic induction grain-oriented silicon steel at home and abroad are summarized,including the technology of improving the Goss alignment,refining domain wall,adding stress coating,decreasing thickness of sheet,and the new technique of reducing heating temperature of casting slab and shortening operational.Moreover,the application of high magnetic induction grain-oriented silicon in power transformer is presented.Developing grain-oriented sili... 

取向硅钢利用析出物作为抑制剂,抑制初次再结晶晶粒的长大,抑制剂是取向硅钢发生二次再结晶的基本条件之一。文中通过低温板坯加热技术制备取向硅钢,采用透射电镜(TEM)观察并研究了高温退火阶段抑制剂的演化过程。结果表明,渗氮后形成的非晶态Si3N4析出物不稳定,在700～750℃退火升温阶段转化为(Al,Si)N;(Al,Si)N颗粒在800℃发生团聚,随后长大并粗化;(Al,Si)N是低温取向硅钢主要抑制剂,随退火温度的升高,(Al,Si)N抑制力大幅下降。 Precipitates as inhibitor are used to inhibit the grain growth of primary recrystallization in grain-oriented silicon steel,and inhibitor is one of the basic conditions for occurring of secondary recrystallization.The grain-oriented silicon steel was produced by low temperature slab heating and nitriding technique.The evolution of inhibitor was observed by transmission electron microscopy.The results show that Si3N4 particles are precipitated after nitriding,and Si3N4 particles are amorphous and...