硅钢资料

采用轧制法制备出具有低铁损高磁感0.23mm厚6.4%(质量分数)Si高硅钢。沿轧制方向的最终磁性能为B8=1.474 T,B50=1.714 T;P10/50=0.30W/kg,P15/50=0.88W/kg。利用X射线衍射及背散射电子衍射(EBSD)技术分析了高硅钢在轧制及退火过程中的织构演变过程。结果表明,通过采用大压下率热轧,确保热轧板次表层中产生更多的高斯织构,随后进行遗传;温轧板中粗大的晶粒有利于冷轧剪切带的形成;冷轧板经脱碳退火后生成强{210}〈001〉织构及次表层较强的高斯织构是在轧向上获得高磁感的原因,归因于其在{111}〈112〉冷轧形变晶粒内的剪切带优先形核并长大;最终退火后虽出现了随机取向,但以{310}〈001〉织构为代表的η织构得以保留并且增强,进一步提高了磁感。随着退火温度的升高及保温时间的延长,高硅钢薄板晶粒尺寸不断增大,铁损明显降低。 6.4wt%Si high silicon steel sheets(0.23mm thick)with low iron loss and high magnetic induction were successfully produced by rolling process.The final magnetic properties along the rolling direction(RD) were:B8=1.474T,B50=1.714T;P10/50=0.30 W/kg,P15/50=0.88 W/kg.The texture evolution during rolling and annealing was investigated by means of X-ray diffraction and electron backscatter diffraction(EBSD).It was found that more Goss textures formed in the subsurface of hot rolled plates by using larg... 

利用电子探针面分析、状态分析及电子背散射衍射相分析技术研究硅钢高温氧化铁皮的显微结构。电子探针面分析可以直观的看出元素的分布状态,初步判断氧化铁皮的结构,而状态分析可以准确表征常规氧化铁皮中铁元素的状态,对于合金元素富集区域则通过电子背散射衍射相分析技术来标定。结果表明,高温氧化铁皮的结构主要有4层,即最外层为厚度约为10μm的Fe2O3相,次外层为Fe3O4相,中间层为FeO相上分布有颗粒状的Fe3O4相,最内层为FeO相和Si元素富集的Fe2SiO4相。其中Fe2SiO4层的分布特征与加热温度密切相关:1 100℃时,Fe2SiO4相呈颗粒状,弥散分布在FeO层;1 200℃时,Fe2SiO4相呈液态,侵入基体和疏松的FeO层,且沿着FeO晶界呈网状分布。 The microstructure of high temperature oxide scale on silicon steel was characterized by electron probe microanalyzer(EPMA)mapping analysis,state analysis and electron backscatter diffraction(EBSD)phase analysis.The element distribution and the initial structure of the oxide scale could be detected by EPMA mapping analysis apparently.And the state of iron in the conventional oxide scales could be determined by state analysis.Meanwhile,the alloy-rich region could be identified by EBSD phase analy... 

热轧轧制工艺对产品性能和轧制稳定性影响很大,对中低牌号无取向电工钢,当在两相区轧制时,热轧塑性明显降低,板形变坏,易出现边裂等情况。以50W1000为例,通过对其变形抗力进行研究,得出把两相区控制在F4与F5之间为最佳轧制工艺的结论。在此基础上制定了一套较为合理的热轧工艺制度。采用新的轧制工艺后,50W1000热轧精轧的稳定性明显改善,热轧产品合格率由开发初期的40%左右提高到95%以上。 The hot rolling process has great influence on product′s performance and rolling stability.For the low medium grade non-oriented electrical steel,when non-oriented electrical steel is rolled in tow phase region,the hot rolling plasticity reduces obviously,the shape of strip goes bad and easily to crack at the edge.The deformation resistance of 50W1000 steel was investigated.The results show that the optimal rolling process is to control the two phase region between F4 and F5.Based on the results... 

利用本钢技术中心试验厂技术手段,并与北京钢铁研究院合作,试制了用作家电用电机、微电机、小电机或部分中型电机铁芯的冷轧无取向电工钢。试制钢硅含量小于0.5%,钢板表面平滑,公称厚度0.5mm,且厚度均匀偏差小,性能测定结果表明,产品的磁性能、力学性能满足其使用要求。 BX STEELTechnology Center pilot plant using technical means,and with Beijing Iron and Steel Research Institute,trial cold rolled non-oriented electrical steel that has been used as appliance motor core,micro motor core,small motor core,or part of the medium-sized motor core。Trial steel of silicon content is less than 0.5%,steel plate surface is smooth,the nominal thickness of 0.5mm,and the thickness deviation is small,performance measurement results show that the magnetic properties,mechanical p... 

结合工业化生产的高效硅钢,进行了RH精炼稀土处理试验研究。针对不同的稀土处理条件,观察了夹杂物的形貌和尺寸分布,探讨了稀土处理后钢中的夹杂物形成、变化规律。结果表明:试验条件下,最佳的稀土合金添加数量为0.6～0.9 kg/t。经过合适的稀土处理后,可以有效抑制尺寸相对较小的、不规则的AlN、MnS复合夹杂生成,促进钢中微细夹杂物的聚合、上浮,钢质纯净度得到明显提高。此时,钢中全氧含量最低,脱硫效果最佳,钢中的夹杂物主要是尺寸相对较大的、近似球形或者椭球形的稀土类夹杂。 Based on the industrial production of non-oriented silicon steel,the experiment on RE treatment during the RH refining process was studied.The morphology and the size distribution were observed for the steel specimens treated with different RE treatment conditions.Further more,the formation and change of inclusions of final steel sheets after RE treatment were discussed.The results show that the suitable RE added amount was 0.6～0.9 kg/t.After the suitable RE treatment,the formation of AlN and Mn... 

以市场上购买的取向硅钢成品板为原料，经不同压下率冷轧至0.23～0.08 mm不等。借助X射线衍射仪(XRD)检测了冷轧后样品中的织构组分及其含量，利用电子背散射技术(EBSD)测量了试样的取向因子分布情况。观察了孪晶的形貌与晶体学特征，分析了硅钢超薄带的塑性变形行为。结果发现，在平面压缩应力下，{112}<111>滑移系的取向因子较大。随冷轧压下率的增加，Goss织构的含量逐渐减少，{212}<141>织构组分的含量先增加后减少，{111}<112>织构组分的含量逐渐增加，织构组分以{110}<001>→{212}<141>→{111}<112>顺序演变。冷轧后样品中出现了孪晶，其晶体取向为{001}<110>,冷轧过程中孪晶取向没有发生变化。 The commercial finished oriented silicon steel plate as the raw material were rolled to 0.23-0.08 mm. With the X-ray diffractometer(XRD), the texture components and their volume fractions in the cold-rolled samples were detected. And the orientation factor distribution of the cross-section of the samples was measured by the electron backscattering technique(EBSD). The morphology and crystallographic characteristics of twins were observed, and the plastic deformation behaviors of the ultra-thin o... 

研究了组织和析出物对高效电机用无取向硅钢退火板磁性能的影响。结果表明:随着退火温度升高,退火板平均晶粒尺寸增加,P15/50明显降低,B50略有升高。退火温度在1 000℃时,退火板的综合性能较好。析出物主要是AlN、(MnS+AlN)和(MnS+Al2O3)复合析出物,尺寸较粗大,主要集中在1.0～2.5μm,还发现少量百纳米以下的细小AlN和TiN。实验室模拟TSCR流程试制的高效电机用无取向硅钢,铁损平均值小于4.00 W/kg,磁感应强度大于1.75 T,适合作中小型高效电机铁芯材料。 Effects of microstructure and precipitation on magnetic property of non-oriented silicon steel sheets after annealing for high-efficiency motor are studied in the paper by experiments.The annealed sheet exhibits a larger average grain size,obviously decreasing iron loss and slightly raising magnetic induction with increasing temperature.The annealed sheet has better comprehensive properties at a annealing temperature of 1 000 ℃.The main precipitates are compounds of AlN、(MnS+AlN)and(MnS+Al2O3) w... 

对3层高硅电工钢复合板铸坯进行热轧及温轧变形加工后，采用正火、退火两种热处理方式处理，并观察轧制过程中产生的裂纹，研究不同状态下复合板的磁性能。对不同状态下的试样进行扩散退火处理，研究复合板中裂纹变化及其对磁性能的影响。结果表明：不同热处理工艺下合金内部的裂纹尺寸差异明显，裂纹尺寸对复合板的磁性能影响显著，相对于深裂纹，其他因素的影响较小；温轧变形加工后，复合板内层出现有序组织，但该有序组织在合金存在深裂纹的前提下并不能从本质上提高合金的磁性能；扩散退火工艺可以消除复合板内部的浅裂纹及微裂纹，但不能消除尺寸较大的裂纹，故而不能显著提高存在深裂纹的复合板的磁性能。 After hot rolling and warm rolling deformation processing of casting billet for three-layer high silicon electrical steel composite plate, it was normalized and annealed for heat treatment. Then, the cracks produced during the rolling process were observed, and the magnetic properties of composite plate in different states were also investigated. Furthermore, the samples in different states were subjected to diffusion annealing treatment, and the changes of crack in composite plate and their eff... 

介绍了国内无底层取向电工钢生产技术水平、产量和用途，简述了无底层取向电工钢作为取向电工钢超/极薄带母料及应用于制作大型发电机组铁心、风电等电机铁心和变压器铁心等的情况。 The production technology level,output and application of domestic glassless grainoriented electrical steel were introduced,and the application of glassless grain-oriented electrical steel as parent material of ultra-thin strip of grain-oriented electrical steel and in making large-scale electric generator cores,wind power motor cores and transformer cores were briefly described. 

取向硅钢常化工序主要采用现场实测带钢温度的方式测定冷却速率，并通过稳定冷却水温、调整冷却水量及喷梁运行数量等方式保证合理的冷却速率，给常化工艺设计和生产带来诸多不便。通过对常化工艺水冷过程带钢的传热分析求解，在建立带钢水冷温度模型的基础上，研究了不同冷却工艺参数对带钢温度及冷却速率的影响规律以及冷却工艺的交互作用结果。结果表明：模型计算结果能够较好地反映取向硅钢在常化水冷过程中的温度及冷却速率的变化，其计算误差为0.80%～4.11%;在特定取向硅钢厚度规格和常化工艺下，随着常化冷却水量及有效冷却长度的增加，带钢水冷温度及冷却速率与呈非线性变化；常化水冷工艺主要通过调控带钢与冷却水之间热交换量和交换时间实现对带钢温度的控制，实际生产中需综合考虑机组速度、冷却水量及有效冷却长度之间的交互作用，选定喷梁投入数量和冷却水量以获得稳定的冷却速率。 The cooling rate of normalization process mainly determined by measuring the grain oriented silicon steel strip temperature on site, and ensures the cooling rate by stabilizing the cooling water temperature, adjusting the cooling water volume and the operation quantity of spray beam, which brings inconvenience to the normalization process design and production. Based on the heat transfer of strip in the water cooling section of normalization process, the water cooling temperature model for the n... 

无氧化炉具有加热效率高、投资与运营成本低、作业率高、表面质量及板型良好、NOx排放相对低等优势,在硅钢热处理领域应用前景广泛。本文阐述了确定无氧化炉(NOF)加热能力详细过程,涵盖炉温、炉断面尺寸、炉长、热平衡结算、加热能力计算等,为今后无氧化炉(NOF)在硅钢热处理应用时的设计提供了借鉴,同时也为今后明火直接加热的工业炉设计提供了参考。 Non-oxidation furnace has the advantage s of high heating efficiency, low investment and operation cost, high operation rate, good surface quality and plate shape, and relatively low NOxemission,and it still has wide application prospect in the field of silicon steel heat treatment. The detailed process of determining the heating capacity of a non-oxidizing furnace(NOF) is described, covering furnace temperature, furnace section size, furnace length, heat balance settlement, heating capacity cal... 

采用自主研发的脉冲磁场退火装置，在取向硅钢脱碳退火过程中分别施加不同强度的磁场，并采用光学显微镜和X射线衍射仪研究了脉冲磁场脱碳退火后试样的显微组织和宏观织构。结果表明，脱碳退火过程中施加脉冲磁场后取向硅钢的平均晶粒尺寸均增加，当磁场强度为40 mT时，平均晶粒尺寸最大，为13.06μm。此外，取向硅钢试样的立方织构{001}<100>强度减弱，高斯织构{110}<001>和{111}<112>织构增强，有利于获得更好的成品织构和磁性能。 Self-developed pulsed magnetic field annealing device was used to apply magnetic field of different intensities during decarburization annealing of an oriented silicon steel, and microstructure and macro-texture of the specimens after decarburization annealing in a pulsed magnetic field were studied by using optical microscope and X-ray diffractometer. The results show that the average grain size of the oriented silicon steel increases with the application of pulsed magnetic field during decarbu...