硅钢资料

采用EBSD技术研究了有、无拉应力作用下无取向硅钢在晶粒长大过程中织构转变及晶界变化的规律。结果表明:在晶粒生长期间,无应力作用下的硅钢中,{111}〈112〉,{111}〈110〉织构组分强化,而{100}〈001〉织构组分弱化;与无拉应力作用下的情况相比,施加5MPa的拉应力时,{111}〈112〉,{111}〈110〉织构组分强化的速率下降,{100}〈001〉织构组分变化不明显。对于在晶粒生长期间持续变化的{111}〈112〉,{111}〈110〉和{100}〈001〉织构组分而言,虽然有、无拉应力作用下硅钢的{111}〈112〉和{111}〈110〉织构组分的高取向差角度晶界频率均下降,而{100}〈001〉织构组分的高取向差角度晶界频率则上升,但当有拉应力作用后,{111}〈112〉和{111}〈110〉织构组分的高取向差角度晶界频率下降的速率变小,{100}〈001〉织构组分的高取向差角度晶界频率上升的速率稍有变小。通过对无取向硅钢在晶粒长大过程中织构转变及晶界变化规律的研究,分析了合金原子在晶界的偏聚行为。 The rules of texture and grain boundary transformation in the nonoriented silicon steel under applied stress or without applied stress during grain growth were investigated by EBSD.The results show that the {111}〈112〉 and {111}〈110〉 components in the nonoriented silicon steel without stress are strengthened during grain growth whereas {100}〈001〉 component is weakened,but the growth rate of {111}〈112〉 and {111}〈110〉 component decreases,while the area fraction of {100}〈001〉 component doesn’t chang... 

以取向电工钢成分为基础,制备了含C或Mn和S的4种实验钢。观察了接近平衡析出状态实验钢经60%冷轧后在600～1000℃范围再结晶退火过程中微观组织演变,统计分析了再结晶体积分数随退火时间的变化规律,进而计算了各实验钢静态再结晶的激活能。观察了高含C实验钢退火初期再结晶晶粒优先出现的部位。结果表明900～1000℃范围内各实验钢铁素体的化学成分相似,因而其再结晶激活能基本一致。在600～800℃范围内铁素体内会有阻碍再结晶进程的三次渗碳体析出,从而使再结晶激活能明显提高。高C含量实验钢中还会有从奥氏体转变而来的粗大珠光体或渗碳体,轧制过程中其附近形成的变形区会促进600～800℃加热时该区域附近率先发生再结晶形核、降低再结晶激活能。固溶的Mn、S元素可微弱提高再结晶激活能,但高Mn、S含量会改变粗渗碳体从奥氏体析出时的形态。 Four experimental steels based on grain oriented electrical steel containing C,or Mn and S were prepared.Microstructure evolution of the steels close to a state of equilibrium precipitation were observed during annealing processes at 600-1000 ℃after 60% cold rolling,the changes of recrystallization volume fraction were analyzed statistically as the annealing was prolonged,and the activation energy for static recrystallization of the steels were calculated.The locations,where the recrystallizatio... 

本文介绍了无取向硅钢C6涂液的性能,研究了配水量、固化程度和涂层厚度等因素对无取向硅钢C6涂层性能的影响。结果表明,随着配水量的增加,完全固化所需的时间增加,涂液固体含量降低,涂层厚度减小;随着固化程度的提高,涂层硬度先增大然后趋于恒定,而柔韧性逐渐变差,在过固化后急剧恶化;涂层厚度对涂层的表面外观、附着性和绝缘层间电阻均有显著影响。 Based on the introduction about the performance of C6 varnish for non-oriented silicon steel sheets,effects of water amount,curing degree and coating thickness are discussed. Results show that with the increase of water amount,the time required to cure completely extends,and both the solid content of C6 varnish and the coating thickness decrease. As the curing degree increases,the hardness of the coating increases first and then tends to be constant,however the flexibility degenerates,especially... 

结合工业化生产过程中出现的同卷带钢头、尾磁性能差异现象,对50SW1300牌号无取向硅钢同卷带钢头、尾试样的夹杂物、晶体织构和显微组织进行了分析研究。结果表明,夹杂物、晶体织构是影响成品钢卷磁性能的重要因素。夹杂物是造成同卷带钢头、尾铁损差异的主要原因。夹杂物数量越多,尤其是小尺寸的夹杂物数量越多,对成品带钢的磁性能影响越大,对于本试验而言,AlN和MnS是影响成品带钢磁性能的主要夹杂物。晶体织构是造成同卷带钢头、尾磁感应强度差异的主要原因。有益的{100}和Goss织构含量越大,有害的{111}<110>和{111}<112>织构含量越小,即有益织构与有害织构含量比越大,成品带钢的磁感应强度越大。 Based on the industrial manufacture of non-oriented silicon steel sheets 50SW1300, the magnetic property variation of head and tail of the same finished steel sheets was discussed by analyzing non-metallic inclusion, crystal texture, and microstructure. Results show that, both of the non-metallic inclusion and the crystal texture will affect the magnetic properties significantly. The non-metallic inclusion is the key factor of the core loss variation of head and tail of the same finished steel s... 

无取向硅钢中夹杂物的存在会抑止晶粒生长,使基体的均匀连续性中断,其在钢中的形态、含量及分布情况都不同程度影响着硅钢的性能,尤其是对磁性能起关键的作用。因此,全尺度分布考察夹杂物对无取向硅钢夹杂物的研究极为重要。本实验确定了适用于不同牌号无取向硅钢夹杂物全尺度分布的分析方法:样品制备—小样电解—过滤喷金—根据不同牌号的要求选择合适的放大倍率扫描观测—夹杂物颗粒的分类统计。通过统计的结果,结合电解的失重量可以得到不同尺度的体积分布数据。实验分析了不同牌号和工艺无取向硅钢夹杂物的种类、形貌、大小和尺度分布,并初步考查了夹杂物与磁性能的关系,对无取向硅钢的工艺研究具有一定参考价值。 Inclusions in non-oriented silica steel could inhibit the growth of grain and cause discontinuity of micro-structure.The configuration,content and size distribution of inclusion have different effects on the performance of silica steel,especially significant on the magnetic property.Therefore,it is very useful to completely characterize inclusions with full size distribution in silica steel.In our research,full size analysis method for inclusion in silica steel had been established as follows: s... 

介绍了CSP工艺生产无取向电工钢各工序的设备特点、采用的工艺控制手段和电工钢产品质量情况,结合生产实践证明了马钢CSP工艺开发的无取向电工钢产品丰富了薄板坯连铸连轧的品种结构,发挥了薄板坯连铸连轧生产无取向电工钢性能均一、稳定的特点。 The equipment characteristic,the process control method and the quality of non-orientated silicon steel by CSP process were introduced.Combined with the production situation,it is proved that production of non-orientated silicon steel developed on Masteel CSP line would enrich product structure of thin slab continuous casting and rolling,and it exerts stable performance of non-orientated silicon steel. 

借助电子背散射(EBSD)技术对AlN为主抑制剂的Hi-B取向硅钢常化工艺的中间冷却制度进行了研究。结果表明:常化后试样均发生了完全再结晶,在60℃/s冷速下组织最均匀;在合适的冷却制度下常化板表层保留了强的Goss织构,它深入到1/4厚度处,并且形成对Goss织构有利的强{554}<225>织构。 The intermediate cooling system of Hi-B oriented silicon steel with AlN main inhibitor in normalizing process was studied by means of electron back diffraction(EBSD) technique. The results show that:the specimens after normalizing are fully recrystallization, and the microstructure is most uniform under the intermediate cooling rate of 60℃/s; under suitable cooling system, normalized plate surface retains strong Goss texture, it penetrates into the 1/4 thickness of the plate and forming strong {... 

通过对湿H2气氛下,相同退火温度、不同退火时间的CGO硅钢初次再结晶样品进行金相组织观察,并进行了EBSD微观织构分析,研究了CGO硅钢初次再结晶过程中的组织及再结晶织构演变行为。结果表明,在湿H2气氛下,820℃保温,CGO硅钢初次再结晶过程约在120 s时完成。随着退火时间的延长,γ面上{111}<112>织构含量逐渐减少,{111}<110>织构先减少后增多,随着再结晶的完成,部分{111}<112>取向晶粒向高斯{110}<001>取向转化的同时,也向{111}<110>取向转化,高斯{110}<001>织构含量逐渐增多。高斯取向晶粒较多是由{111}<112>取向晶粒转化而来,同时也证明了CGO硅钢高斯取向晶粒的二次再结晶异常长大生长机制为择优形核。 Microstructure development and texture evolution of conventional grain oriented silicon steel,which were annealed at same annealing temperature and different annealing time under wet H2 atmosphere,were investigated through metallographic observation and electron backscattered diffraction analyzing.The results show that the primary recrystallization finishes in 120 s at 820 ℃ under wet H2 atmosphere.With the extending of annealing time,{111}<112> texture decreases,{111}<110> texture d... 

研究了含铜低碳低硅无取向电工钢中的析出相及其析出机理.由能谱(EDS)及选区电子衍射(SAED)分析可知,铁素体基体上存在的大量弥散分布的等轴状析出相为类B2结构的铜.这些铜析出相的析出机理可以是一般析出、位错析出、台阶机理相间析出和弓出机理相间析出:一般析出在550、650和750℃三个等温温度均可发生;位错析出只发生在较低的等温温度(550℃),此时析出相呈特殊的平行短列状;台阶机理相间析出也可在上述三个等温温度下发生,但650℃等温时最有利于台阶机理相间析出,此时析出相平直列状分布;弓出机理相间析出只发生在较高的等温温度(750℃),析出相弯曲列状分布. Precipitates in low-carbon low-silicon non-oriented electrical steel containing Cu were studied and the precipitation mechanism was analyzed by means of energy dispersive spectrometry(EDS) and selected area electron diffraction(SAED).It is found that the equiaxed precipitates of Cu with B2-like structure distribute dispersively in the non-oriented electrical steel.The precipitation mechanism involves general precipitation,dislocation precipitation,interphase precipitations formed by the ledge me... 

本文以热轧常化板为初始材料,采用二次冷轧法与三次冷轧法制备了0.1 mm厚的取向硅钢薄带,测定相应的磁性能,并通过EBSD取向成像技术检测了二次冷轧法与三次冷轧法各工艺过程中织构与组织演变规律。结果表明,采用最终冷轧压下率适中的三次冷轧法,能在冷轧至0.1 mm时保存较多的高斯晶核,使得高温退火后的磁性能明显优于二次冷轧法。最终冷轧压下率通过影响脱碳退火后样品中的{111}<112>织构组分及Goss晶粒数量对最终二次再结晶产生重要影响。 Grain-oriented silicon steel sheets with a thickness of 0. 1 mm were produced from hot-rolled and normalized sheets by two-step-rolling and three-step-rolling methods. Their magnetic properties were measured,and the textures were detected by EBSD technique. The results show that the three-step-rolling method,which has a moderate reduction rate of final cold rolling,can maintain more { 110} < 001 >nucleus,and thus obtaining better magnetic properties compared with the two-step-method. The f... 

【作者】 宋波； 朱一知； ...

针对某硅钢车间ST机组的除尘系统除尘效率较低、排放浓度不达标、二次污染较严重的问题,通过现场调研,对除尘系统、含尘气体组分与物性参数等进行测试和分析,运用管道伴热技术改善粉尘黏性后,再选取合适的除尘器对粉尘进行除尘处理,大大地提高了系统的除尘效率。 To solve the problems of low dust removal efficiency, substandard emission concentration and severe secondary pollution, some investigations are conducted to test and analyze the dust removal system,dust-gas composition and relevant physical parameters.Moreover, dust removal efficiency is greatly improved by the use of pipe heat tracing technology and by choosing appropriate dust remover.