钢厂
取向硅钢初次再结晶退火工艺正交试验
以试验室模拟CSP工艺生产的Fe-3Si热轧钢带为研究对象,采用正交试验及方差分析的方法,研究了取向硅钢初次再结晶退火工艺对高温退火后获得锋锐的高斯织构的影响。结果表明:取向硅钢两段式初次再结晶脱碳退火工艺参数加热段保温时间及加热温度是高温退火后获得锋锐高斯织构的主要影响因素,其可信度分别在90%和85%以上;在本试验条件下,通过正交试验获得的最佳退火工艺为:冷硬板经600℃保温3 min和850℃保温6 min。 Fe-3Si hot rolled strip was produced by simulating CSP technology in the laboratory.Orthogonal experiment and analysis of variance were carried out to investigate the influence of primary recrystallization on the sharp Goss texture of the oriented silicon steel.The results show that holding time of the heating section and the heating temperature for a sharp Goss texture of the samples annealed has important implications in this experiment conditions,the two-step decarburization annealing process...
余热利用系统在硅钢连续退火机组中的应用
介绍了烟气余热利用系统的工艺流程及控制思想,结合该系统在钢厂硅钢连续退火机组中的应用实践,估算出烟气余热利用系统每年可节约蒸汽5 040 t,经济效益良好,同时分析了该系统存在的问题及对策。 Introduced a method about the process and control of the application of waste heat system, which had been used into a silicon steel continuous annealing line and profiting a good economic benefit by saving a large number of steam every year, which has been estimated about 5 040 tons, and analyzed the problems and solutions existed in this system.
电工钢中柱状晶对热轧和退火时晶粒取向及组织的影响
利用EBSD技术研究了电工钢中长轴平行于轧向的柱状晶样品在热轧和退火过程中组织和取向的演变规律,并与长轴平行于板法向的样品的已有研究结果进行对比。结果表明,无论柱状晶按何种方向排列,只要表面存在剪切力,热轧后都可形成剪切织构,同时中心形成轧制织构,主要包括旋转立方织构和{112}<1-10>。柱状晶造成的影响主要体现在板中心层,长轴平行于轧向排列的样品热轧时形成的粗大旋转立方晶粒要到脱碳退火后才能完全消除,但破坏了正常的不同取向晶粒间的取向差分布及尺寸均匀性,导致二次再结晶不完全及磁性能降低。 The evolution of microstructure and grain orientation in an electrical steel containing columnar grains with its long axis being parallel to the rolling direction of sheet was studied during hot rolling and annealing by EBSD technique.The results are compared with those of samples containing columnar grains being parallel to normal direction of sheet reported in the reference [3].It was shown that,whether the long axis of columnar grains was arranged in RD or ND,shear textures can be formed in t...
硅钢高温氧化铁皮的显微结构表征
利用电子探针面分析、状态分析及电子背散射衍射相分析技术研究硅钢高温氧化铁皮的显微结构。电子探针面分析可以直观的看出元素的分布状态,初步判断氧化铁皮的结构,而状态分析可以准确表征常规氧化铁皮中铁元素的状态,对于合金元素富集区域则通过电子背散射衍射相分析技术来标定。结果表明,高温氧化铁皮的结构主要有4层,即最外层为厚度约为10μm的Fe2O3相,次外层为Fe3O4相,中间层为FeO相上分布有颗粒状的Fe3O4相,最内层为FeO相和Si元素富集的Fe2SiO4相。其中Fe2SiO4层的分布特征与加热温度密切相关:1 100℃时,Fe2SiO4相呈颗粒状,弥散分布在FeO层;1 200℃时,Fe2SiO4相呈液态,侵入基体和疏松的FeO层,且沿着FeO晶界呈网状分布。 The microstructure of high temperature oxide scale on silicon steel was characterized by electron probe microanalyzer(EPMA)mapping analysis,state analysis and electron backscatter diffraction(EBSD)phase analysis.The element distribution and the initial structure of the oxide scale could be detected by EPMA mapping analysis apparently.And the state of iron in the conventional oxide scales could be determined by state analysis.Meanwhile,the alloy-rich region could be identified by EBSD phase analy...
无取向硅钢热轧边裂的形成原因
利用加热炉模拟、动态再结晶以及热模拟等试验方法以及扫描电镜、金相显微镜等分析观察手段对无取向硅钢边裂的成因进行了探讨。结果表明,长时间加热使得板坯边部晶粒异常长大,晶界氧化并脱碳,轧制过程中边部温度过低,动态再结晶过程变弱,使得板坯边部延伸性能变差,是导致硅钢边裂的主要原因。建议通过适当降低铸坯加热温度、缩短保温时间、提高终轧温度来改善硅钢边裂缺陷。 The behaviors of high temperature oxidation,dynamic recrystallization,and hot ductility,microstructure evolution were investigated on the non-oriented electrical steel sheets to discuss the formation of edge crack.The key causes of cracking was found to be the coarse as-cast microstructure,grain boundary oxidation and decarburization in reheating furnace,as well as reduced temperature at strip edge region during hot rolling process resulting in reduced hot ductility and lack of enough dynamic re...
制备{100}织构无取向电工钢方法综述
{100}织构因具有两个易磁化方向能够明显的提高磁性能,因此如何在表面获得具有{100}织构一直是无取向电工钢研究焦点。本文主要介绍了获得{100}织构的主要工艺方法及其基本原理,并结合实际生产过程对各工艺方法的优缺点进行了分析;一方面,优化无取向电工钢的成分,降低碳、锰元素含量以避免脱碳退火和真空退火,简化生产工艺;另一方面,调节升温速度、降温速度和退火气氛,使{100}晶面的表面能或弹性应变能最低,制备具有{100}织构柱状晶组织的无取向电工钢是今后的发展方向。 Because { 100} texture has two easy magnetization directions,which can significantly improve magnetization properfies,how to develop { 100} texture is a focus for researchers and manufactures. In the paper,main manufacturing processes and basic principle are introdued,and their advantages and disadvantages in practical production are analyzed. On the one hand,the production process can be simplified by optimizing chemical compositions,such as reducing the content of C and Mn,which can avoid deca...
电工钢边缘降控制研究
以马鞍山钢铁集团公司电工钢板形优化控制研究项目为背景,系统地研究了热轧、冷连轧和单机架轧机在电工钢生产过程中的边缘降控制问题。通过现场数据采集、工况数值模拟计算和工业化大生产试验,设计出适用、合理的电工钢板形控制的辊型优化曲线,满足了不同工序、不同机型的板形控制策略要求,解决了电工钢板形质量问题,取得了显著的经济效益。 Based on the project of electric steel strip shape optimization control,problem of edge drop control was systematically studied in production of electric steel of hot-rolling mill,cold-rolling mill and single stand mill.Roll optimization contour was designed out in point and reasonable by collection of work condition data,numerical simulation and test of industrial production.The shape control system can meet with the different working steps and difference mills,and quality problem of electric s...
无取向硅钢冶炼过程中的夹杂物遗传变化
研究表明,硅钢中的夹杂物对成品带钢的磁性能有显著影响。为研究冶炼过程硅钢中的夹杂物遗传变化,进而提出更有效的控制措施加以去除,本文结合典型的无取向硅钢生产炉次,采用非水溶液电解提取+扫描电镜观察方法分析冶炼过程中上述炉次典型试样的夹杂物。结果表明:转炉冶炼结束、RH精炼开始时,钢的氧化物夹杂总量最大,约为0.23%;RH精炼过程中,氧化物夹杂总量不断降低,并在脱碳结束时达到最低,约为0.02%;连铸过程中,氧化物夹杂总量仍有不断降低趋势,但夹杂物的平均尺寸变化不大。本试验条件下,中间包试样的夹杂物数量约为1.59×104个/mm3。 As we all know, the non-metallic inclusion effects magnetic properties of silicon steel sheets obviously. The article aims to study the heredity of non-metallic inclusion in non-oriented silicon steels during the steel making process, and then provides a more effective controlling measure to remove the inclusions. Based on the typical non-oriented silicon steel charges, the non-aqueous solution extraction and SEM observation were adopted to analyze the non-metallic inclusions. Results show that,...
锌浴中钛对含硅钢Fe-Zn反应的抑制作用
选用Q235和Q345钢,在纯锌浴和含钛量分别为0.05%、0.10%、0.15%、0.20%(质量分数)的合金浴中浸镀0.5、1、3、5、8 min。利用扫描电子显微镜和能谱仪研究了钛对热浸镀锌组织和生长动力学的影响,并提出钛对含硅钢铁锌反应抑制作用的机理。结果表明:钛的加入缩短了Γ的孕育期,促进了合金层中δ的生长和ζ的消失,δ的生长依然受扩散控制,呈抛物线生长规律;Zn-0.05%Ti锌浴可以很好的抑制高硅钢的硅反应性;含硅钢热浸镀锌钛合金浴时,在锌浴中会形成锌铁钛三元T相,该相能吸收ζ晶界处富集的硅,从而抑制了铁锌反应。 Both Q235 and Q345 steels were immersed for 0.5 to 8 min in Zn bath with different amount of Ti,ranging from 0 to 0.20 mass%,for galvanization.The effect of Ti in Zn bath on microstructure and growth kinetics of hot-dip galvanizing coatings on the two steels were investigated by means of SEM and EDS analysis.Base on the experiment,the mechanism of Ti additions in controlling Fe-Zn reaction was proposed.The results show that addition of Ti in the zinc bath decreases the incubation time of Γ phase...

