硅钢资料

结合实际生产0.4%Si无取向硅钢，统计了不含Sn和0.025%Sn无取向硅钢的磁性能变化，利用金相显微镜、X射线衍射仪观察分析不同成分下试样的显微组织和微观织构。试验结果表明：Sn元素可以显著降低无取向硅钢的晶粒尺寸，0.025%Sn试样的平均晶粒尺寸比不含Sn减小28.4%;加入Sn元素后抑制了无取向硅钢中不利于磁性能的{111}面织构组分强度，提高了对磁性能有利的{100}面织构组分强度，0.025%Sn与不含Sn相比磁感均值从1.756 T提升至1.768 T,铁损均值从5.476 W/kg降低至5.204 W/kg,明显改善了无取向硅钢磁性能。 In this paper combined with the actual production of 0.4% Si non oriented silicon steel, the magnetic properties of non oriented silicon steel without Sn and 0.025% Sn were counted. The microstructure and microtexture of samples with different compositions were observed and analyzed by metallographic microscope and X-ray diffraction. The results show that: Sn can significantly reduce the grain size of non oriented silicon steel, and the average grain size of 0.025% Sn sample is 28.4% smaller tha... 

含铜抑制剂作为取向硅钢的主抑制剂或辅助抑制剂不仅可以抑制初次晶粒的长大,促进二次再结晶,还可以降低铸坯的加热温度。取向硅钢中主要抑制剂为10～50 nm Cu₂S,在钢的铸坯、热轧、冷轧、脱碳等工艺过程均可析出;（Cu,Mn）_1.8S、Cu_1.8S、ε-Cu等主要作为辅助抑制剂,尺寸一般为30～50 nm（或大于50 nm）,主要在热轧阶段析出。总结了国内外有关取向硅钢中含铜抑制剂析出行为的研究进展,当前主要研究不同生产流程和工序中含铜抑制剂的析出行为和作用机理。 As main inhibitor or auxiliary inhibitor for grain-oriented silicon steel,the particles of inhibitor bearing copper not only inhibit the primary crystal growing and promote the secondary recrystallization,but also decrease the heat temperature of casting slab.The main inhibitor for grain-oriented silicon steel is 10～50 nm Cu₂S,which precipitate in process and procedure including steel casting slab,hot rolling,cold rolling and decarburizing process,while the 30～50 nm or more than 50 nm... 

稀土元素在许多钢中发挥着独特而且不可替代的重要作用。半个世纪以来,它的作用已经在各种低合金和特殊合金钢中的研究及应用中得到充分的证明;然而,作为具有稀土资源优势的中国,在属于重要功能材料的无取向电工钢中稀土的应用却落后于国外,本文就中国稀土在无取向电工钢中的应用研究作简要的评述,希望能够进一步推进此领域的研究,并且促进中国稀土在无取向电工钢中应用技术的发展,缩短与国外差距,并提出了在此应用领域今后需深入开展的研究方向。 Rare earth elements play a unique and irreplaceable role in a lot of steels,it has given the full proof by the practice of various low alloy steels and special alloy steels since half century.However,as our country has the advantage of rare earth resources,RE application technology in non-oriented electrical steels has lagged behind abroad.The application researches of rare earth in non-oriented electrical steel in our country are briefly reviewed in this paper,which hope to promote the research... 

利用DSC、XRD,结合热焓分析对硅钢级氧化镁和二氧化硅的固相反应行为进行了研究。比较了不同二氧化硅原料及混合方法对硅钢级氧化镁反应性的影响,找到了一种更为有效的硅钢级氧化镁反应性的评估方法,克服了传统柠檬酸活性法在比较不同厂家生产的氧化镁的反应性上的局限性。进一步研究了Na₂B₄O₇添加剂、TiO₂添加剂对氧化镁和二氧化硅反应行为的影响,结果表明,Na₂B₄O₇添加剂含量的增加对反应有利,而TiO₂添加剂对反应有阻碍作用。 The solid-state reaction behavior between silicon-steel grade MgO and SiO₂ was investigated by DSC and XRD combined with enthalpimetric analysis.The influence of different kinds of SiO₂ and different preparation methods were studied and a specifical measurement that is more reliable was proposed to evaluate reactivity of silicon steel grade MgO.It overcomes the limitation of the traditional citric acid activity（CAA） method,which can not be used to evaluate the reactivity of... 

【作者】 胡志强； 张文康； ...

针对硅钢连续退火机组的主要能源介质消耗现状,对现有生产工艺和设备研究采取机组循环用水、增加清洗段漂洗级数等措施可节约大概27 m3/h的过滤水量,并可减少78%的弱碱处理量;将炉子烟气换热系统增加一级余热回收,每年回收的余热相当于583 t标煤消耗,可节约蒸汽5 368 t。 The present situation of energy consumption for silicon steel annealing line is analyzed in this paper.In existing process and equipment conditions,increasing the number of cleaning series will lead to a saving of about 27 m3/h of filter water and reduce 78 % of weak base processing volume.For the flue gas heat-exchange system,adding a waste heat recovery device will recover waste heat equivalent to 583 tons of standard coal per year,corresponding to a saving of steam 5 368 t per year. 

为了弄清楚高硫硅钢中的硫化物析出行为及其对钢的微观组织和电磁性能的影响，以便为工业化生产制定更为合理的硫含量控制标准和采取更为有效措施减轻炼钢生产的硫含量控制压力，结合0.25% Si 无取向硅钢 ，采用非水溶液电解提取 + 扫描电镜/透射电镜观察相结合的方法 ，研究了0.006 8%、0.010 2%、0.025 5% 和 0.035 3% 硫含量条件下，钢中的硫化物夹杂物组成和存在形式及其形貌、种类、尺寸、数量变化，以及相应的热轧、成品试样的微观组织和电磁性能变化。结果表明，随着钢中硫含量的增加，钢中的硫化物逐渐由 MnS→MnS+Cu₂S→Cu₂S转变，数量逐渐增多，尺寸向高低两个方向发展。相应地，导致热轧再结晶组织劣化和抑制了成品晶粒尺寸长大。随着钢中硫含量的增加，钢的磁感、铁损劣化程度逐渐增大。钢中的硫含量平均每增加 0.01%，涡流损耗、磁滞损耗分别劣化0.24 W/kg 和 0.41 W/kg，而磁感会劣化 0.009 T。但是 ，在硫含量为 0.010 2% 时 ，铁损可以低于 6.0W/kg，而在硫含量为 0.025 5% ... In order to find out the precipitation behavior of sulfide inclusions and the corresponding changes of microstructure and electromagnetic properties of high sulfur silicon steel sheets, so that to design more suitable sulfur concentration controlling limit for industrial manufacture and to release the steel-making difficulty effectively, Based on the change of given sulfur concentration 0.006 8%, 0.010 2%0.025 3% and 0.035 3%, the type and composition, the size and number, and the size distribut... 

研究了取向硅钢制备过程中常见的两种冷轧工艺,主要研究了一阶段冷轧与两阶段冷轧+中间退火工艺对初次再结晶组织及织构的影响.结果表明:采用两阶段冷轧+中间退火工艺制备以Cu2S为主抑制剂的取向硅钢,其初次再结晶平均晶粒尺寸为18.1μm,高斯晶粒的体积分数为0.6%,迁移性强的重位点阵晶界(Σ5+Σ9)和高能晶界(20°~45°取向偏差角)所占比例分别为1.8%和50.4%.与一阶段冷轧工艺相比,其初次再结晶晶粒较细,且高斯晶核与特征晶界所占的比例较高,有利于高斯晶粒发生二次再结晶. Two common cold-rolling processes of grain oriented silicon steel and the effects of the single stage cold rolling and tw o-stage cold rolling w ith intermediate annealing processes on the primary recrystallization microstructure and texture w ere investigated. The results revealed that for the grain oriented silicon steel prepared under the tw o-stage cold rolling process w ith intermediate annealing w ith Cu 2 S as the main inhibitor,the average grain size of the primary recrystallization micr... 

【作者】 王桦； 舒子龙； ...

利用场发射扫描电镜观察了以MnS为主要抑制剂的普通取向电工钢加工过程中第二相粒子的分布状态,统计了粒子面密度、平均尺寸以及相应的尺寸分布.结果显示,热轧加工造成了大量第二相粒子弥散、细小地析出,同时基体仍保持过饱和状态.冷轧变形会造成第二相粒子的回溶行为,而基体的过饱和状态会减弱回溶现象.中间退火与脱碳退火过程中会同时存在新粒子的形核及已析出粒子的粗化两个过程,而在最终二次再结晶升温阶段则以第二相粒子明显粗化为主. The distribution of second phase particles in conventional grain-oriented electrical steels during manufacturing processes with MnS as inhibitors was observed by field emission scanning electron microscopy,while the areal particle density,the average particle size and the corresponding size distribution were statistically determined.It is indicated that hot rolling leads to dispersive precipitation of a large amount of fine second phase particles and the matrix keeps a supersaturated state furth... 

【作者】 刘玲月； 李军辉； ...

就冷轧硅钢废水处理生产中面临的主要问题进行分析,从技术角度及运行管理角度提出工艺优化升级改进措施及应对策略;同时从后续深度处理,逐步实现零排放目标的角度进行探讨,为冷轧硅钢废水减量化、出路乃至废水零排放提供一些思路。 The main problems in the wastewater treatment process of cold-rolled silicon steel lines are analyzed and process upgrading measures and optimization strategy are put forward from both technical and management views.At the same time,downstream deep treatment to gradually achieve the target of zero discharge is discussed,to provide some ideas for reduction or even zero discharge of wastewater from cold-rolled silicon steel lines.