硅钢资料

主要研究了0.7%Si无取向电工钢退火试样的组织、晶粒尺寸和织构对其磁性能的影响。结果表明,随着退火温度的升高,晶粒尺寸逐渐增大,组织的均匀性得到改善;ɑ取向线上的纤维织构多集中于{114}<110>和{223}<110>附近,再结晶结束后,织构含量变化不大。{111}<110>织构取向密度值随温度升高而下降,{112}<111>织构与{111}<110>织构变化相反。晶粒尺寸增大对磁感强度的影响较小,而对铁损的影响较大。 Influences of microstructure,grain size and texture on the magnetic properties of 0.7% Si non-oriented electrical steels annealed samples were studied.The results show that with annealing temperature increasing the average grain size is increased gradually.Uniformity of the microstructure is improved;the textures of ɑ-fiber gathered in the vicinity of the { 114} < 110 > and { 223 } < 110 > texture.After recrystallization,the volume fraction of texture changes small.{ 111} < 110 &g... 

Fe-6.5%Si高硅钢是一种具有高磁导率、低矫顽力和低铁损等优异软磁性能的合金,但是其室温脆性和低的热加工性能严重影响了其在工业领域的应用。综述了Fe-6.5%Si高硅钢的性能,评述了合金的改性法、特殊轧制法、快速凝固法、沉积扩散法、粉末冶金法等制备工艺。 It is well known that 6.5%Si high silicon steel is one kind of soft magnetic materials with higher re-lative permeability,lower coercive force and iron loss than those of conventional industrial silicon steel.However,their room-temperature embrittleness and poor workability limit their practical applications in the industry.The pre-paration technique such as modification treatment on alloy,special rolling,rapid solidification,CVD and powder me-tallurgy is reviewed. 

通过后天抑制剂获得法制备了取向硅钢,对渗氮前后和高温退火升温阶段析出物的析出和转化规律进行了研究。研究结果表明,渗氮前脱碳退火态基体中存在少量的粗大AlN颗粒和细小AlN颗粒,渗氮处理后新析出大量的Si3N4析出物,高温退火升温阶段Si3N4将转化为(Al,Si)N,随着温度的继续升高(Al,Si)N颗粒将发生粗化,(Al,Si)N是后天抑制剂获得法制备取向硅钢的主要抑制剂。 Grain-oriented silicon steels were produced by acquired inhibitor method.The rule of precipitate transformation was studied after nitriding treatment and high-temperature finishing annealing.The results show that a small amount of large AlN and fine AlN are found in matrix before nitriding treatment,and a large amount of Si3N4 is precipitated in matrix after nitriding treatment.During the temperature rising period of high-temperature finishing annealing,Si3N4 would transform into(Al,Si)N,and(Al,... 

以青海盐湖氯化镁为初级原料,采用喷雾热解法制备原料氧化镁。原料氧化镁通过水化制备氢氧化镁。将氢氧化镁过滤、洗涤、烘干、粉碎、煅烧,制备硅钢级氧化镁。本文重点考察煅烧温度、煅烧时间、料层厚度等因素对氧化镁水化率的影响,采用均匀实验设计和DPS数据处理,确定最优煅烧实验条件为:煅烧温度1250℃,煅烧保温时间4小时,料层厚度0.5cm。在此条件下得到的硅钢级氧化镁完全满足硅钢及氧化镁的行业标准。 The magnesium oxide is prepared by Spray pyrolysis process,which magnesium chloride from Qinghai Salt Lake is used as primary raw material,and hydrated to magnesium hydroxide,then obtained silicon steel magnesia through filtering,washing,drying,crushing and calcinations.In this paper,influences of some factors on magnesia hydration rate are studied,such as calcination temperature,calcination time and material thickness.After average experimental design and DPS data processing,optimal calcination... 

采用电子背散射衍射技术测定50SW1300冷轧无取向硅钢中不同尺寸范围晶粒的含量,利用主成分回归分析法,综合研究不同尺寸范围晶粒的含量对无取向硅钢磁性能的影响。结果表明:通过主成分回归分析法能够从不同尺寸范围晶粒的含量的多个影响因素中获取主要的因素,定量研究它们对无取向硅钢磁性能的影响规律。分析表明,无取向硅钢的铁损与不同尺寸范围晶粒的含量之间存在着可靠的多元线性关系,在一定范围内,较大尺寸晶粒的含量越多,其对铁损优化的作用越明显;而无取向硅钢的磁感与不同尺寸范围晶粒的含量之间并无线性关系。 Distribution of grain size in cold rolled non-oriented silicon steel 50SW1300 was measured by EBSD.The effects of the distribution of grain size on magnetic properties of the non-oriented silicon steel were comprehensively researched by means of principal component regression method.The results indicate that the main factors influencing the magnetic properties in the distribution of grain sizes,which can be used to guantitative study the magnetlic properies of the steel,are obtained by principal... 

对应用动态加热进行短时温度退火的取向电工钢进行了二次再结晶研究。所进行研究的实验用取向电工钢是经过终冷轧和后续罩式退火后的一条工业化生产线生产的。研究结果表明,运用短时热处理条件可引起研究钢完全的异常晶粒长大。在实验室处理的材料的织构和金相组织与工业化生产的经过终退火而获得的相同的取向电工钢类似。但是,在实验室处理的取向电工钢的二次再结晶的矩阵中可观测到\"寄生\"晶粒。从磁性观点看,这些\"寄生\"晶粒含有不理想的{111}取向织构。 The present study was made to investigate secondary recrystallization in grain-oriented steels annealed at short time temperature exposures with application of dynamical heating.The investigated GO(Grain Oriented) steels for experiments were taken from one industrial line after final cold rolling reduction and subsequent box annealing.It was shown that application of short time heat treatment conditions could lead to complete abnormal grain growth in the investigated GO steel.The texture and mic... 

连续酸洗退火机组(CPAL)对于当前生产高磁感取向硅钢和高牌号无取向硅钢是必不可少的一个环节。常化炉是常化酸洗机组关键的组成部分。本文对国内自主建造的两条退火酸洗机组的工艺流程,特别是常化炉段进行了对比分析。总结出了常化炉的工艺及组成特点,对生产过程中暴露的问题进行了仔细的分析并提出了改进的意见,对于以后新建常化炉具有一定的提示作用。 The continous pickling annealing line(CPAL) is an essential step in producing high magnetic induction grain-oriented silicon steel and high grade non-oriented silicon steel.The normalizing furnace is a very important part of the CAPL.In this paper,the process flows of two CAPL with independent manufacture in our country have been compared,especially the part of normalizing furnaces.The characteristics of process and component are summarized and problems of the normalizing furnace during the prod... 

为了确定普通冷轧取向硅钢最优的中间完全脱碳退火工艺,在其一次冷轧后进行5种不同工艺的脱碳退火处理,借助扫描电镜及电子背散射衍射技术研究了不同工艺脱碳退火后的组织、织构和脱碳效果。结果表明:经5种工艺脱碳退火处理后,初次再结晶的平均晶粒尺寸均约为19μm,且不随退火温度和时间的变化而变化;经840℃×10min工艺退火后的晶粒最均匀,高斯织构位向更准确,高斯织构面积分数最多,为3.1%,可将碳脱至0.003 5%。 In order to determine the optimal intermediate complete decarburizing annealing processes for common grain-oriented(CGO)silicon steel,five kinds of intermediate decarburizing annealing processes were conducted,the microstructure,texture and decarbonization after different decarburizing annealing processes were studied by scanning electron microscopy and electro back-scattered diffraction(EBSD)technology.The results show that the average grains sizes of primary recrystallization were about 19μm a... 

抑制回硅是低硅品种钢冶炼的重点和难点,南钢中厚板卷厂通过转炉出钢弱脱氧操作,精炼炉弱脱氧升温,脱氧、脱硫造渣,连铸严格的保护浇注及吹氩塞棒、吹氩浸入式上水口的应用等一系列工艺优化和操作的改进,使整个冶炼过程钢水回硅量稳定控制在200×10-6以内,钢水终点成分完全满足低硅钢要求。 Control of increasing silicon is the emphasis and difficulty in low silicon varieties steel smelting.The Nisco Wide Plate/Coil Plant can control the silicon content in molten steel keeping within 200×10-6 through whole steelmaking process by using oxygen residual operation in converter tapping,oxygen residual and increasing temperature,deoxidation,desulfurization,slag refining,protection cast,blowing argon by plugged nozzle,blowing argon by submerged entry nozzle in continuous casting,and other ... 

采用Nb对Fe-6.5%Si(质量分数)高硅钢进行微合金化处理,结果表明:Nb在高硅钢薄板制备过程中细晶效果明显.铸态、锻态和热轧态组织的晶粒分别细化了17.50%,24.51%和30.13%.铸态样品压缩强度由1365 MPa提高至1520 MPa,延伸率提高77.78%;温轧板试样室温拉伸强度由573 MPa提高至621 MPa,延伸率提高44.44%.利用XRD对厚度为0.30—1.68 mm的温轧板的板面织构演变过程进行跟踪测量,结果发现:初始织构以(011)〈100〉Goss织构为主,单道次变形量为26.2%的情况下,Goss织构完全转化为(100)〈011〉旋转立方织构,随后,在单道次变形为22.6%的情况下,旋转立方织构完全转化为{111}面织构,即纤维织构,并稳定保持至0.30 mm. Fe-6.5%Si（mass fraction） alloy possess perfect magnetic properties,though intermetallics of Fe₁₄Si₂ phase brought 6.5%Si leads to room temperature brittleness and hinder this significant materials industrialization.Nb was adopted into micro-alloying of Fe-6.5%Si high silicon steel. OM,thermal simulated test machine and XRD were employed to study the influence of Nb on high silicon steel in processing stages.Textures of warm-rolled high silicon steel strips were determined b... 

采用双辊薄带连铸工艺制备了厚度为2.4mm的3.98%Si-0.71%Al无取向硅钢带,经常化、冷轧、不同温度退火后,对其显微组织、析出物、织构和磁性能进行了检测分析。结果表明:随着退火温度的提高,退火板晶粒尺寸增大,组织均匀性提高;退火板析出物主要是AlN和MnS与AlN复合析出物,尺寸较粗大,达0.5~2.5μm;退火板织构沿厚度方向变化明显,表层和1/2层存在较强的{100}织构,1/2层还存在较强的{111}织构,1/4层主要是{112}织构;随退火温度的升高相应的铁损和磁感应强度均降低。 Using twin roll thin strip continuous casting technique,the 3.98%Si-0.71%Al no-oriented silicon steel strip in thickness of 2.4mm was produced.The microstructure,precipitates,texture,and magnetic properties of the sheet after normalizing,cold rolling and annealing at different temperatures were studied.The results show that with annealing temperature increase,the grain size and uniformity of annealed sheet increased.The main precipitates in coarse size of 0.5-2.5μm in annealed sheet were AlN and... 

以一种新的Fe-Si合金制备工艺为出发点,研究了不同放电等离子体快速烧结工艺(SPS)和Si含量变化对Fe-Si合金材料显微组织与磁性能的影响。结果表明,在烧结温度为1 000℃时制备的Fe-6.5%Si合金(质量分数,下同)的综合磁性能较好,其在50Hz下的铁损为0.549W/kg,最大磁感应强度为0.124 3T,矫顽力245.6 A/m,磁导率0.338mH/m。另外,材料的最大磁感应强度随Si含量的增加显著增长,1 000Hz下,Fe-10.0%Si的最大磁感应强度可达到Fe-6.5%Si合金的5倍左右。 The effects of Si content and SPS technology on microstructure and magnetic properties of Fe-Si alloy material were studied in the paper.It shows that the magnetic properties are the best when the content of Si is 6.5wt% and the sintering temperature is 1 000℃,the iron loss is 0.549W / kg in 50Hz,maximum magnetic induction is 0.124 3T,coercive force is 245.6A / m and permeability is 0.338mH / m。And,the maximum magnetic induction increases significantly with the increase of Si.The maximum magneti...