硅钢资料

【摘要】 <正>2012年3月29日中国钢铁工业协会在上...

研究了CSP流程试制50W270高牌号无取向硅钢热轧→常化→冷轧→退火过程中织构的演变.利用电子背散射衍射技术对全流程织构进行测量和分析.发现热轧板织构在厚度方向上存在较大差异,表层主要为铜型、黄铜和高斯织构,1/4层存在微弱的高斯织构和旋转立方织构,中心层以γ纤维织构和旋转立方织构为主,还含有较弱的α纤维织构.与热轧板相比,常化板表层和1/4层织构变化不大,中心层旋转立方织构和α纤维织构增强.冷轧板各层均具有α纤维织构和γ纤维织构.与冷轧板相比,成品板各层中α纤维织构基本消失,还出现了立方织构和高斯织构. This article focuses on texture evolution in 50W270 high-brand non-oriented silicon steel produced by CSP in hot rolling,normalizing,cold rolling,and annealing processes.The texture in the whole process was measured and analyzed by electron back-scatter diffraction.It is found that the texture along the thickness direction in hot-rolled strips changes obviously;there are mainly copper,brass,and Goss textures in the surface layer;the 1/4 layer has weak Goss texture and rotating cube texture;γ-fib... 

【作者】 卢鹏； ...

近年来，在节能减排背景之下，国内外众多研究者对无取向电工钢磁性能的提升做了大量研究。为了探索无取向电工钢磁性能提升的方法，对锡或锑对无取向电工钢磁性能的作用机制(晶粒尺寸和晶体织构的控制)进行分析。基于该作用机制，介绍锡或锑的添加对无取向电工钢磁性能的影响。经研究发现，适量的锡或锑在晶界偏聚，不会阻碍晶界的移动并且致使晶粒尺寸降低；与此同时，锡或锑在晶界偏聚不仅抑制{111}织构在原始晶界处形核及生长，还降低(100)晶粒表面能，促进(100)晶粒生长。因此，适量添加锡或锑，可使无取向电工钢铁损下降、磁感提升。最后结合生产工艺，建议无取向电工钢的研究方向应为稀土含量对高牌号无取向硅钢夹杂物尺寸和数量分布的影响，锡或锑的添加量和常化工艺参数(常化时间、常化温度)对常化晶粒尺寸的影响。 In recent years, due to the background of energy saving and emission reduction, numerous researchers all around the world have done a lot of investigations on the improvement of magnetic properties for non-oriented electrical steel. In order to explore the method of improving the magnetic properties of non-oriented electrical steel, the mechanism of tin or antimony on the magnetic properties(the control of grain size and crystallographic texture) of non-oriented electrical steel is illuminated. ... 

【作者】 王桦； 舒子龙； ...

概述了无抑制剂法生产取向电工钢的特性及其用途;总结无抑制剂生产取向电工钢的原理及工艺方案.重点讨论了成分方案,即元素对磁性能的影响和最终高温退火方案对二次再结晶的影响.研究结果表明,无抑制剂取向硅钢化学成分范围没有普通取向硅钢和高磁感取向硅钢严格,提高了成材率;最终高温退火决定了二次再结晶的好坏,从而最终决定成品磁性能,最佳的高温退火温度在850～950℃之间. This article provides an overview on the characteristics and uses of inhibitorless process producing grain-oriented electrical steels.The mechanism of inhibitorless process and technology programs were discussed.The results show that the chemical composition and final annealing were determined according to magnetic properties.The inhibitor-free grain oriented silicon steel has loose range of chemical composition;Secondary recrystallization occurs mainly in the final annealing and the best anneal... 

通过金相分析和电子背散射衍射技术研究了一种新型含铜无取向电工钢在950℃退火不同时间(3～180s)空冷后的组织和织构取向的演变。结果表明:该钢在退火3s时的主要织构为α和γ线织构,{100}<110>织构最强;退火20s时织构以<111><112>、{111}<110>、{112}<110>、高斯织构和立方织构为主,随着退火时间的延长,高斯织构和立方织构强度呈减弱趋势;合理控制保温时间有利于提高{100}、{110}面织构的占有率。 Evolution of microstructure and texture oriented of a new non-oriented electrical steel during annealing at 950℃for different times(3-180) s and air cooling was studied by metallography and electron back-scattering diffraction analysis.The results show that after annealing for 3 s most of the texture oriented alongα-fibre andγ-fibre,the intensity of {100}〈110〉was the strongest.{111}〈112〉,{111}〈110〉,{112}〈110〉,Gauss texture and cube texture were the main texture after annealing for 20 s,with the ... 

通过对激光粒度分析仪测量硅钢级氧化镁(MgO)的分析条件进行优化,如分散介质、分散方式、样品预处理、仪器暗淡度等,探讨了硅钢级MgO粒度范围测量重现性较好的试验方法,满足硅钢生产过程控制对MgO粒度的要求。 The analysis condition of the laser particle size analyzer on grain oriented silicon-steel grade magnesium oxide is optimized,including the dispersion medium,dispersion methods,sample preparation,and instrument obscuration,etc.Therefore,particle size measurement with good reproducibility for silicon-steel magnesium oxide is discussed,which may meet the requirement of MgO particle size for silicon-steel process control. 

运用EBSD和光学显微镜,研究了0.25%~0.45%Cu对无取向电工钢热轧板显微组织,成品板显微组织、织构和磁性能的影响。实验结果表明:卷取过程中Cu元素在热轧板表层的偏聚作用显著阻碍了热轧板表层再结晶晶粒长大,导致热轧板表层晶粒尺寸随着Cu含量增加而逐渐较小,但热轧板中间晶粒尺寸变化不大。同时发现Cu元素能够明显改善织构类型,使有利织构组分增加,不利织构组分减少,同时减弱织构强度。从实验结果可知0.35%Cu能够显著改善电工钢的磁性能,铁损P15/50最低达到4.1 W/kg,磁感B50最高值达到1.8 T。 Effects of high content Cu on microstructure of hot rolled plates and microstructure,texture and magnetic properties of annealed finish product plates of non-oriented electrical steel were examined by means of EBSD technique and optical microscope. The results show that surface segregation of Cu significantly hindered recrystallized grain growth of surface layer in hot rolled plate during the coiling,as a result,the surface grain sizes of the hot-rohed plates decrease with the increase of Cu con... 

研究了硅钢铸坯再加热过程中夹杂物的析出行为。采用非水溶液电解提取+扫描电镜观察方法,观察了试样的显微组织,统计了夹杂物的尺寸、种类、数量、分布。结果表明,均热温度为1 523 K时,水淬试样的夹杂物尺寸绝大部分小于0.5μm,0.5～5.0μm的夹杂物数量很少,没有发现5.0μm以上的夹杂物。此外,均热时间为10、30、60、90、120、240 min时,对应试样中0.05～0.2μm的夹杂物数量分别为4.04×104、4.73×104、3.70×104、3.33×104、3.10×104、1.56×104个/mm3。绝大部分夹杂物以MnS、AlN、CuxS类为主,并以三类夹杂物中的两类复合或三类复合居多。三类复合夹杂物总量占每组试样夹杂物总量的90%或以上。随均热时间延长,典型的夹杂物组成会发生如下变化:MnS+AlN+CuxS MnS+AlN AlN。与此同时,MnS、AlN、CuxS三者复合比例从45.2%(均热10 min)降为9.7%(均热240 min)。 The methods of electrolysis extraction from nonaqueous solution and scanning electron microscope were adopted to study the precipitation behavior of non-metallic inclusions in Si steel slabs during reheating processes.The morphologies,chemical compositions,quantity and size distribution of non-metallic inclusions in these steel samples were analyzed.Results show that,when the soaking temperature is 1 523 K,almost all of the non-metallic inclusions are smaller than 0.5 μm,few are in the range of ... 

采用XRD、SEM和激光粒度仪等手段,观察并研究了不同特性氧化镁在硅钢表面形成硅酸镁底层形貌特点,并结合热力学和差热-失重分析了MgO-SiO2的反应机理。研究结果表明:粒度小,活性值高的特种氧化镁在高温退火过程中与基体表面氧化物生成的硅酸镁底层,界面中硅酸镁底层嵌入基体较多,表面致密,颗粒细小,有利于形成附着性能优良的硅酸镁底层。 Surface microstructure of Mg2SiO4 coatings formed on the surface of oriented silicon steel coated with different kinds of MgO was investigated by XRD and SEM.The reaction mechanism between MgO and SiO2 was analyzed by TG-DSC and thermodynamic calculation.Results revealed that when the MgO with finer microstructure size and higher activity is employed,a dense Mg2SiO4 layer with finer microstructure and good binding to the steel substrate can be obtained.The results are very helpful for the prepar... 

以水氯镁石为原料,采用氨法沉镁-煅烧-添加剂的方法制备硅钢级氧化镁。考察了反应温度、反应pH值、陈化时间对中间体氢氧化镁纯度及转化率的影响;研究了煅烧温度和煅烧时间对氧化镁水化率的影响及添加剂的量对氧化镁悬浮性能的影响。控制实验条件为:反应温度55℃,pH值为9.5,陈化时间2h,煅烧温度1050℃,煅烧时间2h,添加剂量为0.8%,制得氧化镁的纯度为98.99%、水化率为2.92%、悬浮性能为3mm/h,达到硅钢级氧化镁的要求。 Using bischofite as raw material,the preparation of magnesium oxide with silico-steel grade was studied.The effects of reaction temperature,reaction pH value and aging time on the intermediate magnesium hydroxide purity and conversion rate were studied.Calcinations temperature,calcinations time relationship to the hydration rate of MgO and amount of additive to the suspension performance of MgO were investigated.The results indicated that the optimum technological conditions were as follows:reac...