钢厂
ICP-AES法测定硅钢中铌的不确定度评定
分析了电感耦合等离子体发射光谱法(ICP-AES)测定硅钢中铌的检测过程,讨论了该检测过程中不确定度的主要来源,建立了该方法的定量的数学模型,并根据这一模型计算出了检测结果的合成标准不确定度和扩展不确定度。 The measurement of niobium content in silicon steel by inductively coupled plasma atomic emission spectrometry(ICP-AES) was analyzed,by which the main factors affecting the uncertainty of the measurement were ascertained and the calculation formula was given.Finally,according to the formula the combined uncertainty and expanded uncertainty were obtained.
薄带连铸取向硅钢的热轧孪生行为
薄带连铸流程下取向硅钢粗大λ晶粒(〈100〉//ND,normal direction)的“遗传”会导致磁性能恶化.为解决这一问题,针对取向硅钢的热轧孪生行为开展研究,结果表明:凝固组织粗大的取向硅钢在650℃热轧时可产生大量{112}〈111〉形变孪晶,这与具有高层错能的硅钢在较高温度下难以孪生变形的传统认知不同.热轧过程中复杂的应力状态降低了变形孪晶的取向依赖性,由于具有更高的储存能,孪晶界/孪晶界及孪晶界/晶界交叉点成为再结晶形核的优先位置,大大提高了常化过程中的再结晶率,受沿孪晶界应变分布及孪晶间距离的限制,沿孪晶界形核的再结晶晶粒通常呈“饼状”,最终形成以细小且取向漫散的再结晶晶粒为主的常化组织,消除了初始凝固组织中有害的粗大λ晶粒. In strip casting grain-oriented silicon steels, the inheritance of coarse λ grains(〈100〉//ND, normal direction) can deteriorate their magnetic properties. To solve the problem, twinning behaviors in strip casting grain-oriented silicon steels during hot rolling were investigated in this work. It is found that after rolling at 650 ℃, a number of {112}〈111〉deformation twins are formed in the coarse solidification microstructure of the steels, in contrast to the well-accepted view that it is diffic...
Fe-6.5%Si高硅钢铁芯与Epstein Square标准单片铁损检测结果对比及数据差异分析
作为一种具有优异高频铁磁性能的合金,Fe-6.5%Si(质量分数)高硅钢在高频工况条件下降损效果明显,对电气行业应用器件高频化、小型化、节能等具有十分重要的意义。通过与取向硅钢测量B-P数据对比,验证了高硅钢高频超低损特性,且轧制高硅钢与日本CVD法生产高硅钢存在基本相同的铁损值。采用国标Epstein Square法对0.30mm高硅钢薄板进行单片测试,并对由0.30mm高硅钢薄板首次装配成的电感器进行铁损测试,对比测试结果表明,元件测试与单片测试数据基本吻合,高磁感应强度条件下,元件测试结果略低于单片测试,分析原因为:线圈引起励磁压降;元件叠片间出现短路,电流增大,损耗增加;气隙板厚度过大。 As one core material with excellent high-frequency ferromagnetism,Fe-6.5%Si performs obviously reduction on core loss in high field frequency which means much to high frequency,minimization,energy conservation in electric industry.Super low loss was verified by drawing B-P curves based on detected experimental data,and which went equal to Fe-6.5%Si thin strip fabricated by CVD in Japan.Fe-6.5%Si was firstly fabricated as inductor in this research,and its core loss was determined for comparison w...
CSP流程试制50W270高牌号无取向硅钢织构的演变
研究了CSP流程试制50W270高牌号无取向硅钢热轧→常化→冷轧→退火过程中织构的演变.利用电子背散射衍射技术对全流程织构进行测量和分析.发现热轧板织构在厚度方向上存在较大差异,表层主要为铜型、黄铜和高斯织构,1/4层存在微弱的高斯织构和旋转立方织构,中心层以γ纤维织构和旋转立方织构为主,还含有较弱的α纤维织构.与热轧板相比,常化板表层和1/4层织构变化不大,中心层旋转立方织构和α纤维织构增强.冷轧板各层均具有α纤维织构和γ纤维织构.与冷轧板相比,成品板各层中α纤维织构基本消失,还出现了立方织构和高斯织构. This article focuses on texture evolution in 50W270 high-brand non-oriented silicon steel produced by CSP in hot rolling,normalizing,cold rolling,and annealing processes.The texture in the whole process was measured and analyzed by electron back-scatter diffraction.It is found that the texture along the thickness direction in hot-rolled strips changes obviously;there are mainly copper,brass,and Goss textures in the surface layer;the 1/4 layer has weak Goss texture and rotating cube texture;γ-fib...
硅钢水溶性极厚绝缘涂层的热老化行为研究
对两种硅钢水溶性极厚绝缘涂层进行了不同温度的热老化实验。通过TG-DTA,GDS,FT-IR,SEM和光泽度仪等测试方法对老化的涂层进行分析表征,提出了评估硅钢水溶性极厚绝缘涂层热老化性能的合理温度区间,探讨了涂层热老化行为,并分析了两种涂层热老化性能的差异。结果表明,涂层附着性随着老化时间的延长逐渐下降。FT-IR表征结果显示,热老化过程中,涂料交联形成的化学键未发生断裂,交联剂氨基树脂的三嗪环被破坏是聚合物三维网络结构坍塌的主要原因。 Thermal aging expriments at different temperature were carried out on two types of water-soluble and extra-thick insulation coatings for non-oriented silicon steel,and a series of test methods such as glossmeters,TG-DTA,FT-IR,GDS,SEM were applied in analysis.For evaluating the thermal aging effect of this kind of insulation coating,the proper temperature range was proposed.The difference of aging performance between two coatings was been investigated and the related behaviors were been discussed...
硅钢高温退火环形炉炉壳制作与安装技术
硅钢高温退火环形炉炉壳制作与安装精度要求较高,施工时通过对壳体原材料矫正、炉壳板拼焊、下料切割、型钢骨架组装及焊接、骨架及炉壳板矫正、骨架与炉壳板组装及焊接、炉壳矫正、零配件装置、定位钻孔、报验检查、出厂、内侧板安装、外侧板安装、顶板安装等环节的工艺技术控制,能保质高效地完成硅钢高温退火环形炉炉壳制作与安装,为以后同类工程的施工提供可借鉴经验。 The required precision of manufacture and installation technique of the silicon steel high temperature annealing annular-furnace shell is high.During construction , manufacture and installation of the silicon steel high temperature annealing annular-furnace shell could be finished high efficiently through correcting the raw materials of shell , furnace shell plate welding , material cutting , steel frame assembly and welding , skeleton and shell plate correction , skeleton and furnace shell asse...
Fe-6.5%Si高硅钢的性能及制备技术
Fe-6.5%Si高硅钢是一种具有高磁导率、低矫顽力和低铁损等优异软磁性能的合金,但是其室温脆性和低的热加工性能严重影响了其在工业领域的应用。综述了Fe-6.5%Si高硅钢的性能,评述了合金的改性法、特殊轧制法、快速凝固法、沉积扩散法、粉末冶金法等制备工艺。 It is well known that 6.5%Si high silicon steel is one kind of soft magnetic materials with higher re-lative permeability,lower coercive force and iron loss than those of conventional industrial silicon steel.However,their room-temperature embrittleness and poor workability limit their practical applications in the industry.The pre-paration technique such as modification treatment on alloy,special rolling,rapid solidification,CVD and powder me-tallurgy is reviewed.
真空感应炉熔炼高硅电工钢脱氧工艺的研究
在50Kg氧化镁坩埚真空感应炉上进行高硅电工钢的脱氧试验。结果表明,通过控制原料的成分、高真空下的碳氧反应和炉衬分解向钢液中的供氧,可使钢液的总氧含量≤15×10-6;在维持高温高真空条件下,当钢液中的反应达到一定程度后,延长精炼时间并不能降低钢液的总氧含量;完成精炼后加入硅钙合金沉淀脱氧可进一步降低钢液的总含氧量,但脱氧效果有限。 The test of high-silicon electric steel deoxidation has been carried out in 50Kg vacuum induction furnace with magnesium oxide crucible.Results show that the total oxygen could be ≤15×10-6in molten steel by controlling material components,carbon-oxygen reaction in high vacuum and oxygen contamination from crucible materials on molten steel;And when the reaction was carried through to a certain extent,total oxygen in molten steel could not be reduced by the extension of refining period in high va...
锰含量对无取向电工钢组织性能的影响
研究了锰含量对w(Si)=1.8%Si无取向电工钢组织和性能的影响。结果表明,钢中锰含量从0.3%增加到1.2%时,由于α_γ相变的产生,铸坯低倍组织、热轧板金相组织及成品织构等均发生了不同程度的变化,对成品表面质量及磁性能产生了明显的影响。 The effects of manganese content on structure and properties of w(Si)=1.8% non-oriented electrical steels have been studied.Results show that with increasing manganese content to 1.2% from 0.3%,macrostructure of continuous casting slab,hot rolled band metallurgical structure and finished product texture vary in some extent because of the occurrence of α-γ phase transformation,the surface quality and magnetic properties of finished product are affected greatly.
薄板坯连铸连轧生产中低牌号无取向硅钢的实践
本文中简要介绍了武汉钢铁有限公司采用薄板坯连铸连轧CSP(compact strip production, CSP)工艺生产中低牌号无取向硅钢的实践情况.CSP工艺生产的硅钢具有成品磁性均匀、板形好的优势,但是在利用该技术生产中低牌号无取向硅钢时,常存在成品板表面瓦楞状缺陷严重、连铸生产效率低等问题.通过优化炼钢成分、热轧等相关工艺,可消除热轧板厚度方向中心的粗大形变组织,从源头上避免了粗大{100}<011>纤维组织的出现,消除了瓦楞状缺陷;通过提升冶炼效率和控制钢中夹杂物总量,可优化隧道炉的加热温度与在炉时间,大幅度提升了连铸生产效率,实现了中低牌号无取向硅钢的批量稳定制造,使CSP产线成为中低牌号无取向硅钢热轧板原料的主要供给生产线.如何进一步提升钢水纯洁度、提高连铸生产效率、降低生产成本,以及挖掘该产线生产薄带钢的技术优点,是未来工作的重点. This paper briefly introduces the practice of producing medium and low grade non oriented silicon steel(NGO) with CSP(compact strip production, CSP)technology in Wuhan Iron and Steel Co., Ltd.. This technology has the inherent advantages of uniform magnetic properties and good shape for silicon steel finished strip. However, in the actual production process, there are serious corrugated defects on the surface of silicon steel finished strip, and production efficiency of continuous casting is low...

