钢厂
锌浴中钛对含硅钢Fe-Zn反应的抑制作用
选用Q235和Q345钢,在纯锌浴和含钛量分别为0.05%、0.10%、0.15%、0.20%(质量分数)的合金浴中浸镀0.5、1、3、5、8 min。利用扫描电子显微镜和能谱仪研究了钛对热浸镀锌组织和生长动力学的影响,并提出钛对含硅钢铁锌反应抑制作用的机理。结果表明:钛的加入缩短了Γ的孕育期,促进了合金层中δ的生长和ζ的消失,δ的生长依然受扩散控制,呈抛物线生长规律;Zn-0.05%Ti锌浴可以很好的抑制高硅钢的硅反应性;含硅钢热浸镀锌钛合金浴时,在锌浴中会形成锌铁钛三元T相,该相能吸收ζ晶界处富集的硅,从而抑制了铁锌反应。 Both Q235 and Q345 steels were immersed for 0.5 to 8 min in Zn bath with different amount of Ti,ranging from 0 to 0.20 mass%,for galvanization.The effect of Ti in Zn bath on microstructure and growth kinetics of hot-dip galvanizing coatings on the two steels were investigated by means of SEM and EDS analysis.Base on the experiment,the mechanism of Ti additions in controlling Fe-Zn reaction was proposed.The results show that addition of Ti in the zinc bath decreases the incubation time of Γ phase...
新能源车电机用硅钢选材分析
为了提升新能源车用驱动电机的功率密度,各大电机厂商都在不断地提升电机转速,随之而来的问题就是电机的铁耗也在不断增高,如何降低电机铁耗成为了电机厂商必须要解决的难题。本文讨论了电机铁耗的组成部分及影响因素,并对1台8极48槽的永磁同步电机分别使用3种不同厚度的材料进行仿真,对比其效率及铁耗分布,推导出驱动电机中硅钢厚度、铁耗及成本的关系,最后对驱动电机选材提出建议。 In order to increase the power density of traction motor for new energy vehicles,major motor manufacturers have been constantly increasing the motor speed.The following problem that manufacturers have to solve is how to reduce the increasing iron loss when the motor speed is increased.The components and influencing factors of motors’ iron loss were discussed in this paper,and an 8-pole 48-slot permanent magnet synchronous motor using three different thickness materials was simulated.To compare i...
稀土处理无取向硅钢中的夹杂物与电磁性能变化
结合工业化生产的无取向硅钢,进行了RH精炼添加稀土合金实验。结果表明,1.15%(质量分数)Si钢的脱硫反应,主要发生在添加稀土合金之后的前5min。最佳的稀土合金添加量为0.6~0.9kg/t钢。钢液经过稀土处理后,加入的稀土总量越多,稀土氧硫化物夹杂物的尺寸就越大,但热轧带钢再结晶效果会逐渐变差,成品带钢晶粒尺寸先是快速长大,而后逐渐减小。最佳的钢中存留稀土含量与钢的化学成分有关,应严格控制在2.0×10-3%~6.0×10-3%(质量分数)。在此范围内,钢的铁损先是快速降低,而后缓慢升高,钢的磁感应强度则单调降低。 Based on the industrial production of non-oriented electrical steel,rare earth(RE) alloy treatment during the RH refining process was studied.The results showed that the effects of desulfurization and total concentration of RE remained in steel mainly depended on the chemical compositions of different steel grades.For 1.15wt% Si steel grade,the desulfurization reaction mainly focused on the initial 5min after RE alloy added during the RH refining process.The suitable RE alloy addition was 0.6-0....
获得抑制剂法生产低温高磁感取向硅钢的抑制剂控制研究进展
综述了国内外大钢铁企业与研究机构采用获得抑制剂法生产低温高磁感取向硅钢的开发及应用情况,分析了以该法生产高磁感取向硅钢过程中抑制剂的控制技术,包括固有抑制剂组成方案、气态渗氮方式与工艺及高温退火工艺的制定.研究表明,固有抑制剂组成方案的设计思路大体一致,化合物抑制剂以AlN为主、硫化物为辅,同时添加少量Sn,Sb等单元素抑制剂,但组成元素含量存在一定差别;在脱碳退火后用NH3进行非平衡渗氮处理已成为气态渗氮的主要方式,但最佳方式仍未明确,具体选择需依据实际生产条件,相应脱碳及渗氮工艺的控制条件差别较大;高温退火工艺中升温制度差别不大,升温阶段退火气氛中N2含量的选择存在差别.此外,分析了抑制剂控制技术目前存在的关键问题,并指出了进一步的研究方向. The current application and exploitation on production of low-temperature high magnetic induction grain-oriented silicon steel with acquired inhibitor method at both iron and steel enterprises and research institutions in the world are reviewed. The control techniques of inhibitors, which include the composition design for inherent inhibitors, nitriding method and process, and secondary recrystallization annealing, are thoroughly analyzed and proposed. It is indicated that the design ideas for i...
电脉冲对取向硅钢凝固组织的影响研究
对取向硅钢熔融态钢液进行处理,对比研究了不同脉冲参数的作用效果。结果表明,电脉冲对钢锭晶粒组织具有明显的细化作用,凝固组织等轴晶比例大幅上升。在脉冲电容、频率、处理时间和电压中,影响等轴晶比例的最显著性因素为脉冲频率;最优正交实验参数为:电容1 200μF,脉冲频率1 Hz,处理时间5 s,脉冲电压800 V;随着输入能量的增大,等轴晶率先增大后减小,脉冲输入能量为某值时,等轴晶率最大,通过经典形核理论和热力学对这一现象进行了解释。 Research on the influence of the electric pulse on the solidification structure of oriented silicon steel was preformed.Electric pulses in different parameters were applied to molten steel and results were compared.The result shows that solidification structure of oriented silicon steel can be improved by the electric pulse,and the equiaxed crystal ratio increases obviously.Among the four parameter factors of electric capacity,frequency,applied time and voltage,the most effective factor is frequ...
无取向电工钢表面线状缺陷的影响因素分析
结合扫描电镜和大样电解研究了CSP流程W800牌号无取向电工钢表面线状缺陷中夹杂物成分及来源,采用SPSS软件回归分析了生产过程各因素对表面线状缺陷的影响。研究表明:稳态浇铸过程铸坯中大型夹杂物含量为5.39 mg/10 kg。引起无取向电工钢表面线状缺陷的大型夹杂物主要为脱氧产物、镁铝尖晶石和钢包顶渣,主要类型为Al2O3、MgO-Al2O3、CaO-Al2O3-MgO和CaO-Al2O3-SiO2。非稳态浇铸过程钢水洁净度明显降低,热轧板表面线状缺陷比例上升。影响表面线状缺陷的主要因素为RH出站时顶渣的w(CaO)/w(Al2O3)、RH脱氧结束氧位及中间包最低吨位。 Combining scanning electron microscopy and large sample electrolysis, the composition and source of inclusions in the surface linear defects of W800 grade non-oriented electrical steel in the CSP process were studied. SPSS software was used to regress and analyze the main factors which affected the surface linear defects in the steelmaking process. Research shows that the content of large inclusions in the steady state casting process is 5.39 mg/10 kg. The large inclusions which cause linear def...
锡或锑在无取向电工钢中的研究进展
近年来,在节能减排背景之下,国内外众多研究者对无取向电工钢磁性能的提升做了大量研究。为了探索无取向电工钢磁性能提升的方法,对锡或锑对无取向电工钢磁性能的作用机制(晶粒尺寸和晶体织构的控制)进行分析。基于该作用机制,介绍锡或锑的添加对无取向电工钢磁性能的影响。经研究发现,适量的锡或锑在晶界偏聚,不会阻碍晶界的移动并且致使晶粒尺寸降低;与此同时,锡或锑在晶界偏聚不仅抑制{111}织构在原始晶界处形核及生长,还降低(100)晶粒表面能,促进(100)晶粒生长。因此,适量添加锡或锑,可使无取向电工钢铁损下降、磁感提升。最后结合生产工艺,建议无取向电工钢的研究方向应为稀土含量对高牌号无取向硅钢夹杂物尺寸和数量分布的影响,锡或锑的添加量和常化工艺参数(常化时间、常化温度)对常化晶粒尺寸的影响。 In recent years, due to the background of energy saving and emission reduction, numerous researchers all around the world have done a lot of investigations on the improvement of magnetic properties for non-oriented electrical steel. In order to explore the method of improving the magnetic properties of non-oriented electrical steel, the mechanism of tin or antimony on the magnetic properties(the control of grain size and crystallographic texture) of non-oriented electrical steel is illuminated. ...
化学气相沉积法制备6.5%Si高硅钢的研究
采用化学气相沉积(CVD)渗硅处理工艺连续制备6.5%Si高硅钢,具有优质的软磁性能,通过理论研究化学反应并且用简单的试验设备做进一步的探讨。根据试验的结果对连续制备6.5%Si高硅钢的CVD工艺构造提出全面、有效的建议,实现制备6.5%Si高硅钢系统。 CVD method for continuously manufacturing 6.5%Si Steel Sheet has excellent soft magnetic.Carried out a theoretical study of related chemical reaction and performing basic research with a simple test apparatus.Based on the results,finally proposed an overall process configuration to realize such a production-CVD method for continuously manufacturing 6.5%Si Steel Sheet.
新日铁高强度无取向电工钢的研究进展
针对新日铁公开的相关专利,总结日本高强度无取向电工钢的研究进展,分析了各专利化学成分、生产工艺及产品性能的特点,指出固溶强化、细晶强化、析出强化、位错强化都有可能被用来提高无取向电工钢的强度。在高强度无取向电工钢的研发过程中,需要根据其具体用途确定目标性能,再采用合适的强化手段,从而实现力学性能、磁性能和生产性能之间的平衡。 Authors summarize the research progress of high strength non-oriented electrical steel in Japan by learning related patents brought into the public by Nippon Steel. Authors also analyze the characteristics of the chemical composition, production technology and properties of products in the patents and point out that any ones of solution strengthening method, fine-grain strengthening method, precipitation strengthening method or dislocations strengthening method may be used to improve the strengt...

