硅钢资料

Fe-6.5%Si高硅钢是一种具有高磁导率、低矫顽力和低铁损等优异软磁性能的合金,但是其室温脆性和低的热加工性能严重影响了其在工业领域的应用。综述了Fe-6.5%Si高硅钢的性能,评述了合金的改性法、特殊轧制法、快速凝固法、沉积扩散法、粉末冶金法等制备工艺。 It is well known that 6.5%Si high silicon steel is one kind of soft magnetic materials with higher re-lative permeability,lower coercive force and iron loss than those of conventional industrial silicon steel.However,their room-temperature embrittleness and poor workability limit their practical applications in the industry.The pre-paration technique such as modification treatment on alloy,special rolling,rapid solidification,CVD and powder me-tallurgy is reviewed. 

系统研究了无取向硅钢用磷酸盐系涂层性能的影响因素。以氢氧化铝和磷酸为原料制备磷酸二氢铝,再添加适量的添加剂酒石酸铵、二氧化硅、环氧树脂,得到的涂液涂布于硅钢表面,并控制合适的烘干温度,通过耐盐雾实验考察各因素对涂液耐腐蚀性能的影响。实验结果表明,在磷酸与氢氧化铝物质的量比为3.4∶1、酒石酸铵用量为2%、二氧化硅用量为1%、环氧树脂用量为5%、烘干温度为300℃条件下,所得涂层材料的防(耐)腐蚀效果最佳。 The factors influencing the performance of phosphate anticorrosive coating for non-oriented silicon were systematically studied.Aluminum dihydrogen phosphate was prepared with aluminum hydroxide and phosphoric acid as raw materials.Then added the right amount of additives,such as ammonium tartrate,silicon dioxide,and epoxy resin to prepare the liquid coating,which was coated on the surface of the silicon steel,and finally controlled a suitable drying temperature.The influences of various factors... 

采用XRD、SEM和激光粒度仪等手段,观察并研究了不同特性氧化镁在硅钢表面形成硅酸镁底层形貌特点,并结合热力学和差热-失重分析了MgO-SiO2的反应机理。研究结果表明:粒度小,活性值高的特种氧化镁在高温退火过程中与基体表面氧化物生成的硅酸镁底层,界面中硅酸镁底层嵌入基体较多,表面致密,颗粒细小,有利于形成附着性能优良的硅酸镁底层。 Surface microstructure of Mg2SiO4 coatings formed on the surface of oriented silicon steel coated with different kinds of MgO was investigated by XRD and SEM.The reaction mechanism between MgO and SiO2 was analyzed by TG-DSC and thermodynamic calculation.Results revealed that when the MgO with finer microstructure size and higher activity is employed,a dense Mg2SiO4 layer with finer microstructure and good binding to the steel substrate can be obtained.The results are very helpful for the prepar... 

测试了高强无取向电工钢的S-N曲线,并借助光学显微镜、扫描电子显微镜、透射电子显微镜分析了实验钢组织,疲劳断口形貌和位错结构。结果表明:室温条件下,频率为20Hz,应力比R为0.1,循环10~7周次时,实验钢的疲劳强度为360MPa,疲劳裂纹萌生于实验钢的次表面,裂纹萌生点附近有沿晶开裂现象,疲劳裂纹扩展区域有解理台阶与疲劳条纹,瞬间断裂区是韧性断裂,有大量韧窝。实验钢在循环应力作用下基体中产生了大量位错,并有驻留滑移带终止在晶界位置。 The S-N curve of a high strength non-oriented electrical steel was tested.The microstructure and fatigue fracture morphology and dislocation were analyzed by optical microscope,scanning electron microscope,transmission electron microscope.The results showed that:at room temperature and the frequency of 20 Hz and the stress ratio Rof 0.1,the fatigue strength of the experimental steel was 360 MPa when the cycle was 10~7 cycles.The fatigue crack initiation at the surface of the steel and the interg... 

【作者】 马芳； 张春红； ...

通过对湿H2气氛下,相同退火温度、不同退火时间的CGO硅钢初次再结晶样品进行金相组织观察,并进行了EBSD微观织构分析,研究了CGO硅钢初次再结晶过程中的组织及再结晶织构演变行为。结果表明,在湿H2气氛下,820℃保温,CGO硅钢初次再结晶过程约在120 s时完成。随着退火时间的延长,γ面上{111}<112>织构含量逐渐减少,{111}<110>织构先减少后增多,随着再结晶的完成,部分{111}<112>取向晶粒向高斯{110}<001>取向转化的同时,也向{111}<110>取向转化,高斯{110}<001>织构含量逐渐增多。高斯取向晶粒较多是由{111}<112>取向晶粒转化而来,同时也证明了CGO硅钢高斯取向晶粒的二次再结晶异常长大生长机制为择优形核。 Microstructure development and texture evolution of conventional grain oriented silicon steel,which were annealed at same annealing temperature and different annealing time under wet H2 atmosphere,were investigated through metallographic observation and electron backscattered diffraction analyzing.The results show that the primary recrystallization finishes in 120 s at 820 ℃ under wet H2 atmosphere.With the extending of annealing time,{111}<112> texture decreases,{111}<110> texture d... 

借助电子背散射衍射(EBSD)及ZEISS-200MAT金相显微镜对某钢厂普通取向硅钢(CGO)进行研究,研究结果表明:热轧板组织、织构沿板厚方向存在明显的不均匀性,在热轧板表层及次表层发生再结晶,同时存在强度较高的Goss织构,中心层存在较强的{001}<110>变形织构。冷轧组织均呈纤维状条带组织,一次冷轧后,热轧板中的Goss织构消失,织构主要为α、γ织构,经中间脱碳退火后,α、γ织构强度减弱,并出现一定强度的Goss织构和利于Goss织构发展的{554}<225>、{332}<113>等织构,经二次冷轧后,二次冷轧织构类型与一次冷轧织构一致,但织构强度不同。 The grain-oriented silicon steel produced by a steel factory was investigated by EBSD and ZEISS-200 MAT metallographic microscope.The results show that the textures and microstructures along thickness of hot rolled slab are inhomogeneous.The surface layer and the layer near that are recrystallized structure which has a high Goss texture,but there is deformation texture{001}<110>in the central layer.The structure after cold rolling is a structure like fiber strip.After the first cold rollin... 

选用Q235和Q345钢,在纯锌浴和含钛量分别为0.05%、0.10%、0.15%、0.20%(质量分数)的合金浴中浸镀0.5、1、3、5、8 min。利用扫描电子显微镜和能谱仪研究了钛对热浸镀锌组织和生长动力学的影响,并提出钛对含硅钢铁锌反应抑制作用的机理。结果表明:钛的加入缩短了Γ的孕育期,促进了合金层中δ的生长和ζ的消失,δ的生长依然受扩散控制,呈抛物线生长规律;Zn-0.05%Ti锌浴可以很好的抑制高硅钢的硅反应性;含硅钢热浸镀锌钛合金浴时,在锌浴中会形成锌铁钛三元T相,该相能吸收ζ晶界处富集的硅,从而抑制了铁锌反应。 Both Q235 and Q345 steels were immersed for 0.5 to 8 min in Zn bath with different amount of Ti,ranging from 0 to 0.20 mass%,for galvanization.The effect of Ti in Zn bath on microstructure and growth kinetics of hot-dip galvanizing coatings on the two steels were investigated by means of SEM and EDS analysis.Base on the experiment,the mechanism of Ti additions in controlling Fe-Zn reaction was proposed.The results show that addition of Ti in the zinc bath decreases the incubation time of Γ phase... 

为了提升新能源车用驱动电机的功率密度,各大电机厂商都在不断地提升电机转速,随之而来的问题就是电机的铁耗也在不断增高,如何降低电机铁耗成为了电机厂商必须要解决的难题。本文讨论了电机铁耗的组成部分及影响因素,并对1台8极48槽的永磁同步电机分别使用3种不同厚度的材料进行仿真,对比其效率及铁耗分布,推导出驱动电机中硅钢厚度、铁耗及成本的关系,最后对驱动电机选材提出建议。 In order to increase the power density of traction motor for new energy vehicles,major motor manufacturers have been constantly increasing the motor speed.The following problem that manufacturers have to solve is how to reduce the increasing iron loss when the motor speed is increased.The components and influencing factors of motors’ iron loss were discussed in this paper,and an 8-pole 48-slot permanent magnet synchronous motor using three different thickness materials was simulated.To compare i... 

本文研究了丙烯酸树脂含量对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同树脂含量对硅钢绝缘涂层的耐盐雾性能和电化学行为的影响,同时采用SEM对涂层的表面形貌和附着性进行研究.结果表明,树脂含量为19.9~29.4%时,涂层的耐蚀性和附着性最好;树脂含量过多时,涂层的耐蚀性和附着性均较差. This paper studies the influence of acrylic resin on the performance of insulating coating of aluminum dihydrogen phosphate on chromium-free non-oriented silicon steel.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of acrylic resin content on the salt spray resistance and electrochemical behavior of the insulation coating of nonoriented silicon steel.The surface morphologys and adhesion of coating were tested by SEM.... 

针对传统工艺生产硅钢周期长、能耗大等缺点,采用双辊连铸工艺制备3%Si无取向硅钢连铸薄带,利用MEM,SEM和TEM观察了铸带的组织、织构及析出物,同时对比了Al的质量分数为0.6%和0.9%的连铸薄带在组织、织构及析出物特征方面的异同.结果表明:双辊连铸工艺生产的3%Si无取向硅钢铸带的组织为均匀等轴晶粒,平均晶粒尺寸约为300μm;织构组成随Al质量分数的不同具有明显差别,Al质量分数为0.9%的铸带中{100}织构强度是随机织构的7倍;铸带中的析出物为AlN和MnS,最大尺寸分别为500和50 nm左右. Given the lengthy production cycle,high energy consumption,and other shortcomings of the traditional process for producing silicon steel,a twin-roll casting process was used to produce 3%Si non-oriented silicon steel casting strips. MEM,SEM,and TEM were used to compare micro-structure,texture,and precipitate characteristics of a casting strip containing 0.6%Al with another containing 0.9%Al.The structure of 3%Si non-oriented silicon steel produced by the twin-roll casting process was a uniform i... 

采用自主研发的脉冲磁场退火装置，在取向硅钢脱碳退火过程中分别施加不同强度的磁场，并采用光学显微镜和X射线衍射仪研究了脉冲磁场脱碳退火后试样的显微组织和宏观织构。结果表明，脱碳退火过程中施加脉冲磁场后取向硅钢的平均晶粒尺寸均增加，当磁场强度为40 mT时，平均晶粒尺寸最大，为13.06μm。此外，取向硅钢试样的立方织构{001}<100>强度减弱，高斯织构{110}<001>和{111}<112>织构增强，有利于获得更好的成品织构和磁性能。 Self-developed pulsed magnetic field annealing device was used to apply magnetic field of different intensities during decarburization annealing of an oriented silicon steel, and microstructure and macro-texture of the specimens after decarburization annealing in a pulsed magnetic field were studied by using optical microscope and X-ray diffractometer. The results show that the average grain size of the oriented silicon steel increases with the application of pulsed magnetic field during decarbu...