硅钢资料

【摘要】 <正>据武钢股份公司提供的消息,武钢将与...

对取向硅钢在不同气氛下的高温退火工艺进行实验室模拟，利用X射线衍射仪（XRD）分析了硅钢退火至900℃和1170℃时的样品表面氧化层和底层的物相组成，采用场发射扫描电镜（SEM）观察了样品表面氧化层和底层在截面方向上的微观形貌特征，并计算了高温退火一次升温阶段氧化反应的吉布斯自由能以及900℃时退火气氛的氧分压。结果表明：当退火气氛的露点温度保持一定时，较高的氢气含量有利于生成完整连续的底层；当退火气氛的水氢分压比保持一定时，在露点温度与氢气含量两者较低的条件下，底层附着性不佳易脱落，较高条件下，底层中夹杂着较多的铁单质；当氧化层中无FeO时，底层完整连续但易脱落，当FeO层较薄时，底层下方存在部分未反应的SiO₂,当FeO层较厚时，底层不完整连续且有分层。 The high temperature annealing process of grain-oriented silicon steel in different atmospheres was simulated in the laboratory. X-ray diffractometer（XRD） was used to analyze the phase compositions of the surface oxide layer and forsterite film of the silicon steel annealed to 900 ℃ and 1170 ℃. Field-emission scanning electron microscopy（SEM） was used to observe the micro morphology characteristics of the surface oxide layer and forsterite film of the samples in the cross section direction. The ... 

以青海盐湖氯化镁为初级原料,采用喷雾热解法制备原料氧化镁。原料氧化镁通过水化制备氢氧化镁。将氢氧化镁过滤、洗涤、烘干、粉碎、煅烧,制备硅钢级氧化镁。本文重点考察煅烧温度、煅烧时间、料层厚度等因素对氧化镁水化率的影响,采用均匀实验设计和DPS数据处理,确定最优煅烧实验条件为:煅烧温度1250℃,煅烧保温时间4小时,料层厚度0.5cm。在此条件下得到的硅钢级氧化镁完全满足硅钢及氧化镁的行业标准。 The magnesium oxide is prepared by Spray pyrolysis process,which magnesium chloride from Qinghai Salt Lake is used as primary raw material,and hydrated to magnesium hydroxide,then obtained silicon steel magnesia through filtering,washing,drying,crushing and calcinations.In this paper,influences of some factors on magnesia hydration rate are studied,such as calcination temperature,calcination time and material thickness.After average experimental design and DPS data processing,optimal calcination... 

利用OM、EBSD等手段研究了热轧板两段式正火时在700℃保温不同时间(0、10、30、60 min)对含Sb冷轧无取向电工钢磁性能的影响。结果表明,700℃保温10 min处理的样品铁损最小,磁感最高。对成品板的组织分析结果表明,试样的晶粒尺寸随700℃保温时间的延长先增大后减小,保温10 min时晶粒尺寸达到最大;分析成品试样织构发现,有利织构组分随700℃保温时间的延长先增加后减少,保温10 min时有利织构组分所占百分比最高。因此,含Sb冷轧无取向电工钢两段式正火时在700℃保温10 min时磁性能最好。 Effect of two-stage normalization on magnetic property of non-oriented electrical steel containing antimony was investigated by using optical microscope(OM) and electron back-scattered diffraction technology(EBSD).The experimental results show that the iron loss and magnetic permeability of the specimen insulated at 700 ℃ for 10 min are lowest and highest respectively.The grain size of the finish specimens increases first and then decreases with the increase of holding time.Similarly,the advanta... 

通过固溶度积公式计算及热模拟实验,对不同热装和加热温度条件下的无取向硅钢铸坯中析出相进行了研究.在低于950℃热装时,铸坯中AlN的析出量和尺寸不再变化,但MnS和AlN-MnS的数量及平均尺寸随着热装温度降低而进一步增加,并在温度低于600℃时达到最大值后保持不变.与1200℃相比,1100℃加热的铸坯中AlN、MnS的总固溶量相对更少.相比850℃热装,600℃热装再加热到1100℃的铸坯中AlN和MnS的总固溶量更少,且AlN和MnS尺寸更大.合适的热装温度和加热温度分别为600℃和1100℃. Based on solubility product calculation and thermal simulation experiments,precipitated phases in continuous casting slabs of non-oriented silicon steel were systematically studied at different hot charging and heating temperatures.When the hot charging temperature is below 950 ℃,the content and size of AlN remain unchanged,but the quantity and size of MnS and AlN-MnS increase when the hot charging temperature decreases,reach maximum and remain unchanged when the hot charging temperature is belo... 

结合工业化生产的无取向硅钢,探讨了氧硫交互作用对钢中夹杂物生成的影响。借助非水溶液电解+扫描电镜法,研究了不同O、S含量下钢中夹杂物的变化规律。结果表明,本实验条件下,提高O含量、降低S含量,会劣化热轧组织再结晶效果。在劣化效果上,O的作用大于S;低Si、无Al硅钢中,应尽可能降低O含量、适当提高S含量,以粗化钢中微细夹杂物,减少尺寸小于1.0μm的夹杂物的数量;O、S含量与钢中夹杂物数量不具有关联性。生产过程中,不仅要严格控制O、S含量,还要严格控制生产工艺,以免生成较多的有害夹杂物。 Based on the industrial production of non-oriented silicon steel,the effects of interaction between oxygen and sulfur on the formation of inclusions were discussed.The change of non-metallic inclusions in steel sheets was investigated by means of electrolysis with non-aqueous solution under different oxygen and sulfur content.Results show that the recrystallization microstructure of hot rolled sheets will be deteriorated with the increase of oxygen content and the decrease of sulfur content.The ... 

介绍了双蓄热燃烧技术的特点和高温硅钢加热炉的特点,探讨了双蓄热燃烧技术在高温硅钢加热炉中使用的技术难点,分析了双蓄热燃烧技术在高温硅钢加热炉上使用的可能性。 Introduced characteristics of double regenerative combustion technology and high temperature silicon steel reheating furnace,discussed technical difficulties for using double regenerative combustion technology,analyzed the possibility of double regenerative combustion technology applied to high temperature silicon steel reheating furnace. 

分别采用传统冷轧轧制液和纳米TiO₂的冷轧轧制液,对无取向硅钢板进行了四辊冷轧实验.重点研究两种冷轧轧制液的轧制润滑性能和对轧后硅钢薄带表面质量和耐蚀性能的影响.通过场发射电子显微镜和能谱仪对使用两种轧制液轧后得到的硅钢薄带表面形貌和成分进行了分析.给出了轧制液中TiO₂纳米粒子在轧制过程中的抗磨减摩机理.在轧制载荷较高时,纳米TiO₂轧制液具有优良的轧制润滑性能并能显著改善轧后硅钢薄带的表面质量.同时在高载荷作用下,TiO₂纳米粒子被压入硅钢薄带基体,形成一个滑动系来支撑载荷,从而使润滑膜的耐磨性提高. Non-oriented silicon steel strips were rolled on a four-high cold rolling mill lubricated by a traditional cold rolling liquid and a nano-TiO₂ cold rolling liquid,with emphasis on studying the rolling lubrication performance of both the liquids and their effect on the surface quality and corrosion resisting property of the silicon steel strips.The surface micrograph and composition of the silicon steel strips after being rolled with both the liquids were characterized by field emissio... 

通过观察冲剪边缘组织,测量冲剪边缘的显微硬度、残余应力的分布情况和磁性能的变化研究了冲剪加工对无取向硅钢50WW800边缘组织和磁性能的影响。对冲剪后硅钢片进行750℃退火,分析退火对组织和磁性能的影响。结果表明,硅钢片剪切边缘会存在0.4 mm的形变硬化层,边缘应力大,铁损增加。退火后变形减小,形变硬化层变小,残余应力大幅度减少,铁损减少。 The influence of punching process on cutting edge microstructure and magnetic properties of non-oriented silicon steel 50WW800was studied by observing microstructure and measuring microhardness near cutting edge.The residual stress distribution in the silicon steel tooth and magnetic properties were measured.Effect of annealing at 750 ℃ on microstructure and magnetic properties of the silicon steel was analyzed.The results show that a cut-edge hardening layer up to 0.4 mm is observed,residual st... 

提出了一种基于爱泼斯坦方圈族(包括标准25cm爱泼斯坦方圈、缩比的17.5cm和20cm爱泼斯坦方圈)和二级加权处理方法对爱泼斯坦测试数据,包括有效磁路长度、比损耗、励磁功率,进行处理的晶粒取向电工钢磁性能扩展模拟方法。详细地考察了励磁频率、试样剪切角度和环境温度对爱泼斯坦方圈测量结果的影响。研究结果表明,利用本文提出的爱泼斯坦方圈组合以及二级加权处理技术,可以有效地建立取向电工钢损耗模拟模型,从而更加准确地确定了取向电工钢的损耗,改善并提高了爱泼斯坦磁性能测试数据的应用价值。 The extended modeling of the magnetic properties of GO(grain oriented) electrical steel is presented in this paper which is based on a set of standard and scaled-down Epstein frames and a proposed two-level weighted processing of Epstein data, including the mean magnetic path length, specific magnetization loss and exciting power. The effects of excitation frequency, strip angle and ambient temperature on the results obtained from the Epstein frames are investigated. It is shown that using the p... 

针对采用含钒铁水生产无取向电工钢存在的铁水脱硫率低、转炉冶炼过程回硫量大、成品硫含量偏高的问题,通过对含钒钛铁水脱硫,减少转炉冶炼过程回硫以及RH脱硫技术等方面的研究,大幅度降低了电工钢成品硫含量。生产表明钢中w(S)=0.001 9%～0.006 9%,平均为0.004 2%;w(S)≤0.008%的比例达到了100%,且w(S)≤0.005%的比例也达到了91.43%。 In cognizance of the problems of low desulphurization rate for hot metal,large sulfur-recovery in converter as well as high sulfur content in products in producing non-orientation electrical steel with vanadium-content hot metal countermeasures have been carried out.Sulfur content in non-orientation electrical steel is decreased obviously by way of study on technologies of desulphurization for hot metal with vanadium & titanium,sulfur-recovery control in converter and desulphurization in RH ... 

【作者】 潘恒韬； 刘涛； ...