硅钢资料

通过对辉光放电发射光谱参数的优化,以铁元素为内标来消除基体效应,建立了测定硅钢薄板中微量硼元素的方法。优化的实验参数为:放电电压1200 V,放电电流50 mA,预溅射时间40 s,积分时间10 s。校准曲线硼元素含量范围0.0001%~0.022%,相关系数大于0.999,测量结果与认定值一致,相对标准偏差小于10%。完全能够满足日常分析测试的要求。 A glow discharge optical emission spectrometry(GD-OES) method for determining trace boron element in silicon steel sheets were established through optimization of instrumental parameters and using Fe element as an internal standard to eliminate the matrix effect.The optimized instrumental parameters included discharge voltage,discharge current,pre-sputtering time and integration time,which are 1200 V,50 mA,40 s,and 10 s,respectively.The content of boron element that can be determined from the ca... 

研究了薄板坯连铸连轧流程(TSCR)条件下热轧工艺对3.2%Si-0.7%Al无取向硅钢组织、织构演变及磁性能的影响规律。结果表明,提高均热温度和热轧温度有助于获得粗大的变形组织和强烈的{001}〈110〉织构,进而对后续的组织、织构演变进程及磁性能产生有利的遗传影响。与低温均热和低温热轧相比,高温均热和高温热轧得到的最终成品板的再结晶晶粒较粗大,λ纤维再结晶织构较强而γ纤维再结晶织构较弱,磁感应强度较高。 It was investigated that the effects of thin slab cast rolling(TSCR) hot rolling processes on microstructural,textural evolution and magnetic properties of 3.2%Si-0.7%Al non-oriented silicon steel.The results show that much larger hot rolling deformed microstructure and much stronger {001}〈110〉 texture could be obtained by increasing the soaking and hot rolling temperatures,which had good heritable effects on subsequent microstructural,textural evolution and magnetic properties.The final sheets ... 

【机构】 宝山钢铁股份有限公司规划与科技部； ...

系统研究了无取向硅钢用磷酸盐系涂层性能的影响因素。以氢氧化铝和磷酸为原料制备磷酸二氢铝,再添加适量的添加剂酒石酸铵、二氧化硅、环氧树脂,得到的涂液涂布于硅钢表面,并控制合适的烘干温度,通过耐盐雾实验考察各因素对涂液耐腐蚀性能的影响。实验结果表明,在磷酸与氢氧化铝物质的量比为3.4∶1、酒石酸铵用量为2%、二氧化硅用量为1%、环氧树脂用量为5%、烘干温度为300℃条件下,所得涂层材料的防(耐)腐蚀效果最佳。 The factors influencing the performance of phosphate anticorrosive coating for non-oriented silicon were systematically studied.Aluminum dihydrogen phosphate was prepared with aluminum hydroxide and phosphoric acid as raw materials.Then added the right amount of additives,such as ammonium tartrate,silicon dioxide,and epoxy resin to prepare the liquid coating,which was coated on the surface of the silicon steel,and finally controlled a suitable drying temperature.The influences of various factors... 

【作者】 马芳； 张春红； ...

研究了卷取工艺对一种新型含铜无取向电工钢晶粒尺寸、织构演变、铁损和磁感应强度的影响。结果表明,试样织构组分主要为{111}、{112}、{100}和高斯织构,在550℃卷取、保温2～3h,{100}织构有增强趋势,磁感应强度较高,铁损较低。 The effects of coiling process on grain size,texture,core loss and magnetic induction of a new cold rolled non-oriented electrical steel with copper were investigated.The results show that there are mainly {111},{112},{100} and {110}<001> texture.Coiling at 550℃and keeping for 2～3 hours,the {100} texture is enhanced,magnetic induction is higher and core loss is lower. 

根据现场实际的生产控制情况,指出了热轧原料断面轮廓缺陷以一定的比列遗传给了冷轧带钢,分析了不同热轧原料断面轮廓对冷轧电工钢尺寸精度的具体影响,提出了相应的规律。并阐明了严格控制热轧原料断面轮廓形貌,对保证冷轧电工钢尺寸精度具有重大意义,对于中国现行的冷轧电工钢生产具有指导意义。 Based on the actual situation of production control,it was pointed out that the section profile defects of hot-rolled raw materials were geneticed to the cold-rolled strip.The specific impact analysis for the profile of different hot-rolled raw materials to the dimensional accuracy of cold-rolled silicon steel was analyzed.As a result, the corresponding orderliness are given;And the strict control to section profile of the hot-rolled material is of great significance to ensure the dimensional ac... 

就冷轧硅钢废水处理生产中面临的主要问题进行分析,从技术角度及运行管理角度提出工艺优化升级改进措施及应对策略;同时从后续深度处理,逐步实现零排放目标的角度进行探讨,为冷轧硅钢废水减量化、出路乃至废水零排放提供一些思路。 The main problems in the wastewater treatment process of cold-rolled silicon steel lines are analyzed and process upgrading measures and optimization strategy are put forward from both technical and management views.At the same time,downstream deep treatment to gradually achieve the target of zero discharge is discussed,to provide some ideas for reduction or even zero discharge of wastewater from cold-rolled silicon steel lines. 

在15 kg真空感应炉上,用CaO-Al2O3-SiO2-MgO渣系进行脱硫试验,探讨了脱硫渣系碱度、MI、Al2O3、CaF2对脱硫效果的影响。研究结果表明,随脱硫渣系碱度、MI、Al2O3和CaF2含量的增加,脱硫率都呈现先增加后减少的趋势。初始硫含量为0.009 33%~0.010 73%,加入脱硫渣系4 min时间内表观脱硫速率为(0.000 96~0.001 49)%/min,平均脱硫率为81.2%,最高达86.8%。当脱硫渣中w(CaO)=58.15%、w(SiO2)=4.85%、w(Al2O3)=25%、w(MgO)=6%、w(CaF2)=6%,脱硫效果最好,此时钢液中硫为0.001 33%。 Experiments on desulfurization of molten steel using CaO-Al2O3-SiO2-MgO based desulfurization slag was carried out in a 15 kg vacuum induction furnace. The effects of desulfurization slag basicity,MI, Al2O3and CaF2on desulfurization of molten steel were studied. The results show that with the increase of basicity,MI,Al2O3or CaF2in desulfurization slag,the desulfurization rate rises initially and then decreases. In addition,as the initial sulfur content is 0. 009 33% ~ 0. 010 73%,the apparent des... 

概述了高磁感取向硅钢生产工艺的研究现状及发展趋势。介绍了国内外薄板坯连铸连轧流程生产高磁感取向硅钢的研究现状。从流程工序特点、热履历、组织与抑制剂控制方面进行对比,分析了薄板坯连铸连轧流程相对传统板坯流程生产高磁感取向硅钢的技术优势,在此基础上提出了利用该流程生产高磁感取向硅钢需要解决的主要技术难点。 The current status and development trend of production process for high magnetic induction grain-oriented silicon steel are summarized.The research status of producing high magnetic induction grain-oriented silicon steel by thin slab casting and rolling process at home and abroad is introduced.The potential technical advantages of producing high magnetic induction grain-oriented silicon steel by thin slab casting and rolling process are obtained by analyzing in terms of process characteristics,t... 

研究了退火温度和退火时间对电沉积硅钢试样中的断面层组织、硅在试样中的分布情况、织构分布和磁性能的影响。结果表明:退火温度为1000℃、退火时间为210 min时得到的试样晶粒分布均匀、硅在试样中分布均匀、硅平均浓度为6.3715%(接近6.5%)。试样的织构分析及磁性能检测的结果表明,在较高温度下延长退火时间可增加{100}和{110}面织构,降低铁损,所得试样的磁性能较为良好。 The effect of annealing temperature and time on the microstructure, distribution of silicon,texture and magnetism of the high silicon steel prepared by electrodeposition was investigated. The results showed that after annealing at 1000℃ for 210 min, the mean grain size of steel was about 190 μm with a uniform grain size distribution, and the silicon is also uniformly distributed on the entire cross section with an average Si concentration 6.3715%(close to 6.5%); With the increasing annealing tim... 

取向硅钢成品的晶粒尺寸非常大,其易磁化方向[001]晶向对于轧向的偏差角度对其磁性能影响极大。本文介绍了取向硅钢二次再结晶后成品晶粒位向的几种测定方法,包括侵蚀法、劳厄法、OIM法、极图法和非对称X射线衍射法等,并对这几种测量方法进行了比较。 The finished product of grain-oriented silicon steel has immense grain size ranging from millimeters to centimeters and the deviation angles of easy magnetization direction from rolling direction plays a remarkable role in magnetic properties of grain-oriented silicon steel.The methods in common use for determining the deviation angles of crystal direction are introduced,which include the etch-figure method,the Laue method,the OIM method,the pole figure method and the asymmetrical X-Ray diffract...