钢厂
传统和薄板坯连铸连轧流程生产无取向电工钢对比
以不断增长的薄板坯流程为背景,与传统流程对比分析了薄板坯流程无取向电工钢热轧晶粒组织特征;以50W800和50W1300钢为典型实例,探讨了两种流程下成品板晶粒组织、织构、磁性能及其磁时效行为的基体差异和相关原理。研究表明,薄板坯流程热轧板组织较粗大,有利于在成品板中获得粗大的晶粒和有利的织构,从而得到较低的铁损和较高的磁感。然而,薄板坯流程会造成第二相粒子的细小弥散分布与不充分析出,容易因磁时效而使磁性能恶化。 Based on the rapid development of compact strip production(CSP) processing,the characteristics of hot band grain structure produced by CSP processing were analyzed in comparison with those of conventional technology.The basic differences in grain size,texture,magnetic properties and the magnetic aging behaviors of the final sheet products produced by the two processing technologies and the corresponding principles were discussed,while steel 50W800 and 50W1300 were taken as examples.It is indicat...
薄板坯连铸连轧流程试制含钒钛取向硅钢中氮化物析出相
通过热力学计算与模拟试验研究了含钒钛取向硅钢中氮化物析出相的析出规律与析出行为,并探讨了含钒钛元素的氮化物析出相作为薄板坯连铸连轧流程制备取向硅钢中辅助抑制剂的可行性.研究表明,在所冶炼的含钒钛取向硅钢的成分范围内,Ti N在钢液凝固末期便具备析出的热力学条件,而Al N与VN只可能在凝固后的α+γ或α+Fe3C两相区内析出.含钒钛取向硅钢中氮化物析出相以成分复杂的复合析出相为主,且随着钒钛加入量的增加,钢中抑制剂析出相总的分布密度由于含钒钛元素的氮化物析出相的增加而明显提高,使抑制剂抑制初次再结晶晶粒正常长大的能力得以加强,最终成品的磁感应强度值B8由1.857 T提升至1.898 T.同时,加入不高于0.007%的Ti与不高于0.005%的V不会影响中间脱碳退火工序的脱碳效果以及高温退火净化阶段硫、氮的脱除效果,其形成的含钒钛元素的纳米级氮化物析出相适合作为薄板坯连铸连轧流程制备取向硅钢的辅助抑制剂. The precipitation behavior of nitride precipitates in grain-oriented silicon steel containing vanadium and titanium elements produced by thin slab casting and rolling process was studied by thermodynamic calculation and simulation experiment. The feasibility of nitride precipitates containing V and Ti elements as auxiliary inhibitors was also investigated. It is found that Ti N is likely to precipitate at the final stage of solidification in the grain-oriented silicon steel,but VN and Al N can p...
稀土铈含量对1.2%Si无取向电工钢组织、织构及磁性能的影响
在实验室模拟CSP流程制备了不同含量稀土铈(质量分数0~0.018%)的1.2%Si无取向电工钢,并对其进行1 000℃×5min的再结晶退火处理,研究了铈质量分数对无取向电工钢夹杂物、显微组织、再结晶织构和磁性能的影响。结果表明:随着铈质量分数的增加,微细夹杂物数量、再结晶晶粒尺寸、{100}和{110}织构组分、磁感应强度先增后减,{111}织构组分、铁损先减后增;铈的质量分数为0.005 1%时,钢中的夹杂物数量最少,再结晶晶粒尺寸最大,有利织构最多,磁性能最优,铁损P15/50为3.253W·kg-1,磁感应强度B50为1.751T。 Non-oriented electrical steels containing different contents rare earth Ce element(0-0.018wt%) were prepared in the laboratory by simulated CSP(compact strip production)process,and then recrystallization annealing at 1 000 ℃ for 5 min were performed,the effects of Ce content on inclusion,microstructure, recrystallization texture and magnetic properties of non-oriented electrical steels were studied.The results show that with the increase of Ce content,the amounts of fine inclusion,the size of re...
ZnO对无铬无取向硅钢绝缘涂层性能的影响研究
主要研究了氧化锌对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验和动电位极化研究了不同氧化锌含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响.采用SEM和体视显微镜对涂层的表面形貌和附着性能进行研究.结果表明,氧化锌含量为4.0%时,氧化锌能完全中和涂层表面的游离磷酸,涂层的耐蚀性和附着性最好;氧化锌含量过少或过多时,涂层的耐蚀性和附着性都较差. This paper studies the influence of zinc oxide on the performance of chromium-free non-oriented silicon steel insulating coating which based on aluminum dihydrogen phosphate.Salt spray experiment and potentiodynamic polarization were used to study the influence of zinc oxide content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.The surface morphology and adhesion of coating were tested by SEM and stereo microscope.The results show that when t...
退火温度对无取向电工钢磁晶各向异性能的影响
采用取向分布函数分析了无取向电工钢不同再结晶退火温度下的织构变化及织构对磁感应强度和铁损的影响,并计算了无取向电工钢的磁晶各向异性能。结果表明,随着实验钢的再结晶退火温度升高,Goss织构和立方织构组分显著增强,而{111}面织构强度却减弱。较高的退火温度有利于减小织构因子,提高磁感应强度。磁晶各向异性能计算结果显示,随着再结晶退火温度升高,无取向电工钢板的磁晶各向异性能降低。 The recrystallization texture and the relationship of texture to magnetic induction intensity and core loss of a non-oriented electrical steel were investigated by orientation distribution function analysis. The magnetic anisotropy energy of the steel was calculated also. The results show that,the intensity of Goss texture and cubic texture increases,but the intensity of { 111} texture decreases with increasing recrystallization annealing temperatures of the steel. The higher annealing temperatu...
120t转炉冶炼无取向硅钢脱硫技术研究
结合冶炼无取向硅钢的生产实际,对钢中硫的来源,以及炉渣性质、钢水温度、底吹强度对脱硫的影响进行了分析。研究表明,转炉钢中硫的主要来源为铁水、废钢、铁水渣及石灰带入;冶炼硅钢时,终渣碱度为3.0~3.5,w((FeO))≤20%,终点钢水温度大于等于1 680℃,加大底吹搅拌强度能提高转炉脱硫效果。硅钢平均出钢硫的质量分数为0.004 8%,能满足无取向硅钢对硫含量的要求。 With the actual production of non-oriented silicon steel,the source of sulphur and the effect of metallugic parameters like slag properties,temperature of molten steel and bottom stirring on desulphurizing ability were investigated.The results show that the main source of sulphur is molten metal,scrap,the remaining slag volume in hot metal and lime.The degree of desulphurization for smelting silicon steel can be increased through adopting the following measures,such as the basicity of finishing ...
本钢薄板坯连铸机生产无取向电工钢的工艺优化
针对本钢薄板坯铸机在生产无取向电工硅钢的过程中存在的铸坯拉断、中包增碳、增氮等问题,进行了连铸工艺优化。通过采用新型无碳中间包覆盖剂、环保中间包干式料及专用结晶器保护渣后,降低了铸坯增碳量;通过控制钢包到中间包的增氮环节,降低钢水增氮;适当增大二冷水量,控制钢水过热度,防止铸坯拉断等生产事故的发生。改进工艺后,精炼后到成品铸坯的平均增碳量能控制在10×10-6以内,平均增氮量能控制在4×10-6以内。 The technology optimization has been adopted for preventing nitrogen increasing and carbon increasing in Benxi thin slab producing non-oriented silicon steel.Measures accordingly were adopted and satisfactory results were achieved.
无取向电工钢织构的演变及其沿带钢宽度方向上的差异
采用EBSD检测技术,分析了50W800无取向电工钢在重要生产工序间织构的演变以及织构沿带钢宽度方向上的差异性。结果表明:热轧板织构沿带钢宽度方向上的差异性主要体现在表层织构。带钢边部表层织构主要由旋转立方织构、α纤维织构以及少量的γ纤维织构组成,带钢宽度1/4处的表层织构主要存在高斯织构,带钢宽度1/2处的表层织构主要为(110)面织构以及少量的铜型织构。各处的带钢宽度1/4处和1/2处的织构类型基本一致,都以α纤维织构和旋转立方织构为主。冷轧后,各处的表层织构类型差异较小,均为γ纤维织构和α纤维织构。由板宽边部至中心处织构强度值逐渐降低。退火后,各处织构的组分基本一致,为较强的γ纤维织构和较弱的(100)面织构。各处织构强度值差异较小,变化趋势与冷轧板一致。 The texture of non-oriented electrical steel 50W800 was detected by EBSD technique.The evolution of the texture between important processes and the difference of texture along the width direction of strip were analyzed.The result shows that the difference along the width direction of strip of texture at the surface of hot rolled plate is most obvious.The texture at the surface of strip edge is primarily made of rotating cube texture,αfiber texture and weakγfiber texture.Goss texture is mainly co...
