钢厂
无取向电工钢环保绝缘处理液试验研究
针对目前大部分无取向电工钢处理液为含铬处理液、且需在较高温度下固化的情况,在分析成膜物质性质的基础上,试验研究了一种可低温快速固化的电工钢环保绝缘处理液,研究了其涂装工艺,并测定了涂层的附着性、绝缘性、耐热性、耐蚀性等性能。试验结果表明:该处理液可在150~250℃下快速烘干固化,涂层表面光滑且致密均匀,性能优良,可满足中小电机的使用要求。 At present,most of the insulating fluid for non-oriented electrical steel contains chromium,and should be cured at high temperature.On the basis of analyzing the characteristics of the film-forming substance,a kind of eco-friendly insulating fluid with lower curing temperature for non-oriented electrical steel sheet was developed in the experiments.Then its coating process was studied,and the adhesiveness,insulativity,heat resistance,corrosion resistance and other properties of the coating was m...
无取向电工钢孔洞缺陷控制实践
针对马钢无取向电工钢孔洞缺陷的分布规律及形貌特征,对缺陷样进行了显微分析,并利用生产实绩数据分析了该缺陷产生的原因。结合热轧生产过程,主要通过避免带钢撞击导卫以及降低导卫结瘤的产生等措施,可有效抑制热卷异物压入产生,从而降低冷轧工序孔洞的产生。 In viewing of the distribution and morphology characteristics of the hole defect of non-oriented electrical steel in Maanshan Iron and Steel Co.,Ltd.,the causes of the defect were analyzed by micro analysis of the defect sample and the production data.Combined with the production process of hot rolling,by avoiding the impact of strip steel on the guide and reducing the nodule formation on the guide,the pressing of foreign bodies in hot coiling could be effectively suppressed,thus reducing the fo...
Fe-6.5%Si高硅钢的性能及制备技术
Fe-6.5%Si高硅钢是一种具有高磁导率、低矫顽力和低铁损等优异软磁性能的合金,但是其室温脆性和低的热加工性能严重影响了其在工业领域的应用。综述了Fe-6.5%Si高硅钢的性能,评述了合金的改性法、特殊轧制法、快速凝固法、沉积扩散法、粉末冶金法等制备工艺。 It is well known that 6.5%Si high silicon steel is one kind of soft magnetic materials with higher re-lative permeability,lower coercive force and iron loss than those of conventional industrial silicon steel.However,their room-temperature embrittleness and poor workability limit their practical applications in the industry.The pre-paration technique such as modification treatment on alloy,special rolling,rapid solidification,CVD and powder me-tallurgy is reviewed.
树脂含量对半无机型无铬无取向硅钢涂层性能的影响
本文研究了丙烯酸树脂含量对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同树脂含量对硅钢绝缘涂层的耐盐雾性能和电化学行为的影响,同时采用SEM对涂层的表面形貌和附着性进行研究.结果表明,树脂含量为19.9~29.4%时,涂层的耐蚀性和附着性最好;树脂含量过多时,涂层的耐蚀性和附着性均较差. This paper studies the influence of acrylic resin on the performance of insulating coating of aluminum dihydrogen phosphate on chromium-free non-oriented silicon steel.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of acrylic resin content on the salt spray resistance and electrochemical behavior of the insulation coating of nonoriented silicon steel.The surface morphologys and adhesion of coating were tested by SEM....
50W600无取向硅钢在轧制与退火工序间的织构演变
运用电子背散射衍射(EBSD)技术,研究了50W600无取向硅钢在热轧→冷轧→退火工序间织构的演变。结果表明:由于热轧板沿板厚方向的应力场和温度场存在差异,导致热轧板不同层织构类型和强度存在差异;热轧板表层主要存在铜型、黄铜和高斯织构,1/4层织构主要为α纤维织构和较弱的高斯织构,中心层织构较单一,主要为α纤维织构;和热轧板相比,冷轧板各层织构差异较小,为典型的轧制织构(α纤维织构和γ纤维织构);退火板各层都表现为γ纤维织构增强、α纤维织构减弱,旋转立方织构基本消失。 The texture evolution of 50W600non-oriented silicon steel in hot rolling,cold rolling and annealing process was investigated by electron back-scatter diffraction(EBSD)technology.Results show that the hot rolled plate texture types and intensities along thickness direction were different because of the different stress fields and temperature fields.The major texture types in the surface of hot rolled plate were copper,brass and Gauss texture.The texture was composed ofαfibre texture and weaker Ga...
普通取向硅钢轧制过程中组织和织构的演变
借助电子背散射衍射(EBSD)及ZEISS-200MAT金相显微镜对某钢厂普通取向硅钢(CGO)进行研究,研究结果表明:热轧板组织、织构沿板厚方向存在明显的不均匀性,在热轧板表层及次表层发生再结晶,同时存在强度较高的Goss织构,中心层存在较强的{001}<110>变形织构。冷轧组织均呈纤维状条带组织,一次冷轧后,热轧板中的Goss织构消失,织构主要为α、γ织构,经中间脱碳退火后,α、γ织构强度减弱,并出现一定强度的Goss织构和利于Goss织构发展的{554}<225>、{332}<113>等织构,经二次冷轧后,二次冷轧织构类型与一次冷轧织构一致,但织构强度不同。 The grain-oriented silicon steel produced by a steel factory was investigated by EBSD and ZEISS-200 MAT metallographic microscope.The results show that the textures and microstructures along thickness of hot rolled slab are inhomogeneous.The surface layer and the layer near that are recrystallized structure which has a high Goss texture,but there is deformation texture{001}<110>in the central layer.The structure after cold rolling is a structure like fiber strip.After the first cold rollin...
取向硅钢超大高斯晶粒取向偏离角的X射线衍射测量
介绍了一种适用于超大晶粒取向硅钢的高斯晶粒取向偏离角的X射线衍射测量方法,提出了将试探法和探测器扫描法相结合的方式进行测量。结果表明:该方法可以同时获得准确的实际衍射角度和取向偏离角度,试样制备方式简单,对设备的要求低且测量结果准确。 This paper introduces a X-ray diffraction measurement method of Gaussian grain orientation deviation angle for ultra-large grain oriented silicon steel, and puts forward a method of combining the test method with the detector scanning. The results show that this method can obtain accurate actual diffraction angle and orientation deviation angle at the same time. The sample preparation method is simple, the requirements for equipment are low, and the measurement results are accurate.
加热温度对W470高硅钢连铸坯氧化铁皮的影响
采用SEM、EDS和XRD对不同加热温度下W470连铸坯氧化铁皮的微观形貌及相结构进行研究。结果表明,W470氧化铁皮难以除去的原因是氧化铁皮熔化,液相包裹着FeO,凝固时发生共晶反应,生成FeO/Fe2SiO4共晶混合物,并深嵌入基体。降低加热炉的加热温度,使连铸坯全程在FeO/Fe2SiO4共晶混合物熔点(1177℃)以下加热,可降低氧化铁皮与基体的结合力,能够有效解决W470除鳞困难问题。 The microstructure and phase structure of iron scale of W470 continuous casting billet at different heating temperatures were investigated by SEM,EDS,and XRD.The results show that the reason why the iron scale of W470 removes hardly is that iron scale is melted and the FeO is surrounded by the liquid phase,which forms FeO / Fe2SiO4eutectic mixture and is embedded into the matrix after solidification.Lowering the heating temperature and keeping the continuous casting billet heating under the melt...
电感耦合等离子体质谱法测定硅钢中痕量铝钼钒钛铌
研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c...

