硅钢资料

研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c... 

综述了退火温度、时间对无取向电工钢磁性的影响。退火温度主要影响无取向电工钢不同织构的占有率,退火时间主要影响晶粒尺寸的大小,晶粒尺寸的变化对织构的形成也有一定的影响。磁感最高点出现在纤维组织完全消失,(111)面织构组分较弱的组织状态。铁损的降低主要依赖于磁滞损耗的降低,织构的影响不大。 The effects of annealing temperature and time on the non-oriented electrical steel magnetic properties were reviewed.Annealing temperature and time mainly affects the different textures share and the grain sizes of non-oriented electrical steel respectively.Changes of the grain sizes also have a certain effect on textures formation.The highest point of the magnetic induction value in the fibrous tissue completely disappears and{111} plane texture has a lower state of the component content.Iron l... 

研究了退火温度和退火时间对电沉积硅钢试样中的断面层组织、硅在试样中的分布情况、织构分布和磁性能的影响。结果表明:退火温度为1000℃、退火时间为210 min时得到的试样晶粒分布均匀、硅在试样中分布均匀、硅平均浓度为6.3715%(接近6.5%)。试样的织构分析及磁性能检测的结果表明,在较高温度下延长退火时间可增加{100}和{110}面织构,降低铁损,所得试样的磁性能较为良好。 The effect of annealing temperature and time on the microstructure, distribution of silicon,texture and magnetism of the high silicon steel prepared by electrodeposition was investigated. The results showed that after annealing at 1000℃ for 210 min, the mean grain size of steel was about 190 μm with a uniform grain size distribution, and the silicon is also uniformly distributed on the entire cross section with an average Si concentration 6.3715%(close to 6.5%); With the increasing annealing tim... 

结合工业化生产过程中出现的同卷带钢头、尾磁性能差异现象,对50SW1300牌号无取向硅钢同卷带钢头、尾试样的夹杂物、晶体织构和显微组织进行了分析研究。结果表明,夹杂物、晶体织构是影响成品钢卷磁性能的重要因素。夹杂物是造成同卷带钢头、尾铁损差异的主要原因。夹杂物数量越多,尤其是小尺寸的夹杂物数量越多,对成品带钢的磁性能影响越大,对于本试验而言,AlN和MnS是影响成品带钢磁性能的主要夹杂物。晶体织构是造成同卷带钢头、尾磁感应强度差异的主要原因。有益的{100}和Goss织构含量越大,有害的{111}<110>和{111}<112>织构含量越小,即有益织构与有害织构含量比越大,成品带钢的磁感应强度越大。 Based on the industrial manufacture of non-oriented silicon steel sheets 50SW1300, the magnetic property variation of head and tail of the same finished steel sheets was discussed by analyzing non-metallic inclusion, crystal texture, and microstructure. Results show that, both of the non-metallic inclusion and the crystal texture will affect the magnetic properties significantly. The non-metallic inclusion is the key factor of the core loss variation of head and tail of the same finished steel s... 

概述了高磁感取向硅钢生产工艺的研究现状及发展趋势。介绍了国内外薄板坯连铸连轧流程生产高磁感取向硅钢的研究现状。从流程工序特点、热履历、组织与抑制剂控制方面进行对比,分析了薄板坯连铸连轧流程相对传统板坯流程生产高磁感取向硅钢的技术优势,在此基础上提出了利用该流程生产高磁感取向硅钢需要解决的主要技术难点。 The current status and development trend of production process for high magnetic induction grain-oriented silicon steel are summarized.The research status of producing high magnetic induction grain-oriented silicon steel by thin slab casting and rolling process at home and abroad is introduced.The potential technical advantages of producing high magnetic induction grain-oriented silicon steel by thin slab casting and rolling process are obtained by analyzing in terms of process characteristics,t... 

利用背散射衍射技术(EBSD)和XRD,研究了两段式脱碳退火工艺对取向硅钢纵截面初次再结晶的微区取向、取向差分布、特殊晶界(CSL)及高温退火试样高斯织构。分析了初次再结晶晶界特征对取向硅钢高温退火后宏观织构的影响。结果表明:初次再结晶的纵截面基体中Σ3和Σ5晶界使得高斯晶粒有着较高的迁移率,在高温退火时借助20o～45°的大角度晶界的界面能吞并周围{111}<112>晶粒迅速长大,形成密度水平较高的高斯织构。 Micro area orientation of primary recrystallization,the misorientation distribution,special boundaries under different two-stage decarburization annealing and the Goss texture under high temperature annealing the longitudinal section of grain-oriented silicon steel were detected by electron back scattering diffraction(EBSD) and X-ray diffraction(XRD).The effect of primary recrystallization grain boundary on macrotexture after high temperature annealing was analyzed.The results show that the Σ3 a... 

观察了取向硅钢极薄带经冷轧至不同厚度,并经过不同工艺热处理后的显微组织及亚结构。结果表明:冷轧压下量越大,显微组织中位错密度越高,冷变形组织越多,等轴晶粒越少;增加冷轧压下量可以使试样的再结晶温度降低,当钢带厚度为0.08 mm时,在650℃退火时就能发生明显的再结晶。 Microstructure and substructure of the grain oriented ultra-thin silicon steel sheets is analyzed,which are rolled down to different thickness and treated with different heat treatment process.The result shows that there are higher dislocation density,more cold deformation structure and less equiaxed crystal grain in microstructure of the steel sheets with more cold rolled reduction.Increase of cold rolled reduction will decrease recrystallization temperature,and when thickness of the steel shee... 

【摘要】 <正>含6.5%Si的电工钢是软磁特性最佳的电...

对低温法生产的以AlN为主抑制剂的Hi-B取向硅钢高温退火过程进行了中断实验,借助EBSD及TEM技术对高温退火连续升温过程中织构与析出物的演变进行了研究。实验结果表明,800℃时ODF图出现高斯织构组分,但强度很弱,高斯晶粒偏离角在10°以上;950~1 000℃时高斯晶粒异常长大,偏离角3~6°;高温退火过程析出物主要有球形、规则立方形及不规则多面体形3种形貌,由于渗N的影响,Zener因子先增大再减小,并且析出物在高斯晶界前沿优先粗化。 The annealing process at high temperature of Hi-B silicon steel using low slab reheat temperature and with AlN as the inhibitor has been studied by interrupting test,and the evolution of texture and precipitates during continuous heating-up in the annealing process at high temperature was analyzed by EBSD and TEM. The results showed that Goss texture appears in ODF at 800 ℃,but the intensity of Goss texture was very weak and the deviation angle was more than10°. Goss grains grow abnormally durin... 

试验研究了退火温度(850~950℃)和时间(5~18 min)对2.3 mm热轧硅钢板(/%:0.036C,3.15Si,0.21Mn,0.005P,0.007S,0.032A1)6道次轧制的0.35 mm冷轧板组织和织构的影响。结果表明,退火温度越高,晶粒平均尺寸越大,900℃5 min退火时平均晶粒尺寸41.39μm,试样织构主要集中在γ取向线上的{111}<112>织构组分和{111}<110>织构组分;900℃18 min退火时平均晶粒尺寸为48.08μm,试样的{111}面织构和{112}面织构密度都明显减弱,{001}面织构增强,磁性能较优。 The effect of annealing temperature(850 ~950 ℃) and holding time(5 ~ 18 min) on structure and texture of 0.35 mm sheet by 6 passes cold-rolling from 2.3 mm hot-rolled plate of silicon steel(/%:0.036 C,3.15 Si,0.21 Mn,0.005 P,0.007 S,0.032A1) has been tested and studied.Results show that the higher the annealing temperature the coarser the average grain size;As annealing at 900 ℃ for 5 min the average grain size of steel sheet is 41.39 μm,and the texture in sample is mainly concentrated in y orie... 

聚焦无取向硅钢产品标准,从电磁性能、表面性能、机械性能以及尺寸公差与边部质量等维度对国际标准IEC、EN、JIS、ASTM以及国标GB进行了分析研究。分析得出,各类标准在电磁性能方面要求基本一致;ASTM标准的机械性能要求有别于其他几个标准。 In this paper,non-oriented silicon steel standards of EN,JIS,GB and ASTM were compared and analyzed. It is showed that,all types of standards in electromagnetic performance requirements are basically the same. Surface properties in ASTM standard are expressed in the most detailed. The mechanical properties requirements of the standards,except for ASTM,are basically the same. 

绝缘涂层可以有效提高硅钢片的耐蚀、耐腐、磁、绝缘等性能，因此取向硅钢涂装绝缘涂层是取向硅钢生产过程中重要的一环。本文对取向硅钢含铬无机绝缘涂层以及氮化铬涂层的性能优缺点进行了介绍，并对国内无机含铬取向硅钢绝缘涂层及氮化铬涂层的研究现状进行了综述。最后对未来含铬无机绝缘涂层的研发方向进行了展望。 Insulation coating can effectively improve the corrosion resistance of silicon steel sheet, such as corrosion, magnetic, insulation performance, thus oriented silicon steel insulation coating is the important part of oriented silicon steel production process. In this paper, the inorganic insulation coating oriented silicon steel containing chromium and chromium nitride coating performance advantages and disadvantages are introduced.In addition, the research status of insulation coating and chrom...