硅钢资料

用还原分离-原子荧光光谱法分析了硅钢中的痕量汞.分析方法的不确定度主要来自测量重复性,样品溶液浓度,工作曲线变动性,标准溶液,移取、配制标准溶液,仪器变动性等.文章分别对上述构成合成不确定度大小的分量进行了计算讨论. Trace mercury in silicon steel and galvanized sheet was analyzed by adopting reduced separation-atomic fluorescence spectrometry.The uncertainty of the analysis method mainly comes from measurement repeatability,sample concentration,working curve volatility,standard solution,pipetting and preparation of standard solution,and instrument variability,etc.The essay conducted all calculations and discussions on the above components that determine uncertainty. 

根据现场实际的生产控制情况,指出了热轧原料断面轮廓缺陷以一定的比列遗传给了冷轧带钢,分析了不同热轧原料断面轮廓对冷轧电工钢尺寸精度的具体影响,提出了相应的规律。并阐明了严格控制热轧原料断面轮廓形貌,对保证冷轧电工钢尺寸精度具有重大意义,对于中国现行的冷轧电工钢生产具有指导意义。 Based on the actual situation of production control,it was pointed out that the section profile defects of hot-rolled raw materials were geneticed to the cold-rolled strip.The specific impact analysis for the profile of different hot-rolled raw materials to the dimensional accuracy of cold-rolled silicon steel was analyzed.As a result, the corresponding orderliness are given;And the strict control to section profile of the hot-rolled material is of great significance to ensure the dimensional ac... 

采用低温板坯加热制备取向硅钢,通过透射电镜(TEM)观察并研究热轧板中的析出物,用ODF织构法研究热轧板距表面1/8、1/4和1/2处的织构分布。结果表明,热轧板中的析出物主要是密排六方AlN,AlN形貌呈规则长方形,AlN颗粒大小不等,分布密度低;热轧板中的织构沿板厚方向,由亚表层的{110}<001>织构向1/2中心层的α线织构变化,其中{110}<001>织构在热轧板距表面1/4层处最强。 The low temperature grain-oriented silicon steels were produced by acquired inhibitor method.The precipitates in hot rolling strip were observed and studied by transmission electron microscope,and the texture distribution in 1/8,1/4 and 1/2 layers of hot rolling strip were analyzed by ODF method.The results showed that the square shaped h-AlN is the main precipitates in hot rolling strip.The precipitates are varying in size and distribution.The texture of hot rolling strip in thick direction are... 

对1990~2010年在我国申请的冷轧无取向硅钢涂层的专利数量、专利技术领域分布进行了统计,对典型涂层专利技术进行了分析,探讨了无取向硅钢涂层的发展趋势。统计分析结果表明,目前无取向硅钢涂层典型的专利技术主要有自粘结涂层、无铬含稀土元素涂层、含钼酸盐环保涂层及采用有机-无机纳米杂化材料为主成膜物形成的涂层等。无取向硅钢涂层发展的趋势主要是无铬环保的半无机、半有机型涂层。 The patent quantity of cold-rolled non-oriented silicon steel coating and distribution of technology fields applied in China in 1990-2010 were summarized.The analysis results indicate that typical patent technologies include self-adhesion coating,chromium-free and with rare earth element coating,environment-friendly and with molybdate coating,coatings with organic-inorganic hybrid materials as main forming agent and so on.The main development trends of coatings on silicon steel are among semi-in... 

采用电子背散射衍射技术测定50SW1300冷轧无取向硅钢中不同尺寸范围晶粒的含量,利用主成分回归分析法,综合研究不同尺寸范围晶粒的含量对无取向硅钢磁性能的影响。结果表明:通过主成分回归分析法能够从不同尺寸范围晶粒的含量的多个影响因素中获取主要的因素,定量研究它们对无取向硅钢磁性能的影响规律。分析表明,无取向硅钢的铁损与不同尺寸范围晶粒的含量之间存在着可靠的多元线性关系,在一定范围内,较大尺寸晶粒的含量越多,其对铁损优化的作用越明显;而无取向硅钢的磁感与不同尺寸范围晶粒的含量之间并无线性关系。 Distribution of grain size in cold rolled non-oriented silicon steel 50SW1300 was measured by EBSD.The effects of the distribution of grain size on magnetic properties of the non-oriented silicon steel were comprehensively researched by means of principal component regression method.The results indicate that the main factors influencing the magnetic properties in the distribution of grain sizes,which can be used to guantitative study the magnetlic properies of the steel,are obtained by principal... 

结合工业化生产过程中出现的同卷带钢头、尾磁性能差异现象,对50SW1300牌号无取向硅钢同卷带钢头、尾试样的夹杂物、晶体织构和显微组织进行了分析研究。结果表明,夹杂物、晶体织构是影响成品钢卷磁性能的重要因素。夹杂物是造成同卷带钢头、尾铁损差异的主要原因。夹杂物数量越多,尤其是小尺寸的夹杂物数量越多,对成品带钢的磁性能影响越大,对于本试验而言,AlN和MnS是影响成品带钢磁性能的主要夹杂物。晶体织构是造成同卷带钢头、尾磁感应强度差异的主要原因。有益的{100}和Goss织构含量越大,有害的{111}<110>和{111}<112>织构含量越小,即有益织构与有害织构含量比越大,成品带钢的磁感应强度越大。 Based on the industrial manufacture of non-oriented silicon steel sheets 50SW1300, the magnetic property variation of head and tail of the same finished steel sheets was discussed by analyzing non-metallic inclusion, crystal texture, and microstructure. Results show that, both of the non-metallic inclusion and the crystal texture will affect the magnetic properties significantly. The non-metallic inclusion is the key factor of the core loss variation of head and tail of the same finished steel s... 

轧制力是影响冷轧带钢厚度精度的关键因素。为实现高精度的冷轧带钢厚度控制,通过优化变形抗力模型参数和摩擦系数模型参数提高冷轧轧制力模型计算精度,并使用指数平滑法的自学习算法保证轧制力精度的稳定性。在首钢股份公司迁安钢铁公司20辊森基米尔轧机生产线进行S12硅钢钢种轧制力优化试验,将优化的模型参数应用于L2并投入现场生产,结果表明该优化方法不仅提高了轧制力设定精度,而且减小了冷轧硅钢的厚度超差长度,提高了成材率。 The rolling force is the key factor which influences the accuracy of cold-rolling strip thickness. To implement high precision control of cold-rolling strip thickness,we optimize the deformation resistance model parameters and friction coefficient model parameters to improve the calculation precision of cold-rolling force model,and use exponential smoothing self-learn algorithm to ensure the stability of rolling force accuracy. In Shougang Qiangang 20-high Sendzimir mill single stand production ... 

采用热模拟方法及EBSD技术,研究Fe-3 wt%Si电工钢在不同温度下组织的动、静态再结晶及晶粒取向特征,特别是少量奥氏体对铁素体动、静态再结晶组织及取向的影响。结果表明,不同温度形变的组织主要分三类:形变长条铁素体、珠光体和等轴细小铁素体。长条形变铁素体内发生动态回复或连续式的动态再结晶,奥氏体周围的铁素体动态再结晶加速,部分以传统的不连续方式动态再结晶。铁素体、奥氏体都可发生静态再结晶。奥氏体的静态再结晶在1050℃以上明显,铁素体的静态再结晶随温度的升高逐渐进行,最显著的再结晶发生在1050℃。不同温度形变的样品,其形变晶粒取向主要以<111>和<100>为主,小等轴铁素体晶粒除与大形变铁素体取向相近外,出现了<110>取向及其它取向。 Static and dynamic recrystallization and grain orientations in a hot-compressed Fe-3 wt% Si electrical steels were studied at different temperatures using Gleeble simulator and EBSD technique,particularly focusing on the effect of small amount of austenite on ferritic microstructure and orientations.The results show that microstructure of the compressed steel,depending on deformation temperature,consisted of elongated and deformed ferrite,pearlite and fine equal-axed ferrite.The elongated ferrit... 

介绍了CSP工艺生产无取向电工钢各工序的设备特点、采用的工艺控制手段和电工钢产品质量情况,结合生产实践证明了马钢CSP工艺开发的无取向电工钢产品丰富了薄板坯连铸连轧的品种结构,发挥了薄板坯连铸连轧生产无取向电工钢性能均一、稳定的特点。 The equipment characteristic,the process control method and the quality of non-orientated silicon steel by CSP process were introduced.Combined with the production situation,it is proved that production of non-orientated silicon steel developed on Masteel CSP line would enrich product structure of thin slab continuous casting and rolling,and it exerts stable performance of non-orientated silicon steel. 

通过热力学计算及实验室研究,对钙处理前后50W600无取向硅钢退火冷轧板中夹杂物的类型、数量及尺寸进行了系统分析。结果表明,50W600无取向硅钢经钙处理后(w(Ca)=0.002 6%),钙在1 600℃的钢液中主要以固态的CaO·2Al2O3、CaO·6Al2O3及溶解钙的形式存在。在钢液的凝固过程中,钢中的溶解钙和硫反应生成了CaS和CaS-MnS复合夹杂,有效抑制了MnS的弥散析出,减少了钢中微细夹杂物的数量。同时钙处理促进了钢中微细夹杂物的聚合长大,导致显微夹杂物的数量增加。 Based on thermodynamic calculation and laboratory experiment,the type,quantity and size of inclusions in annealed cold-rolled steel sheets of 50W600 non-oriented silicon steel before and after calcium treatment were systematically studied.Results showed that after calcium treatment(w(Ca) = 0.002 6%),calcium was mainly in the form of CaO·2Al2O3,CaO·6Al2O3 and dissolved calcium in steel at 1 600 ℃.Dissolved calcium could combine with sulfur to form CaS inclusions and compound CaS-MnS inclusions du... 

对低温加热工艺生产的普通取向(common grain-oriented,CGO)硅钢的高温退火过程进行了中断实验,材料为含3.0%Si、0.5%Cu、0.009 8%S(均为质量分数)的以Cu2S为主抑制剂的普通取向CGO钢。原始板坯厚度为230 mm,于1 200℃均热后经4道次粗轧、7道次精轧至2.3mm;热轧板采用两次冷轧法轧至0.3mm,中间完全脱碳退火,最后于1 200℃高温退火。最后样品的磁性能:铁损P17/50为1.182W/kg,磁感应强度B8为1.897T。借助配有EDAX OIM电子背散射衍射(EBSD)系统的ZEISS SUPRA 55VP扫描电子显微镜,对高温退火过程中高斯晶粒的演变进行了研究,结果表明:升温过程中晶粒尺寸增长缓慢,650℃时取向分布函数(ODF)图出现高斯织构组分,但强度很弱,高斯晶粒偏离角小于9°;950℃时高斯晶粒平均生长速度超过其他晶粒;950~1 000℃时高斯晶粒异常长大,偏离角降至约3°;在950℃之前高斯取向晶粒相比于其他晶粒没有尺寸优势。 The high-temperature annealing process of common grain-oriented(CGO)silicon steel was investigated by interrupting test.The samples were rolled from CGO silicon steel slab under low reheating temperature.The CGO silicon steel,taking Cu2S as the main inhibitor,contains3.0%Si,0.5%Cu,and 0.0098%S.The original casting slab is 230mm in thickness.After 1 200℃reheating,four-pass rough rolling and seven-pass finish rolling were conducted to make the thickness of the slab get to 2.3mm.Then the hot rolled... 

在实验室模拟CSP工艺条件下制备了取向硅钢,研究了二次冷轧中间退火工艺对组织和织构的影响。结果表明,中间退火温度对取向硅钢脱碳,高温退火组织及织构均产生明显影响。经940℃中间退火后,取向硅钢脱碳再结晶晶粒较850℃中间退火的多,且再经高温退火处理后,晶粒粗化,最大晶粒尺寸达4.8 mm;高斯织构组分密度达27.00,较850℃中间退火试样高。 Grain-oriented silicon steel was prepared by simulated CSP technology in laboratory. Effects of secondary cold-rolled intermediate annealing on microstructure and texture were studied. The results show that intermediate annealing has obvious effects on the microstructure and texture of the steels after decarburization annealing and high temperature annealing. After intermediate annealing at 940 ℃,recrystallized grain of decarburization annealed steel is more than that of intermediate annealed at...