硅钢资料

采用X-射线衍射分析技术测定了取向硅钢热轧板在不同压下率下不同厚度处的织构。结果表明,在压下率低于80%的情况下,几乎所有试样的不同厚度处的织构均为旋转立方织构类型{100}<011>,但不同压下率、不同厚度处的织构强度存在很大差异;在压下率大于80%的情况下,不同试样的不同厚度处的织构类型发生了变化,其织构类型为旋转立方织构或高斯织构{011}<100>,且当织构类型为旋转立方织构时,织构强度存在很大差异,而当织构类型为高斯织构时,织构强度差异相对较小。 The texture of the grain oriented silicon steel hot rolled plate at different compressibility has been measured.The experimental results have shown that the texture of all samples at different thickness is {100}<011> when the compressibility is below 80%,and its intensity at different compressibility and thickness is difference.The texture of all samples at different thickness is variable when the compressibility is above 80%,it is {100}<011> or {011}<100>,and the intensity of ... 

磁性能指标是硅钢产品最关键的质量指标之一，但是目前磁性能判定100%依赖于样品的离线实验室检测结果，生产线配置的在线检测仪的测量结果由于精度问题，不宜直接用于成品牌号判级。本文在现有硅钢产品质量管控体系基础上，利用大数据技术对生产数据进行分析与建模，构建不同磁性能指标在线检测模型，并在现有信息系统上完成模型库的集成部署，实现硅钢产品全长、多指标磁性能结果的拟合数据输出，支撑取样优化、精准分切、辅助综合判定等功能应用，进一步优化硅钢产品质量管控体系。 The magnetic performance index of silicon steel products is one of the most critical quality indexes.However,at present,100%determination of magnetic performance depends on the offline laboratory test results of samples,and the measurement results of the online detector configured in the production line cannot be applied in practice due to the accuracy problem.Based on the existing quality control system of silicon steel products,big data technology was used to analyze and model the production d... 

为了确保硅钢铬酸盐涂料的环保性,需要严格控制涂料的固化工艺,保证涂料固化过程中涂料中的六价铬充分转化为三价铬。对涂料及原料进行热重分析(TG)及差示扫描量热法分析(DSC)。结果表明,MgO与铬酐混合转化为MgCrO4,使六价铬稳定性增强,其中大部分Cr6+转变为Cr3+发生在620~700℃,在450~500℃高于铬酐发生大量失重,因此必须加入还原剂保证涂料中六价铬被充分还原;超过360℃后树脂会发生分解,因此实际板温不能超过360℃;加入了还原剂的整体涂料的失重温度区间主要在260~320℃,因此涂料固化时钢板的实际温度最佳区间为320~360℃。 Because of the silicon steel chromate coating’s environmental requirements,the paint curing process must be controlled strictly to ensure all Cr( Ⅵ) transforms to Cr( Ⅲ). The TG and DSC analyses of the paint are studied. The reaction of MgO and CrO3 would generate MgCrO4,enhancing the stability of Cr( Ⅵ). The most r( Ⅵ) in MgCrO4 changes to Cr( Ⅲ) at 620-700 ℃,while the CrO3 has a large weight loss at 450-500 ℃. The reductant must be added in the paint to make sure the Cr( Ⅵ) could transform suf... 

【作者】 杨洪林； ...

以轻烧氧化镁粉为原料,经消化、碳化制得重镁水,在热解反应前采用络合剂对重镁水中的杂质钙、铁进行络合掩蔽,再经热解得到碱式碳酸镁,碱式碳酸镁经煅烧可制得钙、铁杂质含量较低的氧化镁。在重镁水络合除杂过程中,考察了络合剂三乙醇胺、柠檬酸、草酸单独和复合使用的除铁、除钙效果。以三乙醇胺为络合剂时,在200 mL重镁水中加10 mL三乙醇胺(1∶1),氧化镁产品中w(氧化镁)=99.3%、w(氧化钙)=0.31%、w(氧化铁)=0.042%;使用草酸和柠檬酸作为复合络合剂时,在200 mL重镁水中加入1.0 g柠檬酸和2.0 g草酸,氧化镁产品中w(氧化镁)=98.2%、w(氧化钙)=0.24%、w(氧化铁)=0.030%。 Light-burned magnesia as a raw material was hydrated and carbonated to obtain magnesium bicarbonate liquor.Before the pyrolyzing of magnesium bicarbonate liquor,complexants were used to cover Fe and Ca impurities.Then the treated liquid was pyrolyzed to obtain basic magnesium carbonate which was calcined to magnesium oxide with low calcium and iron content.During the complexing purification of magnesium bicarbonate liquor,the Fe and Ca removing effects of single or compound complexing agents,suc... 

【作者】 凌健； ...

采用RH精炼添加钙合金方式对硅钢进行钙处理,结果表明,钙合金添加量为0.67、1.00和1.67 kg/t钢时,钢中Ca含量分别为0、2×10-6和4×10-(6质量分数);随着钙合金添加量的增加,钢中夹杂物粒度逐渐由0～2μm向2～4μm、4～6μm偏移;不同钙处理条件下,钢中均存在粒径小于1μm和粒径为1～5μm的MnS、CuxS夹杂物,后者或单独存在,或与AlN、CaS夹杂复合;钢中粒径为5～10μm的夹杂物基本以Ca的氧化物和硫化物为主。与未经钙处理的炉次相比,钙合金添加量为0.67、1.00和1.67 kg/t钢时,粒径小于1.0μm的夹杂物减少幅度分别为68.06%、87.50%和94.94%。钙合金添加量为1.67 kg/t钢时,可以去除钢中绝大部分的微细夹杂物。 In order to improve the properties of final silicon steels,the calcium treatment was adopted by adding Ca alloys into the liquid steel during the RH refining process.Results show that when the addition of Ca alloys is 0.67 kg/t,1.00 kg/t and 1.67 kg/t,the corresponding Ca content in silicon steels is 0,2 × 10-6 and 4 × 10-6 respectively.With the increase of Ca alloy addition,the particle sizes of inclusions in steels become 2～4 μm and 4～6 μm,from 0～2 μm.Under different calcium treatments,there e... 

研究了硼酸对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响。用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同硼酸含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响,同时采用SEM对涂层的表面形貌进行了研究。结果表明,硼酸含量为9.7%时,涂层的耐盐雾性及电化学性能最好;硼酸含量过少或过多时,涂层的耐蚀性和电化学性能都较差。 Influence of boric acid on the performance of chromium-free non-oriented silicon steel insulating coating based on aluminum dihydrogen phosphate was investigated.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of boric acid content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.Surface morphologies of the coatings were tested by SEM.Result shows that when the boric ... 

针对新日铁公开的相关专利,总结日本高强度无取向电工钢的研究进展,分析了各专利化学成分、生产工艺及产品性能的特点,指出固溶强化、细晶强化、析出强化、位错强化都有可能被用来提高无取向电工钢的强度。在高强度无取向电工钢的研发过程中,需要根据其具体用途确定目标性能,再采用合适的强化手段,从而实现力学性能、磁性能和生产性能之间的平衡。 Authors summarize the research progress of high strength non-oriented electrical steel in Japan by learning related patents brought into the public by Nippon Steel. Authors also analyze the characteristics of the chemical composition, production technology and properties of products in the patents and point out that any ones of solution strengthening method, fine-grain strengthening method, precipitation strengthening method or dislocations strengthening method may be used to improve the strengt... 

采用热模拟方法及EBSD技术,研究Fe-3 wt%Si电工钢在不同温度下组织的动、静态再结晶及晶粒取向特征,特别是少量奥氏体对铁素体动、静态再结晶组织及取向的影响。结果表明,不同温度形变的组织主要分三类:形变长条铁素体、珠光体和等轴细小铁素体。长条形变铁素体内发生动态回复或连续式的动态再结晶,奥氏体周围的铁素体动态再结晶加速,部分以传统的不连续方式动态再结晶。铁素体、奥氏体都可发生静态再结晶。奥氏体的静态再结晶在1050℃以上明显,铁素体的静态再结晶随温度的升高逐渐进行,最显著的再结晶发生在1050℃。不同温度形变的样品,其形变晶粒取向主要以<111>和<100>为主,小等轴铁素体晶粒除与大形变铁素体取向相近外,出现了<110>取向及其它取向。 Static and dynamic recrystallization and grain orientations in a hot-compressed Fe-3 wt% Si electrical steels were studied at different temperatures using Gleeble simulator and EBSD technique,particularly focusing on the effect of small amount of austenite on ferritic microstructure and orientations.The results show that microstructure of the compressed steel,depending on deformation temperature,consisted of elongated and deformed ferrite,pearlite and fine equal-axed ferrite.The elongated ferrit... 

【摘要】 <正>由西电集团、保定天威集团使用迁钢公...

电工钢反复弯曲次数是电工钢性能检验的重要指标之一,直接影响到用户在使用电工钢过程的机加工性能。主要分析了试样宽度、试样张力、晶粒取向、反复弯曲设备等因素对电工钢反复弯曲试验的影响,并对各个因素的影响程度进行量化以及原因探讨,从而归纳形成各影响因素的基本规律,以便为电工钢实际生产、用户使用提供科学指导。结果表明:试样宽度增加,反复弯曲次数也会不断增加,晶粒位向对取向电工钢的反复弯曲次数影响较大,当支座顶部到拨杆底部的距离减小或拉紧力增加时,反复弯曲次数会不断减小,但当拉紧力达到60N以上时,对反复弯曲次数影响不大,试样经退火后,反复弯曲次数略有上升。 The reverse bend number is an important performance of electrical steels′capabilities,affecting the machining performance directly when the customers used.It investigated some factors,such as sample′s width,sample′s tension load,grain orientation and equipment,how to effect the reverse bend test for electrical steel,measured the influence degree,and discussed the reason,in order to form basic rules which could be guided the manufacturing and using for electrical steel.Results showed that the rev...