硅钢资料

采用热模拟方法及EBSD技术,研究Fe-3 wt%Si电工钢在不同温度下组织的动、静态再结晶及晶粒取向特征,特别是少量奥氏体对铁素体动、静态再结晶组织及取向的影响。结果表明,不同温度形变的组织主要分三类:形变长条铁素体、珠光体和等轴细小铁素体。长条形变铁素体内发生动态回复或连续式的动态再结晶,奥氏体周围的铁素体动态再结晶加速,部分以传统的不连续方式动态再结晶。铁素体、奥氏体都可发生静态再结晶。奥氏体的静态再结晶在1050℃以上明显,铁素体的静态再结晶随温度的升高逐渐进行,最显著的再结晶发生在1050℃。不同温度形变的样品,其形变晶粒取向主要以<111>和<100>为主,小等轴铁素体晶粒除与大形变铁素体取向相近外,出现了<110>取向及其它取向。 Static and dynamic recrystallization and grain orientations in a hot-compressed Fe-3 wt% Si electrical steels were studied at different temperatures using Gleeble simulator and EBSD technique,particularly focusing on the effect of small amount of austenite on ferritic microstructure and orientations.The results show that microstructure of the compressed steel,depending on deformation temperature,consisted of elongated and deformed ferrite,pearlite and fine equal-axed ferrite.The elongated ferrit... 

概述了无抑制剂法生产取向电工钢的特性及其用途;总结无抑制剂生产取向电工钢的原理及工艺方案.重点讨论了成分方案,即元素对磁性能的影响和最终高温退火方案对二次再结晶的影响.研究结果表明,无抑制剂取向硅钢化学成分范围没有普通取向硅钢和高磁感取向硅钢严格,提高了成材率;最终高温退火决定了二次再结晶的好坏,从而最终决定成品磁性能,最佳的高温退火温度在850～950℃之间. This article provides an overview on the characteristics and uses of inhibitorless process producing grain-oriented electrical steels.The mechanism of inhibitorless process and technology programs were discussed.The results show that the chemical composition and final annealing were determined according to magnetic properties.The inhibitor-free grain oriented silicon steel has loose range of chemical composition;Secondary recrystallization occurs mainly in the final annealing and the best anneal... 

通过对激光粒度分析仪测量硅钢级氧化镁(MgO)的分析条件进行优化,如分散介质、分散方式、样品预处理、仪器暗淡度等,探讨了硅钢级MgO粒度范围测量重现性较好的试验方法,满足硅钢生产过程控制对MgO粒度的要求。 The analysis condition of the laser particle size analyzer on grain oriented silicon-steel grade magnesium oxide is optimized,including the dispersion medium,dispersion methods,sample preparation,and instrument obscuration,etc.Therefore,particle size measurement with good reproducibility for silicon-steel magnesium oxide is discussed,which may meet the requirement of MgO particle size for silicon-steel process control. 

热卷箱位于热连轧带钢生产线粗轧与精轧机之间,是热连轧生产中比较理想的中间保温设备。由于取向硅钢变形温度区间较窄,在生产中易出现边裂现象,同时中间坯的边部温度难于得到保证,因此一般不采用热卷箱设备生产,限制了传统热连轧生产线产品开发的品种。通过合理优化热卷箱控制工艺参数,解决了某厂传统热连轧生产线用热卷箱生产取向硅钢的边部质量问题,成功地生产出取向硅钢带。 The hot coil-box is an ideal heat retaining apparatus for hot rolling,lined between roughing mill and finishing mill. But oriented silicon steel has a narrow deformation temperature range,so that the edge crack easily occurs and it is difficult to insure the temperature of the intermediate blank. Therefore,the hot coil-box is rarely used in producing oriented silicon steel,which restricts the product development of the traditional hot rolling line. The article reasonable optimized process parame... 

6.5%Si电工钢是一种优异的软磁材料,织构对其磁性能影响很大。利用温轧工艺对6.5%Si电工钢热轧板进行不同压下率轧制,研究了温轧板织构随压下率的变化规律。实验结果显示,随着压下率的增大,{100}〈110〉、{110}〈100〉和γ纤维织构在薄板表层中的强度先增强后减弱,当压下率达到75%时,沿板厚方向形成3个组织区域:表层细晶粒区({110}〈100〉取向为主)、过渡层({111}〈110〉和{111}〈112〉变形晶粒区)和中心层(以拉长的γ纤维织构和{100}〈110〉取向晶粒为主),这种组织和织构不均性对后期织构的发展有重大影响。 6.5wt% Si electric steel has excellent soft magnetic properties,on which texture play important role.In this experiment,warm rolling technique was employed to investigate the effect of rolling reduction on texture.It was found that the density of {100}〈110〉,{110}〈100〉 and γ-fiber textures first increased and then decreased with increasing of the rolling reduction.At 75% reduction,the microstructure along the thickness of the sheet formed three zones,containing surface layer with {110}〈100〉 orien... 

综述了退火温度、时间对无取向电工钢磁性的影响。退火温度主要影响无取向电工钢不同织构的占有率,退火时间主要影响晶粒尺寸的大小,晶粒尺寸的变化对织构的形成也有一定的影响。磁感最高点出现在纤维组织完全消失,(111)面织构组分较弱的组织状态。铁损的降低主要依赖于磁滞损耗的降低,织构的影响不大。 The effects of annealing temperature and time on the non-oriented electrical steel magnetic properties were reviewed.Annealing temperature and time mainly affects the different textures share and the grain sizes of non-oriented electrical steel respectively.Changes of the grain sizes also have a certain effect on textures formation.The highest point of the magnetic induction value in the fibrous tissue completely disappears and{111} plane texture has a lower state of the component content.Iron l... 

利用电子探针面分析、状态分析及电子背散射衍射相分析技术研究硅钢高温氧化铁皮的显微结构。电子探针面分析可以直观的看出元素的分布状态,初步判断氧化铁皮的结构,而状态分析可以准确表征常规氧化铁皮中铁元素的状态,对于合金元素富集区域则通过电子背散射衍射相分析技术来标定。结果表明,高温氧化铁皮的结构主要有4层,即最外层为厚度约为10μm的Fe2O3相,次外层为Fe3O4相,中间层为FeO相上分布有颗粒状的Fe3O4相,最内层为FeO相和Si元素富集的Fe2SiO4相。其中Fe2SiO4层的分布特征与加热温度密切相关:1 100℃时,Fe2SiO4相呈颗粒状,弥散分布在FeO层;1 200℃时,Fe2SiO4相呈液态,侵入基体和疏松的FeO层,且沿着FeO晶界呈网状分布。 The microstructure of high temperature oxide scale on silicon steel was characterized by electron probe microanalyzer(EPMA)mapping analysis,state analysis and electron backscatter diffraction(EBSD)phase analysis.The element distribution and the initial structure of the oxide scale could be detected by EPMA mapping analysis apparently.And the state of iron in the conventional oxide scales could be determined by state analysis.Meanwhile,the alloy-rich region could be identified by EBSD phase analy... 

【作者】 陶永根； ...

涂层技术在高磁感取向硅钢生产中起着重要的作用.根据生产实践,介绍了高磁感取向硅钢生产中涂层的种类和作用、涂料的成分和对产品性能的影响、涂层工艺质量控制要点和检验方法等,并提出了通过优化涂层工艺改善高磁感取向硅钢性能和外观质量的方法. Surface coating technique plays an important role in producing high magnetic inductivity grain-oriented silicon steel.Based on production practice,this paper describes the types and function of the coating,the composition of the coating and its effect on the product performance,the quality control and inspection method for the coatings,as well as proposes ways to improve the magnetic property and surface quality of the steel by optimizing the coating process. 

利用光学显微镜（OM）和扫描电镜（SEM）研究了不同稀土Ce含量的50W470无取向硅钢的铸坯、热轧板和冷轧退火板的宏观和微观组织，并采用磁性能测试仪测定其磁性能。结果表明：当稀土Ce的加入量从0增加到66×10^-6（质量分数）时，铸坯的柱状晶平均宽度从3.82 mm减小到3.24 mm,等轴晶率从43.1%增加到51.3%;热轧板的平均晶粒尺寸逐渐增加，从26.2μm增加到33.3μm,再结晶百分数从24%增加到37%;退火板的平均晶粒尺寸从36.2μm增加到39.3μm;磁性能测试表明，微观组织的变化有利于50W470无取向硅钢铁损降低和磁感提高。 Macro-structure and microstructure of as-cast plate, hot rolled plate and cold rolled annealed plate of 50 W470 non-oriented silicon steel with different rare earth Ce content was studied by optical microscope（OM） and scanning electron microscopy（SEM）, and their magnetic properties were measured by magnetic property tester. The results show that when the addition amount of rare earth Ce increases from 0 to 66×10^-6（mass fraction）, the average width of columnar crystal of the as-cast pl... 

利用热模拟试验机、光学显微镜和X射线衍射仪对Fe-3.2%Si低温取向硅钢热轧工艺参数对组织及织构的影响进行了研究。结果表明,Fe-3.2%Si硅钢在1110℃粗轧、880℃终轧,轧后以10℃/s的速度冷却到550℃卷取,然后空冷到室温,热轧硅钢板沿板厚方向的显微组织不均匀性显著,对后续发展完善的二次再结晶有重要作用。无论是热轧板,常化板还是冷轧板,它们的织构集中分布在γ取向线上,γ取向线的织构除取向密度不同外,织构种类是一致的,这说明γ取向线上织构是有继承性的。从热轧到常化,织构取向密度显著减小,经二次冷轧后,织构密度又显著升高,可见,轧制变形有助于织构的形成并使织构强度升高。 The influence of hot-rolled process parameters on the microstructure and texture of Fe-3.2%Si low temperature hot rolled grain-oriented silicon steel were researched by hot simulation experiment machine,light microscope and X-ray diffractometer.The results show that,Fe-3.2%Si silicon steel is rolled by the technology with a temperature of rough rolling of1110℃,finish rolling of 880℃,coiling with the speed of 10℃ /s,and then cooled to room temperature with air.The microstructure of hot-rolled sil... 

研究了常化温度、常化时间及常化后冷却速度对Si的质量分数为1.6%的无取向电工钢成品磁性能的影响。结果表明:在850~1 050℃范围内,随着常化温度的升高,成品铁损先减小后增大,成品磁感应强度先增大后减小;当常化温度为1 000℃时,成品平均铁损最低,平均磁感应强度最高;常化时间从3min延长到7min时,成品铁损先减小后增大,成品磁感应强度则呈单调下降趋势;随着常化冷却速度的降低,成品铁损先减小后增大,成品磁感应强度则呈单调增大趋势;对于Si的质量分数为1.6%的无取向电工钢,最佳的常化制度为:在1 000℃进行常化,时间5min,常化后空冷。对热轧板进行常化后,热轧板发生了不同程度的再结晶和晶粒长大。提高常化温度、延长常化时间、降低冷却速度,都能使常化板晶粒粗化,进而粗化成品板晶粒,改善磁性能。通过扫描电镜观察发现,成品板中析出物主要为AlN和MnS的复合析出物,以及少量的单独析出的AlN和MnS,而常化工艺主要是通过粗化析出相,减少细小析出相数量,从而减少对晶界钉扎作用来改善成品磁性能。 The effects of normalizing temperature,normalizing time and cooling rate after normalizing on magnetic properties of non-oriented electrical steel with mass fraction of Si of 1.6% were investigated.The results show that core loss of product decreases first and then increases,while magnetic induction increases first and then decreases with the increase of normalizing temperature from 850 to 1 050℃.Average core loss of product is the lowest and average magnetic induction is the highest when normal...