钢厂
钙合金处理硅钢中的夹杂物及晶粒成长变化
采用RH精炼添加钙合金方式对硅钢进行钙处理,结果表明,钙合金添加量为0.67、1.00和1.67 kg/t钢时,钢中Ca含量分别为0、2×10-6和4×10-(6质量分数);随着钙合金添加量的增加,钢中夹杂物粒度逐渐由0~2μm向2~4μm、4~6μm偏移;不同钙处理条件下,钢中均存在粒径小于1μm和粒径为1~5μm的MnS、CuxS夹杂物,后者或单独存在,或与AlN、CaS夹杂复合;钢中粒径为5~10μm的夹杂物基本以Ca的氧化物和硫化物为主。与未经钙处理的炉次相比,钙合金添加量为0.67、1.00和1.67 kg/t钢时,粒径小于1.0μm的夹杂物减少幅度分别为68.06%、87.50%和94.94%。钙合金添加量为1.67 kg/t钢时,可以去除钢中绝大部分的微细夹杂物。 In order to improve the properties of final silicon steels,the calcium treatment was adopted by adding Ca alloys into the liquid steel during the RH refining process.Results show that when the addition of Ca alloys is 0.67 kg/t,1.00 kg/t and 1.67 kg/t,the corresponding Ca content in silicon steels is 0,2 × 10-6 and 4 × 10-6 respectively.With the increase of Ca alloy addition,the particle sizes of inclusions in steels become 2~4 μm and 4~6 μm,from 0~2 μm.Under different calcium treatments,there e...
RH精炼喂CaSi线去除无取向硅钢中的非金属夹杂物
结合工业化生产的无取向硅钢,进行了RH精炼喂CaSi线去除钢中的非金属夹杂物试验研究。针对不同的钙处理条件,分析了CaS夹杂生成热力学,观察了夹杂物的形貌和尺寸分布,确定了夹杂物的类型、数量,探讨了钙处理后钢中夹杂物的变化规律。结果表明,本试验条件下,钙处理可以有效抑制MnS、AlN夹杂物的生成,有效促进钢中微细夹杂物的聚合、上浮、去除,钢质纯净度明显提高。经过合适的钙处理后,钢中的夹杂物以独立存在的CaO为主,同时有少量含CaO、SiO2、MgO的复合夹杂,没有发现CaS夹杂存在。这部分夹杂物的尺寸集中分布在2~20μm,数量约为1.8×105个/mm3。 Experimental study on removal of non-metallic inclusions in non-oriented silicon steel obtained from industrial production by CaSi wire feeding during RH refining process was carried out.The thermodynamics of CaS inclusion formation was analyzed,the morphology and the size distribution of inclusions were observed,and the numbers and types of inclusions were also determined for the steel specimens treated under different calcium treatment conditions.Furthermore,the variation of inclusion characte...
含核壳异质结构6.5% Si高硅钢铁芯的制备与磁性能
以构建高磁感、低铁损、免轧制高硅电工钢铁芯为出发点,提出采用单辊甩带制备非晶铁硅合金薄带、微氧化法在铁硅合金粉末表面包覆高电阻率铁硅氧化物薄膜制备核壳异质结构高硅电工钢纳米粉末、放电等离子烧结快速成形制备颗粒间绝缘的高硅电工钢铁芯。研究了不同氧化包覆时间对SPS烧结试样密度、物相组成、微观结构和静磁性能的影响。研究表明,在氧化包覆5h烧结温度800℃工艺条件下,制备的6.5%Si高硅电工钢铁芯的静磁性能最佳,饱和磁化强度为128.84A.m2/kg、矫顽力为2.25kA/m、剩磁为3.47A.m2/kg。其饱和磁化强度与粉末压延法制备的高硅钢相当,但矫顽力降低了1/3。 The paper takes preparation 6.5%Si steel with high induction,low core loss and removing rolling as the starting point,amorphous Fe-Si ribbons was synthesized by melt spinning method,6.5%Si steel nanopowders with high resietivity core shell structure was prepared by the slight oxidation process and 6.5% Si steel iron core with evaluating internal was sintered by spark plasma sintering process(SPS).The essay focuses studies the effects of different oxidation cladding time on sample density,phase c...
高温卷取的热轧态原料与常化态原料生产高牌号无取向硅钢的比较
研究了采用高温卷取热轧态原料和常化态原料生产高牌号冷轧无取向电工钢组织、织构和磁性能。研究发现钢卷采用750℃高温卷取,下线后立即采用\"保温罩\"对钢卷进行保温,时间96h,然后空冷至100℃时上线生产的工艺可取代常化工艺生产高牌号冷轧无取向电工钢。冷轧上线前,热轧态原料的表层为大量的再结晶组织,这部分组织包括了热轧轧制时保留下来的动态再结晶组织,钢卷本身高温回复后产生再结晶晶粒,以及在保温罩内保温时形成的再结晶组织。高温卷取的热轧态和常化态的热轧卷作为原料时,试样织构类型相似,取向分布密度接近,再结晶后织构类型仍然相似,取向分布密度仍然接近。Goss织构对磁性能增加有促进作用。实验钢中较好的磁性能对应的织构[{100}+Goss]/{111}的比值较高,体现了织构的遗传性。 Microstructure,texture and magnetic properties of high grade cold rolled nonoriented electrical steel which made of hot rolled material with high temperature coiling and with normalization were studied.Steels coiled in high temperature(at 750 ℃),stacked with insulation cover for 96hand air cooled to 100 ℃ were using to manufacture high grade nonoriented electrical steel.The process can replace the normalization process.There are a lot of recrystallized grains in the surface layer of the coil wit...
免常化处理的耐酸蚀无取向电工钢的研制
在现普通冷轧无取向硅钢的基础上,降低Si含量,复合添加少量辅助元素,组合热轧板处理和成品退火加热技术,研制出了免常化处理的高磁感、低铁损并具有良好耐酸腐蚀性能的新系列无取向电工钢。 Based on existing common cold rolled non-oriented silicon steel,a new series of non-orientedelectrical steel with high induction,low core loss and excellent anti-corrosion property has been developed by reducing Si element,adding complexly a small amount of supplementary elements,and employing combined treatment of hot rolled sheet and finished product annealed heated technology.
高磁感取向硅钢涂层技术
涂层技术在高磁感取向硅钢生产中起着重要的作用.根据生产实践,介绍了高磁感取向硅钢生产中涂层的种类和作用、涂料的成分和对产品性能的影响、涂层工艺质量控制要点和检验方法等,并提出了通过优化涂层工艺改善高磁感取向硅钢性能和外观质量的方法. Surface coating technique plays an important role in producing high magnetic inductivity grain-oriented silicon steel.Based on production practice,this paper describes the types and function of the coating,the composition of the coating and its effect on the product performance,the quality control and inspection method for the coatings,as well as proposes ways to improve the magnetic property and surface quality of the steel by optimizing the coating process.
冷轧取向硅钢工程混凝土结构裂缝控制施工技术
冷轧取向硅钢工程中有很多的超长、大体积以及薄壁的混凝土结构,裂缝控制是土建施工的关键。在工程中,按照\"抗放兼施、先放后抗、以抗为主\"的原则,采用\"无缝分块跳仓法\",防止超长混凝土结构收缩产生裂缝;在隧道和池体的底板与墙板施工中,采用\"整体浇筑\"法,避免了墙板因约束应力而产生的裂缝。 In the Cold-rolled grain-oriented silicon steel project,there are many overlength,bulk mass,thin-walled concretes structures,how to control the crack is the key of civil engineering construction.In these projects,according to the principle of\"release with resist,resist before release,resist is dominant \",the crack of the over-long structure and shrinkage can be prevented by the method of\"seamless block skip bin \".In the construction of the bottom plate and wall of the tunnel and the pool,the cra...
晶界位向对硅钢立方/旋转立方取向双晶轧制取向变化的影响
晶界和{100}柱状晶在硅钢生产过程中对织构的遗传和演变有关键作用,因此本文利用晶体塑性有限元方法进行立方和旋转立方取向双晶在晶界不同位向时晶体取向演变的全场模拟。模拟显示,三种晶界位向下,晶界都具有诱发晶内产生S形状形变不均匀和缓解局部形变不均匀区取向转动的特点,立方和旋转立方取向双晶在带有剪切作用的轧制条件下都显示明显的取向稳定性。GB⊥RD(表示晶界垂直于轧向)晶界位向时,旋转立方取向晶粒优先在晶界中心位置发生取向转动,而立方取向则优先在远离晶界的端部发生取向转动。GB⊥TD(表示晶界垂直于横向)的晶界位向下,其晶界阻碍作用最小,双晶内产生的取向漫散度大,织构强度较低;除绕TD转动外,也具有复杂的绕RD、ND的取向转动。GB⊥ND(表示晶界垂直于法向)的晶界位向下,取向转动与GB⊥RD时相近,但有少量取向绕ND转动。 Grain boundaries and initial{100}columnar grains play a key role in the inheritance and evolution of texture in the production of electrical steels.In this paper,the crystal plasticity finite element method was used to simulate the grain orientation evolution of cube and rotated-cube oriented bicrystals when grain boundary was set to different orientations.It was shown that the grain boundary in three grain boundary orientations demonstrated the characteristics of inducing Sshape deformation inh...
无取向电工钢中夹杂物的分析
对无取向电工钢中的夹杂进行了系统的分析。利用小样电解,采取不同电解液,不同的分离方法对无取向电工钢中稳定和不稳定夹杂物进行了提取、分离和收集。利用扫描电镜(SEM)、X-射线衍射、ICP等对电解分离收集的夹杂物进行了定性和定量分析。 The inclusion analysis of the non-oriented electrical steel has been investigated.By using small sample electrolytic analysis,with different electrolytes and different separation ways,the stable inclusions and unstable inclusions was drew,separated,and collected.With utilizing the methods of SEM,X-ray and ICP,the qualitative and quantitative analysis of inclusions in the non-oriented electrical steel was obtained.
“双碳”大背景下的中国电工钢走势
阐述了电工钢在\"双碳\"中的作用,强调了电工钢的生产工艺技术及在减少碳排放、降低能耗中的作用,对下游能效升级带来明显的节能及降碳成果。同时,分析了2021年电工钢的生产运行情况,介绍了电工钢的未来发展,并针对如何减少碳排放以及生产更多的更低铁损、更高磁感的电工钢谈了几点启示。 The effects of electrical steels on carbon peak and carbon neutralization were expounded,especially on the achievements of obvious energy saving and carbon reduction to the downstream energy efficiency upgrading bringing from the production technology of electrical steels and their effects to reducing carbon emission and energy consumption.Meanwhile the production situation of electrical steels in 2021 was analyzed,and the future development of electrical steels was introduced,and some advices w...
Al含量对2.2%Si无取向硅钢组织、织构和磁性能的影响
通过实验室25 kg真空感应炉冶炼和锻轧研究了0.26%~0.95%Al含量对0.5 mm 2.2%Si无取向硅钢冷轧板组织、织构和磁性能的影响。试验结果表明,0.26%~0.81%Al含量时,随钢中Al含量的增加,成品退火钢板的晶粒尺寸增加同时铁损减少;当Al含量大于0.81%时,随Al含量增加,钢板的晶粒尺寸减小,同时铁损增加。Al含量对硅钢板磁感的影响没有明显的规律。2.2%Si无取向硅钢的合适Al含量为0.48%~0.81%。 The effect of 0.26%~0.95%Al content on structure,texture and magnetic performance of 0.5 mm cold rolled sheet of 2.2%Si non-oriented silicon steel has been studied by a 25 kg vacuum induction furnace smelting,and forging -rolling in laboratory.Results show that as 0.26%~0.81%Al,with increasing Al content in steel the grain size of annealed finished sheet increases while iron loss of sheet decreases,and as Al content in steel is more than 0.81%,the grain size of sheet decreases while iron loss in...
硅钢铸坯再加热过程中夹杂物的析出行为
研究了硅钢铸坯再加热过程中夹杂物的析出行为。采用非水溶液电解提取+扫描电镜观察方法,观察了试样的显微组织,统计了夹杂物的尺寸、种类、数量、分布。结果表明,均热温度为1 523 K时,水淬试样的夹杂物尺寸绝大部分小于0.5μm,0.5~5.0μm的夹杂物数量很少,没有发现5.0μm以上的夹杂物。此外,均热时间为10、30、60、90、120、240 min时,对应试样中0.05~0.2μm的夹杂物数量分别为4.04×104、4.73×104、3.70×104、3.33×104、3.10×104、1.56×104个/mm3。绝大部分夹杂物以MnS、AlN、CuxS类为主,并以三类夹杂物中的两类复合或三类复合居多。三类复合夹杂物总量占每组试样夹杂物总量的90%或以上。随均热时间延长,典型的夹杂物组成会发生如下变化:MnS+AlN+CuxS MnS+AlN AlN。与此同时,MnS、AlN、CuxS三者复合比例从45.2%(均热10 min)降为9.7%(均热240 min)。 The methods of electrolysis extraction from nonaqueous solution and scanning electron microscope were adopted to study the precipitation behavior of non-metallic inclusions in Si steel slabs during reheating processes.The morphologies,chemical compositions,quantity and size distribution of non-metallic inclusions in these steel samples were analyzed.Results show that,when the soaking temperature is 1 523 K,almost all of the non-metallic inclusions are smaller than 0.5 μm,few are in the range of ...

