钢厂
取向电工钢加工过程中第二相粒子的析出行为
利用场发射扫描电镜观察了以MnS为主要抑制剂的普通取向电工钢加工过程中第二相粒子的分布状态,统计了粒子面密度、平均尺寸以及相应的尺寸分布.结果显示,热轧加工造成了大量第二相粒子弥散、细小地析出,同时基体仍保持过饱和状态.冷轧变形会造成第二相粒子的回溶行为,而基体的过饱和状态会减弱回溶现象.中间退火与脱碳退火过程中会同时存在新粒子的形核及已析出粒子的粗化两个过程,而在最终二次再结晶升温阶段则以第二相粒子明显粗化为主. The distribution of second phase particles in conventional grain-oriented electrical steels during manufacturing processes with MnS as inhibitors was observed by field emission scanning electron microscopy,while the areal particle density,the average particle size and the corresponding size distribution were statistically determined.It is indicated that hot rolling leads to dispersive precipitation of a large amount of fine second phase particles and the matrix keeps a supersaturated state furth...
硅钢常化退火炉辊印缺陷预测分类预警方法研究
针对宝钢硅钢常化退火过程中产生的退火炉辊印缺陷问题,通过实际生产的大数据与产品质量问题相结合,将数据挖掘、数据分析方法应用到实际,一定程度上解决了现场实际生产中的痛点,为现场生产提供决策支撑,避免了以前通过人工识别判定存在疏漏和无法定量判断的问题,形成了一套具有鲁棒性和可操作性的钢铁生产过程数据分析方法。通过智慧决策系统平台获取实际生产和表检仪数据,基于Pearson相关系数算法进行变量挑选和特征工程,并应用随机森林算法对数据建立分类预测模型,实现了质量问题的溯源和监控,通过数据量化预测了炉辊印缺陷是否可通过轧制消除的质量问题,识别准确率达到96.43%。 In views of the normalizing annealing furnace roll marks problem occurred in the process of normalizing annealing of silicon steel in Baosteel,by combining big data from actual production with product quality problems,data mining and data analysis methods were applied to actual production to solve the pain points and provide decision support,a robust and practical data analysis method for the steel production process has been developed,which avoided the previous problems of omission and non-quan...
120t转炉冶炼无取向硅钢脱硫技术研究
结合冶炼无取向硅钢的生产实际,对钢中硫的来源,以及炉渣性质、钢水温度、底吹强度对脱硫的影响进行了分析。研究表明,转炉钢中硫的主要来源为铁水、废钢、铁水渣及石灰带入;冶炼硅钢时,终渣碱度为3.0~3.5,w((FeO))≤20%,终点钢水温度大于等于1 680℃,加大底吹搅拌强度能提高转炉脱硫效果。硅钢平均出钢硫的质量分数为0.004 8%,能满足无取向硅钢对硫含量的要求。 With the actual production of non-oriented silicon steel,the source of sulphur and the effect of metallugic parameters like slag properties,temperature of molten steel and bottom stirring on desulphurizing ability were investigated.The results show that the main source of sulphur is molten metal,scrap,the remaining slag volume in hot metal and lime.The degree of desulphurization for smelting silicon steel can be increased through adopting the following measures,such as the basicity of finishing ...
大压下率冷轧无取向硅钢织构演变及性能
组织和织构是影响无取向硅钢性能的重要因素。为改善产品性能,研究了冷轧压下率(71.7%~87.0%)对高牌号无取向硅钢组织、织构、磁性能和力学性能的影响。结果表明,随冷轧压下率的增加,退火晶粒平均尺寸先减小后增大;高斯和立方织构强度减弱,γ纤维织构增强,α纤维织构转变为较强的α*({h, 1, 1}〈1/h, 1, 2〉)织构,并随冷轧压下率的增加而增强,同时其峰值逐渐向{111}面移动;工频铁损P1.5/50、高频铁损P1.0/400和磁极化强度J5000同时降低,屈服强度变化不大,表面硬度逐渐增加。当冷轧压下率由84.7%增至87.0%、厚度减至0.30 mm时,高频铁损降幅是工频铁损的11倍,表面硬度增幅变大。以上研究成果对硅钢减薄后织构及组织的优化提供了很好的指导。 Microstructure and texture are critical factors on non-oriented silicon steel properties. In order to improve product properties, this paper studied the effect of cold rolling reduction rate(71.7%-87.0%) on microstructure, texture, magnetic properties and mechanical properties of high-grade non-oriented silicon steel. The results show that with the increase of cold rolling reduction rate, the average size of annealing grain decreases first and then increases. The intensity of Goss and λ fiber te...
取向硅钢中含铜抑制剂的固溶析出行为
含铜抑制剂作为取向硅钢的主抑制剂或辅助抑制剂不仅可以抑制初次晶粒的长大,促进二次再结晶,还可以降低铸坯的加热温度。取向硅钢中主要抑制剂为10~50 nm Cu2S,在钢的铸坯、热轧、冷轧、脱碳等工艺过程均可析出;(Cu,Mn)1.8S、Cu1.8S、ε-Cu等主要作为辅助抑制剂,尺寸一般为30~50 nm(或大于50 nm),主要在热轧阶段析出。总结了国内外有关取向硅钢中含铜抑制剂析出行为的研究进展,当前主要研究不同生产流程和工序中含铜抑制剂的析出行为和作用机理。 As main inhibitor or auxiliary inhibitor for grain-oriented silicon steel,the particles of inhibitor bearing copper not only inhibit the primary crystal growing and promote the secondary recrystallization,but also decrease the heat temperature of casting slab.The main inhibitor for grain-oriented silicon steel is 10~50 nm Cu2S,which precipitate in process and procedure including steel casting slab,hot rolling,cold rolling and decarburizing process,while the 30~50 nm or more than 50 nm...
高硫硅钢的硫化物析出行为及其微观组织和电磁性能变化
为了弄清楚高硫硅钢中的硫化物析出行为及其对钢的微观组织和电磁性能的影响,以便为工业化生产制定更为合理的硫含量控制标准和采取更为有效措施减轻炼钢生产的硫含量控制压力,结合0.25% Si 无取向硅钢 ,采用非水溶液电解提取 + 扫描电镜/透射电镜观察相结合的方法 ,研究了0.006 8%、0.010 2%、0.025 5% 和 0.035 3% 硫含量条件下,钢中的硫化物夹杂物组成和存在形式及其形貌、种类、尺寸、数量变化,以及相应的热轧、成品试样的微观组织和电磁性能变化。结果表明,随着钢中硫含量的增加,钢中的硫化物逐渐由 MnS→MnS+Cu2S→Cu2S转变,数量逐渐增多,尺寸向高低两个方向发展。相应地,导致热轧再结晶组织劣化和抑制了成品晶粒尺寸长大。随着钢中硫含量的增加,钢的磁感、铁损劣化程度逐渐增大。钢中的硫含量平均每增加 0.01%,涡流损耗、磁滞损耗分别劣化0.24 W/kg 和 0.41 W/kg,而磁感会劣化 0.009 T。但是 ,在硫含量为 0.010 2% 时 ,铁损可以低于 6.0W/kg,而在硫含量为 0.025 5% ... In order to find out the precipitation behavior of sulfide inclusions and the corresponding changes of microstructure and electromagnetic properties of high sulfur silicon steel sheets, so that to design more suitable sulfur concentration controlling limit for industrial manufacture and to release the steel-making difficulty effectively, Based on the change of given sulfur concentration 0.006 8%, 0.010 2%0.025 3% and 0.035 3%, the type and composition, the size and number, and the size distribut...
高效电机用无取向硅钢退火板组织和析出物研究
研究了组织和析出物对高效电机用无取向硅钢退火板磁性能的影响。结果表明:随着退火温度升高,退火板平均晶粒尺寸增加,P15/50明显降低,B50略有升高。退火温度在1 000℃时,退火板的综合性能较好。析出物主要是AlN、(MnS+AlN)和(MnS+Al2O3)复合析出物,尺寸较粗大,主要集中在1.0~2.5μm,还发现少量百纳米以下的细小AlN和TiN。实验室模拟TSCR流程试制的高效电机用无取向硅钢,铁损平均值小于4.00 W/kg,磁感应强度大于1.75 T,适合作中小型高效电机铁芯材料。 Effects of microstructure and precipitation on magnetic property of non-oriented silicon steel sheets after annealing for high-efficiency motor are studied in the paper by experiments.The annealed sheet exhibits a larger average grain size,obviously decreasing iron loss and slightly raising magnetic induction with increasing temperature.The annealed sheet has better comprehensive properties at a annealing temperature of 1 000 ℃.The main precipitates are compounds of AlN、(MnS+AlN)and(MnS+Al2O3) w...
轧制裂纹及热处理工艺对高硅电工钢复合板磁性能的影响
对3层高硅电工钢复合板铸坯进行热轧及温轧变形加工后,采用正火、退火两种热处理方式处理,并观察轧制过程中产生的裂纹,研究不同状态下复合板的磁性能。对不同状态下的试样进行扩散退火处理,研究复合板中裂纹变化及其对磁性能的影响。结果表明:不同热处理工艺下合金内部的裂纹尺寸差异明显,裂纹尺寸对复合板的磁性能影响显著,相对于深裂纹,其他因素的影响较小;温轧变形加工后,复合板内层出现有序组织,但该有序组织在合金存在深裂纹的前提下并不能从本质上提高合金的磁性能;扩散退火工艺可以消除复合板内部的浅裂纹及微裂纹,但不能消除尺寸较大的裂纹,故而不能显著提高存在深裂纹的复合板的磁性能。 After hot rolling and warm rolling deformation processing of casting billet for three-layer high silicon electrical steel composite plate, it was normalized and annealed for heat treatment. Then, the cracks produced during the rolling process were observed, and the magnetic properties of composite plate in different states were also investigated. Furthermore, the samples in different states were subjected to diffusion annealing treatment, and the changes of crack in composite plate and their eff...

