硅钢资料

【作者】 卢鹏； ...

通过对辉光放电发射光谱参数的优化,以铁元素为内标来消除基体效应,建立了测定硅钢薄板中微量硼元素的方法。优化的实验参数为:放电电压1200 V,放电电流50 mA,预溅射时间40 s,积分时间10 s。校准曲线硼元素含量范围0.0001%~0.022%,相关系数大于0.999,测量结果与认定值一致,相对标准偏差小于10%。完全能够满足日常分析测试的要求。 A glow discharge optical emission spectrometry(GD-OES) method for determining trace boron element in silicon steel sheets were established through optimization of instrumental parameters and using Fe element as an internal standard to eliminate the matrix effect.The optimized instrumental parameters included discharge voltage,discharge current,pre-sputtering time and integration time,which are 1200 V,50 mA,40 s,and 10 s,respectively.The content of boron element that can be determined from the ca... 

本发明提供一种改善表面麻点缺陷的薄规格中低牌号无取向硅钢及其生产方法，成分C≤0.0025％，1.2≤Si≤1.65％，0.25％≤Mn≤0.35％，0.06％≤P≤0.11％，0.1％≤Als≤0.2％，S≤0.0025％、N≤0.0025％，Ti≤0.0025％，其余为Fe及不可避免的杂质。与现有技术相比，本发明采用较低氢气浓度，防止炉内氧化铁皮还原，减轻碳套辊的腐蚀程度，减少碳套辊结瘤率，改善带钢表面质量；采用合理合金成分设计，提高带钢的力学强度，降低碳套辊结瘤对带钢表面的影响程度，改善带钢表面质量。产品厚度为0.35mm，板面麻点发生率降低，无手感，且辊身周长周期范围内麻点个数≤5个。

取向硅钢热轧板中织构梯度对发展完善的二次再结晶十分关键,通过添加铜可以显著降低取向硅钢板坯加热温度,从而影响热轧板织构分布。利用X射线衍射仪,分析了实验室模拟薄板坯连铸连轧(TSCR)工艺的3种不同铜含量的取向硅钢热轧板织构。结果表明:不同铜含量热轧板表面到厚度1/4处均为弱的热轧织构,热轧板心部主要为{100}面织构;铜含量约在0.4%时,热轧板次表层的{110}<001>织构比例最高,而热轧板心部的{100}<110>织构比例最低;铜含量对热轧织构中{114}<110>和{001}<100>织构发展有显著影响。 The texture gradient in hot rolled grain oriented silicon steel strip is one of the essential factors to achieve a perfect secondary recrystallization.The addition of copper can significantly reduce the slab reheating temperature of grain oriented silicon steel,so as to impact the texture distribution in the hot rolled strip.The texture of hot rolled grain oriented silicon steel strip as-rolled by thin slab casting and rolling process(TSCR) in laboratory with three different copper contents was ... 

本文以热轧常化板为初始材料,采用二次冷轧法与三次冷轧法制备了0.1 mm厚的取向硅钢薄带,测定相应的磁性能,并通过EBSD取向成像技术检测了二次冷轧法与三次冷轧法各工艺过程中织构与组织演变规律。结果表明,采用最终冷轧压下率适中的三次冷轧法,能在冷轧至0.1 mm时保存较多的高斯晶核,使得高温退火后的磁性能明显优于二次冷轧法。最终冷轧压下率通过影响脱碳退火后样品中的{111}<112>织构组分及Goss晶粒数量对最终二次再结晶产生重要影响。 Grain-oriented silicon steel sheets with a thickness of 0. 1 mm were produced from hot-rolled and normalized sheets by two-step-rolling and three-step-rolling methods. Their magnetic properties were measured,and the textures were detected by EBSD technique. The results show that the three-step-rolling method,which has a moderate reduction rate of final cold rolling,can maintain more { 110} < 001 >nucleus,and thus obtaining better magnetic properties compared with the two-step-method. The f... 

本发明涉及一种提高取向硅钢冷轧加工性的生产方法，工艺流程为：冶炼、连铸、热轧、常化、酸洗、冷轧、脱碳渗氮、涂MgO、高温退火、涂绝缘层及热拉伸平整；粗轧中坯厚度35‑45mm，两段常化后进行带钢横向分段式冷却水分布。本发明通过对热轧中坯厚度、终轧温度及卷取温度，常化冷却水量及控制方式的调控，使轧前表层晶粒尺寸降低5‑10μm、珠光体体积分数降低6％，轧材冷轧加工性明显改善、成材率可提高8％以上。通过后续冷轧、脱碳退火和高温退火等工序处理，可保证完善的二次再结晶组织及良好磁性能。

研究了退火温度对3.1%Si无取向硅钢组织和磁性能的影响规律。结果表明:退火温度从940℃提高至1 000℃,平均晶粒尺寸由98μm增加到145μm,铁损P_1.5/50从2.576 W/kg降低至2.408W/kg。随着退火温度的升高,γ不利织构组分强度逐渐降低,{111}〈112〉织构组分强度降低约16%,磁感B₅₀逐渐升高,磁性能水平提高。 The effects of annealing temperature on microstructure and texture and magnetic properties of 3.1%Si non-oriented silicon steel were investigated in this paper.The results showed that,when the annealing temperature increased from 940℃ to 1 000℃,the average grain size of metallographic structure increased from 98μm to 145μm,the iron loss value P_1.5/50 decreased from2.576 W/kg to 2.408 W/kg.And as the annealing temperature increased,the strength of the unfavorable texture componentγgrad... 

本发明公开了一种批量稳定生产高牌号无取向电工钢的方法，包括以下步骤：开卷→加热→水套冷却→水雾冷却→水喷淋冷却→抛丸→酸洗→切边→卷取→使用单机架六辊轧机进行轧制成卷；该方法可实现高牌号无取向电工钢在六辊UCM轧机冷轧后无边裂产生，可将带钢板形值控制在‑5I～+5I，厚度精度控制在±3μm，该方法生产的高牌号无取向电工钢无板形及表面质量缺陷，产品质量良好，可实现高牌号无取向电工钢的批量稳定轧制。

本发明提供了一种CSP流程生产高效冷轧无取向电工钢及生产方法，成分：C≤0.0030％、Si 1.00‑1.70％、Als≤0.0050％、Mn 0.10‑0.30％、Sn0.01‑0.3％、P≤0.050％、S≤0.0080％、N≤0.0030％、Nb≤0.0030％、V≤0.0030％、Ti≤0.0030％，其余为Fe以及不可避免的杂质。与现有技术相比，本发明CSP流程生产高效冷轧无取向电工钢的方法，通过控制钢中的化学成分，并采用合适的生产工艺，实现了表面质量优良，低铁损、高磁感、低制造成本且生产高效。

为开发高效电机用冷轧无取向电工钢,借助实验室薄板坯连铸连轧模拟设备及扫描电镜、透射电镜等检验手段研究了成分、组织、织构和析出物等对无取向电工钢磁性能的影响规律;结果表明:常化处理使组织均匀化并增加有利于磁性提高的织构组分;采用CSP流程开发的高效电机用无取向电工钢铁损平均值3.4 0 W/kg,磁感≥1.68 T。 In order to develop electrical steel for high efficiency motor,effect of components,microstructure,texture and precipitation on magnetic property of electrical steel are analyzed.From the result,normalizing treatment makes microstructure uniform and increases component of favorable texture.Iron loss of electrical steel developed by CSP line is 3.40W/kg and magnetic induction is more than 1.68T. 

介绍了CSP工艺生产无取向电工钢各工序的设备特点、采用的工艺控制手段和电工钢产品质量情况,结合生产实践证明了马钢CSP工艺开发的无取向电工钢产品丰富了薄板坯连铸连轧的品种结构,发挥了薄板坯连铸连轧生产无取向电工钢性能均一、稳定的特点。 The equipment characteristic,the process control method and the quality of non-orientated silicon steel by CSP process were introduced.Combined with the production situation,it is proved that production of non-orientated silicon steel developed on Masteel CSP line would enrich product structure of thin slab continuous casting and rolling,and it exerts stable performance of non-orientated silicon steel. 

本发明一种解决取向硅钢热轧板晶粒粗大的方法，在取向硅钢的成分设计中减少固溶温度较高的MnS的含量，降低铸坯加热温度，同时计算实际取向硅钢成分中γ‑相含量与温度之间的关系，依据计算结果设计取向硅钢的热轧工艺，可以保证20％～30％的γ‑相数量，成功解决取向硅钢热轧板晶粒粗大的问题。