硅钢资料

【作者】 康凌晨； 王丽娜； ...

采用节能、环保、经济型的生产技术与工艺来制造高磁感取向硅钢目前已成为世界各大取向硅钢生产厂的研发热点。总结了国内外各大钢铁企业与研究机构采用低温板坯加热技术生产高磁感取向硅钢的开发及应用情况,概括了传统流程实现低温板坯加热技术的方法。介绍了薄板坯连铸连轧与双辊薄带连铸等短流程工艺生产高磁感取向硅钢的研发现状。在此基础上,探讨了高磁感取向硅钢生产技术与工艺的发展趋势及方向。 Utilizing energy-efficient,environmentally friendly,economic production processes and technologies to manufacture high magnetic induction grain-oriented silicon steel has become the focus of current research work.Based on using low-temperature slab reheating techniques to produce high magnetic induction grain-oriented silicon steel at both iron and steel enterprises and research institutions all over the world,the current application and exploitation was thoroughly generalized;the implementation... 

常化快冷是生产高牌号无取向硅钢和高磁感取向硅钢不可缺少的一个工艺环节,气-雾冷却则是实现常化快冷的关键方式之一。介绍了国内自主设计建设的常化酸洗机组气雾冷却系统的技术特性,并对其特点进行了系统分析,最后给出该系统在设计、运行参数的选择上若干注意事项,对气-雾冷却系统设计和使用具有一定的指导作用。 The normalizing rapid cooling is a indispensable process to high grade non-oriented silicon steel and high magnetic induction oriented silicon steel’ s production. The fog cooling is a key ways of coming true the normalizing rapid cooling. This paper introduces the technical features of the fog cooling system in normalizing pickling line which is the domestic independent design and construction. Meanwhile,the fog cooling system’s characteristic is analyzed systematacially. In the end,this paper ... 

对低温法生产的以AlN为主抑制剂的Hi-B取向硅钢高温退火过程进行了中断实验,借助EBSD及TEM技术对高温退火连续升温过程中织构与析出物的演变进行了研究。实验结果表明,800℃时ODF图出现高斯织构组分,但强度很弱,高斯晶粒偏离角在10°以上;950~1 000℃时高斯晶粒异常长大,偏离角3~6°;高温退火过程析出物主要有球形、规则立方形及不规则多面体形3种形貌,由于渗N的影响,Zener因子先增大再减小,并且析出物在高斯晶界前沿优先粗化。 The annealing process at high temperature of Hi-B silicon steel using low slab reheat temperature and with AlN as the inhibitor has been studied by interrupting test,and the evolution of texture and precipitates during continuous heating-up in the annealing process at high temperature was analyzed by EBSD and TEM. The results showed that Goss texture appears in ODF at 800 ℃,but the intensity of Goss texture was very weak and the deviation angle was more than10°. Goss grains grow abnormally durin... 

介绍了EB5325涂层液的主要性能和中冶新材生产冷轧无取向电工钢所用的涂层设备,通过多次试验摸索出使用EB5325涂层液的工艺,对涂层出现的缺陷进行分析研究,并提出解决方法,使中冶新材生产的冷轧无取向电工钢的涂层质量满足了用户的要求。 This article introduces the main properties of EB5325 and the coating equipments for cold-rolled non-oriented electrical steel. A process using EB5325 coating liquid is made through many time experiments and exploration. The appeared defects in the coating are studied and analyzed,and the solutions are proposed. The coating quality meets clients’ requirements of cold rolled non-oriented electrical steel. 

从取向硅钢生产路线的选择、工艺技术的改进和生产设备的改造三方面进行了生产取向硅钢的节能降耗技术改造.通过完善多元抑制剂配方生产低温取向硅钢,通过加抛丸的酸洗、带面超声波清洗、改进连续退火炉以及余热循环利用等技术改造,使2012年取向硅钢的产量与未进行技术改造前的2009年相比提高了2.5倍,产品磁性上升了一个半牌号,能耗下降了8.9%,成材率提高了6.4%,生产成本下降了22%,综合效益显著. Energy saving technological transformation was carried out in the production of grain oriented silicon steel from three aspects of the oriented silicon steel production process route selection,technology improvement and equipment renovation.Through the improvement of multiple inhibitor formulations for producing low-temperature grain-oriented silicon steel,and by adding the blasting pickling,the belt surface ultrasonic cleaning,improvement of continuous annealing furnace,waste heat recycling tec... 

通过热力学计算与模拟试验研究了含钒钛取向硅钢中氮化物析出相的析出规律与析出行为,并探讨了含钒钛元素的氮化物析出相作为薄板坯连铸连轧流程制备取向硅钢中辅助抑制剂的可行性.研究表明,在所冶炼的含钒钛取向硅钢的成分范围内,Ti N在钢液凝固末期便具备析出的热力学条件,而Al N与VN只可能在凝固后的α+γ或α+Fe3C两相区内析出.含钒钛取向硅钢中氮化物析出相以成分复杂的复合析出相为主,且随着钒钛加入量的增加,钢中抑制剂析出相总的分布密度由于含钒钛元素的氮化物析出相的增加而明显提高,使抑制剂抑制初次再结晶晶粒正常长大的能力得以加强,最终成品的磁感应强度值B8由1.857 T提升至1.898 T.同时,加入不高于0.007%的Ti与不高于0.005%的V不会影响中间脱碳退火工序的脱碳效果以及高温退火净化阶段硫、氮的脱除效果,其形成的含钒钛元素的纳米级氮化物析出相适合作为薄板坯连铸连轧流程制备取向硅钢的辅助抑制剂. The precipitation behavior of nitride precipitates in grain-oriented silicon steel containing vanadium and titanium elements produced by thin slab casting and rolling process was studied by thermodynamic calculation and simulation experiment. The feasibility of nitride precipitates containing V and Ti elements as auxiliary inhibitors was also investigated. It is found that Ti N is likely to precipitate at the final stage of solidification in the grain-oriented silicon steel,but VN and Al N can p... 

介绍了一种适用于超大晶粒取向硅钢的高斯晶粒取向偏离角的X射线衍射测量方法，提出了将试探法和探测器扫描法相结合的方式进行测量。结果表明：该方法可以同时获得准确的实际衍射角度和取向偏离角度，试样制备方式简单，对设备的要求低且测量结果准确。 This paper introduces a X-ray diffraction measurement method of Gaussian grain orientation deviation angle for ultra-large grain oriented silicon steel, and puts forward a method of combining the test method with the detector scanning. The results show that this method can obtain accurate actual diffraction angle and orientation deviation angle at the same time. The sample preparation method is simple, the requirements for equipment are low, and the measurement results are accurate. 

组织和织构是影响无取向硅钢性能的重要因素。为改善产品性能，研究了冷轧压下率（71.7%～87.0%）对高牌号无取向硅钢组织、织构、磁性能和力学性能的影响。结果表明，随冷轧压下率的增加，退火晶粒平均尺寸先减小后增大；高斯和立方织构强度减弱，γ纤维织构增强，α纤维织构转变为较强的α^*（{h, 1, 1}〈1/h, 1, 2〉）织构，并随冷轧压下率的增加而增强，同时其峰值逐渐向{111}面移动；工频铁损P_1.5/50、高频铁损P_1.0/400和磁极化强度J₅₀₀₀同时降低，屈服强度变化不大，表面硬度逐渐增加。当冷轧压下率由84.7%增至87.0%、厚度减至0.30 mm时，高频铁损降幅是工频铁损的11倍，表面硬度增幅变大。以上研究成果对硅钢减薄后织构及组织的优化提供了很好的指导。 Microstructure and texture are critical factors on non-oriented silicon steel properties. In order to improve product properties, this paper studied the effect of cold rolling reduction rate（71.7%-87.0%） on microstructure, texture, magnetic properties and mechanical properties of high-grade non-oriented silicon steel. The results show that with the increase of cold rolling reduction rate, the average size of annealing grain decreases first and then increases. The intensity of Goss and λ fiber te... 

【作者】 王磊； ...

【作者】 宋波； ...

研究了含铜低碳低硅无取向电工钢中的析出相及其析出机理.由能谱(EDS)及选区电子衍射(SAED)分析可知,铁素体基体上存在的大量弥散分布的等轴状析出相为类B2结构的铜.这些铜析出相的析出机理可以是一般析出、位错析出、台阶机理相间析出和弓出机理相间析出:一般析出在550、650和750℃三个等温温度均可发生;位错析出只发生在较低的等温温度(550℃),此时析出相呈特殊的平行短列状;台阶机理相间析出也可在上述三个等温温度下发生,但650℃等温时最有利于台阶机理相间析出,此时析出相平直列状分布;弓出机理相间析出只发生在较高的等温温度(750℃),析出相弯曲列状分布. Precipitates in low-carbon low-silicon non-oriented electrical steel containing Cu were studied and the precipitation mechanism was analyzed by means of energy dispersive spectrometry(EDS) and selected area electron diffraction(SAED).It is found that the equiaxed precipitates of Cu with B2-like structure distribute dispersively in the non-oriented electrical steel.The precipitation mechanism involves general precipitation,dislocation precipitation,interphase precipitations formed by the ledge me...