钢厂
无取向硅钢磷酸盐型杂化涂层性能测试
以质量分数为25%的丙烯酸乳液MC-102、15%Al(H2PO4)3溶液、0.01%H3BO3、0.01%Zn(Ac)2·2H2O和2%二乙二醇丁醚组分,在不同固化工艺下制备涂层。极化曲线和电导率测试发现300℃处理60 s得到的涂层具有良好的耐腐蚀性和绝缘性;水煮实验证明该涂层具有良好的耐水性;断口线扫描发现涂层具有良好的附着性。 A formula comprising MC-102 acrylic emulsion 25%,aluminium dihydrogen phosphate15%,boric acid 0. 01%,zinc acetate dihydrate 0. 01% and diethylene glycol monobutyl ether 2% was used to prepare coatings via different treatment process. The conductivity test and polarization curves revealed that a coating cured at 300 ℃ for 60 s showed good insulative and anticorrosive properties. The water boiling test indicated that the said coating had good water resistance. A cross section of the coating was in...
ZnO对无铬无取向硅钢绝缘涂层性能的影响研究
主要研究了氧化锌对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验和动电位极化研究了不同氧化锌含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响.采用SEM和体视显微镜对涂层的表面形貌和附着性能进行研究.结果表明,氧化锌含量为4.0%时,氧化锌能完全中和涂层表面的游离磷酸,涂层的耐蚀性和附着性最好;氧化锌含量过少或过多时,涂层的耐蚀性和附着性都较差. This paper studies the influence of zinc oxide on the performance of chromium-free non-oriented silicon steel insulating coating which based on aluminum dihydrogen phosphate.Salt spray experiment and potentiodynamic polarization were used to study the influence of zinc oxide content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.The surface morphology and adhesion of coating were tested by SEM and stereo microscope.The results show that when t...
真空感应炉熔炼高硅电工钢脱氧工艺的研究
在50Kg氧化镁坩埚真空感应炉上进行高硅电工钢的脱氧试验。结果表明,通过控制原料的成分、高真空下的碳氧反应和炉衬分解向钢液中的供氧,可使钢液的总氧含量≤15×10-6;在维持高温高真空条件下,当钢液中的反应达到一定程度后,延长精炼时间并不能降低钢液的总氧含量;完成精炼后加入硅钙合金沉淀脱氧可进一步降低钢液的总含氧量,但脱氧效果有限。 The test of high-silicon electric steel deoxidation has been carried out in 50Kg vacuum induction furnace with magnesium oxide crucible.Results show that the total oxygen could be ≤15×10-6in molten steel by controlling material components,carbon-oxygen reaction in high vacuum and oxygen contamination from crucible materials on molten steel;And when the reaction was carried through to a certain extent,total oxygen in molten steel could not be reduced by the extension of refining period in high va...
热轧无取向低硅钢SGG的研制开发及生产
针对川威950的工艺现状,结合无取向低硅钢SGG生产的工艺特点,主要从控制其钢坯加热和轧制以及终轧温度和卷曲温度几方面入手,进行无取向低硅钢生产的工艺控制研究。同时根据近6000吨的生产实践表明,该工艺措施能很好的满足该钢种的需要。 950 process Chuanwei status quo,with non-oriented silicon steel production process features low,mainly from the control of billet heating and rolling and finish rolling temperature and coiling temperature of several aspects,for non-oriented silicon steel production process of low control at the same time According to nearly 6,000 tons of production practice shows that the process measures could well meet the needs of the steel.
钙合金处理硅钢中的夹杂物及晶粒成长变化
采用RH精炼添加钙合金方式对硅钢进行钙处理,结果表明,钙合金添加量为0.67、1.00和1.67 kg/t钢时,钢中Ca含量分别为0、2×10-6和4×10-(6质量分数);随着钙合金添加量的增加,钢中夹杂物粒度逐渐由0~2μm向2~4μm、4~6μm偏移;不同钙处理条件下,钢中均存在粒径小于1μm和粒径为1~5μm的MnS、CuxS夹杂物,后者或单独存在,或与AlN、CaS夹杂复合;钢中粒径为5~10μm的夹杂物基本以Ca的氧化物和硫化物为主。与未经钙处理的炉次相比,钙合金添加量为0.67、1.00和1.67 kg/t钢时,粒径小于1.0μm的夹杂物减少幅度分别为68.06%、87.50%和94.94%。钙合金添加量为1.67 kg/t钢时,可以去除钢中绝大部分的微细夹杂物。 In order to improve the properties of final silicon steels,the calcium treatment was adopted by adding Ca alloys into the liquid steel during the RH refining process.Results show that when the addition of Ca alloys is 0.67 kg/t,1.00 kg/t and 1.67 kg/t,the corresponding Ca content in silicon steels is 0,2 × 10-6 and 4 × 10-6 respectively.With the increase of Ca alloy addition,the particle sizes of inclusions in steels become 2~4 μm and 4~6 μm,from 0~2 μm.Under different calcium treatments,there e...
冷轧无取向硅钢表面麻面缺陷成因分析及其控制措施
针对某厂DMS森吉米尔轧机生产无取向硅钢表面麻面缺陷的问题,根据生产实际,对其形成原因从乳化液及工作辊两方面因素进行了分析。结果表明:乳化液对麻面缺陷的产生有一定影响,但不是主要因素,主要原因是由于二十辊森吉米尔轧机工作辊辊径较小,轧制相同长度带钢轧辊运转周期较大,容易产生疲劳失效而导致。为此,提出通过调整冷轧工序成品轧制道次的压下率以减小轧制力,从而减小工作辊的磨损疲劳;通过对轧制乳化液浓度、温度的合理控制,以改善润滑效果、提高轧制速度,而进一步缓解轧辊疲劳的改进措施,使该钢厂无取向硅钢麻面缺陷发生率由原来的18%降至0.8%,带钢表面质量明显改善。 For the problem of surface pockmarks of non-oriented silicon steel strip produced by a DMS Sendzimir mill, based on the production practice, the formation causes were analyzed from two aspects of emulsion and working roll. The results show that the emulsion has a certain effect on the formation of surface pockmarks defects, but it is not the main factor. The main reason is that the working roll diameter of the 20-high Sendzimir mill is small, and the running period of the roll rolling the same l...
常化温度对TSCR流程制备低碳低硅无取向硅钢组织和性能的影响
在实验室试制了TSCR流程的低碳低硅无取向硅钢,研究了在850~1050℃不同温度常化对冷轧量0.5mm厚钢板再经950℃×7min退火后的组织、织构和磁性能的影响。结果表明:随常化温度的升高,使热轧板晶粒尺寸增大,晶界更清晰,组织均匀性更好;由于第二相AlN和MnS析出物尺寸比较大,使冷轧退火后钢板晶粒也随常化温度升高呈单调增大趋势;γ有利织构和{111}、{112}不利织构与常化温度升高同时增强,但前者增强更多;冷轧板退火后铁损随常化温度升高呈单调下降,磁感呈单调上升趋势。 The low-carbon and low-silicon non-oriented silicon steel was prepared by thin slab casting and rolling(TSCR) in lab.The effect of normalizing at different temperatures in 850-1 050℃on microstructure, texture and magnetic properties of 0.5 mm cold-rolled sheets after annealing at 950℃for 7 min was researched. The results show that with increasing the normalizing temperature,the grain size of hot-rolled sheets increased,the grain boundaries were more clear and the rnicrostructure uniformity was b...
纳米TiO_2轧制液对硅钢冷轧性能的影响
分别采用传统冷轧轧制液和纳米TiO2的冷轧轧制液,对无取向硅钢板进行了四辊冷轧实验.重点研究两种冷轧轧制液的轧制润滑性能和对轧后硅钢薄带表面质量和耐蚀性能的影响.通过场发射电子显微镜和能谱仪对使用两种轧制液轧后得到的硅钢薄带表面形貌和成分进行了分析.给出了轧制液中TiO2纳米粒子在轧制过程中的抗磨减摩机理.在轧制载荷较高时,纳米TiO2轧制液具有优良的轧制润滑性能并能显著改善轧后硅钢薄带的表面质量.同时在高载荷作用下,TiO2纳米粒子被压入硅钢薄带基体,形成一个滑动系来支撑载荷,从而使润滑膜的耐磨性提高. Non-oriented silicon steel strips were rolled on a four-high cold rolling mill lubricated by a traditional cold rolling liquid and a nano-TiO2 cold rolling liquid,with emphasis on studying the rolling lubrication performance of both the liquids and their effect on the surface quality and corrosion resisting property of the silicon steel strips.The surface micrograph and composition of the silicon steel strips after being rolled with both the liquids were characterized by field emissio...
热轧卷取时间对新型冷轧无取向电工钢组织和性能的影响
研究了热轧卷取时间对无取向电工钢晶粒组织、织构演变、铁损和磁感的影响。结果表明,成品晶粒尺寸在120~140μm之间,随卷取时间的增加,成品晶粒尺寸增大。成品织构主要由γ纤维、а纤维和高斯织构等构成。随着保温时间的增加,{111}<110>和{112}<110>织构强度降低。随卷取时间的增加,成品P1.5降低。热轧板最佳的卷取工艺为550℃保温2~3 h,电工钢的综合磁性能优良。 The effects of hot-rolling coiling time on microstructure,texture,core loss and magnetic induction of a new cold-rolled non-oriented electrical steel containing copper were investigated.The test results showed that for final product the grain sizes are 120-140um,with the increase of coiling time,the grain size increase.For final product there are mainly γ-fibre,а-fibre,and {110}<001> texture,Coiling at 550℃ for hot rolled plate,the {111}<110>,{112}<110> texture was weaked with ...
稀土元素Ce含量对50W470无取向硅钢显微组织及性能的影响
利用光学显微镜(OM)和扫描电镜(SEM)研究了不同稀土Ce含量的50W470无取向硅钢的铸坯、热轧板和冷轧退火板的宏观和微观组织,并采用磁性能测试仪测定其磁性能。结果表明:当稀土Ce的加入量从0增加到66×10-6(质量分数)时,铸坯的柱状晶平均宽度从3.82 mm减小到3.24 mm,等轴晶率从43.1%增加到51.3%;热轧板的平均晶粒尺寸逐渐增加,从26.2μm增加到33.3μm,再结晶百分数从24%增加到37%;退火板的平均晶粒尺寸从36.2μm增加到39.3μm;磁性能测试表明,微观组织的变化有利于50W470无取向硅钢铁损降低和磁感提高。 Macro-structure and microstructure of as-cast plate, hot rolled plate and cold rolled annealed plate of 50 W470 non-oriented silicon steel with different rare earth Ce content was studied by optical microscope(OM) and scanning electron microscopy(SEM), and their magnetic properties were measured by magnetic property tester. The results show that when the addition amount of rare earth Ce increases from 0 to 66×10-6(mass fraction), the average width of columnar crystal of the as-cast pl...

