硅钢资料

目的提高硅钢的磁性能。方法采用多弧离子镀技术,在普通取向硅钢薄板两面沉积高硅FeSi合金层制得高硅梯度硅钢,并进行热处理,观察其显微组织,测量磁性能。结果退火态高硅梯度硅钢表面的高硅FeSi合金层与基底结合紧密,均匀致密。高硅梯度硅钢中硅含量呈梯度分布,最表层硅质量分数为11.0%,随着深度增加,硅含量逐渐降低,在距表面20μm处硅质量分数仍能达到6.5%。沉积态高硅梯度硅钢的电阻率ρ、低频铁损P10/50、高频铁损P10/1k及磁感应强度B8分别为68.6μΩ·cm,0.82W/kg,83.3 W/kg和1.73 T,退火后分别为63.1μΩ·cm,0.44 W/kg,54.38 W/kg和1.89 T。结论由于表层高硅FeSi合金层的存在,梯度高硅钢的低频磁学性能良好,但高频损耗需进一步改善。 Objective To improve the magnetic properties of silicon steel. Methods FeSi alloy coatings with high-silicon content were deposited on the surface of common grain-oriented silicon steel by cathodic arc plasma evaporation,and then a kind of high silicon gradient steel was prepared. The morphologies,content and magnetic properties of the samples were tested. Results FeSi alloy coatings were featured with compact microstructures and excellent adhesive quality with the substrates. The silicon conten... 

采用磁控溅射方法,分别在纯Fe以及低硅钢基片上沉积富Si膜,并对其进行真空扩散热处理.通过能谱分析及X射线衍射研究了Si在纯Fe与低硅钢基体中的扩散特征,运用DICTRA软件建立了扩散模型.研究发现Si在纯Fe基体中扩散时发生γ-Fe(Si)→α-Fe(Si)相转变,扩散速率受控于相界面的迁移.当沿截面Si含量梯度不足以驱动相界面正向迁移时,延长扩散时间会发生相界面回迁现象,最终趋于单一相内均匀化扩散过程.Si在低硅钢基体中的扩散符合Fick扩散第二定律. Si-rich films were deposited on pure iron and low-Si steel substrates by direct current magnetron sputtering,and then were subjected to vacuum annealing.The distribution characteristics of Si across Fe and low-Si steel substrates were studied by energy spectrum analysis(EDS) and X-ray diffraction(XRD).DICTRA software was used to simulate the diffusion models.It is found that the diffusion behavior of Si in the Fe substrate is from γ-Fe(Si) phase to α-Fe(Si) phase and the rate of diffusion is con... 

针对薄板坯连铸连轧流程结合\"获得抑制剂法\"所制备的低温高磁感取向硅钢,通过热力学计算研究了AlN与MnS在连铸与均热过程中的析出规律与行为。计算结果表明,连铸过程中AlN在凝固后的高温α相中便可能析出,而MnS仅可能在凝固后的α+γ两相区内析出。钢中AlN与MnS在均热过程中均处于部分固溶与部分析出的状态。后续高温渗氮处理后初次晶粒的异常长大并不明显,表明渗氮处理前钢中固有抑制剂的数量相对充足。 The precipitation behavior of MnS and AlN in low-temperature high magnetic induction grain-oriented silicon steel produced by thin slab casting and rolling process with\"acquired inhibitor method\"during continuous casting and soaking was studied by thermodynamic calculation.The calculated results show that AlN is likely to precipitate in ferrite after solidification.However,MnS can precipitate only in the two phase region of ferrite and austenite.Meanwhile,MnS and AlN in the steel can not be comp... 

针对新日铁公开的相关专利,总结日本高强度无取向电工钢的研究进展,分析了各专利化学成分、生产工艺及产品性能的特点,指出固溶强化、细晶强化、析出强化、位错强化都有可能被用来提高无取向电工钢的强度。在高强度无取向电工钢的研发过程中,需要根据其具体用途确定目标性能,再采用合适的强化手段,从而实现力学性能、磁性能和生产性能之间的平衡。 Authors summarize the research progress of high strength non-oriented electrical steel in Japan by learning related patents brought into the public by Nippon Steel. Authors also analyze the characteristics of the chemical composition, production technology and properties of products in the patents and point out that any ones of solution strengthening method, fine-grain strengthening method, precipitation strengthening method or dislocations strengthening method may be used to improve the strengt... 

应用CAFE法对6.5%Si高硅钢铸锭凝固组织进行了模拟研究,确定出了适合高硅钢组织模拟的模型。进一步用该模型研究了过热度及冷却条件对凝固组织的影响,结果表明,随着过热度的降低,凝固组织中柱状晶比例和晶粒平均面积均减小。水冷条件下,高硅钢铸锭凝固组织几乎全是柱状晶,而且晶粒粗大。空冷条件下,等轴晶区扩大,但柱状晶仍占主要部分。缓冷条件下,等轴晶区占主要部分,晶粒平均面积和空冷条件下相当。 The solidification structure of 6. 5% Si steel ingot was simulated based on CAFE method and the model suitable for simulating the structure of high silicon steel wad ascertained. The influence of superheat and cooling condition on the solidification structure were studied. It was shown that with the superheat decreasing,the proportion of columnar crystals decrease,and the average grain size become smaller. Under water cooling condition,the solidification structure of casting was composed of almo... 

【作者】 王桦； 舒子龙； ...

无氧化炉具有加热效率高、投资与运营成本低、作业率高、表面质量及板型良好、NOx排放相对低等优势,在硅钢热处理领域应用前景广泛。本文阐述了确定无氧化炉(NOF)加热能力详细过程,涵盖炉温、炉断面尺寸、炉长、热平衡结算、加热能力计算等,为今后无氧化炉(NOF)在硅钢热处理应用时的设计提供了借鉴,同时也为今后明火直接加热的工业炉设计提供了参考。 Non-oxidation furnace has the advantage s of high heating efficiency, low investment and operation cost, high operation rate, good surface quality and plate shape, and relatively low NOxemission,and it still has wide application prospect in the field of silicon steel heat treatment. The detailed process of determining the heating capacity of a non-oxidizing furnace(NOF) is described, covering furnace temperature, furnace section size, furnace length, heat balance settlement, heating capacity cal... 

采用\"热轧复合+冷轧减薄+退火\"方法成功制备了0.20mm厚的硅浓度梯度高硅钢薄带,并采用SEM和X射线衍射技术对制备过程中组织和织构演变进行了研究。热轧复合板微观组织呈明显层状分布,复合界面为紧密冶金结合且经过83%的大冷轧变形未开裂。热轧和冷轧复合板带中均形成强α和γ织构,再结晶退火后形成强γ织构。冷轧和退火织构沿板厚呈显著的梯度分布特征,其主要来自于复合界面两侧硅浓度和初始热轧织构的差异性以及冷变形的不均匀性。 Gradient high silicon steel thin sheets with thickness of 0.20 mm were successfully produced by the rolling and annealing method,including hot rolling bonding,cold rolling,and annealing.Microstructure and texture evolution was investigated by means of SEM and X-ray diffraction.Microstructure of hot-rolling-bonding shows obviously layered distribution,the composite interface was closely metallurgical bonding and no cracking appears even after 83%cold rolling.Strongαandγfibers develop in the hot a... 

采用XRD、SEM和激光粒度仪等手段,观察并研究了不同特性氧化镁在硅钢表面形成硅酸镁底层形貌特点,并结合热力学和差热-失重分析了MgO-SiO2的反应机理。研究结果表明:粒度小,活性值高的特种氧化镁在高温退火过程中与基体表面氧化物生成的硅酸镁底层,界面中硅酸镁底层嵌入基体较多,表面致密,颗粒细小,有利于形成附着性能优良的硅酸镁底层。 Surface microstructure of Mg2SiO4 coatings formed on the surface of oriented silicon steel coated with different kinds of MgO was investigated by XRD and SEM.The reaction mechanism between MgO and SiO2 was analyzed by TG-DSC and thermodynamic calculation.Results revealed that when the MgO with finer microstructure size and higher activity is employed,a dense Mg2SiO4 layer with finer microstructure and good binding to the steel substrate can be obtained.The results are very helpful for the prepar... 

传统轧制法制备6.5wt.%高硅钢过程中温轧工艺具有显著不同于3 wt.%Si的电工钢的特点及组织织构特征,是开发新型基于织构优化的高硅钢的关键环节。采用EBSD技术对通过热轧、温轧、冷轧及退火工艺制备0.3mm厚的6.5wt.%Si电工钢板的组织和织构进行分析,重点研究温轧过程中的中间退火和大、小压下率组合以控制织构。结果表明,在热轧退火板是部分再结晶组织的情况下,一次性温轧或先小形变量、中间退火后再大形变量的工艺可得到更多的Goss晶粒;经过最终退火后Goss取向会发生偏转,形成部分黄铜取向,而{111}〈112〉取向的晶粒内形核生成近Goss取向的再结晶晶粒;大压下量轧制是最终组织中{111}取向晶粒较多的主要原因。 Warm rolling,a key process of developing new type high-Si electrical steel based on texture optimization,has significant different characteristics from 3wt% Si steel in conventional preparing process. 0. 3mm thickness 6. 5wt. % Si steel,obtained by a series of processes including hot and warm rolling,intermediate annealing and then cold rolling,was analyzed from microstructure and texture by EBSD,which are utilized mainly for investigating the intermediate annealing process and the combination o... 

冷轧中中低牌号的无取向硅钢多采用万能凸度轧机(Universal crown mill,UCM)生产,其板形好坏受制于UCM轧机板形调节手段的协调使用。为掌握UCM轧机的板形控制特点,建立基于二维变厚度有限元的辊系弹性变形和基于三维差分的轧件塑性变形的六辊轧机耦合模型,对UCM轧机的板形调控性能进行详尽的分析,包括工作辊和中间辊弯辊、中间辊窜辊的调控功效、辊间接触压力分布等。在此基础上,提出可用指导生产的板形控制策略,指出UCM轧机在横向厚差控制方面的不足。针对工业生产中UCM轧机轧制无取向硅钢横向厚差大的问题,在大量仿真计算的基础上,开发具有高次曲线函数的边部变凸度(Edge variable crown,EVC)的工作辊。采用该工作辊后,各种品种的无取向硅钢的横向厚差不大于10μm的百分比由24%提高到99%,横向厚差的均值小于6μm,远小于之前的13μm。 Medium-low grade non-oriented silicon steel is rolled often by universal crown mill(UCM) during cold rolling.Its shape quality is dependent on the coordinated control of several shape adjustment devices of UCM.In order to understand the shape control characteristics of UCM,coupling model of six-high rolling mill,based on two-dimensional varying thickness finite element rolls elastic deformation model and three-dimensional finite difference strip plastic deformation model,is setup for the detaile... 

研究了取向硅钢制备过程中常见的两种冷轧工艺,主要研究了一阶段冷轧与两阶段冷轧+中间退火工艺对初次再结晶组织及织构的影响.结果表明:采用两阶段冷轧+中间退火工艺制备以Cu2S为主抑制剂的取向硅钢,其初次再结晶平均晶粒尺寸为18.1μm,高斯晶粒的体积分数为0.6%,迁移性强的重位点阵晶界(Σ5+Σ9)和高能晶界(20°~45°取向偏差角)所占比例分别为1.8%和50.4%.与一阶段冷轧工艺相比,其初次再结晶晶粒较细,且高斯晶核与特征晶界所占的比例较高,有利于高斯晶粒发生二次再结晶. Two common cold-rolling processes of grain oriented silicon steel and the effects of the single stage cold rolling and tw o-stage cold rolling w ith intermediate annealing processes on the primary recrystallization microstructure and texture w ere investigated. The results revealed that for the grain oriented silicon steel prepared under the tw o-stage cold rolling process w ith intermediate annealing w ith Cu 2 S as the main inhibitor,the average grain size of the primary recrystallization micr...