硅钢资料

【作者】 徐刚； ...

综述了国内外大钢铁企业与研究机构采用获得抑制剂法生产低温高磁感取向硅钢的开发及应用情况,分析了以该法生产高磁感取向硅钢过程中抑制剂的控制技术,包括固有抑制剂组成方案、气态渗氮方式与工艺及高温退火工艺的制定.研究表明,固有抑制剂组成方案的设计思路大体一致,化合物抑制剂以AlN为主、硫化物为辅,同时添加少量Sn,Sb等单元素抑制剂,但组成元素含量存在一定差别;在脱碳退火后用NH3进行非平衡渗氮处理已成为气态渗氮的主要方式,但最佳方式仍未明确,具体选择需依据实际生产条件,相应脱碳及渗氮工艺的控制条件差别较大;高温退火工艺中升温制度差别不大,升温阶段退火气氛中N2含量的选择存在差别.此外,分析了抑制剂控制技术目前存在的关键问题,并指出了进一步的研究方向. The current application and exploitation on production of low-temperature high magnetic induction grain-oriented silicon steel with acquired inhibitor method at both iron and steel enterprises and research institutions in the world are reviewed. The control techniques of inhibitors, which include the composition design for inherent inhibitors, nitriding method and process, and secondary recrystallization annealing, are thoroughly analyzed and proposed. It is indicated that the design ideas for i... 

【作者】 刘玲月； 李军辉； ...

采用CVD法制备6.5%Si高硅钢,介绍了具体的制备工艺过程,研究了温度对渗硅速率和试样质量减轻的影响,同时分析了扩散时间对高硅钢中硅分布的影响。结果表明:在CVD反应过程中,反应温度高于1050℃将大大提高渗硅速率,但当温度大于1200℃后,渗硅速率趋于稳定;渗硅后,试样会减轻、减薄,随着温度升高,试样质量减轻的速率逐渐增大,在1200℃左右趋于稳定;扩散时间越长,硅分布越均匀,结合制备效率进行考虑,满足Δw表-中/b≤5的时间为适宜的扩散时间。 6.5%Si high silicon steel was manufactured by using CVD method and the process was introduced,the influence of temperature on the siliconizing rate and quality reducing rate,diffusion time on silicon distribution were investigated.Results as follows: the siliconizing rate will increase quickly when the temperature is higher than 1050 ℃,but the siliconizing rate will become steadily as the temperature up to 1200 ℃;The quality reducing rate will increase with the elevating of temperature and the r... 

研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%～100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters... 

结合扫描电镜和大样电解研究了CSP流程W800牌号无取向电工钢表面线状缺陷中夹杂物成分及来源，采用SPSS软件回归分析了生产过程各因素对表面线状缺陷的影响。研究表明：稳态浇铸过程铸坯中大型夹杂物含量为5.39 mg/10 kg。引起无取向电工钢表面线状缺陷的大型夹杂物主要为脱氧产物、镁铝尖晶石和钢包顶渣，主要类型为Al₂O₃、MgO-Al₂O₃、CaO-Al₂O₃-MgO和CaO-Al₂O₃-SiO₂。非稳态浇铸过程钢水洁净度明显降低，热轧板表面线状缺陷比例上升。影响表面线状缺陷的主要因素为RH出站时顶渣的w（CaO）/w（Al₂O₃）、RH脱氧结束氧位及中间包最低吨位。 Combining scanning electron microscopy and large sample electrolysis, the composition and source of inclusions in the surface linear defects of W800 grade non-oriented electrical steel in the CSP process were studied. SPSS software was used to regress and analyze the main factors which affected the surface linear defects in the steelmaking process. Research shows that the content of large inclusions in the steady state casting process is 5.39 mg/10 kg. The large inclusions which cause linear def... 

【作者】 王磊； ...

针对川威950的工艺现状,结合无取向低硅钢SGG生产的工艺特点,主要从控制其钢坯加热和轧制以及终轧温度和卷曲温度几方面入手,进行无取向低硅钢生产的工艺控制研究。同时根据近6000吨的生产实践表明,该工艺措施能很好的满足该钢种的需要。 950 process Chuanwei status quo,with non-oriented silicon steel production process features low,mainly from the control of billet heating and rolling and finish rolling temperature and coiling temperature of several aspects,for non-oriented silicon steel production process of low control at the same time According to nearly 6,000 tons of production practice shows that the process measures could well meet the needs of the steel. 

2.9 mm热轧3%Si高牌号无取向硅钢板（/%:0.004 6C、3.04Si、0.32Mn、0.49Als、0.004S、0.013P、0.0042N）由CSP（Compact Strip Production紧凑式带材生产线）流程:120 t BOF-70 mm CC-热轧工艺生产。热轧终轧温度872℃,卷取温度683℃。铸坯及热轧板的组织和夹杂物的分析结果表明,铸坯组织为典型的贯穿柱状晶组织;热轧板边部为再结晶组织,中部为纤维组织带有少量再结晶晶粒;高牌号无取向硅钢的主要夹杂物为铸坯-Al₂O₃,AlN和Cu₂S+MnS;热轧板-Al₂O₃,AlN,AIN+MnS和Cu₂S+MnS。 The 2.9 mm hot rolled 3%Si high grade non-oriented silicon steel plate（/%:0.004 6C,3.04Si, 0.32Mn,0.49Als,0.004S,0.013P,0.004 2N） is produced by CSP（Compact Strip Production） flow sheet i.e.120 t BOF-70 mm CC-hot rolling process with end rolling at 872℃and coiling at 683℃.The analysis results on structure and inclusions in casting slab and hot rolled plate show that the structure of slab is typical trans-columnar crystal,the structure of hot rolled plate at edge is recrystallized grain and in ce... 

研究稀土Ce的添加对含Sn高磁感无取向电工钢磁性能及夹杂物的影响。对比分析了两种成分钢的磁性能以及各过程工艺条件下夹杂物种类和分布情况。结果表明,在含Sn高磁感无取向电工钢中加入稀土元素Ce可以粗化夹杂物,提高成品晶粒的均匀性,有效降低铁损;同时Ce的添加不影响Sn元素提高磁感的效果,磁感保持不变。 Effect of Ce on magnetic properties and inclusion of Sn-bearing high permeability non-oriented electrical steel was investigated. A comparative analysis of the magnetic properties and the types and distributions of inclusion in the two sheets with different composition shows that the addition of Ce to the Sn-bearing high permeability non-oriented electrical steel can coarse the inclusion,improve the homogeneity of the finished grain and effectively decrease the core loss. Also,the addition of Ce... 

分析了冲裁硅钢芯片时出现的质量问题,针对影响硅钢芯片冲裁质量的4大因素——人、原材料状态、工艺和工装进行了工艺试验和分析,根据原材料状态的差异,采用不同工艺方案,特别是如何合理选择冲裁模具间隙,解决了硅钢芯片冲裁时产生的主要质量问题,使冲裁的硅钢芯片达到最佳质量状态,并满足硅钢芯片的使用性能。 The problems occurred during silicon steel chip punching and the factors that affect the quality of silicon steel chip punching were analyzed,the factors include 4aspects,that is,people,raw material status,process and frock,at the same time,process tests and analysis aimed at the factors that affect punching quality were did,according to the difference of raw material status,corresponding process schedules wee taken,especially in how to reasonably select punching dies clearance,which solved the ... 

通过实验室25 kg真空感应炉冶炼和锻轧研究了0.26%～0.95%Al含量对0.5 mm 2.2%Si无取向硅钢冷轧板组织、织构和磁性能的影响。试验结果表明,0.26%～0.81%Al含量时,随钢中Al含量的增加,成品退火钢板的晶粒尺寸增加同时铁损减少;当Al含量大于0.81%时,随Al含量增加,钢板的晶粒尺寸减小,同时铁损增加。Al含量对硅钢板磁感的影响没有明显的规律。2.2%Si无取向硅钢的合适Al含量为0.48%～0.81%。 The effect of 0.26%～0.95%Al content on structure,texture and magnetic performance of 0.5 mm cold rolled sheet of 2.2%Si non-oriented silicon steel has been studied by a 25 kg vacuum induction furnace smelting,and forging -rolling in laboratory.Results show that as 0.26%～0.81%Al,with increasing Al content in steel the grain size of annealed finished sheet increases while iron loss of sheet decreases,and as Al content in steel is more than 0.81%,the grain size of sheet decreases while iron loss in...