硅钢资料

运用EBSD和光学显微镜,研究了0.25%~0.45%Cu对无取向电工钢热轧板显微组织,成品板显微组织、织构和磁性能的影响。实验结果表明:卷取过程中Cu元素在热轧板表层的偏聚作用显著阻碍了热轧板表层再结晶晶粒长大,导致热轧板表层晶粒尺寸随着Cu含量增加而逐渐较小,但热轧板中间晶粒尺寸变化不大。同时发现Cu元素能够明显改善织构类型,使有利织构组分增加,不利织构组分减少,同时减弱织构强度。从实验结果可知0.35%Cu能够显著改善电工钢的磁性能,铁损P15/50最低达到4.1 W/kg,磁感B50最高值达到1.8 T。 Effects of high content Cu on microstructure of hot rolled plates and microstructure,texture and magnetic properties of annealed finish product plates of non-oriented electrical steel were examined by means of EBSD technique and optical microscope. The results show that surface segregation of Cu significantly hindered recrystallized grain growth of surface layer in hot rolled plate during the coiling,as a result,the surface grain sizes of the hot-rohed plates decrease with the increase of Cu con... 

针对本钢薄板坯铸机在生产无取向电工硅钢的过程中存在的铸坯拉断、中包增碳、增氮等问题,进行了连铸工艺优化。通过采用新型无碳中间包覆盖剂、环保中间包干式料及专用结晶器保护渣后,降低了铸坯增碳量;通过控制钢包到中间包的增氮环节,降低钢水增氮;适当增大二冷水量,控制钢水过热度,防止铸坯拉断等生产事故的发生。改进工艺后,精炼后到成品铸坯的平均增碳量能控制在10×10-6以内,平均增氮量能控制在4×10-6以内。 The technology optimization has been adopted for preventing nitrogen increasing and carbon increasing in Benxi thin slab producing non-oriented silicon steel.Measures accordingly were adopted and satisfactory results were achieved. 

【摘要】 <正>2012年3月29日中国钢铁工业协会在上...

在15 kg真空感应炉上,用CaO-Al2O3-SiO2-MgO渣系进行脱硫试验,探讨了脱硫渣系碱度、MI、Al2O3、CaF2对脱硫效果的影响。研究结果表明,随脱硫渣系碱度、MI、Al2O3和CaF2含量的增加,脱硫率都呈现先增加后减少的趋势。初始硫含量为0.009 33%~0.010 73%,加入脱硫渣系4 min时间内表观脱硫速率为(0.000 96~0.001 49)%/min,平均脱硫率为81.2%,最高达86.8%。当脱硫渣中w(CaO)=58.15%、w(SiO2)=4.85%、w(Al2O3)=25%、w(MgO)=6%、w(CaF2)=6%,脱硫效果最好,此时钢液中硫为0.001 33%。 Experiments on desulfurization of molten steel using CaO-Al2O3-SiO2-MgO based desulfurization slag was carried out in a 15 kg vacuum induction furnace. The effects of desulfurization slag basicity,MI, Al2O3and CaF2on desulfurization of molten steel were studied. The results show that with the increase of basicity,MI,Al2O3or CaF2in desulfurization slag,the desulfurization rate rises initially and then decreases. In addition,as the initial sulfur content is 0. 009 33% ~ 0. 010 73%,the apparent des... 

利用EBSD技术研究了电工钢中不同的柱状晶尺寸及退火工艺下{100}织构的演变规律。结果表明,初始晶粒尺寸的影响最显著。细小柱状晶热轧后经过常化处理,组织已均匀,但中心层有强{100}织构。粗大柱状晶中{100}织构的遗传性强,常化及中间退火后,中心层仍有粗大的以{100}取向为主的晶粒;脱碳退火后才能完成组织均匀化和织构梯度的弱化。常化时的升温速度也对织构演变存在影响,低的升温速度有利于{100}织构的保留,但升温速度的影响没有初始晶粒尺寸及退火次数的影响显著。细小柱状晶样品经过热轧及三次退火工艺适合制备取向电工钢。 Evolution of {100} texture of different columnar grains and annealing process was investigated in electrical steels with the help of EBSD technique.The results show that the effect of initial grain size is the strongest.The initial fine-grained specimen shows uniform microstructure after the normalizing process,while {100} grains appear preferentially in the central layer of sheets.The heredity of {100} texture in the initial coarse-grained specimen is more significant.{100} mainly-oriented coar... 

介绍了微合金元素锡、铌、稀土对无取向硅钢性能的影响,并扼要分析了这些元素对硅钢性能的影响机理:晶界偏聚元素Sn可细化晶粒提高硅钢磁性能;微合金元素Nb细化铁素体晶粒,提高硅钢的强度、韧性和塑性及磁性能;稀土元素(RE)在硅钢中的主要作用包括净化钢液、变质夹杂物、改善铸态组织和性能及微合金化,减少晶界上出现偏析的几率。 The influence of micro-alloy elements on properties of non-oriented silicon steel and the mechanism for effect of the micro-alloy elements including Sn、Nb and RE on the properties of steel are presented and analyzed in this paper.Grain boundary segregation elements Sn in steel can grain refinement and improve the magnetic properties;Micro-alloy elements Nb can refine the ferrite grain,increase the silicon steel strength,toughness and plastic;The main role of the RE in the silicon steel including... 

在实验室模拟CSP工艺条件下制备了取向硅钢,研究了二次冷轧中间退火工艺对组织和织构的影响。结果表明,中间退火温度对取向硅钢脱碳,高温退火组织及织构均产生明显影响。经940℃中间退火后,取向硅钢脱碳再结晶晶粒较850℃中间退火的多,且再经高温退火处理后,晶粒粗化,最大晶粒尺寸达4.8 mm;高斯织构组分密度达27.00,较850℃中间退火试样高。 Grain-oriented silicon steel was prepared by simulated CSP technology in laboratory. Effects of secondary cold-rolled intermediate annealing on microstructure and texture were studied. The results show that intermediate annealing has obvious effects on the microstructure and texture of the steels after decarburization annealing and high temperature annealing. After intermediate annealing at 940 ℃,recrystallized grain of decarburization annealed steel is more than that of intermediate annealed at... 

阐述了国内外高磁感取向硅钢的生产研究水平与发展趋势,包括通过提高高斯晶粒取向度、细化磁畴、涂覆张力涂层、减薄钢片厚度进一步降低铁损以及低温加热技术和短流程技术新工艺。分析高磁感取向硅钢在我国大型电力变压器上的应用情况,结果表明,发展更薄规格高磁感、低铁损、低磁致伸缩取向硅钢可为大型变压器的安全性、节能性及环保性提供有效保障。 The research progress and development trend of high magnetic induction grain-oriented silicon steel at home and abroad are summarized,including the technology of improving the Goss alignment,refining domain wall,adding stress coating,decreasing thickness of sheet,and the new technique of reducing heating temperature of casting slab and shortening operational.Moreover,the application of high magnetic induction grain-oriented silicon in power transformer is presented.Developing grain-oriented sili... 

介绍了烟气余热利用系统的工艺流程及控制思想,结合该系统在钢厂硅钢连续退火机组中的应用实践,估算出烟气余热利用系统每年可节约蒸汽5 040 t,经济效益良好,同时分析了该系统存在的问题及对策。 Introduced a method about the process and control of the application of waste heat system, which had been used into a silicon steel continuous annealing line and profiting a good economic benefit by saving a large number of steam every year, which has been estimated about 5 040 tons, and analyzed the problems and solutions existed in this system. 

为了更好的解决电力系统防污闪涂料RTV-Ⅰ长期应用暴露出来的问题以及目前RTV-Ⅱ防污闪涂料存在的一些不足,结合具体实际需求,在电力系统外绝缘领域,应用新型防污闪硬质涂层——防污闪纳米硅钢涂层,并对分别喷涂了防污闪纳米硅钢涂层以及RTV涂料的绝缘子进行对比运行情况研究分析。研究结果表明,防污闪纳米硅钢涂层是一种同时具有优异憎水性迁移性能和自洁性能的新型涂层,具有良好的应用前景。 In order to solve the problem exposed of anti-pollution flashover coating RTV-Ⅰwhich has been used long-term in power system,as well as to better solve some shortcomings of the current anti-pollution flashover coating RTV-Ⅱ,in this paper,a new anti-pollution flashover hard coating — anti-pollution flashover nanometer silicon hard coating(NSHC) is applied in the field of power system insulation for the specific practical needs.At the same time insulators which are separately sprayed by the NSHC a... 

以CaO-CaF2复合渣系为脱硫剂,在RH精炼过程采用真空投入法进行高牌号无取向电工钢深脱硫工业试验,采用KTH模型计算分析了RH炉渣成分对硫容量CS的影响。研究结果表明,炉渣成分控制在w((CaO))/w((SiO2))为5~7,w((CaO))/w((Al2O3))为1.5~1.8,w((Al2O3))为25%~30%,w((FeO+MnO))<5%,脱硫剂加入量为6~8kg/t时,钢中硫质量分数从平均0.003 1%降低到0.001 8%,最高脱硫率达到47.1%,平均脱硫率为41.7%。 The industrial trials on deep desulphurization of high grade non-oriented electrical steel were finished through using CaO-CaF2complex based fluxes in RH process.Using the KTH model,the effect of refining slag composition on the sulfide capacities was analyzed.The results show that the chemical composition of refining slag(mass fraction,%)is w((CaO/SiO2))between 5to 7,w((CaO))/w((Al2O3))beween 1.5to 1.8,w((Al2O3)) between 25%to 30%,w((FeO+MnO))less than 5%,and the desulphurizer addition level of... 

采用自主研发的脉冲磁场退火装置，在取向硅钢脱碳退火过程中分别施加不同强度的磁场，并采用光学显微镜和X射线衍射仪研究了脉冲磁场脱碳退火后试样的显微组织和宏观织构。结果表明，脱碳退火过程中施加脉冲磁场后取向硅钢的平均晶粒尺寸均增加，当磁场强度为40 mT时，平均晶粒尺寸最大，为13.06μm。此外，取向硅钢试样的立方织构{001}<100>强度减弱，高斯织构{110}<001>和{111}<112>织构增强，有利于获得更好的成品织构和磁性能。 Self-developed pulsed magnetic field annealing device was used to apply magnetic field of different intensities during decarburization annealing of an oriented silicon steel, and microstructure and macro-texture of the specimens after decarburization annealing in a pulsed magnetic field were studied by using optical microscope and X-ray diffractometer. The results show that the average grain size of the oriented silicon steel increases with the application of pulsed magnetic field during decarbu...