硅钢资料

通过热力学计算,分析了实验钢中主要析出物析出的可能性。结果表明:在液相和固液两相区中,AlN和MnS均不能析出;在奥氏体区,AlN和MnS具备热力学析出条件,平衡析出温度分别为1547、1582 K。成品退火板中的析出物主要为AlN和MnS。扫描电镜下观察到的AlN形貌多为长条状,MnS形貌多为棒状或近似球形。这两种析出物占了析出物总量的85%以上,尺寸集中分布在400~800nm;复合析出物主要是(Al2O3+MnS)和(AlN+MnS),形貌不规则,尺寸集中在0.7~1.5μm;透射电镜下观察到了少量100nm以下独立的AlN析出。 According to thermodynamic calculation, the precipitation probability of precipitates was analyzed, AlN and MnS can not precipitate in liquid phase area and solid-liquid two-phase area. In austenite area, both the AlN and MnS have precipitation condition in thermodynamics and precipitates at 1547 K and 1582 K, respectively. The precipitates in annealing plate are mainly AlN and MnS. The shape of AlN is mostly strip, and MnS is stick or near sphericity. They accounted for over 85% of the total qu... 

随着中国电工钢产量的增加,硅钢级氧化镁需求量不断增加,传统的以白云石为原料制备氧化镁的工艺已经无法满足市场需求。中国是一个卤水资源丰富的国家,因此,研究如何资源化综合利用盐湖资源变得越来越重要。硅钢级氧化镁是一种制备取向硅钢的涂层材料,主要用于取向硅钢高温退火处理阶段,起到隔离剂、绝缘膜层、脱硫、脱磷等作用。综述了制备硅钢级氧化镁的方法、工艺流程、研究进展及存在的问题,指出了硅钢级氧化镁制备技术的发展方向,并对中国卤水资源的利用提出了建议。 With the increasing output of electric steel,the demand for silicon steel grade magnesium oxide(MgO) is larger and larger in China,and the traditional MgO production process with dolomite as raw material has been unable to meet market demand.China is a brine resource-rich country,the study of how to comprehensively utilize salt lake resources has become increasingly important.As a coating material used for preparing oriented silicon steel,silicon steel grade MgO is mainly used in the process of ... 

【作者】 陶永根； ...

叠片系数是冷轧无取向电工钢的重要质量指标。为了提高叠片系数,必须保证无取向电工钢板形良好以及横向厚差小。针对攀钢冷轧厂4机架HC轧机轧制无取向电工钢的边部减薄问题,以无取向电工钢横向厚差最小作为目标函数,建立了一套针对无取向电工钢边部减薄控制的辊型曲线优化数学模型,开发了无取向电工钢专用辊型曲线,使无取向电工钢横向厚差从25μm降低到10μm以下,取得了良好的控制效果。 The lamination factor is an important quality index of non-oriented silicon steel strip.Considering the lamination factor,the non-oriented silicon steel must have a good shape and a smaller transverse thickness difference.In order to solve the edge thinning of non-oriented silicon steel strip in Panzhihua Steel,a mathematic model for designing the roll shape is built.In the model,the transverse thickness difference of non-oriented silicon steel strip is taken as the objective function.Based on t... 

以CaO-CaF2复合渣系为脱硫剂,在RH精炼过程采用真空投入法进行高牌号无取向电工钢深脱硫工业试验,采用KTH模型计算分析了RH炉渣成分对硫容量CS的影响。研究结果表明,炉渣成分控制在w((CaO))/w((SiO2))为5~7,w((CaO))/w((Al2O3))为1.5~1.8,w((Al2O3))为25%~30%,w((FeO+MnO))<5%,脱硫剂加入量为6~8kg/t时,钢中硫质量分数从平均0.003 1%降低到0.001 8%,最高脱硫率达到47.1%,平均脱硫率为41.7%。 The industrial trials on deep desulphurization of high grade non-oriented electrical steel were finished through using CaO-CaF2complex based fluxes in RH process.Using the KTH model,the effect of refining slag composition on the sulfide capacities was analyzed.The results show that the chemical composition of refining slag(mass fraction,%)is w((CaO/SiO2))between 5to 7,w((CaO))/w((Al2O3))beween 1.5to 1.8,w((Al2O3)) between 25%to 30%,w((FeO+MnO))less than 5%,and the desulphurizer addition level of... 

【作者】 张正贵； 李战库； ...

采用磁控溅射方法,分别在纯Fe以及低硅钢基片上沉积富Si膜,并对其进行真空扩散热处理.通过能谱分析及X射线衍射研究了Si在纯Fe与低硅钢基体中的扩散特征,运用DICTRA软件建立了扩散模型.研究发现Si在纯Fe基体中扩散时发生γ-Fe(Si)→α-Fe(Si)相转变,扩散速率受控于相界面的迁移.当沿截面Si含量梯度不足以驱动相界面正向迁移时,延长扩散时间会发生相界面回迁现象,最终趋于单一相内均匀化扩散过程.Si在低硅钢基体中的扩散符合Fick扩散第二定律. Si-rich films were deposited on pure iron and low-Si steel substrates by direct current magnetron sputtering,and then were subjected to vacuum annealing.The distribution characteristics of Si across Fe and low-Si steel substrates were studied by energy spectrum analysis(EDS) and X-ray diffraction(XRD).DICTRA software was used to simulate the diffusion models.It is found that the diffusion behavior of Si in the Fe substrate is from γ-Fe(Si) phase to α-Fe(Si) phase and the rate of diffusion is con... 

热轧轧制工艺对产品性能和轧制稳定性影响很大,对中低牌号无取向电工钢,当在两相区轧制时,热轧塑性明显降低,板形变坏,易出现边裂等情况。以50W1000为例,通过对其变形抗力进行研究,得出把两相区控制在F4与F5之间为最佳轧制工艺的结论。在此基础上制定了一套较为合理的热轧工艺制度。采用新的轧制工艺后,50W1000热轧精轧的稳定性明显改善,热轧产品合格率由开发初期的40%左右提高到95%以上。 The hot rolling process has great influence on product′s performance and rolling stability.For the low medium grade non-oriented electrical steel,when non-oriented electrical steel is rolled in tow phase region,the hot rolling plasticity reduces obviously,the shape of strip goes bad and easily to crack at the edge.The deformation resistance of 50W1000 steel was investigated.The results show that the optimal rolling process is to control the two phase region between F4 and F5.Based on the results... 

为研究常化温度对热轧无取向硅钢组织与织构的影响,采用光学显微镜、背电子散射衍射技术研究了不同常化温度对其影响。结果表明,实验硅钢板在700～850℃温度下常化时,随常化温度的升高,晶粒尺寸增大,有利组分α织构增强,不利组分γ织构降低。对比研究了800℃和850℃常化热轧板CSL晶界分布图与取向差分布图,在本文研究条件下,Goss织构易在Σ=3,9的CSL晶界及晶粒取向差为30°～55°处形成。 The hot strips normalized at different temperatures were investigated by optical microscope and EBSD to study the effect of normalizing temperature on microstructure and texture of hot-rolled non-oriented silicon steel sheets.The results show that the grain size increases,the intensity of α-fibre texture increases,and the γ-fibre texture decreases when the hot strips are normalized at the 700-850 ℃.And CSL boundaries of Σ=3 and 15,and misorientation angles between 30° and 55° are more likely rel... 

冷轧取向硅钢工程中有很多的超长、大体积以及薄壁的混凝土结构,裂缝控制是土建施工的关键。在工程中,按照\"抗放兼施、先放后抗、以抗为主\"的原则,采用\"无缝分块跳仓法\",防止超长混凝土结构收缩产生裂缝;在隧道和池体的底板与墙板施工中,采用\"整体浇筑\"法,避免了墙板因约束应力而产生的裂缝。 In the Cold-rolled grain-oriented silicon steel project,there are many overlength,bulk mass,thin-walled concretes structures,how to control the crack is the key of civil engineering construction.In these projects,according to the principle of\"release with resist,resist before release,resist is dominant \",the crack of the over-long structure and shrinkage can be prevented by the method of\"seamless block skip bin \".In the construction of the bottom plate and wall of the tunnel and the pool,the cra... 

对低温加热工艺生产的以AlN为主抑制剂的高磁感取向硅钢高温退火过程进行中断实验,借助电子背散射衍射技术对高温退火过程中高斯晶粒的演变进行了研究.在升温过程中高斯晶粒平均尺寸先减小再增大.800℃时取向分布函数图出现高斯织构组分,但强度很弱,高斯晶粒偏离角在10°以上;900℃时高斯晶粒平均生长速率超过其他晶粒;950~1000℃时高斯晶粒异常长大,偏离角3°~6°;在1000℃之前高斯取向晶粒相比于其他晶粒没有尺寸优势. The high-temperature annealing process of high permeability grain-oriented silicon steel with AlN as an inhibitor was studied by interrupting test.The evolution of Goss texture in this process was analyzed by electron back-scattered diffraction.It is found that the Goss grain size first decreases and then increases with the rise of temperature.Goss texture appears in the orientation distribution function at 800 ℃,but the intensity is very weak and the deviation angle is more than 10°.The average... 

以一种新的Fe-Si合金制备工艺为出发点,研究了不同放电等离子体快速烧结工艺(SPS)和Si含量变化对Fe-Si合金材料显微组织与磁性能的影响。结果表明,在烧结温度为1 000℃时制备的Fe-6.5%Si合金(质量分数,下同)的综合磁性能较好,其在50Hz下的铁损为0.549W/kg,最大磁感应强度为0.124 3T,矫顽力245.6 A/m,磁导率0.338mH/m。另外,材料的最大磁感应强度随Si含量的增加显著增长,1 000Hz下,Fe-10.0%Si的最大磁感应强度可达到Fe-6.5%Si合金的5倍左右。 The effects of Si content and SPS technology on microstructure and magnetic properties of Fe-Si alloy material were studied in the paper.It shows that the magnetic properties are the best when the content of Si is 6.5wt% and the sintering temperature is 1 000℃,the iron loss is 0.549W / kg in 50Hz,maximum magnetic induction is 0.124 3T,coercive force is 245.6A / m and permeability is 0.338mH / m。And,the maximum magnetic induction increases significantly with the increase of Si.The maximum magneti...