硅钢资料

采用RH精炼添加钙合金方式对硅钢进行钙处理。结果表明,钙合金添加量为0.67、1.00、1.67kg/t钢时,钢中钙含量分别为0、2×10-6、4×10-6;随着钙合金添加量增大,钢中夹杂物粒度逐渐由0～2μm向2～4、4～6μm偏移;不同钙处理条件下,钢中均存在粒径小于1μm和粒径为1～5μm的MnS、CuxS夹杂物,后者或单独存在,或同AlN、CaS夹杂复合;粒径为5～10μm区间,钢中的夹杂物基本以钙的氧、硫化物为主。与钙处理前相比,钙合金添加量为0.67、1.00、1.67kg/t钢时,粒径小于1.0μm的微细夹杂物减少幅度分别为68.06%、87.50%、94.94%。钙合金添加量为1.67kg/t钢时,可以去除钢中绝大部分的微细夹杂物。 Ca alloy was added into the liquid steel during RH refining,and the results show that Ca concentration in final Si steel sheets is insignificant,about 0,2×10-6 and 4×10-6 when the added amount of Ca is 0.67,1.00 and 1.67 kg/t steel,respectively.With the increase in the added Ca alloy amount,the inclusions in the steel gradually change from those of 0～2 μm to those of 2～4 and 4～6 μm.Under different Ca treatments,there exist MnS and CuxS inclusions whose size is below 1 μm as well as MnS and CuxS ... 

采用XRD、SEM和激光粒度仪等手段,观察并研究了不同特性氧化镁在硅钢表面形成硅酸镁底层形貌特点,并结合热力学和差热-失重分析了MgO-SiO2的反应机理。研究结果表明:粒度小,活性值高的特种氧化镁在高温退火过程中与基体表面氧化物生成的硅酸镁底层,界面中硅酸镁底层嵌入基体较多,表面致密,颗粒细小,有利于形成附着性能优良的硅酸镁底层。 Surface microstructure of Mg2SiO4 coatings formed on the surface of oriented silicon steel coated with different kinds of MgO was investigated by XRD and SEM.The reaction mechanism between MgO and SiO2 was analyzed by TG-DSC and thermodynamic calculation.Results revealed that when the MgO with finer microstructure size and higher activity is employed,a dense Mg2SiO4 layer with finer microstructure and good binding to the steel substrate can be obtained.The results are very helpful for the prepar... 

试验研究了退火温度(850~950℃)和时间(5~18 min)对2.3 mm热轧硅钢板(/%:0.036C,3.15Si,0.21Mn,0.005P,0.007S,0.032A1)6道次轧制的0.35 mm冷轧板组织和织构的影响。结果表明,退火温度越高,晶粒平均尺寸越大,900℃5 min退火时平均晶粒尺寸41.39μm,试样织构主要集中在γ取向线上的{111}<112>织构组分和{111}<110>织构组分;900℃18 min退火时平均晶粒尺寸为48.08μm,试样的{111}面织构和{112}面织构密度都明显减弱,{001}面织构增强,磁性能较优。 The effect of annealing temperature(850 ~950 ℃) and holding time(5 ~ 18 min) on structure and texture of 0.35 mm sheet by 6 passes cold-rolling from 2.3 mm hot-rolled plate of silicon steel(/%:0.036 C,3.15 Si,0.21 Mn,0.005 P,0.007 S,0.032A1) has been tested and studied.Results show that the higher the annealing temperature the coarser the average grain size;As annealing at 900 ℃ for 5 min the average grain size of steel sheet is 41.39 μm,and the texture in sample is mainly concentrated in y orie... 

对两种硅钢水溶性极厚绝缘涂层进行了不同温度的热老化实验。通过TG-DTA,GDS,FT-IR,SEM和光泽度仪等测试方法对老化的涂层进行分析表征,提出了评估硅钢水溶性极厚绝缘涂层热老化性能的合理温度区间,探讨了涂层热老化行为,并分析了两种涂层热老化性能的差异。结果表明,涂层附着性随着老化时间的延长逐渐下降。FT-IR表征结果显示,热老化过程中,涂料交联形成的化学键未发生断裂,交联剂氨基树脂的三嗪环被破坏是聚合物三维网络结构坍塌的主要原因。 Thermal aging expriments at different temperature were carried out on two types of water-soluble and extra-thick insulation coatings for non-oriented silicon steel,and a series of test methods such as glossmeters,TG-DTA,FT-IR,GDS,SEM were applied in analysis.For evaluating the thermal aging effect of this kind of insulation coating,the proper temperature range was proposed.The difference of aging performance between two coatings was been investigated and the related behaviors were been discussed... 

为进行磷酸盐系无铬无取向硅钢涂层烧结固化工艺研究,首先对磷酸盐系无铬无取向硅钢涂层进行热重-差示扫描量热(TG-DSC)分析;然后在不同烧结固化温度条件下,测定涂层板温随时间变化曲线;最终获得涂层烧结固化温度与时间(T-t)工艺曲线。通过中性盐雾试验、动电位极化、交流阻抗、涂层附着力以及扫描电子显微镜(SEM)和能谱(EDS)分析验证。结果表明,根据涂层烧结固化温度与时间(T-t)工艺曲线制备的涂层结构致密、性能优异,证明该工艺曲线具有合理性与正确性。 In order to study the curing process of chromium-free non-oriented silicon steel coatings,phosphatic chromium-free non-oriented silicon steel insulating coating was prepared and TG-DSC analysis of the coating was conducted,then the change of the actual temperature of the coated non-oriented silicon steel sheet with time at different curing temperatures was studied. Based on the experiments,the processing curves of curing temperature vs. curing time( T-t) for the chromium-free non-oriented silico... 

【作者】 刘玲月； 李军辉； ...

提出了一种基于爱泼斯坦方圈族(包括标准25cm爱泼斯坦方圈、缩比的17.5cm和20cm爱泼斯坦方圈)和二级加权处理方法对爱泼斯坦测试数据,包括有效磁路长度、比损耗、励磁功率,进行处理的晶粒取向电工钢磁性能扩展模拟方法。详细地考察了励磁频率、试样剪切角度和环境温度对爱泼斯坦方圈测量结果的影响。研究结果表明,利用本文提出的爱泼斯坦方圈组合以及二级加权处理技术,可以有效地建立取向电工钢损耗模拟模型,从而更加准确地确定了取向电工钢的损耗,改善并提高了爱泼斯坦磁性能测试数据的应用价值。 The extended modeling of the magnetic properties of GO(grain oriented) electrical steel is presented in this paper which is based on a set of standard and scaled-down Epstein frames and a proposed two-level weighted processing of Epstein data, including the mean magnetic path length, specific magnetization loss and exciting power. The effects of excitation frequency, strip angle and ambient temperature on the results obtained from the Epstein frames are investigated. It is shown that using the p... 

通过热力学计算及实验室研究,对钙处理前后50W600无取向硅钢退火冷轧板中夹杂物的类型、数量及尺寸进行了系统分析。结果表明,50W600无取向硅钢经钙处理后(w(Ca)=0.002 6%),钙在1 600℃的钢液中主要以固态的CaO·2Al2O3、CaO·6Al2O3及溶解钙的形式存在。在钢液的凝固过程中,钢中的溶解钙和硫反应生成了CaS和CaS-MnS复合夹杂,有效抑制了MnS的弥散析出,减少了钢中微细夹杂物的数量。同时钙处理促进了钢中微细夹杂物的聚合长大,导致显微夹杂物的数量增加。 Based on thermodynamic calculation and laboratory experiment,the type,quantity and size of inclusions in annealed cold-rolled steel sheets of 50W600 non-oriented silicon steel before and after calcium treatment were systematically studied.Results showed that after calcium treatment(w(Ca) = 0.002 6%),calcium was mainly in the form of CaO·2Al2O3,CaO·6Al2O3 and dissolved calcium in steel at 1 600 ℃.Dissolved calcium could combine with sulfur to form CaS inclusions and compound CaS-MnS inclusions du... 

【摘要】 <正>编号:2012016获奖等级:特等完成单位:...

采用EBSD检测技术,分析了50W800无取向电工钢在重要生产工序间织构的演变以及织构沿带钢宽度方向上的差异性。结果表明:热轧板织构沿带钢宽度方向上的差异性主要体现在表层织构。带钢边部表层织构主要由旋转立方织构、α纤维织构以及少量的γ纤维织构组成,带钢宽度1/4处的表层织构主要存在高斯织构,带钢宽度1/2处的表层织构主要为(110)面织构以及少量的铜型织构。各处的带钢宽度1/4处和1/2处的织构类型基本一致,都以α纤维织构和旋转立方织构为主。冷轧后,各处的表层织构类型差异较小,均为γ纤维织构和α纤维织构。由板宽边部至中心处织构强度值逐渐降低。退火后,各处织构的组分基本一致,为较强的γ纤维织构和较弱的(100)面织构。各处织构强度值差异较小,变化趋势与冷轧板一致。 The texture of non-oriented electrical steel 50W800 was detected by EBSD technique.The evolution of the texture between important processes and the difference of texture along the width direction of strip were analyzed.The result shows that the difference along the width direction of strip of texture at the surface of hot rolled plate is most obvious.The texture at the surface of strip edge is primarily made of rotating cube texture,αfiber texture and weakγfiber texture.Goss texture is mainly co... 

运用电子背散射衍射(EBSD)技术,研究了50W600无取向硅钢在热轧→冷轧→退火工序间织构的演变。结果表明:由于热轧板沿板厚方向的应力场和温度场存在差异,导致热轧板不同层织构类型和强度存在差异;热轧板表层主要存在铜型、黄铜和高斯织构,1/4层织构主要为α纤维织构和较弱的高斯织构,中心层织构较单一,主要为α纤维织构;和热轧板相比,冷轧板各层织构差异较小,为典型的轧制织构(α纤维织构和γ纤维织构);退火板各层都表现为γ纤维织构增强、α纤维织构减弱,旋转立方织构基本消失。 The texture evolution of 50W600non-oriented silicon steel in hot rolling,cold rolling and annealing process was investigated by electron back-scatter diffraction(EBSD)technology.Results show that the hot rolled plate texture types and intensities along thickness direction were different because of the different stress fields and temperature fields.The major texture types in the surface of hot rolled plate were copper,brass and Gauss texture.The texture was composed ofαfibre texture and weaker Ga... 

研究了硼酸对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响。用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同硼酸含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响,同时采用SEM对涂层的表面形貌进行了研究。结果表明,硼酸含量为9.7%时,涂层的耐盐雾性及电化学性能最好;硼酸含量过少或过多时,涂层的耐蚀性和电化学性能都较差。 Influence of boric acid on the performance of chromium-free non-oriented silicon steel insulating coating based on aluminum dihydrogen phosphate was investigated.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of boric acid content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.Surface morphologies of the coatings were tested by SEM.Result shows that when the boric ...