钢厂
铝和铬在无取向电工钢晶粒长大过程中对晶界的作用
研究了铝和铬元素在无取向电工钢晶粒长大过程中对织构及晶界变化的影响规律。试验结果表明:电工钢在晶粒长大过程中的主要织构组分均为{111}<112>。在晶粒生长期间,不加铝的1号试样中,{111}<112>、{111}<110>织构组分强化,而{100}<001>织构组分弱化;与1号试样相比,在加入0.2%的铝(质量分数,下同)的2号试样中,{111}<112>、{111}<110>织构组分强化(增加)的速率下降,{100}<001>织构组分变化不明显,甚至稍有增加。在含铝的试样中再加入0.3 5%的铬之后(3号试样),{111}<112>{、111}<110>和{100}<001>织构组分的变化规律与1号试样相似,但当电工钢中加入0.72%的铬之后(4号试样),上述3种织构组分的变化规律与2号试样相似。对于在晶粒生长期间持续变化的3种织构组分而言,1号试样的{1 1 1}<112>和{111}<110>织构组分的高(低)取向差角度晶界频率下降(... The effect rule of Aluminm and Chromium on texture and grain boundary transformation in the nonoriented electrical steel during grain growth was investigated.The experimental result shows that the main texture component is {111}<112> in the electrical steel.The {111}<112> and {111}<110> components in specimen 1 without Alumium were strengthened during grain growth whereas {100}<001> component was weakened.But the growth rate of {111}<112> and {111}<110> compon...
稀土Ce对含Sn高磁感无取向电工钢磁性能及夹杂物的影响
研究稀土Ce的添加对含Sn高磁感无取向电工钢磁性能及夹杂物的影响。对比分析了两种成分钢的磁性能以及各过程工艺条件下夹杂物种类和分布情况。结果表明,在含Sn高磁感无取向电工钢中加入稀土元素Ce可以粗化夹杂物,提高成品晶粒的均匀性,有效降低铁损;同时Ce的添加不影响Sn元素提高磁感的效果,磁感保持不变。 Effect of Ce on magnetic properties and inclusion of Sn-bearing high permeability non-oriented electrical steel was investigated. A comparative analysis of the magnetic properties and the types and distributions of inclusion in the two sheets with different composition shows that the addition of Ce to the Sn-bearing high permeability non-oriented electrical steel can coarse the inclusion,improve the homogeneity of the finished grain and effectively decrease the core loss. Also,the addition of Ce...
Si在纯Fe及低硅钢中扩散行为
采用磁控溅射方法,分别在纯Fe以及低硅钢基片上沉积富Si膜,并对其进行真空扩散热处理.通过能谱分析及X射线衍射研究了Si在纯Fe与低硅钢基体中的扩散特征,运用DICTRA软件建立了扩散模型.研究发现Si在纯Fe基体中扩散时发生γ-Fe(Si)→α-Fe(Si)相转变,扩散速率受控于相界面的迁移.当沿截面Si含量梯度不足以驱动相界面正向迁移时,延长扩散时间会发生相界面回迁现象,最终趋于单一相内均匀化扩散过程.Si在低硅钢基体中的扩散符合Fick扩散第二定律. Si-rich films were deposited on pure iron and low-Si steel substrates by direct current magnetron sputtering,and then were subjected to vacuum annealing.The distribution characteristics of Si across Fe and low-Si steel substrates were studied by energy spectrum analysis(EDS) and X-ray diffraction(XRD).DICTRA software was used to simulate the diffusion models.It is found that the diffusion behavior of Si in the Fe substrate is from γ-Fe(Si) phase to α-Fe(Si) phase and the rate of diffusion is con...
高效电机用无取向硅钢退火板组织和析出物研究
研究了组织和析出物对高效电机用无取向硅钢退火板磁性能的影响。结果表明:随着退火温度升高,退火板平均晶粒尺寸增加,P15/50明显降低,B50略有升高。退火温度在1 000℃时,退火板的综合性能较好。析出物主要是AlN、(MnS+AlN)和(MnS+Al2O3)复合析出物,尺寸较粗大,主要集中在1.0~2.5μm,还发现少量百纳米以下的细小AlN和TiN。实验室模拟TSCR流程试制的高效电机用无取向硅钢,铁损平均值小于4.00 W/kg,磁感应强度大于1.75 T,适合作中小型高效电机铁芯材料。 Effects of microstructure and precipitation on magnetic property of non-oriented silicon steel sheets after annealing for high-efficiency motor are studied in the paper by experiments.The annealed sheet exhibits a larger average grain size,obviously decreasing iron loss and slightly raising magnetic induction with increasing temperature.The annealed sheet has better comprehensive properties at a annealing temperature of 1 000 ℃.The main precipitates are compounds of AlN、(MnS+AlN)and(MnS+Al2O3) w...
抑制剂成分对取向硅钢夹杂物析出及磁性能的影响
利用FE-SEM、EDS分析了含不同抑制剂成分的成品取向硅钢中夹杂物的组成和形貌,统计其尺寸及数量分布;结合对磁性能测试的结果,分析了Sn、Cu、Nb和Cr对取向硅钢磁性能影响的机理。结果表明:含Sn的取向硅钢试样中夹杂物主要为块状的微米级Al-Ti-C-N-O复合物,还有少量的球形Al-N-O颗粒和块状Ti-C-N-O颗粒,棒状夹杂物较少;含Cr的取向硅钢试样中夹杂物主要为球形的微米级Al2O3,还有少量Cu-Al-N-O-S复合物,棒状夹杂物和不规则夹杂物均较少;含Cr试样中1~3μm夹杂物的平均尺寸较含Sn试样小,但数量多,而大于3μm夹杂物的平均尺寸较含Sn试样大,但数量很少。磁性能测试结果表明,外场为800A/m和2500A/m时,含Cr试样磁感应强度偏低,铁损值P1.7/50较含Sn试样高,为1.171W/kg。 The composition and morphology of inclusions in the finished grain-oriented silicon steels are analyzed by using FE-SEM and EDS, and the number density and size distribution of the inclusions are counted. The influence mechanism of Sn, Cu, Nb, and Cr on the magnetic properties of the steel is also discussed. Results show that the inclusions composition in the grain-oriented silicon steel samples containing Sn is mainly block Al-Ti-C-N-O, compounding with a few spherical Al-N-O and block Ti-C-N-O...
高效电机用无取向电工钢组织和析出物研究及产品开发
为开发高效电机用冷轧无取向电工钢,借助实验室薄板坯连铸连轧模拟设备及扫描电镜、透射电镜等检验手段研究了成分、组织、织构和析出物等对无取向电工钢磁性能的影响规律;结果表明:常化处理使组织均匀化并增加有利于磁性提高的织构组分;采用CSP流程开发的高效电机用无取向电工钢铁损平均值3.4 0 W/kg,磁感≥1.68 T。 In order to develop electrical steel for high efficiency motor,effect of components,microstructure,texture and precipitation on magnetic property of electrical steel are analyzed.From the result,normalizing treatment makes microstructure uniform and increases component of favorable texture.Iron loss of electrical steel developed by CSP line is 3.40W/kg and magnetic induction is more than 1.68T.
高牌号无取向电工钢热轧板常化退火组织的EBSD分析
借助于EBSD对比研究了常化退火对高牌号无取向电工钢热轧组织和织构演变的影响,分析了常化退火对热轧板各厚度层织构的演变规律。结果表明,常化退火改善了热轧组织的均匀性,并弱化了热轧变形的γ纤维织构。升高常化退火温度,可增大热轧板的晶粒尺寸,提高{100}和{110}织构组分占有率,有利于提高无取向电工钢成品板的磁性能。 Effects of normalizing annealing on microstructure and texture of high-grade non-oriented electrical steel hot-rolled sheet were investigated by EBSD. Emphasis was put on the effects of normalizing annealing on texture evolution in the sheet thickness. The results show that the hot-rolled microstructure homogeneity is improved and the γ-fiber texture is weakened by normalizing annealing treatment. The grain size of hot-rolled sheet and intensity of the {100} and {110} favorable texture can be in...
试样剪切应力对冷轧无取向电工钢磁性能的影响
电工钢试样加工产生的剪切应力会恶化钢板的磁性,对不同牌号硅钢片的横向、纵向试样退火前后磁性能的变化进行研究,结果表明:无取向硅钢片在剪切过程中横向、纵向的磁性受到剪切应力影响是不一样的。 The electrical steel sample processing magnetic of electrical steel will worsen due to the shear stress of sample. In this paper,the magnetic change of transverse,longitudinal specimens of different type of silicon steel sheet before and after annealing are studied. The results show that the magnetic of non- oriented silicon steel sheet affected in the process of shear is not the same in horizontal and vertical direction.
50W600无取向硅钢钙处理的热力学分析及实验研究
通过热力学计算及实验室研究,对钙处理前后50W600无取向硅钢退火冷轧板中夹杂物的类型、数量及尺寸进行了系统分析。结果表明,50W600无取向硅钢经钙处理后(w(Ca)=0.002 6%),钙在1 600℃的钢液中主要以固态的CaO·2Al2O3、CaO·6Al2O3及溶解钙的形式存在。在钢液的凝固过程中,钢中的溶解钙和硫反应生成了CaS和CaS-MnS复合夹杂,有效抑制了MnS的弥散析出,减少了钢中微细夹杂物的数量。同时钙处理促进了钢中微细夹杂物的聚合长大,导致显微夹杂物的数量增加。 Based on thermodynamic calculation and laboratory experiment,the type,quantity and size of inclusions in annealed cold-rolled steel sheets of 50W600 non-oriented silicon steel before and after calcium treatment were systematically studied.Results showed that after calcium treatment(w(Ca) = 0.002 6%),calcium was mainly in the form of CaO·2Al2O3,CaO·6Al2O3 and dissolved calcium in steel at 1 600 ℃.Dissolved calcium could combine with sulfur to form CaS inclusions and compound CaS-MnS inclusions du...
硅钢车间ST机组粉尘调质与除尘系统改造
针对某硅钢车间ST机组的除尘系统除尘效率较低、排放浓度不达标、二次污染较严重的问题,通过现场调研,对除尘系统、含尘气体组分与物性参数等进行测试和分析,运用管道伴热技术改善粉尘黏性后,再选取合适的除尘器对粉尘进行除尘处理,大大地提高了系统的除尘效率。 To solve the problems of low dust removal efficiency, substandard emission concentration and severe secondary pollution, some investigations are conducted to test and analyze the dust removal system,dust-gas composition and relevant physical parameters.Moreover, dust removal efficiency is greatly improved by the use of pipe heat tracing technology and by choosing appropriate dust remover.

