硅钢资料

以青海盐湖氯化镁为初级原料,采用喷雾热解法制备原料氧化镁。原料氧化镁通过水化制备氢氧化镁。将氢氧化镁过滤、洗涤、烘干、粉碎、煅烧,制备硅钢级氧化镁。本文重点考察煅烧温度、煅烧时间、料层厚度等因素对氧化镁水化率的影响,采用均匀实验设计和DPS数据处理,确定最优煅烧实验条件为:煅烧温度1250℃,煅烧保温时间4小时,料层厚度0.5cm。在此条件下得到的硅钢级氧化镁完全满足硅钢及氧化镁的行业标准。 The magnesium oxide is prepared by Spray pyrolysis process,which magnesium chloride from Qinghai Salt Lake is used as primary raw material,and hydrated to magnesium hydroxide,then obtained silicon steel magnesia through filtering,washing,drying,crushing and calcinations.In this paper,influences of some factors on magnesia hydration rate are studied,such as calcination temperature,calcination time and material thickness.After average experimental design and DPS data processing,optimal calcination... 

本文介绍了无取向硅钢C6涂液的性能,研究了配水量、固化程度和涂层厚度等因素对无取向硅钢C6涂层性能的影响。结果表明,随着配水量的增加,完全固化所需的时间增加,涂液固体含量降低,涂层厚度减小;随着固化程度的提高,涂层硬度先增大然后趋于恒定,而柔韧性逐渐变差,在过固化后急剧恶化;涂层厚度对涂层的表面外观、附着性和绝缘层间电阻均有显著影响。 Based on the introduction about the performance of C6 varnish for non-oriented silicon steel sheets,effects of water amount,curing degree and coating thickness are discussed. Results show that with the increase of water amount,the time required to cure completely extends,and both the solid content of C6 varnish and the coating thickness decrease. As the curing degree increases,the hardness of the coating increases first and then tends to be constant,however the flexibility degenerates,especially... 

研究了退火温度对3.1%Si无取向硅钢组织和磁性能的影响规律。结果表明:退火温度从940℃提高至1 000℃,平均晶粒尺寸由98μm增加到145μm,铁损P_1.5/50从2.576 W/kg降低至2.408W/kg。随着退火温度的升高,γ不利织构组分强度逐渐降低,{111}〈112〉织构组分强度降低约16%,磁感B₅₀逐渐升高,磁性能水平提高。 The effects of annealing temperature on microstructure and texture and magnetic properties of 3.1%Si non-oriented silicon steel were investigated in this paper.The results showed that,when the annealing temperature increased from 940℃ to 1 000℃,the average grain size of metallographic structure increased from 98μm to 145μm,the iron loss value P_1.5/50 decreased from2.576 W/kg to 2.408 W/kg.And as the annealing temperature increased,the strength of the unfavorable texture componentγgrad... 

对w(Si)=3%无取向硅钢进行表面机械研磨处理(SMAT)和异步轧制(CSR),获得表面纳米结构,再进行550～650℃、4 h固体粉末渗硅处理,用透射电镜(TEM)、扫描电镜(SEM)和X射线衍射仪(XRD)研究表层组织演变。结果表明:经过SMAT后,w(Si)=3%无取向硅钢表面形成了等轴状、取向呈随机分布的、晶粒尺寸为10 nm的纳米晶组织;异步轧制后,表面纳米晶组织保持不变;550～650℃、4 h渗硅处理后,SMAT+CSR样品表面形成化合物层,其厚度随着温度的升高由17μm增加到52μm;化合物层由Fe3Si和FeSi相组成. Nanostructured surface layer was fabricated on a 3%(mass fraction) non-grain oriented silicon steel by means of surface mechanical attrition treatment(SMAT) and cross-shear rolling(CSR),and then a solid powder siliconizing treatment was carried out for the SMAT+CSR sample at 550~650 ℃ for 4 h.The microstructural evolution was examined by using transmission electron microscopy(TEM),scanning electron microscopy(SEM) and X-ray diffraction(XRD).Experimental results show that: equiaxed nanocrystallin... 

试验研究了退火温度(850~950℃)和时间(5~18 min)对2.3 mm热轧硅钢板(/%:0.036C,3.15Si,0.21Mn,0.005P,0.007S,0.032A1)6道次轧制的0.35 mm冷轧板组织和织构的影响。结果表明,退火温度越高,晶粒平均尺寸越大,900℃5 min退火时平均晶粒尺寸41.39μm,试样织构主要集中在γ取向线上的{111}<112>织构组分和{111}<110>织构组分;900℃18 min退火时平均晶粒尺寸为48.08μm,试样的{111}面织构和{112}面织构密度都明显减弱,{001}面织构增强,磁性能较优。 The effect of annealing temperature(850 ~950 ℃) and holding time(5 ~ 18 min) on structure and texture of 0.35 mm sheet by 6 passes cold-rolling from 2.3 mm hot-rolled plate of silicon steel(/%:0.036 C,3.15 Si,0.21 Mn,0.005 P,0.007 S,0.032A1) has been tested and studied.Results show that the higher the annealing temperature the coarser the average grain size;As annealing at 900 ℃ for 5 min the average grain size of steel sheet is 41.39 μm,and the texture in sample is mainly concentrated in y orie... 

分别采用传统冷轧轧制液和纳米TiO₂的冷轧轧制液,对无取向硅钢板进行了四辊冷轧实验.重点研究两种冷轧轧制液的轧制润滑性能和对轧后硅钢薄带表面质量和耐蚀性能的影响.通过场发射电子显微镜和能谱仪对使用两种轧制液轧后得到的硅钢薄带表面形貌和成分进行了分析.给出了轧制液中TiO₂纳米粒子在轧制过程中的抗磨减摩机理.在轧制载荷较高时,纳米TiO₂轧制液具有优良的轧制润滑性能并能显著改善轧后硅钢薄带的表面质量.同时在高载荷作用下,TiO₂纳米粒子被压入硅钢薄带基体,形成一个滑动系来支撑载荷,从而使润滑膜的耐磨性提高. Non-oriented silicon steel strips were rolled on a four-high cold rolling mill lubricated by a traditional cold rolling liquid and a nano-TiO₂ cold rolling liquid,with emphasis on studying the rolling lubrication performance of both the liquids and their effect on the surface quality and corrosion resisting property of the silicon steel strips.The surface micrograph and composition of the silicon steel strips after being rolled with both the liquids were characterized by field emissio... 

对取向硅钢在不同气氛下的高温退火工艺进行实验室模拟，利用X射线衍射仪（XRD）分析了硅钢退火至900℃和1170℃时的样品表面氧化层和底层的物相组成，采用场发射扫描电镜（SEM）观察了样品表面氧化层和底层在截面方向上的微观形貌特征，并计算了高温退火一次升温阶段氧化反应的吉布斯自由能以及900℃时退火气氛的氧分压。结果表明：当退火气氛的露点温度保持一定时，较高的氢气含量有利于生成完整连续的底层；当退火气氛的水氢分压比保持一定时，在露点温度与氢气含量两者较低的条件下，底层附着性不佳易脱落，较高条件下，底层中夹杂着较多的铁单质；当氧化层中无FeO时，底层完整连续但易脱落，当FeO层较薄时，底层下方存在部分未反应的SiO₂,当FeO层较厚时，底层不完整连续且有分层。 The high temperature annealing process of grain-oriented silicon steel in different atmospheres was simulated in the laboratory. X-ray diffractometer（XRD） was used to analyze the phase compositions of the surface oxide layer and forsterite film of the silicon steel annealed to 900 ℃ and 1170 ℃. Field-emission scanning electron microscopy（SEM） was used to observe the micro morphology characteristics of the surface oxide layer and forsterite film of the samples in the cross section direction. The ... 

为研究退火工艺对普通取向硅钢初次再结晶组织的影响,对经不同温度、保温时间和升温速率退火后的材料组织进行了分析。结果表明:在等温退火条件下,加热至600℃时开始发生初次再结晶,800℃以上初次再结晶组织发展完善;而在最终冷轧板直接进行最终高温退火的情况下,加热温度在500～700℃时,将升温速率提高到80℃/h,初次再结晶组织更易于发展完善。 To investigate the influence of annealing process on the recrystallization of common grain oriented silicon steel,microstructures of sheets annealed at different temperature,soaking time and heating rate are observed.Results show that under the condition of isothermal annealing,recrystallization begins at 600℃ and fully develops above 800℃,while in the case that the final cold rolled sheets are directly thrown to final high temperature annealing,recrystallization is likely to develop with the he... 

针对宝钢硅钢常化退火过程中产生的退火炉辊印缺陷问题,通过实际生产的大数据与产品质量问题相结合,将数据挖掘、数据分析方法应用到实际,一定程度上解决了现场实际生产中的痛点,为现场生产提供决策支撑,避免了以前通过人工识别判定存在疏漏和无法定量判断的问题,形成了一套具有鲁棒性和可操作性的钢铁生产过程数据分析方法。通过智慧决策系统平台获取实际生产和表检仪数据,基于Pearson相关系数算法进行变量挑选和特征工程,并应用随机森林算法对数据建立分类预测模型,实现了质量问题的溯源和监控,通过数据量化预测了炉辊印缺陷是否可通过轧制消除的质量问题,识别准确率达到96.43%。 In views of the normalizing annealing furnace roll marks problem occurred in the process of normalizing annealing of silicon steel in Baosteel,by combining big data from actual production with product quality problems,data mining and data analysis methods were applied to actual production to solve the pain points and provide decision support,a robust and practical data analysis method for the steel production process has been developed,which avoided the previous problems of omission and non-quan... 

基于简化的取向硅钢片模型,系统地对不同的交流激励下的硅钢叠片内铁损、交链磁通和空气中指定位置的法向漏磁的分布进行了\"单片级\"的测量,并建立了相应的硅钢叠片级问题的三维有限元分析模型,进行了大规模的数值计算分析。模型实验和数值分析的结果表明垂直进入硅钢片的漏磁通和损耗呈现浅透入的特点,在硅钢片内引起的涡流损耗在总铁损中占据了\"举足轻重\"的份额。用电磁场有限元分析软件MagNet瞬态场时步法计算结果与测量结果相吻合,说明本文方法研究复杂的硅钢叠片问题的有效性。 The measurement and 3D finite element analysis of the iron loss,interlinkage flux inside the laminated silicon steel sheets and the magnetic flux densities at the specified positions are carried out based on a verifying silicon steel sheet model.The modeling results show that the leakage flux vertically through the silicon steel sheets has the peculiarity of shin effect,and the eddy current loss caused by the AC leakage flux is a significant component of the total iron loss.The calculated result... 

以试验室模拟CSP工艺生产的Fe-3Si热轧钢带为研究对象,采用正交试验及方差分析的方法,研究了取向硅钢初次再结晶退火工艺对高温退火后获得锋锐的高斯织构的影响。结果表明:取向硅钢两段式初次再结晶脱碳退火工艺参数加热段保温时间及加热温度是高温退火后获得锋锐高斯织构的主要影响因素,其可信度分别在90%和85%以上;在本试验条件下,通过正交试验获得的最佳退火工艺为:冷硬板经600℃保温3 min和850℃保温6 min。 Fe-3Si hot rolled strip was produced by simulating CSP technology in the laboratory.Orthogonal experiment and analysis of variance were carried out to investigate the influence of primary recrystallization on the sharp Goss texture of the oriented silicon steel.The results show that holding time of the heating section and the heating temperature for a sharp Goss texture of the samples annealed has important implications in this experiment conditions,the two-step decarburization annealing process... 

以构建高磁感、低铁损、免轧制高硅电工钢铁芯为出发点,提出采用单辊甩带制备非晶铁硅合金薄带、微氧化法在铁硅合金粉末表面包覆高电阻率铁硅氧化物薄膜制备核壳异质结构高硅电工钢纳米粉末、放电等离子烧结快速成形制备颗粒间绝缘的高硅电工钢铁芯。研究了不同氧化包覆时间对SPS烧结试样密度、物相组成、微观结构和静磁性能的影响。研究表明,在氧化包覆5h烧结温度800℃工艺条件下,制备的6.5%Si高硅电工钢铁芯的静磁性能最佳,饱和磁化强度为128.84A.m2/kg、矫顽力为2.25kA/m、剩磁为3.47A.m2/kg。其饱和磁化强度与粉末压延法制备的高硅钢相当,但矫顽力降低了1/3。 The paper takes preparation 6.5%Si steel with high induction,low core loss and removing rolling as the starting point,amorphous Fe-Si ribbons was synthesized by melt spinning method,6.5%Si steel nanopowders with high resietivity core shell structure was prepared by the slight oxidation process and 6.5% Si steel iron core with evaluating internal was sintered by spark plasma sintering process(SPS).The essay focuses studies the effects of different oxidation cladding time on sample density,phase c...