钢厂
剪切方式对冷轧无取向硅钢边部磁畴的影响
为提高无取向硅钢导磁性能,研究了不同剪切方式对无取向硅钢剪切处磁畴结构的影响。利用纳米磁流体观测无取向硅钢剪切后边部磁畴结构。结果表明,硅钢无论在机械剪切还是线切割后的边部磁畴都会发生不同程度的改变:线切割对边部磁畴结构改变较小,边部磁畴分布均匀且连续,在距边缘0~20μm范围内出现磁畴宽度变小现象;机械剪切对磁畴的改变较为严重,剪切处磁畴零乱且不连续,在距边缘20μm处仍难以观察到完整的磁畴结构。 The effects of different shearing modes on magnetic domain structure of cold rolled non-oriented silicon steel are studied in this paper.The magnetic domain of cold rolled non-oriented silicon steel is observed by nanometer magnetic fluid pattern method.The results show that the edge magnetic domain structure will be changed by mechanical shear and wire-electrode cutting,the variation of edge magnetic domain structure wire-electrode cutting edge is very small,the magnetic domain structure is wel...
碳化法制备硅钢氧化镁过程中杂质脱除研究
以轻烧氧化镁粉为原料,经消化、碳化制得重镁水,在热解反应前采用络合剂对重镁水中的杂质钙、铁进行络合掩蔽,再经热解得到碱式碳酸镁,碱式碳酸镁经煅烧可制得钙、铁杂质含量较低的氧化镁。在重镁水络合除杂过程中,考察了络合剂三乙醇胺、柠檬酸、草酸单独和复合使用的除铁、除钙效果。以三乙醇胺为络合剂时,在200 mL重镁水中加10 mL三乙醇胺(1∶1),氧化镁产品中w(氧化镁)=99.3%、w(氧化钙)=0.31%、w(氧化铁)=0.042%;使用草酸和柠檬酸作为复合络合剂时,在200 mL重镁水中加入1.0 g柠檬酸和2.0 g草酸,氧化镁产品中w(氧化镁)=98.2%、w(氧化钙)=0.24%、w(氧化铁)=0.030%。 Light-burned magnesia as a raw material was hydrated and carbonated to obtain magnesium bicarbonate liquor.Before the pyrolyzing of magnesium bicarbonate liquor,complexants were used to cover Fe and Ca impurities.Then the treated liquid was pyrolyzed to obtain basic magnesium carbonate which was calcined to magnesium oxide with low calcium and iron content.During the complexing purification of magnesium bicarbonate liquor,the Fe and Ca removing effects of single or compound complexing agents,suc...
二次冷轧法对薄带连铸无取向高硅钢组织和磁性能的影响
采用双辊薄带连铸技术试制了3.98%Si-0.71%Al无取向硅钢铸带,研究了二次冷轧法对硅钢组织和磁性能的影响。结果表明:硅钢铸带显微组织为等轴晶组织,铸带再结晶较完全,常化对铸带显微组织影响较小。二次冷轧工艺和一次冷轧工艺下,最终退火后成品显微组织为等轴晶组织,二次冷轧法最终退火后的晶粒尺寸小于一次冷轧法。二次冷轧法能够提高成品磁性能. Effect of double cold rolling on magnetic properties and microstructure of 3.98%Si-0.71%Al non-oriented silicon Steel Sheets cast by twin-roll thin strip casting process were investigated.The results show that the structure of the thin strip is equiaxed crystal,the recrystallization is complete and normalizing has lesser effect on microstructure.Using both cold rolled and double cold rolled process,the microstructure is equiaxed grain after final annealing.The average grain size of annealed shee...
Sn含量对高磁感取向硅钢热轧板织构的影响
实验室模拟薄板坯连铸连轧(TSCR)流程制造高磁感取向硅钢,借助电子背散射衍射(EBSD)技术对不同Sn含量的热轧板织构进行了研究。研究结果表明:不同Sn含量热轧板表层及次表层均为高斯织构、铜型织构及黄铜织构的混合织构,中心层为{100}面织构;Sn含量为0.1%时,热轧板表层及次表层高斯织构组分最多,取向密度最大,成品磁感最高,达到1.875 T。 Texture of grain oriented silicon steel hot rolled by thin slab casting and rolling process(TSCR) in laboratory with different Sn contents was analyzed by electron back-scattered diffraction(EBSD).The results show that the hot rolled slabs with different Sn contents have the same texture,i.e.,Goss,Copper and Brass.Specifically,the texture of core layer is {100};While the hot rolled slab with 0.10% Sn,the surface layer and subsurface layer have a sharpness Goss texture and the finished products h...
冷轧硅钢废水处理现状、问题及对策浅析
就冷轧硅钢废水处理生产中面临的主要问题进行分析,从技术角度及运行管理角度提出工艺优化升级改进措施及应对策略;同时从后续深度处理,逐步实现零排放目标的角度进行探讨,为冷轧硅钢废水减量化、出路乃至废水零排放提供一些思路。 The main problems in the wastewater treatment process of cold-rolled silicon steel lines are analyzed and process upgrading measures and optimization strategy are put forward from both technical and management views.At the same time,downstream deep treatment to gradually achieve the target of zero discharge is discussed,to provide some ideas for reduction or even zero discharge of wastewater from cold-rolled silicon steel lines.
热轧加热时间对稀土取向硅钢抑制剂固溶行为的影响
借助OM、激光共聚焦显微镜、质谱仪和电解萃取等设备和方法,研究了添加微量稀土La(质量分数0.001 1%)的取向硅钢在轧制前采用不同加热保温时间对抑制剂固溶行为的影响。结果表明:当稀土取向硅钢在1 250℃分别保温10、20、30 min后,试验钢晶粒尺寸随保温时间延长有先快后慢的长大趋势;三种抑制剂元素Mn、Cu和Al均发生固溶,保温时间对Mn和Cu两种元素的固溶影响明显,固溶量分别由69.8%和43.7%增加至84.2%和85.2%;随着保温时间的延长,稀土取向硅钢中抑制剂的小尺寸未溶物逐渐减少直至消失,较大尺寸未溶物(300~600 nm)逐渐转变为小尺寸未溶物逐步溶入基体中,数量减少且未溶物的类型由复杂逐渐转变为单一。 In this paper the solid solution behavior of the inhibitor under various holding time in 0.001 1 %La oriented silicon steel during reheating had been investigated by using OM, LM, methods of electrolytic extraction and mass spectrometer. The results showed that grain size of the test steel increased significantly with the holding time prolonging when the rare earth oriented silicon steel was heated to1 250 ℃ and held for 10, 20 min and 30 min respectively, and the growth trend slowed down after ...
硅钢RH处理过程碳和硫行为分析
分析了太原钢铁(集团)有限公司第二炼钢厂80 t RH生产冷轧硅钢脱碳、脱硫原理及影响因素,认为通过合理控制RH到站钢水碳和氧含量、加大插入管内径、采用快速抽真空度等可提高脱碳效果。降低顶渣中FeO和MnO含量,保证脱硫剂加入后的循环时间可以提高RH脱硫率。 The present article analyzes the principle of decarburization and desulfurization in refining the cold rolled silicon steel in the 80 t RH in No.2 Steelmaking Plant of Taiyuan Iron & Steel(Group) Corp.,and its influencing factors.It’s determined that the decarburization effect can be achieved by properly controlling the cabon and oxygen contents in the hot metal coming into the RH station,enlarging the inner diameter of snorkel and adopting the fast evacuation method.In the meanwhile the des...
高硅FeSi合金层对普通取向硅钢磁性能的影响
目的提高硅钢的磁性能。方法采用多弧离子镀技术,在普通取向硅钢薄板两面沉积高硅FeSi合金层制得高硅梯度硅钢,并进行热处理,观察其显微组织,测量磁性能。结果退火态高硅梯度硅钢表面的高硅FeSi合金层与基底结合紧密,均匀致密。高硅梯度硅钢中硅含量呈梯度分布,最表层硅质量分数为11.0%,随着深度增加,硅含量逐渐降低,在距表面20μm处硅质量分数仍能达到6.5%。沉积态高硅梯度硅钢的电阻率ρ、低频铁损P10/50、高频铁损P10/1k及磁感应强度B8分别为68.6μΩ·cm,0.82W/kg,83.3 W/kg和1.73 T,退火后分别为63.1μΩ·cm,0.44 W/kg,54.38 W/kg和1.89 T。结论由于表层高硅FeSi合金层的存在,梯度高硅钢的低频磁学性能良好,但高频损耗需进一步改善。 Objective To improve the magnetic properties of silicon steel. Methods FeSi alloy coatings with high-silicon content were deposited on the surface of common grain-oriented silicon steel by cathodic arc plasma evaporation,and then a kind of high silicon gradient steel was prepared. The morphologies,content and magnetic properties of the samples were tested. Results FeSi alloy coatings were featured with compact microstructures and excellent adhesive quality with the substrates. The silicon conten...
热轧组织对无取向硅钢织构的影响
采用X射线衍射仪分析无取向硅钢冷轧织构和再结晶退火织构的演化,研究了热轧组织对无取向硅钢织构以及磁性能的影响。结果表明,具有均匀、粗大晶粒组织的热轧板,冷轧形成更多的剪切带,导致成品板形成高的高斯织构组分,并提高了{100}织构强度,降低了γ纤维织构,最终导致成品磁感应强度升高,铁损下降。 The texture evolution of non-oriented silicon steel during cold-rolling and recrystallization annealing was investigated by X-ray diffractometer.The effects of hot band microstructure on the texture and magnetic properties of non-oriented silicon steel were analyzed.The results show that more shear bands appear during cold rolling due to homogeneous coarse grain in hot band.So strong{110}<001> texture after recrystallization annealing forms.At the same time,the {100} texture components inc...
取向电工钢加工过程中第二相粒子的析出行为
利用场发射扫描电镜观察了以MnS为主要抑制剂的普通取向电工钢加工过程中第二相粒子的分布状态,统计了粒子面密度、平均尺寸以及相应的尺寸分布.结果显示,热轧加工造成了大量第二相粒子弥散、细小地析出,同时基体仍保持过饱和状态.冷轧变形会造成第二相粒子的回溶行为,而基体的过饱和状态会减弱回溶现象.中间退火与脱碳退火过程中会同时存在新粒子的形核及已析出粒子的粗化两个过程,而在最终二次再结晶升温阶段则以第二相粒子明显粗化为主. The distribution of second phase particles in conventional grain-oriented electrical steels during manufacturing processes with MnS as inhibitors was observed by field emission scanning electron microscopy,while the areal particle density,the average particle size and the corresponding size distribution were statistically determined.It is indicated that hot rolling leads to dispersive precipitation of a large amount of fine second phase particles and the matrix keeps a supersaturated state furth...

