硅钢资料

{100}织构因具有两个易磁化方向能够明显的提高磁性能,因此如何在表面获得具有{100}织构一直是无取向电工钢研究焦点。本文主要介绍了获得{100}织构的主要工艺方法及其基本原理,并结合实际生产过程对各工艺方法的优缺点进行了分析;一方面,优化无取向电工钢的成分,降低碳、锰元素含量以避免脱碳退火和真空退火,简化生产工艺;另一方面,调节升温速度、降温速度和退火气氛,使{100}晶面的表面能或弹性应变能最低,制备具有{100}织构柱状晶组织的无取向电工钢是今后的发展方向。 Because { 100} texture has two easy magnetization directions,which can significantly improve magnetization properfies,how to develop { 100} texture is a focus for researchers and manufactures. In the paper,main manufacturing processes and basic principle are introdued,and their advantages and disadvantages in practical production are analyzed. On the one hand,the production process can be simplified by optimizing chemical compositions,such as reducing the content of C and Mn,which can avoid deca... 

采用RH精炼添加钙合金方式对硅钢进行钙处理。结果表明,钙合金添加量为0.67、1.00、1.67kg/t钢时,钢中钙含量分别为0、2×10-6、4×10-6;随着钙合金添加量增大,钢中夹杂物粒度逐渐由0～2μm向2～4、4～6μm偏移;不同钙处理条件下,钢中均存在粒径小于1μm和粒径为1～5μm的MnS、CuxS夹杂物,后者或单独存在,或同AlN、CaS夹杂复合;粒径为5～10μm区间,钢中的夹杂物基本以钙的氧、硫化物为主。与钙处理前相比,钙合金添加量为0.67、1.00、1.67kg/t钢时,粒径小于1.0μm的微细夹杂物减少幅度分别为68.06%、87.50%、94.94%。钙合金添加量为1.67kg/t钢时,可以去除钢中绝大部分的微细夹杂物。 Ca alloy was added into the liquid steel during RH refining,and the results show that Ca concentration in final Si steel sheets is insignificant,about 0,2×10-6 and 4×10-6 when the added amount of Ca is 0.67,1.00 and 1.67 kg/t steel,respectively.With the increase in the added Ca alloy amount,the inclusions in the steel gradually change from those of 0～2 μm to those of 2～4 and 4～6 μm.Under different Ca treatments,there exist MnS and CuxS inclusions whose size is below 1 μm as well as MnS and CuxS ... 

研究了锰含量对w(Si)=1.8%Si无取向电工钢组织和性能的影响。结果表明,钢中锰含量从0.3%增加到1.2%时,由于α_γ相变的产生,铸坯低倍组织、热轧板金相组织及成品织构等均发生了不同程度的变化,对成品表面质量及磁性能产生了明显的影响。 The effects of manganese content on structure and properties of w(Si)=1.8% non-oriented electrical steels have been studied.Results show that with increasing manganese content to 1.2% from 0.3%,macrostructure of continuous casting slab,hot rolled band metallurgical structure and finished product texture vary in some extent because of the occurrence of α-γ phase transformation,the surface quality and magnetic properties of finished product are affected greatly. 

冷轧中中低牌号的无取向硅钢多采用万能凸度轧机(Universal crown mill,UCM)生产,其板形好坏受制于UCM轧机板形调节手段的协调使用。为掌握UCM轧机的板形控制特点,建立基于二维变厚度有限元的辊系弹性变形和基于三维差分的轧件塑性变形的六辊轧机耦合模型,对UCM轧机的板形调控性能进行详尽的分析,包括工作辊和中间辊弯辊、中间辊窜辊的调控功效、辊间接触压力分布等。在此基础上,提出可用指导生产的板形控制策略,指出UCM轧机在横向厚差控制方面的不足。针对工业生产中UCM轧机轧制无取向硅钢横向厚差大的问题,在大量仿真计算的基础上,开发具有高次曲线函数的边部变凸度(Edge variable crown,EVC)的工作辊。采用该工作辊后,各种品种的无取向硅钢的横向厚差不大于10μm的百分比由24%提高到99%,横向厚差的均值小于6μm,远小于之前的13μm。 Medium-low grade non-oriented silicon steel is rolled often by universal crown mill(UCM) during cold rolling.Its shape quality is dependent on the coordinated control of several shape adjustment devices of UCM.In order to understand the shape control characteristics of UCM,coupling model of six-high rolling mill,based on two-dimensional varying thickness finite element rolls elastic deformation model and three-dimensional finite difference strip plastic deformation model,is setup for the detaile... 

含铜抑制剂作为取向硅钢的主抑制剂或辅助抑制剂不仅可以抑制初次晶粒的长大,促进二次再结晶,还可以降低铸坯的加热温度。取向硅钢中主要抑制剂为10～50 nm Cu₂S,在钢的铸坯、热轧、冷轧、脱碳等工艺过程均可析出;（Cu,Mn）_1.8S、Cu_1.8S、ε-Cu等主要作为辅助抑制剂,尺寸一般为30～50 nm（或大于50 nm）,主要在热轧阶段析出。总结了国内外有关取向硅钢中含铜抑制剂析出行为的研究进展,当前主要研究不同生产流程和工序中含铜抑制剂的析出行为和作用机理。 As main inhibitor or auxiliary inhibitor for grain-oriented silicon steel,the particles of inhibitor bearing copper not only inhibit the primary crystal growing and promote the secondary recrystallization,but also decrease the heat temperature of casting slab.The main inhibitor for grain-oriented silicon steel is 10～50 nm Cu₂S,which precipitate in process and procedure including steel casting slab,hot rolling,cold rolling and decarburizing process,while the 30～50 nm or more than 50 nm... 

轧制力是影响冷轧带钢厚度精度的关键因素。为实现高精度的冷轧带钢厚度控制,通过优化变形抗力模型参数和摩擦系数模型参数提高冷轧轧制力模型计算精度,并使用指数平滑法的自学习算法保证轧制力精度的稳定性。在首钢股份公司迁安钢铁公司20辊森基米尔轧机生产线进行S12硅钢钢种轧制力优化试验,将优化的模型参数应用于L2并投入现场生产,结果表明该优化方法不仅提高了轧制力设定精度,而且减小了冷轧硅钢的厚度超差长度,提高了成材率。 The rolling force is the key factor which influences the accuracy of cold-rolling strip thickness. To implement high precision control of cold-rolling strip thickness,we optimize the deformation resistance model parameters and friction coefficient model parameters to improve the calculation precision of cold-rolling force model,and use exponential smoothing self-learn algorithm to ensure the stability of rolling force accuracy. In Shougang Qiangang 20-high Sendzimir mill single stand production ... 

6.5%Si硅钢具有优异的磁学性能和广泛的应用前景。本文综述了6.5%Si硅钢的物理、机械及磁学特性,讨论了传统轧制、温轧、薄带连铸、快速凝固、CVD、粉末轧制等不同制备工艺的关键技术及特点,概括了6.5%Si硅钢在高效节能电机、汽车马达及磁屏蔽等领域中的主要应用,介绍了硅钢的制备技术取得的研究进展,并指出了其广阔的发展前景。 6.5% Si silicon steel has good magnetic properties and wide applications.In this paper physical and mechanical magnetic properties were summarized,and key technology and characteristic of several preparation methods,such as traditional rolling,warm rolling,thin strip continuous casting,rapid solidification,CVD and powder rolling,were discussed.Main applications of 6.5% Si steel in the fields of high-efficiency electrical motors,automobile motors,transformer cores and magnetic shielding were gene... 

【摘要】 <正>编号:2012016获奖等级:特等完成单位:...

研究了无取向硅钢钙处理前后夹杂物的行为,重点考察了钙处理前后夹杂物的成分、类型、形貌和尺寸研究的变化情况,为实际生产中无取向硅钢的钙处理提供理论指导。试验发现:钙处理前夹杂物主要以Al2O3、Al2O3-MgO为主,且在夹杂物表面有AlN析出,钙处理后夹杂物以Al2O3-MgO-CaS-CaO系复合夹杂物为主,还含有少量的SiO2或AlN;钙处理前后,夹杂物形貌由多边形或不规则形逐渐向球形或近似球形转变,并且夹杂物尺寸不断增大;钙处理前后,含钙夹杂物的比例发生突变,由10%增大到74.5%,且随着钙处理时间的延长,含钙夹杂物比例下降,表明钙处理使夹杂物变性后易聚集长大并上浮去除。 Behavior of inclusions before and after calcium treatment in non-oriented silicon steel was researched by investigating changes of compositions,types,shapes and sizes of inclusions before and after calcium treatment,for the purpose of providing theoretical guidance for calcium treatment of non-oriented silicon steel in actual situation. Results indicated that Al2O3 and Al2O3-MgO were main types of inclusions before calcium treatment,sometimes AlN maybe precipitate in the outer of inclusions. Al2... 

采用XRD、SEM和激光粒度仪等手段,观察并研究了不同特性氧化镁在硅钢表面形成硅酸镁底层形貌特点,并结合热力学和差热-失重分析了MgO-SiO2的反应机理。研究结果表明:粒度小,活性值高的特种氧化镁在高温退火过程中与基体表面氧化物生成的硅酸镁底层,界面中硅酸镁底层嵌入基体较多,表面致密,颗粒细小,有利于形成附着性能优良的硅酸镁底层。 Surface microstructure of Mg2SiO4 coatings formed on the surface of oriented silicon steel coated with different kinds of MgO was investigated by XRD and SEM.The reaction mechanism between MgO and SiO2 was analyzed by TG-DSC and thermodynamic calculation.Results revealed that when the MgO with finer microstructure size and higher activity is employed,a dense Mg2SiO4 layer with finer microstructure and good binding to the steel substrate can be obtained.The results are very helpful for the prepar... 

实验室模拟薄板坯连铸连轧(TSCR)流程制造高磁感取向硅钢,借助电子背散射衍射(EBSD)技术对不同Sn含量的热轧板织构进行了研究。研究结果表明:不同Sn含量热轧板表层及次表层均为高斯织构、铜型织构及黄铜织构的混合织构,中心层为{100}面织构;Sn含量为0.1%时,热轧板表层及次表层高斯织构组分最多,取向密度最大,成品磁感最高,达到1.875 T。 Texture of grain oriented silicon steel hot rolled by thin slab casting and rolling process(TSCR) in laboratory with different Sn contents was analyzed by electron back-scattered diffraction(EBSD).The results show that the hot rolled slabs with different Sn contents have the same texture,i.e.,Goss,Copper and Brass.Specifically,the texture of core layer is {100};While the hot rolled slab with 0.10% Sn,the surface layer and subsurface layer have a sharpness Goss texture and the finished products h... 

采用CVD法制备6.5%Si高硅钢,介绍了具体的制备工艺过程,研究了温度对渗硅速率和试样质量减轻的影响,同时分析了扩散时间对高硅钢中硅分布的影响。结果表明:在CVD反应过程中,反应温度高于1050℃将大大提高渗硅速率,但当温度大于1200℃后,渗硅速率趋于稳定;渗硅后,试样会减轻、减薄,随着温度升高,试样质量减轻的速率逐渐增大,在1200℃左右趋于稳定;扩散时间越长,硅分布越均匀,结合制备效率进行考虑,满足Δw表-中/b≤5的时间为适宜的扩散时间。 6.5%Si high silicon steel was manufactured by using CVD method and the process was introduced,the influence of temperature on the siliconizing rate and quality reducing rate,diffusion time on silicon distribution were investigated.Results as follows: the siliconizing rate will increase quickly when the temperature is higher than 1050 ℃,but the siliconizing rate will become steadily as the temperature up to 1200 ℃;The quality reducing rate will increase with the elevating of temperature and the r...