钢厂
高磁感取向硅钢涂层技术
涂层技术在高磁感取向硅钢生产中起着重要的作用.根据生产实践,介绍了高磁感取向硅钢生产中涂层的种类和作用、涂料的成分和对产品性能的影响、涂层工艺质量控制要点和检验方法等,并提出了通过优化涂层工艺改善高磁感取向硅钢性能和外观质量的方法. Surface coating technique plays an important role in producing high magnetic inductivity grain-oriented silicon steel.Based on production practice,this paper describes the types and function of the coating,the composition of the coating and its effect on the product performance,the quality control and inspection method for the coatings,as well as proposes ways to improve the magnetic property and surface quality of the steel by optimizing the coating process.
抑制剂成分对取向硅钢夹杂物析出及磁性能的影响
利用FE-SEM、EDS分析了含不同抑制剂成分的成品取向硅钢中夹杂物的组成和形貌,统计其尺寸及数量分布;结合对磁性能测试的结果,分析了Sn、Cu、Nb和Cr对取向硅钢磁性能影响的机理。结果表明:含Sn的取向硅钢试样中夹杂物主要为块状的微米级Al-Ti-C-N-O复合物,还有少量的球形Al-N-O颗粒和块状Ti-C-N-O颗粒,棒状夹杂物较少;含Cr的取向硅钢试样中夹杂物主要为球形的微米级Al2O3,还有少量Cu-Al-N-O-S复合物,棒状夹杂物和不规则夹杂物均较少;含Cr试样中1~3μm夹杂物的平均尺寸较含Sn试样小,但数量多,而大于3μm夹杂物的平均尺寸较含Sn试样大,但数量很少。磁性能测试结果表明,外场为800A/m和2500A/m时,含Cr试样磁感应强度偏低,铁损值P1.7/50较含Sn试样高,为1.171W/kg。 The composition and morphology of inclusions in the finished grain-oriented silicon steels are analyzed by using FE-SEM and EDS, and the number density and size distribution of the inclusions are counted. The influence mechanism of Sn, Cu, Nb, and Cr on the magnetic properties of the steel is also discussed. Results show that the inclusions composition in the grain-oriented silicon steel samples containing Sn is mainly block Al-Ti-C-N-O, compounding with a few spherical Al-N-O and block Ti-C-N-O...
稀土铈含量对1.2%Si无取向电工钢组织、织构及磁性能的影响
在实验室模拟CSP流程制备了不同含量稀土铈(质量分数0~0.018%)的1.2%Si无取向电工钢,并对其进行1 000℃×5min的再结晶退火处理,研究了铈质量分数对无取向电工钢夹杂物、显微组织、再结晶织构和磁性能的影响。结果表明:随着铈质量分数的增加,微细夹杂物数量、再结晶晶粒尺寸、{100}和{110}织构组分、磁感应强度先增后减,{111}织构组分、铁损先减后增;铈的质量分数为0.005 1%时,钢中的夹杂物数量最少,再结晶晶粒尺寸最大,有利织构最多,磁性能最优,铁损P15/50为3.253W·kg-1,磁感应强度B50为1.751T。 Non-oriented electrical steels containing different contents rare earth Ce element(0-0.018wt%) were prepared in the laboratory by simulated CSP(compact strip production)process,and then recrystallization annealing at 1 000 ℃ for 5 min were performed,the effects of Ce content on inclusion,microstructure, recrystallization texture and magnetic properties of non-oriented electrical steels were studied.The results show that with the increase of Ce content,the amounts of fine inclusion,the size of re...
低温取向硅钢热轧析出物与织构的研究
采用低温板坯加热制备取向硅钢,通过透射电镜(TEM)观察并研究热轧板中的析出物,用ODF织构法研究热轧板距表面1/8、1/4和1/2处的织构分布。结果表明,热轧板中的析出物主要是密排六方AlN,AlN形貌呈规则长方形,AlN颗粒大小不等,分布密度低;热轧板中的织构沿板厚方向,由亚表层的{110}<001>织构向1/2中心层的α线织构变化,其中{110}<001>织构在热轧板距表面1/4层处最强。 The low temperature grain-oriented silicon steels were produced by acquired inhibitor method.The precipitates in hot rolling strip were observed and studied by transmission electron microscope,and the texture distribution in 1/8,1/4 and 1/2 layers of hot rolling strip were analyzed by ODF method.The results showed that the square shaped h-AlN is the main precipitates in hot rolling strip.The precipitates are varying in size and distribution.The texture of hot rolling strip in thick direction are...
TSCR试制高强度无取向电工钢
采用固溶强化、细晶强化和位错强化方法,模拟TSCR流程试开发高强度无取向电工钢,试开发钢的主要合金成分为3%Si、0.83%Al和2.99%Mn。分析热轧、常化、退火后的钢板组织,并针对不同的成品板组织,详尽地分析了相应的力学性能和磁性能。试验电工钢平均晶粒直径为12.37μm时,R p0.2为530 MPa,R m为618 MPa;当退火制度为700℃×4 min,成品组织完全为未再结晶的回复组织时,R p0.2为853.5 MPa,R m为895.5 MPa。该成分的电工钢P15/50或P10/400最小时,对应的平均晶粒直径都大于59.67μm;P10/800或P10/1000最小时,对应的平均晶粒直径都处于12.37~59.67μm尺寸区间。 TSCR was simulated to develop high-strength non-oriented electrical steel with 3% of Si,0.83% of Al and 2.99% of Mn by solution strengthening,grain refinement strengthening and dislocation strengthening.The microstructures of hot rolled plates,normalized plates and annealed plates were analyzed.Furthermore,the mechanical properties and magnetic properties of products with different microstructures were detailedly studied.As the average grain diameter of the steel was 12.37 μm,the yield strength ...
无取向硅钢磷酸盐型杂化涂层性能测试
以质量分数为25%的丙烯酸乳液MC-102、15%Al(H2PO4)3溶液、0.01%H3BO3、0.01%Zn(Ac)2·2H2O和2%二乙二醇丁醚组分,在不同固化工艺下制备涂层。极化曲线和电导率测试发现300℃处理60 s得到的涂层具有良好的耐腐蚀性和绝缘性;水煮实验证明该涂层具有良好的耐水性;断口线扫描发现涂层具有良好的附着性。 A formula comprising MC-102 acrylic emulsion 25%,aluminium dihydrogen phosphate15%,boric acid 0. 01%,zinc acetate dihydrate 0. 01% and diethylene glycol monobutyl ether 2% was used to prepare coatings via different treatment process. The conductivity test and polarization curves revealed that a coating cured at 300 ℃ for 60 s showed good insulative and anticorrosive properties. The water boiling test indicated that the said coating had good water resistance. A cross section of the coating was in...
成品第二次退火工艺对高牌号无取向电工钢35W300组织和性能的影响
对高牌号无取向电工钢35W300的成品进行了第二次退火,对第二次退火后的成品性能、纵横向磁性能差异和组织变化进行了分析。结果表明,随着第二次退火温度的升高,晶粒长大,磁性能优化。铁损平均值下降0.087 5W/kg,磁感平均值升高0.008T。第二次退火温度为820℃的产品的磁性能能够满足用户使用要求。 The product of high grade non-oriented electrical steel 35W300 was annealed at the second time.Microstructure,the difference of magnetic properties in the vertical and horizontal and were studied.The results show that the grain grew up and magnetic properties optimized with the increase of annealing temperature for the second time.Iron loss average declines in 0.0875 W/kg,magnetic induction average increases 0.008 T.The magnetic properties can meet the requirements of users at the second anneali...
