硅钢资料

对两种硅钢水溶性极厚绝缘涂层进行了不同温度的热老化实验。通过TG-DTA,GDS,FT-IR,SEM和光泽度仪等测试方法对老化的涂层进行分析表征,提出了评估硅钢水溶性极厚绝缘涂层热老化性能的合理温度区间,探讨了涂层热老化行为,并分析了两种涂层热老化性能的差异。结果表明,涂层附着性随着老化时间的延长逐渐下降。FT-IR表征结果显示,热老化过程中,涂料交联形成的化学键未发生断裂,交联剂氨基树脂的三嗪环被破坏是聚合物三维网络结构坍塌的主要原因。 Thermal aging expriments at different temperature were carried out on two types of water-soluble and extra-thick insulation coatings for non-oriented silicon steel,and a series of test methods such as glossmeters,TG-DTA,FT-IR,GDS,SEM were applied in analysis.For evaluating the thermal aging effect of this kind of insulation coating,the proper temperature range was proposed.The difference of aging performance between two coatings was been investigated and the related behaviors were been discussed... 

运用电子背散射衍射(EBSD)和X射线衍射(XRD)技术对硅钢热轧板的织构在板厚方向的分布进行了研究,并分析了两种织构测量方法的特点。EBSD技术能直观给出板厚方向的微观织构,XRD能得到钢板的宏观统计织构信息,结合两种技术的分析,能更直观更精确的研究不同织构在板厚方向的分布。 The texture distribution along the thickness of the silicon steel has been investigated by electron backscatter diffraction(EBSD) and X-ray diffraction(XRD) technique.The characteristics of two technique of texture analysis have been investigated.Combined the two techniques,the texture distribution along the thickness of the silicon steel could be realized distinctly and accurately. 

在实验室试制了TSCR流程的低碳低硅无取向硅钢,研究了在850～1050℃不同温度常化对冷轧量0.5mm厚钢板再经950℃×7min退火后的组织、织构和磁性能的影响。结果表明:随常化温度的升高,使热轧板晶粒尺寸增大,晶界更清晰,组织均匀性更好;由于第二相AlN和MnS析出物尺寸比较大,使冷轧退火后钢板晶粒也随常化温度升高呈单调增大趋势;γ有利织构和{111}、{112}不利织构与常化温度升高同时增强,但前者增强更多;冷轧板退火后铁损随常化温度升高呈单调下降,磁感呈单调上升趋势。 The low-carbon and low-silicon non-oriented silicon steel was prepared by thin slab casting and rolling(TSCR) in lab.The effect of normalizing at different temperatures in 850-1 050℃on microstructure, texture and magnetic properties of 0.5 mm cold-rolled sheets after annealing at 950℃for 7 min was researched. The results show that with increasing the normalizing temperature,the grain size of hot-rolled sheets increased,the grain boundaries were more clear and the rnicrostructure uniformity was b... 

借助高温激光共聚焦显微镜,在线观察了不同Mn含量的无取向硅钢中夹杂物的尺寸、类型、数量变化。结果表明,Mn含量(质量分数)为0.77%、0.32%时,试样中的夹杂物数量分别约为1000万个/mm3、1600万个/mm3。Mn含量较高的钢种,会优先析出球形、椭球形MnS夹杂物,其析出数量较少,尺寸相对较大,可以有效抑制AlN、CuxS夹杂物析出;Mn含量较低的钢种,会在试样再加热后冷却过程中,先析出相当数量MnS夹杂物,并作为AlN夹杂物析出核心,形成MnS+AlN复合夹杂物。这种复合夹杂物数量较多,尺寸也较大。 Based on the high temperature confocal microscope, the chage of size, type, and quantity of inclusions in non-oriented silicon steels with different Mn content were observed by in-situ SEM. Results show that the inclusion quantities are 10 million per mm3 and 16 million per mm3,while the mass fractions of Mn are 0.77% and 0.32%, respectively. In the silicon steel with higher Mn content, the spherical and ellipsoidal MnS inclusion will precipitate first, which can retard the precipitation of AlN ... 

【作者】 姚昌国； ...

通过热力学计算及实验室研究,对钙处理前后50W600无取向硅钢退火冷轧板中夹杂物的类型、数量及尺寸进行了系统分析。结果表明,50W600无取向硅钢经钙处理后(w(Ca)=0.002 6%),钙在1 600℃的钢液中主要以固态的CaO·2Al2O3、CaO·6Al2O3及溶解钙的形式存在。在钢液的凝固过程中,钢中的溶解钙和硫反应生成了CaS和CaS-MnS复合夹杂,有效抑制了MnS的弥散析出,减少了钢中微细夹杂物的数量。同时钙处理促进了钢中微细夹杂物的聚合长大,导致显微夹杂物的数量增加。 Based on thermodynamic calculation and laboratory experiment,the type,quantity and size of inclusions in annealed cold-rolled steel sheets of 50W600 non-oriented silicon steel before and after calcium treatment were systematically studied.Results showed that after calcium treatment(w(Ca) = 0.002 6%),calcium was mainly in the form of CaO·2Al2O3,CaO·6Al2O3 and dissolved calcium in steel at 1 600 ℃.Dissolved calcium could combine with sulfur to form CaS inclusions and compound CaS-MnS inclusions du... 

为了确定普通冷轧取向硅钢最优的中间完全脱碳退火工艺,在其一次冷轧后进行5种不同工艺的脱碳退火处理,借助扫描电镜及电子背散射衍射技术研究了不同工艺脱碳退火后的组织、织构和脱碳效果。结果表明:经5种工艺脱碳退火处理后,初次再结晶的平均晶粒尺寸均约为19μm,且不随退火温度和时间的变化而变化;经840℃×10min工艺退火后的晶粒最均匀,高斯织构位向更准确,高斯织构面积分数最多,为3.1%,可将碳脱至0.003 5%。 In order to determine the optimal intermediate complete decarburizing annealing processes for common grain-oriented(CGO)silicon steel,five kinds of intermediate decarburizing annealing processes were conducted,the microstructure,texture and decarbonization after different decarburizing annealing processes were studied by scanning electron microscopy and electro back-scattered diffraction(EBSD)technology.The results show that the average grains sizes of primary recrystallization were about 19μm a... 

通过实验室25 kg真空感应炉冶炼和锻轧研究了0.26%～0.95%Al含量对0.5 mm 2.2%Si无取向硅钢冷轧板组织、织构和磁性能的影响。试验结果表明,0.26%～0.81%Al含量时,随钢中Al含量的增加,成品退火钢板的晶粒尺寸增加同时铁损减少;当Al含量大于0.81%时,随Al含量增加,钢板的晶粒尺寸减小,同时铁损增加。Al含量对硅钢板磁感的影响没有明显的规律。2.2%Si无取向硅钢的合适Al含量为0.48%～0.81%。 The effect of 0.26%～0.95%Al content on structure,texture and magnetic performance of 0.5 mm cold rolled sheet of 2.2%Si non-oriented silicon steel has been studied by a 25 kg vacuum induction furnace smelting,and forging -rolling in laboratory.Results show that as 0.26%～0.81%Al,with increasing Al content in steel the grain size of annealed finished sheet increases while iron loss of sheet decreases,and as Al content in steel is more than 0.81%,the grain size of sheet decreases while iron loss in... 

冷轧中中低牌号的无取向硅钢多采用万能凸度轧机(Universal crown mill,UCM)生产,其板形好坏受制于UCM轧机板形调节手段的协调使用。为掌握UCM轧机的板形控制特点,建立基于二维变厚度有限元的辊系弹性变形和基于三维差分的轧件塑性变形的六辊轧机耦合模型,对UCM轧机的板形调控性能进行详尽的分析,包括工作辊和中间辊弯辊、中间辊窜辊的调控功效、辊间接触压力分布等。在此基础上,提出可用指导生产的板形控制策略,指出UCM轧机在横向厚差控制方面的不足。针对工业生产中UCM轧机轧制无取向硅钢横向厚差大的问题,在大量仿真计算的基础上,开发具有高次曲线函数的边部变凸度(Edge variable crown,EVC)的工作辊。采用该工作辊后,各种品种的无取向硅钢的横向厚差不大于10μm的百分比由24%提高到99%,横向厚差的均值小于6μm,远小于之前的13μm。 Medium-low grade non-oriented silicon steel is rolled often by universal crown mill(UCM) during cold rolling.Its shape quality is dependent on the coordinated control of several shape adjustment devices of UCM.In order to understand the shape control characteristics of UCM,coupling model of six-high rolling mill,based on two-dimensional varying thickness finite element rolls elastic deformation model and three-dimensional finite difference strip plastic deformation model,is setup for the detaile... 

某冷连轧机生产无取向硅钢板材时,其边缘降的长度合格率频繁超标。为满足用户的叠片厚度精度要求,这类产品必须以增大切边量的方式来保证交货质量,而这种方式又直接降低了金属收得率,提高了生产成本。基于此,以该产线现有设备特性为基础,详细分析其软、硬件功能模式,分别对辊形与反馈控制进行全面分析与优化改进。通过现场试验论证,充分明确依托辊形优化与反馈控制程序的改进能显著提高边缘降的控制水平,该技术的使用为生产现场的边缘降控制提供了合理的技术支撑。 A cold rolling mill production of non-oriented silicon steel sheet,the thickness difference of the edge( edge-drop) is usually exceed the preset standard value,In order to meet the accuracy requirements of the user flatness,these production must be trimed wider length to meet the delivery quality of the user need, which directly reduce the metal yield and increase the manufacturing cost. Therefor,the software and hardware of the production line has been analyzed, and the work roll shape and feed... 

采用双辊薄带连铸技术试制了3.98%Si-0.71%Al无取向硅钢铸带,研究了二次冷轧法对硅钢组织和磁性能的影响。结果表明:硅钢铸带显微组织为等轴晶组织,铸带再结晶较完全,常化对铸带显微组织影响较小。二次冷轧工艺和一次冷轧工艺下,最终退火后成品显微组织为等轴晶组织,二次冷轧法最终退火后的晶粒尺寸小于一次冷轧法。二次冷轧法能够提高成品磁性能. Effect of double cold rolling on magnetic properties and microstructure of 3.98%Si-0.71%Al non-oriented silicon Steel Sheets cast by twin-roll thin strip casting process were investigated.The results show that the structure of the thin strip is equiaxed crystal,the recrystallization is complete and normalizing has lesser effect on microstructure.Using both cold rolled and double cold rolled process,the microstructure is equiaxed grain after final annealing.The average grain size of annealed shee... 

采用RH精炼添加钙合金方式对硅钢进行钙处理。结果表明,钙合金添加量为0.67、1.00、1.67kg/t钢时,钢中钙含量分别为0、2×10-6、4×10-6;随着钙合金添加量增大,钢中夹杂物粒度逐渐由0～2μm向2～4、4～6μm偏移;不同钙处理条件下,钢中均存在粒径小于1μm和粒径为1～5μm的MnS、CuxS夹杂物,后者或单独存在,或同AlN、CaS夹杂复合;粒径为5～10μm区间,钢中的夹杂物基本以钙的氧、硫化物为主。与钙处理前相比,钙合金添加量为0.67、1.00、1.67kg/t钢时,粒径小于1.0μm的微细夹杂物减少幅度分别为68.06%、87.50%、94.94%。钙合金添加量为1.67kg/t钢时,可以去除钢中绝大部分的微细夹杂物。 Ca alloy was added into the liquid steel during RH refining,and the results show that Ca concentration in final Si steel sheets is insignificant,about 0,2×10-6 and 4×10-6 when the added amount of Ca is 0.67,1.00 and 1.67 kg/t steel,respectively.With the increase in the added Ca alloy amount,the inclusions in the steel gradually change from those of 0～2 μm to those of 2～4 and 4～6 μm.Under different Ca treatments,there exist MnS and CuxS inclusions whose size is below 1 μm as well as MnS and CuxS ...