硅钢资料

6.5%Si电工钢是一种优异的软磁材料,织构对其磁性能影响很大。利用温轧工艺对6.5%Si电工钢热轧板进行不同压下率轧制,研究了温轧板织构随压下率的变化规律。实验结果显示,随着压下率的增大,{100}〈110〉、{110}〈100〉和γ纤维织构在薄板表层中的强度先增强后减弱,当压下率达到75%时,沿板厚方向形成3个组织区域:表层细晶粒区({110}〈100〉取向为主)、过渡层({111}〈110〉和{111}〈112〉变形晶粒区)和中心层(以拉长的γ纤维织构和{100}〈110〉取向晶粒为主),这种组织和织构不均性对后期织构的发展有重大影响。 6.5wt% Si electric steel has excellent soft magnetic properties,on which texture play important role.In this experiment,warm rolling technique was employed to investigate the effect of rolling reduction on texture.It was found that the density of {100}〈110〉,{110}〈100〉 and γ-fiber textures first increased and then decreased with increasing of the rolling reduction.At 75% reduction,the microstructure along the thickness of the sheet formed three zones,containing surface layer with {110}〈100〉 orien... 

【作者】 王爱华； ...

为进行磷酸盐系无铬无取向硅钢涂层烧结固化工艺研究,首先对磷酸盐系无铬无取向硅钢涂层进行热重-差示扫描量热(TG-DSC)分析;然后在不同烧结固化温度条件下,测定涂层板温随时间变化曲线;最终获得涂层烧结固化温度与时间(T-t)工艺曲线。通过中性盐雾试验、动电位极化、交流阻抗、涂层附着力以及扫描电子显微镜(SEM)和能谱(EDS)分析验证。结果表明,根据涂层烧结固化温度与时间(T-t)工艺曲线制备的涂层结构致密、性能优异,证明该工艺曲线具有合理性与正确性。 In order to study the curing process of chromium-free non-oriented silicon steel coatings,phosphatic chromium-free non-oriented silicon steel insulating coating was prepared and TG-DSC analysis of the coating was conducted,then the change of the actual temperature of the coated non-oriented silicon steel sheet with time at different curing temperatures was studied. Based on the experiments,the processing curves of curing temperature vs. curing time( T-t) for the chromium-free non-oriented silico... 

【作者】 宋波； 朱一知； ...

采用热模拟方法及EBSD技术,研究Fe-3 wt%Si电工钢在不同温度下组织的动、静态再结晶及晶粒取向特征,特别是少量奥氏体对铁素体动、静态再结晶组织及取向的影响。结果表明,不同温度形变的组织主要分三类:形变长条铁素体、珠光体和等轴细小铁素体。长条形变铁素体内发生动态回复或连续式的动态再结晶,奥氏体周围的铁素体动态再结晶加速,部分以传统的不连续方式动态再结晶。铁素体、奥氏体都可发生静态再结晶。奥氏体的静态再结晶在1050℃以上明显,铁素体的静态再结晶随温度的升高逐渐进行,最显著的再结晶发生在1050℃。不同温度形变的样品,其形变晶粒取向主要以<111>和<100>为主,小等轴铁素体晶粒除与大形变铁素体取向相近外,出现了<110>取向及其它取向。 Static and dynamic recrystallization and grain orientations in a hot-compressed Fe-3 wt% Si electrical steels were studied at different temperatures using Gleeble simulator and EBSD technique,particularly focusing on the effect of small amount of austenite on ferritic microstructure and orientations.The results show that microstructure of the compressed steel,depending on deformation temperature,consisted of elongated and deformed ferrite,pearlite and fine equal-axed ferrite.The elongated ferrit... 

对高牌号无取向电工钢35W300的成品进行了第二次退火,对第二次退火后的成品性能、纵横向磁性能差异和组织变化进行了分析。结果表明,随着第二次退火温度的升高,晶粒长大,磁性能优化。铁损平均值下降0.087 5W/kg,磁感平均值升高0.008T。第二次退火温度为820℃的产品的磁性能能够满足用户使用要求。 The product of high grade non-oriented electrical steel 35W300 was annealed at the second time.Microstructure,the difference of magnetic properties in the vertical and horizontal and were studied.The results show that the grain grew up and magnetic properties optimized with the increase of annealing temperature for the second time.Iron loss average declines in 0.0875 W/kg,magnetic induction average increases 0.008 T.The magnetic properties can meet the requirements of users at the second anneali... 

组织和织构是影响无取向硅钢性能的重要因素。为改善产品性能，研究了冷轧压下率（71.7%～87.0%）对高牌号无取向硅钢组织、织构、磁性能和力学性能的影响。结果表明，随冷轧压下率的增加，退火晶粒平均尺寸先减小后增大；高斯和立方织构强度减弱，γ纤维织构增强，α纤维织构转变为较强的α^*（{h, 1, 1}〈1/h, 1, 2〉）织构，并随冷轧压下率的增加而增强，同时其峰值逐渐向{111}面移动；工频铁损P_1.5/50、高频铁损P_1.0/400和磁极化强度J₅₀₀₀同时降低，屈服强度变化不大，表面硬度逐渐增加。当冷轧压下率由84.7%增至87.0%、厚度减至0.30 mm时，高频铁损降幅是工频铁损的11倍，表面硬度增幅变大。以上研究成果对硅钢减薄后织构及组织的优化提供了很好的指导。 Microstructure and texture are critical factors on non-oriented silicon steel properties. In order to improve product properties, this paper studied the effect of cold rolling reduction rate（71.7%-87.0%） on microstructure, texture, magnetic properties and mechanical properties of high-grade non-oriented silicon steel. The results show that with the increase of cold rolling reduction rate, the average size of annealing grain decreases first and then increases. The intensity of Goss and λ fiber te... 

为了确保硅钢铬酸盐涂料的环保性,需要严格控制涂料的固化工艺,保证涂料固化过程中涂料中的六价铬充分转化为三价铬。对涂料及原料进行热重分析(TG)及差示扫描量热法分析(DSC)。结果表明,MgO与铬酐混合转化为MgCrO4,使六价铬稳定性增强,其中大部分Cr6+转变为Cr3+发生在620~700℃,在450~500℃高于铬酐发生大量失重,因此必须加入还原剂保证涂料中六价铬被充分还原;超过360℃后树脂会发生分解,因此实际板温不能超过360℃;加入了还原剂的整体涂料的失重温度区间主要在260~320℃,因此涂料固化时钢板的实际温度最佳区间为320~360℃。 Because of the silicon steel chromate coating’s environmental requirements,the paint curing process must be controlled strictly to ensure all Cr( Ⅵ) transforms to Cr( Ⅲ). The TG and DSC analyses of the paint are studied. The reaction of MgO and CrO3 would generate MgCrO4,enhancing the stability of Cr( Ⅵ). The most r( Ⅵ) in MgCrO4 changes to Cr( Ⅲ) at 620-700 ℃,while the CrO3 has a large weight loss at 450-500 ℃. The reductant must be added in the paint to make sure the Cr( Ⅵ) could transform suf... 

采用非水溶液电解方法来提取无取向硅钢中夹杂物。通过扫描电镜(SEM)观察结果表明:无取向硅钢中主要夹杂物为六棱柱的AlN、不规则硅酸盐及球状的铁的硫化物和氧化物,其中AlN夹杂尺寸在1~5μm,数量较多,还有部分AlN的复合夹杂。进一步研究了AlN复合夹杂形成机理,采用了Thermo-Calc热力学计算软件计算出该钢样中AlN、MnS析出温度分别为1 240℃、1 200℃,而Al2O3析出温度大于1 800℃,从而为AlN复合夹杂形成机理提供了一个理论依据。 Extracting inclusions from non-oriented silicon steel in non-aqueous electrolysis is a nondestructive method to gain inclusions.Scanning electron microscopy shows that the main inclusions in non-oriented silicon steel were hexagonal AlN,which was of large quantity,irregular silicate,spherical iron sulfide and oxide.The size of AlN inclusions ranged from 1to 5μm,and there were some duplex inclusions of AlN.To further study the formation mechanism of AlN duplex inclusions,Thermo-Calc thermodynamic... 

结合工业化生产的无取向硅钢,进行了RH精炼添加稀土合金实验。结果表明,1.15%(质量分数)Si钢的脱硫反应,主要发生在添加稀土合金之后的前5min。最佳的稀土合金添加量为0.6～0.9kg/t钢。钢液经过稀土处理后,加入的稀土总量越多,稀土氧硫化物夹杂物的尺寸就越大,但热轧带钢再结晶效果会逐渐变差,成品带钢晶粒尺寸先是快速长大,而后逐渐减小。最佳的钢中存留稀土含量与钢的化学成分有关,应严格控制在2.0×10-3%～6.0×10-3%(质量分数)。在此范围内,钢的铁损先是快速降低,而后缓慢升高,钢的磁感应强度则单调降低。 Based on the industrial production of non-oriented electrical steel,rare earth(RE) alloy treatment during the RH refining process was studied.The results showed that the effects of desulfurization and total concentration of RE remained in steel mainly depended on the chemical compositions of different steel grades.For 1.15wt% Si steel grade,the desulfurization reaction mainly focused on the initial 5min after RE alloy added during the RH refining process.The suitable RE alloy addition was 0.6-0.... 

利用电子背散射衍射(EBSD)技术和场发射电子扫描显微镜(FESEM)研究了电工钢中柱状晶不同初始取向50%热压缩变形后的演变规律及其对粒子析出行为的影响。结果表明:〈100〉晶粒形变后仍为〈100〉取向,只发生绕ND∥〈100〉方向的转动,具有遗传性,粒子析出数量少。柱状晶长轴与压缩轴的偏转度增加,取向的稳定性变差,超过40°,可形成〈111〉取向,期间发生复杂的滑移系交互作用,产生较高的缺陷密度,促进粒子析出。MnS粒子主要在晶内析出,变形温度高、形变量低,粒子均无法充分析出。回复时,形变晶粒内高的储能和缺陷密度是促进粒子进一步析出的必要条件。 The evolution of initial orientations and their influence on precipitation of columnar-grained electrical steel after 50% hot compression deformation were investigated by electron backscatter diffraction technique and field emission scanning electron microscopy.The results indicate that the〈100〉orientated columnar grains remain still〈100〉after hot compression deformation,with only rotation around ND parallel to〈100〉direction,with heredity,and less precipitation.As the deviation angle between the... 

冷轧取向硅钢工程中有很多的超长、大体积以及薄壁的混凝土结构,裂缝控制是土建施工的关键。在工程中,按照\"抗放兼施、先放后抗、以抗为主\"的原则,采用\"无缝分块跳仓法\",防止超长混凝土结构收缩产生裂缝;在隧道和池体的底板与墙板施工中,采用\"整体浇筑\"法,避免了墙板因约束应力而产生的裂缝。 In the Cold-rolled grain-oriented silicon steel project,there are many overlength,bulk mass,thin-walled concretes structures,how to control the crack is the key of civil engineering construction.In these projects,according to the principle of\"release with resist,resist before release,resist is dominant \",the crack of the over-long structure and shrinkage can be prevented by the method of\"seamless block skip bin \".In the construction of the bottom plate and wall of the tunnel and the pool,the cra...