硅钢资料

利用加热炉模拟、动态再结晶以及热模拟等试验方法以及扫描电镜、金相显微镜等分析观察手段对无取向硅钢边裂的成因进行了探讨。结果表明,长时间加热使得板坯边部晶粒异常长大,晶界氧化并脱碳,轧制过程中边部温度过低,动态再结晶过程变弱,使得板坯边部延伸性能变差,是导致硅钢边裂的主要原因。建议通过适当降低铸坯加热温度、缩短保温时间、提高终轧温度来改善硅钢边裂缺陷。 The behaviors of high temperature oxidation,dynamic recrystallization,and hot ductility,microstructure evolution were investigated on the non-oriented electrical steel sheets to discuss the formation of edge crack.The key causes of cracking was found to be the coarse as-cast microstructure,grain boundary oxidation and decarburization in reheating furnace,as well as reduced temperature at strip edge region during hot rolling process resulting in reduced hot ductility and lack of enough dynamic re... 

以取向电工钢成分为基础,制备了含C或Mn和S的4种实验钢。观察了接近平衡析出状态实验钢经60%冷轧后在600～1000℃范围再结晶退火过程中微观组织演变,统计分析了再结晶体积分数随退火时间的变化规律,进而计算了各实验钢静态再结晶的激活能。观察了高含C实验钢退火初期再结晶晶粒优先出现的部位。结果表明900～1000℃范围内各实验钢铁素体的化学成分相似,因而其再结晶激活能基本一致。在600～800℃范围内铁素体内会有阻碍再结晶进程的三次渗碳体析出,从而使再结晶激活能明显提高。高C含量实验钢中还会有从奥氏体转变而来的粗大珠光体或渗碳体,轧制过程中其附近形成的变形区会促进600～800℃加热时该区域附近率先发生再结晶形核、降低再结晶激活能。固溶的Mn、S元素可微弱提高再结晶激活能,但高Mn、S含量会改变粗渗碳体从奥氏体析出时的形态。 Four experimental steels based on grain oriented electrical steel containing C,or Mn and S were prepared.Microstructure evolution of the steels close to a state of equilibrium precipitation were observed during annealing processes at 600-1000 ℃after 60% cold rolling,the changes of recrystallization volume fraction were analyzed statistically as the annealing was prolonged,and the activation energy for static recrystallization of the steels were calculated.The locations,where the recrystallizatio... 

研究了硅钢铸坯再加热过程中夹杂物的析出行为。采用非水溶液电解提取+扫描电镜观察方法,观察了试样的显微组织,统计了夹杂物的尺寸、种类、数量、分布。结果表明,均热温度为1 523 K时,水淬试样的夹杂物尺寸绝大部分小于0.5μm,0.5～5.0μm的夹杂物数量很少,没有发现5.0μm以上的夹杂物。此外,均热时间为10、30、60、90、120、240 min时,对应试样中0.05～0.2μm的夹杂物数量分别为4.04×104、4.73×104、3.70×104、3.33×104、3.10×104、1.56×104个/mm3。绝大部分夹杂物以MnS、AlN、CuxS类为主,并以三类夹杂物中的两类复合或三类复合居多。三类复合夹杂物总量占每组试样夹杂物总量的90%或以上。随均热时间延长,典型的夹杂物组成会发生如下变化:MnS+AlN+CuxS MnS+AlN AlN。与此同时,MnS、AlN、CuxS三者复合比例从45.2%(均热10 min)降为9.7%(均热240 min)。 The methods of electrolysis extraction from nonaqueous solution and scanning electron microscope were adopted to study the precipitation behavior of non-metallic inclusions in Si steel slabs during reheating processes.The morphologies,chemical compositions,quantity and size distribution of non-metallic inclusions in these steel samples were analyzed.Results show that,when the soaking temperature is 1 523 K,almost all of the non-metallic inclusions are smaller than 0.5 μm,few are in the range of ... 

【作者】 李波； 杨晓江； ...

对两种硅钢水溶性极厚绝缘涂层进行了不同温度的热老化实验。通过TG-DTA,GDS,FT-IR,SEM和光泽度仪等测试方法对老化的涂层进行分析表征,提出了评估硅钢水溶性极厚绝缘涂层热老化性能的合理温度区间,探讨了涂层热老化行为,并分析了两种涂层热老化性能的差异。结果表明,涂层附着性随着老化时间的延长逐渐下降。FT-IR表征结果显示,热老化过程中,涂料交联形成的化学键未发生断裂,交联剂氨基树脂的三嗪环被破坏是聚合物三维网络结构坍塌的主要原因。 Thermal aging expriments at different temperature were carried out on two types of water-soluble and extra-thick insulation coatings for non-oriented silicon steel,and a series of test methods such as glossmeters,TG-DTA,FT-IR,GDS,SEM were applied in analysis.For evaluating the thermal aging effect of this kind of insulation coating,the proper temperature range was proposed.The difference of aging performance between two coatings was been investigated and the related behaviors were been discussed... 

以试验室模拟CSP工艺生产的Fe-3Si热轧钢带为研究对象,采用正交试验及方差分析的方法,研究了取向硅钢初次再结晶退火工艺对高温退火后获得锋锐的高斯织构的影响。结果表明:取向硅钢两段式初次再结晶脱碳退火工艺参数加热段保温时间及加热温度是高温退火后获得锋锐高斯织构的主要影响因素,其可信度分别在90%和85%以上;在本试验条件下,通过正交试验获得的最佳退火工艺为:冷硬板经600℃保温3 min和850℃保温6 min。 Fe-3Si hot rolled strip was produced by simulating CSP technology in the laboratory.Orthogonal experiment and analysis of variance were carried out to investigate the influence of primary recrystallization on the sharp Goss texture of the oriented silicon steel.The results show that holding time of the heating section and the heating temperature for a sharp Goss texture of the samples annealed has important implications in this experiment conditions,the two-step decarburization annealing process... 

针对某厂DMS森吉米尔轧机生产无取向硅钢表面麻面缺陷的问题，根据生产实际，对其形成原因从乳化液及工作辊两方面因素进行了分析。结果表明：乳化液对麻面缺陷的产生有一定影响，但不是主要因素，主要原因是由于二十辊森吉米尔轧机工作辊辊径较小，轧制相同长度带钢轧辊运转周期较大，容易产生疲劳失效而导致。为此，提出通过调整冷轧工序成品轧制道次的压下率以减小轧制力，从而减小工作辊的磨损疲劳；通过对轧制乳化液浓度、温度的合理控制，以改善润滑效果、提高轧制速度，而进一步缓解轧辊疲劳的改进措施，使该钢厂无取向硅钢麻面缺陷发生率由原来的18%降至0.8%,带钢表面质量明显改善。 For the problem of surface pockmarks of non-oriented silicon steel strip produced by a DMS Sendzimir mill, based on the production practice, the formation causes were analyzed from two aspects of emulsion and working roll. The results show that the emulsion has a certain effect on the formation of surface pockmarks defects, but it is not the main factor. The main reason is that the working roll diameter of the 20-high Sendzimir mill is small, and the running period of the roll rolling the same l... 

【作者】 康凌晨； 王丽娜； ...

采用节能、环保、经济型的生产技术与工艺来制造高磁感取向硅钢目前已成为世界各大取向硅钢生产厂的研发热点。总结了国内外各大钢铁企业与研究机构采用低温板坯加热技术生产高磁感取向硅钢的开发及应用情况,概括了传统流程实现低温板坯加热技术的方法。介绍了薄板坯连铸连轧与双辊薄带连铸等短流程工艺生产高磁感取向硅钢的研发现状。在此基础上,探讨了高磁感取向硅钢生产技术与工艺的发展趋势及方向。 Utilizing energy-efficient,environmentally friendly,economic production processes and technologies to manufacture high magnetic induction grain-oriented silicon steel has become the focus of current research work.Based on using low-temperature slab reheating techniques to produce high magnetic induction grain-oriented silicon steel at both iron and steel enterprises and research institutions all over the world,the current application and exploitation was thoroughly generalized;the implementation... 

利用OM、SEM、TEM等实验方法研究了卷取工艺对一种新型含铜无取向电工钢晶粒度和析出相的影响。结果表明,该电工钢热轧带卷取后的晶粒尺寸为18～24μm,在卷取过程中,热轧带中有一定数量的第二相析出,经EDS能谱及选区电子衍射分析,这些析出相主要为AlN。随着卷取工艺的变化,该电工钢的晶粒度大小变化不明显,析出相的类型、尺寸大小不发生改变,体积分数发生一定的改变。 The effects of coiling process on grain size and precipitates of a new copper-bearing non-oriented electrical steel were investigated by OM,TEM and other experimental method.The results show that the grain size of hot-rolled bands after coiling is 18～24 μm.The second phases precipitate during coiling process.They are mainly AlN by EDS spectra and selected area electron diffraction.With the change of coiling process,the grain size of the electrical steel does not change significantly;the type and... 

利用光学显微镜、TEM和EBSD研究了退火温度对双辊连铸无取向硅钢再结晶组织的影响。结果表明,900℃退火后组织分布不均匀,有大量带状组织,平均晶粒尺寸29.5μm。提高退火温度,晶粒尺寸增大,组织均匀化程度增加,1050℃退火时,带状组织基本消失,平均晶粒尺寸42.2μm。 Effect of annealing temperature on recrystallization microstructure of non-oriented electrical steel produced by twin-roll casting process was investigated using OM,TEM and EBSD.The results show that the recrystallization microstructure is uneven because of many banded grains existing,average grain size is 29.5 μm.With annealing temperature increasing,the recrystallization grain size increases,microstructure becomes more homogeneous.When 1050 ℃ annealing,the banded structure almost disappear and... 

分析了电感耦合等离子体发射光谱法(ICP-AES)测定硅钢中铌的检测过程,讨论了该检测过程中不确定度的主要来源,建立了该方法的定量的数学模型,并根据这一模型计算出了检测结果的合成标准不确定度和扩展不确定度。 The measurement of niobium content in silicon steel by inductively coupled plasma atomic emission spectrometry(ICP-AES) was analyzed,by which the main factors affecting the uncertainty of the measurement were ascertained and the calculation formula was given.Finally,according to the formula the combined uncertainty and expanded uncertainty were obtained.