硅钢资料

对碳-锰-硅钢进行不同配分温度的Q&P(Quenching and Partitioning)处理,测试了热处理后不同钢的力学性能和残余奥氏体含量,并用扫描电子显微镜和透射电镜观察其显微组织,分析了配分温度对显微组织和力学性能的影响。结果表明:试验钢显微组织基本由低碳板条状马氏体、块状铁素体和条状残余奥氏体组成;随配分温度的升高,试验钢的抗拉强度呈下降趋势,伸长率与奥氏体含量的变化趋势相同,但变化规律不确定;提高锰含量能稳定残余奥氏体,从而提高试验钢的伸长率,并使伸长率对配分温度不敏感。 The C-Mn-Si steel was quenched and partitioned at different partitioning temperatures,the mechanical properties and residual austenite contents were investigated,the microstructure was observed by SEM and TEM,and the effect of partitioning temperature on microstructure and mechanical properties was analyzed.The results show that the microstructure of the tested steel consisted of lath martensite with low carbon,nubby ferrite and banded residual austenite.The tensile strength of the tested steel ... 

【作者】 姚昌国； ...

在实验室试制了TSCR流程的低碳低硅无取向硅钢,研究了在850～1050℃不同温度常化对冷轧量0.5mm厚钢板再经950℃×7min退火后的组织、织构和磁性能的影响。结果表明:随常化温度的升高,使热轧板晶粒尺寸增大,晶界更清晰,组织均匀性更好;由于第二相AlN和MnS析出物尺寸比较大,使冷轧退火后钢板晶粒也随常化温度升高呈单调增大趋势;γ有利织构和{111}、{112}不利织构与常化温度升高同时增强,但前者增强更多;冷轧板退火后铁损随常化温度升高呈单调下降,磁感呈单调上升趋势。 The low-carbon and low-silicon non-oriented silicon steel was prepared by thin slab casting and rolling(TSCR) in lab.The effect of normalizing at different temperatures in 850-1 050℃on microstructure, texture and magnetic properties of 0.5 mm cold-rolled sheets after annealing at 950℃for 7 min was researched. The results show that with increasing the normalizing temperature,the grain size of hot-rolled sheets increased,the grain boundaries were more clear and the rnicrostructure uniformity was b... 

采用低温板坯加热制备取向硅钢,通过透射电镜(TEM)观察并研究热轧板中的析出物,用ODF织构法研究热轧板距表面1/8、1/4和1/2处的织构分布。结果表明,热轧板中的析出物主要是密排六方AlN,AlN形貌呈规则长方形,AlN颗粒大小不等,分布密度低;热轧板中的织构沿板厚方向,由亚表层的{110}<001>织构向1/2中心层的α线织构变化,其中{110}<001>织构在热轧板距表面1/4层处最强。 The low temperature grain-oriented silicon steels were produced by acquired inhibitor method.The precipitates in hot rolling strip were observed and studied by transmission electron microscope,and the texture distribution in 1/8,1/4 and 1/2 layers of hot rolling strip were analyzed by ODF method.The results showed that the square shaped h-AlN is the main precipitates in hot rolling strip.The precipitates are varying in size and distribution.The texture of hot rolling strip in thick direction are... 

以一种新的Fe-Si合金制备工艺为出发点,研究了不同放电等离子体快速烧结工艺(SPS)和Si含量变化对Fe-Si合金材料显微组织与磁性能的影响。结果表明,在烧结温度为1 000℃时制备的Fe-6.5%Si合金(质量分数,下同)的综合磁性能较好,其在50Hz下的铁损为0.549W/kg,最大磁感应强度为0.124 3T,矫顽力245.6 A/m,磁导率0.338mH/m。另外,材料的最大磁感应强度随Si含量的增加显著增长,1 000Hz下,Fe-10.0%Si的最大磁感应强度可达到Fe-6.5%Si合金的5倍左右。 The effects of Si content and SPS technology on microstructure and magnetic properties of Fe-Si alloy material were studied in the paper.It shows that the magnetic properties are the best when the content of Si is 6.5wt% and the sintering temperature is 1 000℃,the iron loss is 0.549W / kg in 50Hz,maximum magnetic induction is 0.124 3T,coercive force is 245.6A / m and permeability is 0.338mH / m。And,the maximum magnetic induction increases significantly with the increase of Si.The maximum magneti... 

轧制力是影响冷轧带钢厚度精度的关键因素。为实现高精度的冷轧带钢厚度控制,通过优化变形抗力模型参数和摩擦系数模型参数提高冷轧轧制力模型计算精度,并使用指数平滑法的自学习算法保证轧制力精度的稳定性。在首钢股份公司迁安钢铁公司20辊森基米尔轧机生产线进行S12硅钢钢种轧制力优化试验,将优化的模型参数应用于L2并投入现场生产,结果表明该优化方法不仅提高了轧制力设定精度,而且减小了冷轧硅钢的厚度超差长度,提高了成材率。 The rolling force is the key factor which influences the accuracy of cold-rolling strip thickness. To implement high precision control of cold-rolling strip thickness,we optimize the deformation resistance model parameters and friction coefficient model parameters to improve the calculation precision of cold-rolling force model,and use exponential smoothing self-learn algorithm to ensure the stability of rolling force accuracy. In Shougang Qiangang 20-high Sendzimir mill single stand production ... 

采用双辊连铸工艺制备了硅的质量分数分别为0.5%,1.0%,3.0%,4.5%的硅钢薄带,用光学显微镜观察其组织,并研究了后处理工艺对薄带组织和性能的影响。结果表明:硅含量为0.5%和1.0%的薄带适合采用一次冷轧+850～950℃退火的后处理工艺,而硅含量在3.0%以上的薄带适合采用二次冷轧+950℃退火的后处理工艺;硅含量为3.0%和4.5%的薄带在冷轧并950℃退火后,其磁性能最佳,铁芯损耗约为4.30 W·kg^-1,磁感应强度约为1.68T。 Silicon steel thin strips with silicon content of 0.5wt%,1.0wt%,3.0wt%and 4.5wt%were prepared by twin-roll continuous casting process,and the microstructure of the strips were observed by means of optical microscopy,and on the basis,the effect of post-treatment process on microstructure and properties of the strips was studied.The results show that the post-treatment process of one-time cold rolling and annealing between 850—950℃was suitable for the strips with silicon content of 0.5wt%and 1.0wt... 

研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c... 

为满足用户对无取向电工钢中硫含量的要求,采用CaO-CaF2复合渣系为脱硫剂,利用RH投入法对无取向电工钢进行深脱硫试验。试验结果表明,RH精炼渣成分控制在w CaO43%~51%、w Al2O325%~31%、w MgO4%~6%、w SiO29%~12%、w(FeO+MnO)3%~6%,在脱硫剂加入量为6~8 kg/t时,钢中平均硫含量从32×10-6降低到18×10-6,RH平均脱硫率为43.3%,最高达47.1%。利用KTH模型计算精炼终渣平均硫容量为0.003 1,RH精炼结束时渣-钢间实际平均硫分配比从14增加到52。 In order to satisfy the requirements of consumers on sulfur content in non-oriented electrical steel,taking( CaO-CaF 2) based flux as desulfurizer,industrial experiments on deep desulphurization of non-oriented electrical steel were carried out during RH process. The results show that as the compositions of refining slag are appropriately controlled with w CaO of 43% ~ 51%,w Al2O3 of 25% ~ 31%,w MgO of 4% ~ 6%,w SiO2 of 9% ~ 12%,and w( FeO + MnO) of 3% ~ 6%,and the desulfurizer added are at 6 ~ ... 

通过热力学计算及实验室研究,对钙处理前后50W600无取向硅钢退火冷轧板中夹杂物的类型、数量及尺寸进行了系统分析。结果表明,50W600无取向硅钢经钙处理后(w(Ca)=0.002 6%),钙在1 600℃的钢液中主要以固态的CaO·2Al2O3、CaO·6Al2O3及溶解钙的形式存在。在钢液的凝固过程中,钢中的溶解钙和硫反应生成了CaS和CaS-MnS复合夹杂,有效抑制了MnS的弥散析出,减少了钢中微细夹杂物的数量。同时钙处理促进了钢中微细夹杂物的聚合长大,导致显微夹杂物的数量增加。 Based on thermodynamic calculation and laboratory experiment,the type,quantity and size of inclusions in annealed cold-rolled steel sheets of 50W600 non-oriented silicon steel before and after calcium treatment were systematically studied.Results showed that after calcium treatment(w(Ca) = 0.002 6%),calcium was mainly in the form of CaO·2Al2O3,CaO·6Al2O3 and dissolved calcium in steel at 1 600 ℃.Dissolved calcium could combine with sulfur to form CaS inclusions and compound CaS-MnS inclusions du... 

研究了常化对CSP流程生产的wSi=1.6%的无取向电工钢组织、织构和成品磁性能的影响。结果表明,经CSP流程生产,且在相同的冷轧及退火制度下,经1 000℃×2min常化处理的wSi=1.6%的无取向电工钢热轧板,其最终退火成品的铁损P15/50比不常化试样下降了10.5%,磁感B50比不常化试样提高了2.5%;常化使wSi=1.6%的无取向电工钢成品的平均晶粒尺寸增大,成品铁损P15/50相应减小;同时,常化使wSi=1.6%的无取向电工钢成品中高斯织构的强度增加,γ纤维织构的强度减弱,这有利于成品磁感B50的提高。 The effect of normalizing on microstructure,texture and magnetic properties of non-oriented electrical steel with wSi=1.6% produced by CSP process was investigated.The results show that,under the same cold rolling and annealing system,the iron loss(P15/50) of annealed samples whose hot bands has been normalized by 1 000 ℃×2 min process decreases by 10.5% and magnetic induction(B50) increases by 2.5% compared with the samples whose hot bands was not normalized.The average grain size of non-orient... 

采用光学显微镜、X射线衍射仪等分析了宁波钢铁有限公司生产的取向硅钢不同工序下的组织及织构演变规律。结果表明:铸坯经过热轧后,沿着厚度方向组织不均匀;一次冷轧并经脱碳退火后,组织由条状纤维状变成等轴状的初次再结晶晶粒,初次再结晶平均晶粒尺寸为18.17μm,织构主要以α织构和γ织构为主;在二次冷轧后,晶粒再次被压缩,转变为纤维状,织构主要为γ织构;经过高温退火后,发生二次再结晶,晶粒异常长大,晶粒尺寸达到厘米级,织构成分为单一且锋锐的Goss织构。 The microstructure and texture evolution of oriented silicon steel produced by Ningbo Iron and Steel Co.,Ltd.were analyzed by optical microscope and X-ray diffraction.The results showed that the microstructure of the slab was inhomogenous along the thickness direction after hot rolling.After first cold rolling and decarburizing annealing,the microstructure changed from strip fibrous to equiaxed primary recrystallized grains,and the average grain size of the primary recrystallization microstructu...