硅钢资料

介绍了一种适用于超大晶粒取向硅钢的高斯晶粒取向偏离角的X射线衍射测量方法，提出了将试探法和探测器扫描法相结合的方式进行测量。结果表明：该方法可以同时获得准确的实际衍射角度和取向偏离角度，试样制备方式简单，对设备的要求低且测量结果准确。 This paper introduces a X-ray diffraction measurement method of Gaussian grain orientation deviation angle for ultra-large grain oriented silicon steel, and puts forward a method of combining the test method with the detector scanning. The results show that this method can obtain accurate actual diffraction angle and orientation deviation angle at the same time. The sample preparation method is simple, the requirements for equipment are low, and the measurement results are accurate. 

通过对湿H2气氛下,相同退火温度、不同退火时间的CGO硅钢初次再结晶样品进行金相组织观察,并进行了EBSD微观织构分析,研究了CGO硅钢初次再结晶过程中的组织及再结晶织构演变行为。结果表明,在湿H2气氛下,820℃保温,CGO硅钢初次再结晶过程约在120 s时完成。随着退火时间的延长,γ面上{111}<112>织构含量逐渐减少,{111}<110>织构先减少后增多,随着再结晶的完成,部分{111}<112>取向晶粒向高斯{110}<001>取向转化的同时,也向{111}<110>取向转化,高斯{110}<001>织构含量逐渐增多。高斯取向晶粒较多是由{111}<112>取向晶粒转化而来,同时也证明了CGO硅钢高斯取向晶粒的二次再结晶异常长大生长机制为择优形核。 Microstructure development and texture evolution of conventional grain oriented silicon steel,which were annealed at same annealing temperature and different annealing time under wet H2 atmosphere,were investigated through metallographic observation and electron backscattered diffraction analyzing.The results show that the primary recrystallization finishes in 120 s at 820 ℃ under wet H2 atmosphere.With the extending of annealing time,{111}<112> texture decreases,{111}<110> texture d... 

概述了无抑制剂法生产取向电工钢的特性及其用途;总结无抑制剂生产取向电工钢的原理及工艺方案.重点讨论了成分方案,即元素对磁性能的影响和最终高温退火方案对二次再结晶的影响.研究结果表明,无抑制剂取向硅钢化学成分范围没有普通取向硅钢和高磁感取向硅钢严格,提高了成材率;最终高温退火决定了二次再结晶的好坏,从而最终决定成品磁性能,最佳的高温退火温度在850～950℃之间. This article provides an overview on the characteristics and uses of inhibitorless process producing grain-oriented electrical steels.The mechanism of inhibitorless process and technology programs were discussed.The results show that the chemical composition and final annealing were determined according to magnetic properties.The inhibitor-free grain oriented silicon steel has loose range of chemical composition;Secondary recrystallization occurs mainly in the final annealing and the best anneal... 

借助OM、激光共聚焦显微镜、质谱仪和电解萃取等设备和方法，研究了添加微量稀土La（质量分数0.001 1%）的取向硅钢在轧制前采用不同加热保温时间对抑制剂固溶行为的影响。结果表明：当稀土取向硅钢在1 250℃分别保温10、20、30 min后，试验钢晶粒尺寸随保温时间延长有先快后慢的长大趋势；三种抑制剂元素Mn、Cu和Al均发生固溶，保温时间对Mn和Cu两种元素的固溶影响明显，固溶量分别由69.8%和43.7%增加至84.2%和85.2%；随着保温时间的延长，稀土取向硅钢中抑制剂的小尺寸未溶物逐渐减少直至消失，较大尺寸未溶物（300～600 nm）逐渐转变为小尺寸未溶物逐步溶入基体中，数量减少且未溶物的类型由复杂逐渐转变为单一。 In this paper the solid solution behavior of the inhibitor under various holding time in 0.001 1 %La oriented silicon steel during reheating had been investigated by using OM, LM, methods of electrolytic extraction and mass spectrometer. The results showed that grain size of the test steel increased significantly with the holding time prolonging when the rare earth oriented silicon steel was heated to1 250 ℃ and held for 10, 20 min and 30 min respectively, and the growth trend slowed down after ... 

无取向硅钢中夹杂物的存在会抑止晶粒生长,使基体的均匀连续性中断,其在钢中的形态、含量及分布情况都不同程度影响着硅钢的性能,尤其是对磁性能起关键的作用。因此,全尺度分布考察夹杂物对无取向硅钢夹杂物的研究极为重要。本实验确定了适用于不同牌号无取向硅钢夹杂物全尺度分布的分析方法:样品制备—小样电解—过滤喷金—根据不同牌号的要求选择合适的放大倍率扫描观测—夹杂物颗粒的分类统计。通过统计的结果,结合电解的失重量可以得到不同尺度的体积分布数据。实验分析了不同牌号和工艺无取向硅钢夹杂物的种类、形貌、大小和尺度分布,并初步考查了夹杂物与磁性能的关系,对无取向硅钢的工艺研究具有一定参考价值。 Inclusions in non-oriented silica steel could inhibit the growth of grain and cause discontinuity of micro-structure.The configuration,content and size distribution of inclusion have different effects on the performance of silica steel,especially significant on the magnetic property.Therefore,it is very useful to completely characterize inclusions with full size distribution in silica steel.In our research,full size analysis method for inclusion in silica steel had been established as follows: s... 

通过观察冲剪边缘组织,测量冲剪边缘的显微硬度、残余应力的分布情况和磁性能的变化研究了冲剪加工对无取向硅钢50WW800边缘组织和磁性能的影响。对冲剪后硅钢片进行750℃退火,分析退火对组织和磁性能的影响。结果表明,硅钢片剪切边缘会存在0.4 mm的形变硬化层,边缘应力大,铁损增加。退火后变形减小,形变硬化层变小,残余应力大幅度减少,铁损减少。 The influence of punching process on cutting edge microstructure and magnetic properties of non-oriented silicon steel 50WW800was studied by observing microstructure and measuring microhardness near cutting edge.The residual stress distribution in the silicon steel tooth and magnetic properties were measured.Effect of annealing at 750 ℃ on microstructure and magnetic properties of the silicon steel was analyzed.The results show that a cut-edge hardening layer up to 0.4 mm is observed,residual st... 

试验研究了0.3 mm取向硅钢冷轧板(/%:0.046C,3.07Si,0.09Mn,0.029P,0.004S,0.005A1)的退火温度(760~880℃7 min)和退火时间(820℃3~9 min)对该钢的晶粒尺寸,再结晶和织构的影响。结果表明,最佳初次再结晶退火工艺为820℃5 min,该钢的平均晶粒尺寸为14.20μm,完全再结晶率为92%,不利{111}<110>结构含量为3.16%,有利织构{111}<112>,{012}<001>和高斯织构含量分别0.40%,4.73%和2.46%。 The effect of annealing temperature(at 760 ~ 880 X.for 7 min) and time(at 820℃ for 3~9 min) on grain size,recrystallization rate and texture of 0.3 mm cold-rolled sheet of oriented silicon steel(/%:0.046C,3.07Si,0.09Mn,0.029P,0.004S,0.005Al) has been tested and studied.Results show that with optimum recrystallized annealing at 820℃ for 5 min,the silicon steel average grain size is 14.20 fun,the complete recrystaUization rate is 92%,the unfavourable-texture {111}< 110 > content in steel is ... 

介绍了国内无底层取向电工钢生产技术水平、产量和用途，简述了无底层取向电工钢作为取向电工钢超/极薄带母料及应用于制作大型发电机组铁心、风电等电机铁心和变压器铁心等的情况。 The production technology level,output and application of domestic glassless grainoriented electrical steel were introduced,and the application of glassless grain-oriented electrical steel as parent material of ultra-thin strip of grain-oriented electrical steel and in making large-scale electric generator cores,wind power motor cores and transformer cores were briefly described. 

采用铸坯低倍组织检验和化学分析的方法,研究板坯连铸机二冷区电磁搅拌器电流和频率参数对无取向电工钢XG800WR板坯中心偏析和等轴晶率的影响,结果表明:铸坯等轴晶率随着搅拌器电流强度和电流频率的增大而增加。采用二冷区电磁搅拌可减小中心易偏析元素S的偏析,试验得出:减小铸坯S偏析效果最好的电磁搅拌参数为电流380～400A,频率6Hz。 The effect of electromagnetic stirring current and frequency parameter at secondary cooling area on the central segregation and equiaxed crystal ratio of XG800WR non - oriented electrical steels slab was investigated through the methods of chemical and macrostructure analysis.The results shows that the rate of equiaxed crystal zone is going up with increasing of current intensity and current frequency.Electromagnetic stirring in the secondary cooling area can be easily reduced segregation caused... 

通过固溶度积公式计算及热模拟实验,对不同热装和加热温度条件下的无取向硅钢铸坯中析出相进行了研究.在低于950℃热装时,铸坯中AlN的析出量和尺寸不再变化,但MnS和AlN-MnS的数量及平均尺寸随着热装温度降低而进一步增加,并在温度低于600℃时达到最大值后保持不变.与1200℃相比,1100℃加热的铸坯中AlN、MnS的总固溶量相对更少.相比850℃热装,600℃热装再加热到1100℃的铸坯中AlN和MnS的总固溶量更少,且AlN和MnS尺寸更大.合适的热装温度和加热温度分别为600℃和1100℃. Based on solubility product calculation and thermal simulation experiments,precipitated phases in continuous casting slabs of non-oriented silicon steel were systematically studied at different hot charging and heating temperatures.When the hot charging temperature is below 950 ℃,the content and size of AlN remain unchanged,but the quantity and size of MnS and AlN-MnS increase when the hot charging temperature decreases,reach maximum and remain unchanged when the hot charging temperature is belo... 

结合工业化生产的无取向硅钢,进行了RH精炼喂CaSi线去除钢中的非金属夹杂物试验研究。针对不同的钙处理条件,分析了CaS夹杂生成热力学,观察了夹杂物的形貌和尺寸分布,确定了夹杂物的类型、数量,探讨了钙处理后钢中夹杂物的变化规律。结果表明,本试验条件下,钙处理可以有效抑制MnS、AlN夹杂物的生成,有效促进钢中微细夹杂物的聚合、上浮、去除,钢质纯净度明显提高。经过合适的钙处理后,钢中的夹杂物以独立存在的CaO为主,同时有少量含CaO、SiO2、MgO的复合夹杂,没有发现CaS夹杂存在。这部分夹杂物的尺寸集中分布在2～20μm,数量约为1.8×105个/mm3。 Experimental study on removal of non-metallic inclusions in non-oriented silicon steel obtained from industrial production by CaSi wire feeding during RH refining process was carried out.The thermodynamics of CaS inclusion formation was analyzed,the morphology and the size distribution of inclusions were observed,and the numbers and types of inclusions were also determined for the steel specimens treated under different calcium treatment conditions.Furthermore,the variation of inclusion characte... 

【作者】 朱凤泉； 黄生银； ...