硅钢资料

阐述了国内外高磁感取向硅钢的生产研究水平与发展趋势,包括通过提高高斯晶粒取向度、细化磁畴、涂覆张力涂层、减薄钢片厚度进一步降低铁损以及低温加热技术和短流程技术新工艺。分析高磁感取向硅钢在我国大型电力变压器上的应用情况,结果表明,发展更薄规格高磁感、低铁损、低磁致伸缩取向硅钢可为大型变压器的安全性、节能性及环保性提供有效保障。 The research progress and development trend of high magnetic induction grain-oriented silicon steel at home and abroad are summarized,including the technology of improving the Goss alignment,refining domain wall,adding stress coating,decreasing thickness of sheet,and the new technique of reducing heating temperature of casting slab and shortening operational.Moreover,the application of high magnetic induction grain-oriented silicon in power transformer is presented.Developing grain-oriented sili... 

对硅钢板材分别进行异步和同步轧制,研究了轧制参数包括速比、压下量和道次对板材表面显微组织的演变的作用.结果表明,异步轧制硅钢板材表面形成了晶粒尺寸为10~50 nm,取向接近随机分布的纳米晶,而同步轧制板材的表面只形成了位错胞,证明异步轧制可以诱发表面纳米化.异步轧制板材表面纳米晶的形成过程为:在剪切力的反复作用下,高密度位错形成、滑移、湮灭和重组形成亚微米尺度的亚微晶/位错胞.随着压下量和轧制道次增加,高密度位错重复以上过程使晶粒尺寸减小、取向差增大,最终形成取向接近随机分布的纳米晶组织.大压下量和多道次是异步轧制诱发板材表面纳米化的关键,而速比的增加可以加快纳米化进程. Surface nanocrystallization(SNC) can effectively enhance the surface and global properties of the metallic materials,such as microhardness,intensity,fatigue,wear and corrosion resistances,therefore provides more promising practical industrial applicability.Up to now,several SNC treatment methods were developed based either on the principles of ball impactions or friction sliding,however,difficulty still exists for the surface treatment of large-dimensional samples with high efficiency.Recently,m... 

采用扫描电镜、原子力显微镜研究了铬酸镁半无机绝缘涂层的微观结构。结果表明,涂层厚度为数微米,涂层中的有机树脂乳液颗粒均匀分布在无机涂层的表面,从而保证了涂层具有良好的冲片性能。采用极化曲线研究了涂层的耐蚀性能,发现铬酸镁与铬酸锌绝缘涂层的耐蚀性能相当。 In this paper,the microstructure and anti-corrosion property of magnesium chromate coating on non-oriented silicon steel were studied.The microstructure was observed by SEM and AFM.The anti-corrosion properties were evaluated by polarization curves.The results show that the thickness of coating is several microns and the polymer particles were scattered on the surface of inorganic coating,which is the guarantee for lamination property.The corrosion resistance of the magnesium chromate film was e... 

广泛应用于电子电力行业的取向硅钢材料的磁性能与其晶体取向密切关联，对取向硅钢晶体衍射花样的研究非常重要.采用理论计算的方式研究了取向硅钢的晶体衍射花样特征，并绘制了取向硅钢的高斯织构理论极图、理论单晶透射电子衍射斑点花样和理论电子背散射衍射(Electron backscatter diffraction, EBSD)菊池花样.取向硅钢理论单晶衍射花样不仅可以为以后标定样品实测晶体衍射花样提供一种简单快捷的方法，也可以为样品检测提供一种标准.这种研究方法不仅限于取向硅钢，也被期待应用于其他材料晶体衍射花样研究. The magnetic properties of oriented silicon steels which are widely used in electronic and power industries are closely related to their crystal orientations, so it is very important to study the crystal diffraction patterns of oriented silicon steels. The characteristics of crystal diffraction patterns of oriented silicon steels are studied by means of theoretical calculation. The theoretical pole figures, theoretical single crystal transmitted electron diffraction patterns and theoretical elec... 

基于BOF→RH→CSP生产工艺,研究了RH精炼过程钢中夹杂物类型演变及MgO·Al2O3夹杂物形成规律,同时对MgO·Al2O3夹杂物的形成条件进行了热力学计算,借助CFD数值模拟软件研究了RH精炼过程卷渣行为。研究发现,RH精炼过程20和30 min时,w([MgO])/w([Al2O3])为0.005~0.020,未发现MgO·Al2O3夹杂物;RH出站后夹杂物w([MgO])/w([Al2O3])为0.3~0.5,且RH精炼结束后MgO·Al2O3夹杂物占夹杂物总量的58.4%;另外,RH精炼过程钢液表面速度CFD模拟结果为0.57 m/s,大于临界卷渣速度0.45 m/s,且顶渣成分与夹杂物成分相近,存在卷渣现象。热力学计算表明,钢液与炉渣平衡时钢中w([Al])为0.31%~0.37%,w([Mg])为0.00024%~0.00028%,在MgO·Al2O3生成区域之内。减少RH处理过程卷渣,浇铸过程下渣及控制顶渣和包衬相中MgO质量分数可抑制MgO·Al2O3夹杂物形成。 Based on the practical production of non-oriented silicon steel, the evolution of inclusion type and the formation of MgO·Al2O3inclusion were analyzed in the process of BOF→RH→CSP. The thermodynamic conditions for forming MgO·Al2O3inclusion were discussed and the behavior of slag entrapment of molten steel was also simulated by CFD software during RH refining. The results showed that the value of w([MgO])/w([Al2O3]) was in the range of 0.005-0.020 and no MgO · Al2O3 inclusion was observed at 20 ... 

主要研究了氧化锌对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验和动电位极化研究了不同氧化锌含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响.采用SEM和体视显微镜对涂层的表面形貌和附着性能进行研究.结果表明,氧化锌含量为4.0%时,氧化锌能完全中和涂层表面的游离磷酸,涂层的耐蚀性和附着性最好;氧化锌含量过少或过多时,涂层的耐蚀性和附着性都较差. This paper studies the influence of zinc oxide on the performance of chromium-free non-oriented silicon steel insulating coating which based on aluminum dihydrogen phosphate.Salt spray experiment and potentiodynamic polarization were used to study the influence of zinc oxide content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.The surface morphology and adhesion of coating were tested by SEM and stereo microscope.The results show that when t... 

通过实验室25 kg真空感应炉冶炼和锻轧研究了0.26%～0.95%Al含量对0.5 mm 2.2%Si无取向硅钢冷轧板组织、织构和磁性能的影响。试验结果表明,0.26%～0.81%Al含量时,随钢中Al含量的增加,成品退火钢板的晶粒尺寸增加同时铁损减少;当Al含量大于0.81%时,随Al含量增加,钢板的晶粒尺寸减小,同时铁损增加。Al含量对硅钢板磁感的影响没有明显的规律。2.2%Si无取向硅钢的合适Al含量为0.48%～0.81%。 The effect of 0.26%～0.95%Al content on structure,texture and magnetic performance of 0.5 mm cold rolled sheet of 2.2%Si non-oriented silicon steel has been studied by a 25 kg vacuum induction furnace smelting,and forging -rolling in laboratory.Results show that as 0.26%～0.81%Al,with increasing Al content in steel the grain size of annealed finished sheet increases while iron loss of sheet decreases,and as Al content in steel is more than 0.81%,the grain size of sheet decreases while iron loss in... 

利用热模拟试验机、光学显微镜和X射线衍射仪对Fe-3.2%Si低温取向硅钢热轧工艺参数对组织及织构的影响进行了研究。结果表明,Fe-3.2%Si硅钢在1110℃粗轧、880℃终轧,轧后以10℃/s的速度冷却到550℃卷取,然后空冷到室温,热轧硅钢板沿板厚方向的显微组织不均匀性显著,对后续发展完善的二次再结晶有重要作用。无论是热轧板,常化板还是冷轧板,它们的织构集中分布在γ取向线上,γ取向线的织构除取向密度不同外,织构种类是一致的,这说明γ取向线上织构是有继承性的。从热轧到常化,织构取向密度显著减小,经二次冷轧后,织构密度又显著升高,可见,轧制变形有助于织构的形成并使织构强度升高。 The influence of hot-rolled process parameters on the microstructure and texture of Fe-3.2%Si low temperature hot rolled grain-oriented silicon steel were researched by hot simulation experiment machine,light microscope and X-ray diffractometer.The results show that,Fe-3.2%Si silicon steel is rolled by the technology with a temperature of rough rolling of1110℃,finish rolling of 880℃,coiling with the speed of 10℃ /s,and then cooled to room temperature with air.The microstructure of hot-rolled sil... 

研究了卷取工艺对一种新型含铜无取向电工钢晶粒尺寸、织构演变、铁损和磁感应强度的影响。结果表明,试样织构组分主要为{111}、{112}、{100}和高斯织构,在550℃卷取、保温2～3h,{100}织构有增强趋势,磁感应强度较高,铁损较低。 The effects of coiling process on grain size,texture,core loss and magnetic induction of a new cold rolled non-oriented electrical steel with copper were investigated.The results show that there are mainly {111},{112},{100} and {110}<001> texture.Coiling at 550℃and keeping for 2～3 hours,the {100} texture is enhanced,magnetic induction is higher and core loss is lower. 

在现普通冷轧无取向硅钢的基础上,降低Si含量,复合添加少量辅助元素,组合热轧板处理和成品退火加热技术,研制出了免常化处理的高磁感、低铁损并具有良好耐酸腐蚀性能的新系列无取向电工钢。 Based on existing common cold rolled non-oriented silicon steel,a new series of non-orientedelectrical steel with high induction,low core loss and excellent anti-corrosion property has been developed by reducing Si element,adding complexly a small amount of supplementary elements,and employing combined treatment of hot rolled sheet and finished product annealed heated technology. 

取向硅钢常化工序主要采用现场实测带钢温度的方式测定冷却速率，并通过稳定冷却水温、调整冷却水量及喷梁运行数量等方式保证合理的冷却速率，给常化工艺设计和生产带来诸多不便。通过对常化工艺水冷过程带钢的传热分析求解，在建立带钢水冷温度模型的基础上，研究了不同冷却工艺参数对带钢温度及冷却速率的影响规律以及冷却工艺的交互作用结果。结果表明：模型计算结果能够较好地反映取向硅钢在常化水冷过程中的温度及冷却速率的变化，其计算误差为0.80%～4.11%;在特定取向硅钢厚度规格和常化工艺下，随着常化冷却水量及有效冷却长度的增加，带钢水冷温度及冷却速率与呈非线性变化；常化水冷工艺主要通过调控带钢与冷却水之间热交换量和交换时间实现对带钢温度的控制，实际生产中需综合考虑机组速度、冷却水量及有效冷却长度之间的交互作用，选定喷梁投入数量和冷却水量以获得稳定的冷却速率。 The cooling rate of normalization process mainly determined by measuring the grain oriented silicon steel strip temperature on site, and ensures the cooling rate by stabilizing the cooling water temperature, adjusting the cooling water volume and the operation quantity of spray beam, which brings inconvenience to the normalization process design and production. Based on the heat transfer of strip in the water cooling section of normalization process, the water cooling temperature model for the n... 

【作者】 陈迪安； 李春生； ...