钢厂
电感耦合等离子体质谱法测定硅钢中痕量铜和镍
研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%~100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters...
无取向硅钢热轧边裂的形成原因
利用加热炉模拟、动态再结晶以及热模拟等试验方法以及扫描电镜、金相显微镜等分析观察手段对无取向硅钢边裂的成因进行了探讨。结果表明,长时间加热使得板坯边部晶粒异常长大,晶界氧化并脱碳,轧制过程中边部温度过低,动态再结晶过程变弱,使得板坯边部延伸性能变差,是导致硅钢边裂的主要原因。建议通过适当降低铸坯加热温度、缩短保温时间、提高终轧温度来改善硅钢边裂缺陷。 The behaviors of high temperature oxidation,dynamic recrystallization,and hot ductility,microstructure evolution were investigated on the non-oriented electrical steel sheets to discuss the formation of edge crack.The key causes of cracking was found to be the coarse as-cast microstructure,grain boundary oxidation and decarburization in reheating furnace,as well as reduced temperature at strip edge region during hot rolling process resulting in reduced hot ductility and lack of enough dynamic re...
常化和退火工艺对冷轧无取向硅钢高频磁性能和强度的影响
冷轧无取向硅钢(/%:0.003C,2.35Si,0.22Mn,0.011P,0.002S,0.36A1,0.003 0N)经890℃或940℃3 min常化的2.3 mm热轧板冷轧成0.35 mm薄板。研究了常化温度和800920℃3 min退火对该钢高频(400Hz)磁性能和抗拉强度的影响。结果表明,830920℃退火时高频铁损P10/400值最低,随退火温度增加,晶粒尺寸增大,钢的抗拉强度降低;该钢的最佳热处理工艺为常化温度940℃,退火温度830℃,其抗拉强度Rm、高频铁损P10/400和磁感应强度J50分别为565 MPa,21.5 W/kg和1.69 T。 The cold-rolled non-oriented silicon steel(/%:0.003C,2.35Si,0.22Mn,0.011P,0.002S,0.36A1,0.003 0N) is cold-rolled to 0.35 mm sheet from 2.3 mm hot-rolled plate normalized at 890 ℃ or 940℃ for 3 min.The effect of normalizing temperature and annealing process at 800 920 °C for 3 min on high frequency(400 Hz) magnetic properties and tensile strength of the steel has been tested and studied.Results show that with annealing at 830 920 ℃the high frequency iron loss value P10...
硅钢脱硫影响因素分析研究
对RH法(真空循环脱气法)生产的冷轧硅钢的脱硫原理及影响因素进行了分析研究。研究表明:降低顶渣中FeO、MnO的含量,提高钢液温度,增加脱硫剂的加入量并延长其循环时间有利于提高脱硫效率。 The principles of desulfurization and its influence factors of cold rolling silicon steel during RH process have been studied in this paper.The result indicated that reducing contents of FeO and MnO,rising temperature of the liquid steel,increasing quantity of desulfurizer,lengthening cycle time of desulfurzer are benefit for desulfurization.
宝钢无取向电工钢发展历程及生产技术进步
简要介绍了宝钢无取向电工钢的发展历程、产品大纲、电磁性能控制情况,以及高附加值新产品的开发、应用情况。概述了近年来宝钢无取向电工钢生产技术进步,主要包括夹杂物控制技术、连轧机高牌号硅钢制造技术、同板差控制技术、环保涂层开发技术等。 This paper briefly summarizes the development history, product catalogue, and magnetic properties of non-oriented electrical steel sheets at Baosteel, as well as the development and application of high-value-added steel grades. Recent advances in manufacturing electrical steel sheets are also introduced, including technologies for controlling inclusion, producing high-grade steel strips by a tandem rolling mill, and controlling the transverse thickness difference of steel sheets, as well as the ...
进入硅钢叠片内的漏磁通和附加损耗的模拟实验与仿真
基于简化的取向硅钢片模型,系统地对不同的交流激励下的硅钢叠片内铁损、交链磁通和空气中指定位置的法向漏磁的分布进行了\"单片级\"的测量,并建立了相应的硅钢叠片级问题的三维有限元分析模型,进行了大规模的数值计算分析。模型实验和数值分析的结果表明垂直进入硅钢片的漏磁通和损耗呈现浅透入的特点,在硅钢片内引起的涡流损耗在总铁损中占据了\"举足轻重\"的份额。用电磁场有限元分析软件MagNet瞬态场时步法计算结果与测量结果相吻合,说明本文方法研究复杂的硅钢叠片问题的有效性。 The measurement and 3D finite element analysis of the iron loss,interlinkage flux inside the laminated silicon steel sheets and the magnetic flux densities at the specified positions are carried out based on a verifying silicon steel sheet model.The modeling results show that the leakage flux vertically through the silicon steel sheets has the peculiarity of shin effect,and the eddy current loss caused by the AC leakage flux is a significant component of the total iron loss.The calculated result...
国产化高牌号无取向硅钢退火、涂层炉新技术
从影响高牌号无取向硅钢退火工艺的主要参数入手,介绍高牌号无取向硅钢退火炉在加热、气氛控制、冷却、涂层烘烤方面的新技术,并展望无取向硅钢退火炉的发展方向。 Based on the technology parameters of high-grade non-oriented silicon steel annealing,the new technology of the annealing line,which includes heating,atmosphere control,cooling,coating baking,is introduced,and the development direction of non-oriented silicon steel annealing furnace is pointed out.
我国冷轧无取向硅钢涂层专利技术分析
对1990~2010年在我国申请的冷轧无取向硅钢涂层的专利数量、专利技术领域分布进行了统计,对典型涂层专利技术进行了分析,探讨了无取向硅钢涂层的发展趋势。统计分析结果表明,目前无取向硅钢涂层典型的专利技术主要有自粘结涂层、无铬含稀土元素涂层、含钼酸盐环保涂层及采用有机-无机纳米杂化材料为主成膜物形成的涂层等。无取向硅钢涂层发展的趋势主要是无铬环保的半无机、半有机型涂层。 The patent quantity of cold-rolled non-oriented silicon steel coating and distribution of technology fields applied in China in 1990-2010 were summarized.The analysis results indicate that typical patent technologies include self-adhesion coating,chromium-free and with rare earth element coating,environment-friendly and with molybdate coating,coatings with organic-inorganic hybrid materials as main forming agent and so on.The main development trends of coatings on silicon steel are among semi-in...
奥氏体化温度对高碳含硅钢等温转变的影响
采用XRD物相分析、金相组织观察及TEM精细组织分析研究了奥氏体组织结构状态对Fe-0.88C-1.35Si-1.03Cr-0.43Mn钢中温等温相变鼻温和孕育期的影响,以及不同温度奥氏体化后240℃等温20 min试样的组织结构特征。试验发现,随着奥氏体化温度的升高,中温等温开始转变的鼻温移向更低温度并且相变孕育期缩短;不同温度奥氏体化后同为240℃等温20 min处理,虽然均形成由贝氏体铁素体亚条平行排列构成的束状贝氏体组织,但贝氏体组织的精细结构状态不同,突出的差别在于对应低温奥氏体化贝氏体亚条端部边界具有凸起结构,而对应高温奥氏体化贝氏体亚条端部边界较为平齐且呈现楔形结构。不能简单地以马氏体切变机制认识试验钢中贝氏体组织的形成。 The influence of austenitization temperature on the incubation period and the bainitic phase transformation behaviour in high-carbon silicon steel has been investigated using X-ray diffraction(XRD), optical microscopy and transmission electron microscopy(TEM). The microstructure characteristics of the isothermal transformation(240 ℃, 20 min)products were also studied. It was found that the nose temperature of bainite transformation and incubation period decreased with the increasing austenitizin...

