钢厂
碳化法制备硅钢氧化镁过程中杂质脱除研究
以轻烧氧化镁粉为原料,经消化、碳化制得重镁水,在热解反应前采用络合剂对重镁水中的杂质钙、铁进行络合掩蔽,再经热解得到碱式碳酸镁,碱式碳酸镁经煅烧可制得钙、铁杂质含量较低的氧化镁。在重镁水络合除杂过程中,考察了络合剂三乙醇胺、柠檬酸、草酸单独和复合使用的除铁、除钙效果。以三乙醇胺为络合剂时,在200 mL重镁水中加10 mL三乙醇胺(1∶1),氧化镁产品中w(氧化镁)=99.3%、w(氧化钙)=0.31%、w(氧化铁)=0.042%;使用草酸和柠檬酸作为复合络合剂时,在200 mL重镁水中加入1.0 g柠檬酸和2.0 g草酸,氧化镁产品中w(氧化镁)=98.2%、w(氧化钙)=0.24%、w(氧化铁)=0.030%。 Light-burned magnesia as a raw material was hydrated and carbonated to obtain magnesium bicarbonate liquor.Before the pyrolyzing of magnesium bicarbonate liquor,complexants were used to cover Fe and Ca impurities.Then the treated liquid was pyrolyzed to obtain basic magnesium carbonate which was calcined to magnesium oxide with low calcium and iron content.During the complexing purification of magnesium bicarbonate liquor,the Fe and Ca removing effects of single or compound complexing agents,suc...
6.5%Si硅钢的制备技术和发展前景
6.5%Si硅钢具有优异的磁学性能和广泛的应用前景。本文综述了6.5%Si硅钢的物理、机械及磁学特性,讨论了传统轧制、温轧、薄带连铸、快速凝固、CVD、粉末轧制等不同制备工艺的关键技术及特点,概括了6.5%Si硅钢在高效节能电机、汽车马达及磁屏蔽等领域中的主要应用,介绍了硅钢的制备技术取得的研究进展,并指出了其广阔的发展前景。 6.5% Si silicon steel has good magnetic properties and wide applications.In this paper physical and mechanical magnetic properties were summarized,and key technology and characteristic of several preparation methods,such as traditional rolling,warm rolling,thin strip continuous casting,rapid solidification,CVD and powder rolling,were discussed.Main applications of 6.5% Si steel in the fields of high-efficiency electrical motors,automobile motors,transformer cores and magnetic shielding were gene...
修正GTN模型及其在预测硅钢冷轧边裂中的应用
考虑剪应变对微孔洞损伤演化的影响,对GTN损伤模型的损伤演化机制进行修正,建立了适用于不同应力三轴度水平的损伤模型。结合隐式应力更新算法和显式有限元计算,采用VUMAT子程序实现了修正GTN模型在有限元软件ABAQUS中的数值计算。通过模拟纯剪切和剪切-拉伸两组试样的损伤演化和断裂行为,验证了修正GTN模型在不同应力三轴度承载条件下的有效性。运用修正GTN损伤模型模拟含边部缺口的带钢在轧制过程中裂纹的萌生和扩展行为,模拟结果与实验相一致,表明该模型可有效地用于带钢缺陷在轧制过程中扩展行为的分析和预测。模拟和实验结果表明,带钢边部缺口在轧制过程中,缺口前沿和后沿均会萌生裂纹,且后沿裂纹扩展更为明显。 Considering the effect of shear strain of micro-void on damage evolution, a modified GTN model applicable to various stress triaxiality conditions is proposed by modifying the damage evolution mechanism of the GTN damage model. The modified model is implemented in commercial finite element software ABAQUS by combining the implicit stress update method with an explicit finite element solving algorithm and through the user-defined material subroutine VUMAT. The damage evolution and the failure pro...
常化温度对热轧无取向硅钢组织与磁性能的影响
为研究常化温度对热轧无取向硅钢组织与织构的影响,采用光学显微镜、背电子散射衍射技术研究了不同常化温度对其影响。结果表明,实验硅钢板在700~850℃温度下常化时,随常化温度的升高,晶粒尺寸增大,有利组分α织构增强,不利组分γ织构降低。对比研究了800℃和850℃常化热轧板CSL晶界分布图与取向差分布图,在本文研究条件下,Goss织构易在Σ=3,9的CSL晶界及晶粒取向差为30°~55°处形成。 The hot strips normalized at different temperatures were investigated by optical microscope and EBSD to study the effect of normalizing temperature on microstructure and texture of hot-rolled non-oriented silicon steel sheets.The results show that the grain size increases,the intensity of α-fibre texture increases,and the γ-fibre texture decreases when the hot strips are normalized at the 700-850 ℃.And CSL boundaries of Σ=3 and 15,and misorientation angles between 30° and 55° are more likely rel...
融入结构张量和活动轮廓的硅钢表面缺陷分割
为了解决在纹理背景下冷轧硅钢表面缺陷的分割问题,提出了基于局部信息结构张量和活动轮廓模型的硅钢表面缺陷分割方法。将图像的局部信息引入到结构张量中;在结构张量提取的特征空间中,以KL距离作为区域的概率密度相似性度量建立分割图像的活动轮廓模型;采用Split-Bregman数值解法对模型进行求解。运用提出的分割方法对硅钢表面的一些常见缺陷如纵向划伤、横向划伤、异物和孔洞等进行分割实验。实验结果表明,该方法可以准确地分割出硅钢表面缺陷区域,验证了该方法的有效性。 In order to address the segmentation problem for cold rolled silicon steel surface defect based on the texture background,a novel method based on structure tensor and active contour model is proposed.Image local information is introduced to the structure tensor.In the extracted feature space of structure tensor,KL distance is treated as a regional similarity measure of the probability density to establish active contour model for image segmentation.The numerical solution of Split-Bregman is used...
稀土在无取向电工钢中应用的研究进展
稀土元素在许多钢中发挥着独特而且不可替代的重要作用。半个世纪以来,它的作用已经在各种低合金和特殊合金钢中的研究及应用中得到充分的证明;然而,作为具有稀土资源优势的中国,在属于重要功能材料的无取向电工钢中稀土的应用却落后于国外,本文就中国稀土在无取向电工钢中的应用研究作简要的评述,希望能够进一步推进此领域的研究,并且促进中国稀土在无取向电工钢中应用技术的发展,缩短与国外差距,并提出了在此应用领域今后需深入开展的研究方向。 Rare earth elements play a unique and irreplaceable role in a lot of steels,it has given the full proof by the practice of various low alloy steels and special alloy steels since half century.However,as our country has the advantage of rare earth resources,RE application technology in non-oriented electrical steels has lagged behind abroad.The application researches of rare earth in non-oriented electrical steel in our country are briefly reviewed in this paper,which hope to promote the research...
奥氏体化温度对高碳含硅钢等温转变的影响
采用XRD物相分析、金相组织观察及TEM精细组织分析研究了奥氏体组织结构状态对Fe-0.88C-1.35Si-1.03Cr-0.43Mn钢中温等温相变鼻温和孕育期的影响,以及不同温度奥氏体化后240℃等温20 min试样的组织结构特征。试验发现,随着奥氏体化温度的升高,中温等温开始转变的鼻温移向更低温度并且相变孕育期缩短;不同温度奥氏体化后同为240℃等温20 min处理,虽然均形成由贝氏体铁素体亚条平行排列构成的束状贝氏体组织,但贝氏体组织的精细结构状态不同,突出的差别在于对应低温奥氏体化贝氏体亚条端部边界具有凸起结构,而对应高温奥氏体化贝氏体亚条端部边界较为平齐且呈现楔形结构。不能简单地以马氏体切变机制认识试验钢中贝氏体组织的形成。 The influence of austenitization temperature on the incubation period and the bainitic phase transformation behaviour in high-carbon silicon steel has been investigated using X-ray diffraction(XRD), optical microscopy and transmission electron microscopy(TEM). The microstructure characteristics of the isothermal transformation(240 ℃, 20 min)products were also studied. It was found that the nose temperature of bainite transformation and incubation period decreased with the increasing austenitizin...
低温板坯加热取向3%硅钢热轧板的研究
研究的两种取向硅钢(%:No1-0.042C、3.16Si、0.009Al、0.07Mn、0.50Cu、0.015S、0.0084N和No2-0.040C、3.20Si、0.014Al、0.22Mn、0.49Cu、0.016S、0.008 2N)由50 kg真空感应炉冶炼,锻成(mm)350×120×35板坯,经1 250℃30 min加热,开轧温度1 100℃,5道次热轧成2.3 mm板,终轧温度950~1 000℃。实验结果表明,两热轧板沿板厚方向存在组织和织构的不均匀性,热轧板次表层为再结晶组织,有较强的Goss织构组分;中心层为形变组织,具有典型的形变织构。含0.22%Mn的No2钢次表层{110}〈001〉织构组分比含0.07%Mn的No1钢弱,中心层{001}〈110〉织构组分大大强于0.07%Mn No1钢,导致两者磁性能差异,0.22%Mn No2钢磁感应强度(B800)和铁损(P1.7/50)分别为1.87 T和1.24 W/kg,0.07%Mn No1钢分别为1.88 T和1.18 W/kg。 Studied both grain-oriented silicon steels(%:No1- 0.042C,3.16Si,0.009Al,0.07Mn,0.50Cu, 0.015S,0.0084N and No2-0.040C,3.20Si,0.014Al,0.22Mn,0.49Cu,0.016S,0.0082N) are melted by a 50 kg vacuum induction furnace,forged to(mm) 350×120×35 slab,heated at 1 250℃for 30 min,with beginning rolling temperature 1 100℃hot-rolled to 2.3 mm plate by 5 passes,finishing-rolled at 950~1000℃.Test results show that the structure and texture along thickness of both hot-rolled plates are inhomogeneous:the subsurface ...
压下率对取向硅钢热轧板织构的影响
采用X-射线衍射分析技术测定了取向硅钢热轧板在不同压下率下不同厚度处的织构。结果表明,在压下率低于80%的情况下,几乎所有试样的不同厚度处的织构均为旋转立方织构类型{100}<011>,但不同压下率、不同厚度处的织构强度存在很大差异;在压下率大于80%的情况下,不同试样的不同厚度处的织构类型发生了变化,其织构类型为旋转立方织构或高斯织构{011}<100>,且当织构类型为旋转立方织构时,织构强度存在很大差异,而当织构类型为高斯织构时,织构强度差异相对较小。 The texture of the grain oriented silicon steel hot rolled plate at different compressibility has been measured.The experimental results have shown that the texture of all samples at different thickness is {100}<011> when the compressibility is below 80%,and its intensity at different compressibility and thickness is difference.The texture of all samples at different thickness is variable when the compressibility is above 80%,it is {100}<011> or {011}<100>,and the intensity of ...
无取向硅钢晶粒长大过程中应力对织构和晶界变化的影响
采用EBSD技术研究了有、无拉应力作用下无取向硅钢在晶粒长大过程中织构转变及晶界变化的规律。结果表明:在晶粒生长期间,无应力作用下的硅钢中,{111}〈112〉,{111}〈110〉织构组分强化,而{100}〈001〉织构组分弱化;与无拉应力作用下的情况相比,施加5MPa的拉应力时,{111}〈112〉,{111}〈110〉织构组分强化的速率下降,{100}〈001〉织构组分变化不明显。对于在晶粒生长期间持续变化的{111}〈112〉,{111}〈110〉和{100}〈001〉织构组分而言,虽然有、无拉应力作用下硅钢的{111}〈112〉和{111}〈110〉织构组分的高取向差角度晶界频率均下降,而{100}〈001〉织构组分的高取向差角度晶界频率则上升,但当有拉应力作用后,{111}〈112〉和{111}〈110〉织构组分的高取向差角度晶界频率下降的速率变小,{100}〈001〉织构组分的高取向差角度晶界频率上升的速率稍有变小。通过对无取向硅钢在晶粒长大过程中织构转变及晶界变化规律的研究,分析了合金原子在晶界的偏聚行为。 The rules of texture and grain boundary transformation in the nonoriented silicon steel under applied stress or without applied stress during grain growth were investigated by EBSD.The results show that the {111}〈112〉 and {111}〈110〉 components in the nonoriented silicon steel without stress are strengthened during grain growth whereas {100}〈001〉 component is weakened,but the growth rate of {111}〈112〉 and {111}〈110〉 component decreases,while the area fraction of {100}〈001〉 component doesn’t chang...

