钢厂
脉冲电场对取向硅钢磁性能及织构的影响
采用硅钢自动测量装置及X射线衍射仪检测出样品在实验前后的磁性能参数和织构强度.结果表明:较低的电压、9 Hz、较长的处理时间以及退火温度为650℃有利于增高铁损降低比例;较低的电压、较高的频率以及退火温度为650℃有利于增加磁感应强度增高比例.最佳的提高磁性能的实验参数是:频率为9 Hz,电压为500 V,处理时间为6 min,退火温度为650℃.通过织构分析可以验证:取向硅钢磁感应强度的变化取决于{110}<001>晶粒取向度值,而{110}<001>取向度值可看成是一个反映总体平均偏离角大小情况的综合值. An automatic measurement system for silicon steel and an X-ray diffraction meter were used for measuring the magnetic property parameters and texture of ex-processed samples and processed samples.It is shown that under the condition of a lower voltage,9Hz,a longer processed time and an annealing temperature of 650℃,the decrease rate of iron loss can be increased;a lower voltage,a higher frequency and an annealing temperature of 650℃ are in favor of improving the increase rate of magnetic inducti...
真空感应炉熔炼高硅电工钢脱氧工艺的研究
在50Kg氧化镁坩埚真空感应炉上进行高硅电工钢的脱氧试验。结果表明,通过控制原料的成分、高真空下的碳氧反应和炉衬分解向钢液中的供氧,可使钢液的总氧含量≤15×10-6;在维持高温高真空条件下,当钢液中的反应达到一定程度后,延长精炼时间并不能降低钢液的总氧含量;完成精炼后加入硅钙合金沉淀脱氧可进一步降低钢液的总含氧量,但脱氧效果有限。 The test of high-silicon electric steel deoxidation has been carried out in 50Kg vacuum induction furnace with magnesium oxide crucible.Results show that the total oxygen could be ≤15×10-6in molten steel by controlling material components,carbon-oxygen reaction in high vacuum and oxygen contamination from crucible materials on molten steel;And when the reaction was carried through to a certain extent,total oxygen in molten steel could not be reduced by the extension of refining period in high va...
脉冲磁场退火对取向硅钢磁性能的影响
通过对取向硅钢进行脉冲磁场退火实验,发现在相同的退火时间(6.0 min)内,低于1 T的脉冲磁场可以在一定程度上提高取向硅钢的磁感(B8),而高于1 T的脉冲磁场则会使取向硅钢的磁性能急剧恶化.同时发现,脉冲直流电加热方式会使取向硅钢的磁性能恶化.研究表明,脉冲磁场退火有望成为一种调控材料微观结构的有效手段. We have carried out experiments of annealing by pulse magnetic field.The results show that a pulse magnetic field with intensity lower than 1 T can promote magnetic induction density(B8) of grain-oriented silicon steel,while the magnetic properties deteriorate sharply when intensity is higher than 1 T.It has also been found that heating by using pulse direct current can cause the magnetic properties to deteriorate,in contrast to the traditional heating using resistance furnace.Our research shows...
冷轧压下量对取向硅钢极薄带显微组织的影响
观察了取向硅钢极薄带经冷轧至不同厚度,并经过不同工艺热处理后的显微组织及亚结构。结果表明:冷轧压下量越大,显微组织中位错密度越高,冷变形组织越多,等轴晶粒越少;增加冷轧压下量可以使试样的再结晶温度降低,当钢带厚度为0.08 mm时,在650℃退火时就能发生明显的再结晶。 Microstructure and substructure of the grain oriented ultra-thin silicon steel sheets is analyzed,which are rolled down to different thickness and treated with different heat treatment process.The result shows that there are higher dislocation density,more cold deformation structure and less equiaxed crystal grain in microstructure of the steel sheets with more cold rolled reduction.Increase of cold rolled reduction will decrease recrystallization temperature,and when thickness of the steel shee...
高磁感取向硅钢涂层技术
涂层技术在高磁感取向硅钢生产中起着重要的作用.根据生产实践,介绍了高磁感取向硅钢生产中涂层的种类和作用、涂料的成分和对产品性能的影响、涂层工艺质量控制要点和检验方法等,并提出了通过优化涂层工艺改善高磁感取向硅钢性能和外观质量的方法. Surface coating technique plays an important role in producing high magnetic inductivity grain-oriented silicon steel.Based on production practice,this paper describes the types and function of the coating,the composition of the coating and its effect on the product performance,the quality control and inspection method for the coatings,as well as proposes ways to improve the magnetic property and surface quality of the steel by optimizing the coating process.
电工钢冶炼过程中硫含量控制
介绍了攀钢冶炼电工钢过程硫含量变化以及过程回硫、增硫情况,采取针对性措施,如:提高铁水装入量、转炉采用石英砂代替复合造渣剂造渣、RH脱硫等,降低钢中硫含量。结果表明:采取相应措施后,电工钢炼成率大幅提高,成品w[S]≤0.008%的比例由改进前的62%提高到92.4%,取得了明显的冶金效果。 The resulfurization and the change of sulphur content in production of electrical steel is analyzed.The targeted measures have been taken,such as increase the loaded quantity of liquid iron,quartz sand replaces the composite slagging agent in the converter and RH desulfurization to decrease the sulphur content of the steel.The result shows,after the measures have been taken,the finished product ratio of electrical steel increase a lot.The ratio of sulfur content of finished product no more than ...
大压下率冷轧无取向硅钢再结晶织构演变
研究了冷轧95%变形量无取向硅钢不同退火温度(710~1 050℃)下再结晶织构特征.再结晶刚完成时(710℃退火),呈现强γ({111<112>~<134>)与弱{114}<481>织构特征;随退火温度升高至900℃,γ明显减弱,{114}<481>组分持续增强,形成典型的{h,1,1}<1/h,1,2>织构;进一步升温至1 050℃,再结晶织构不再发生明显变化.基于EBSD分析,{114}<481>组分的持续强化可归因于其明显的尺寸优势以及较高频率的高能晶界(取向差角为20°~45°). A non-oriented silicon steel was heavily rolled to 95% reduction and subsequently annealed at 710~1 050 ℃ to investigate recrystallization texture evolution.When annealed at 710 ℃ with complete recrystallization,the texture is characterized by a strong partial γ fiber spreading from {111}<112> to {111}<134> and a weak {114}<481> component.As annealing at 900 ℃,γ fiber is decreased significantly while {114}<481> is increased consistently,producing a typical {h,1,1}<1/h,...
铸坯热装温度对无取向硅钢中AlN和MnS析出行为的影响
通过固溶度积公式计算及热模拟实验,对不同热装和加热温度条件下的无取向硅钢铸坯中析出相进行了研究.在低于950℃热装时,铸坯中AlN的析出量和尺寸不再变化,但MnS和AlN-MnS的数量及平均尺寸随着热装温度降低而进一步增加,并在温度低于600℃时达到最大值后保持不变.与1200℃相比,1100℃加热的铸坯中AlN、MnS的总固溶量相对更少.相比850℃热装,600℃热装再加热到1100℃的铸坯中AlN和MnS的总固溶量更少,且AlN和MnS尺寸更大.合适的热装温度和加热温度分别为600℃和1100℃. Based on solubility product calculation and thermal simulation experiments,precipitated phases in continuous casting slabs of non-oriented silicon steel were systematically studied at different hot charging and heating temperatures.When the hot charging temperature is below 950 ℃,the content and size of AlN remain unchanged,but the quantity and size of MnS and AlN-MnS increase when the hot charging temperature decreases,reach maximum and remain unchanged when the hot charging temperature is belo...
RH精炼工艺对无取向硅钢MgO·Al_2O_3夹杂物演变影响及控制
基于BOF→RH→CSP生产工艺,研究了RH精炼过程钢中夹杂物类型演变及MgO·Al2O3夹杂物形成规律,同时对MgO·Al2O3夹杂物的形成条件进行了热力学计算,借助CFD数值模拟软件研究了RH精炼过程卷渣行为。研究发现,RH精炼过程20和30 min时,w([MgO])/w([Al2O3])为0.005~0.020,未发现MgO·Al2O3夹杂物;RH出站后夹杂物w([MgO])/w([Al2O3])为0.3~0.5,且RH精炼结束后MgO·Al2O3夹杂物占夹杂物总量的58.4%;另外,RH精炼过程钢液表面速度CFD模拟结果为0.57 m/s,大于临界卷渣速度0.45 m/s,且顶渣成分与夹杂物成分相近,存在卷渣现象。热力学计算表明,钢液与炉渣平衡时钢中w([Al])为0.31%~0.37%,w([Mg])为0.00024%~0.00028%,在MgO·Al2O3生成区域之内。减少RH处理过程卷渣,浇铸过程下渣及控制顶渣和包衬相中MgO质量分数可抑制MgO·Al2O3夹杂物形成。 Based on the practical production of non-oriented silicon steel, the evolution of inclusion type and the formation of MgO·Al2O3inclusion were analyzed in the process of BOF→RH→CSP. The thermodynamic conditions for forming MgO·Al2O3inclusion were discussed and the behavior of slag entrapment of molten steel was also simulated by CFD software during RH refining. The results showed that the value of w([MgO])/w([Al2O3]) was in the range of 0.005-0.020 and no MgO · Al2O3 inclusion was observed at 20 ...
单道次热轧对Fe-1.5Si硅钢氧化层形貌的影响
将Fe-1.5Si硅钢试样分别在1 000~1 200℃空气条件下氧化30 min,观察发现在1 000℃和1 100℃时,氧化层与基体界面处存在硅酸亚铁,而当温度为1 200℃时,硅酸亚铁不但存在于界面处,同时也存在于氧化层中.将各温度下得到的带有氧化层的试样进行单道次热轧试验,压下率分别为10%和30%,发现1 000℃和1 100℃时,较高的压下率使氧化层破碎更加严重,但是单道次热轧未能改变氧化层的结构;当温度为1 200℃时,由于液态的硅酸亚铁的出现,单道次热轧能够将界面处的液化的硅酸亚铁层挤压到氧化层中,消除了硅酸亚铁层的钉扎基体的效应,改善了氧化层与基体界面的平直度. Specimens of Fe-1.5Si silicon steel were oxidized at 1 000 ~ 1 200 ℃ in air for 30 min.At 1 000 ℃ and 1 100 ℃ fayalite was observed at the scale/substrate interface.While at 1 200 ℃fayalite was found both at the scale/substrate interface and at the outer oxide layer.Then after the single-pass hot rolling process,with the compression ratio of 10% and 30%,it was found that at 1000 ℃ and 1 100 ℃,higher compression rate accelerated the broken of the scale layers,but the scale structure was not affec...

