钢厂
硅钢高温氧化铁皮的显微结构表征
利用电子探针面分析、状态分析及电子背散射衍射相分析技术研究硅钢高温氧化铁皮的显微结构。电子探针面分析可以直观的看出元素的分布状态,初步判断氧化铁皮的结构,而状态分析可以准确表征常规氧化铁皮中铁元素的状态,对于合金元素富集区域则通过电子背散射衍射相分析技术来标定。结果表明,高温氧化铁皮的结构主要有4层,即最外层为厚度约为10μm的Fe2O3相,次外层为Fe3O4相,中间层为FeO相上分布有颗粒状的Fe3O4相,最内层为FeO相和Si元素富集的Fe2SiO4相。其中Fe2SiO4层的分布特征与加热温度密切相关:1 100℃时,Fe2SiO4相呈颗粒状,弥散分布在FeO层;1 200℃时,Fe2SiO4相呈液态,侵入基体和疏松的FeO层,且沿着FeO晶界呈网状分布。 The microstructure of high temperature oxide scale on silicon steel was characterized by electron probe microanalyzer(EPMA)mapping analysis,state analysis and electron backscatter diffraction(EBSD)phase analysis.The element distribution and the initial structure of the oxide scale could be detected by EPMA mapping analysis apparently.And the state of iron in the conventional oxide scales could be determined by state analysis.Meanwhile,the alloy-rich region could be identified by EBSD phase analy...
提高硅钢退火炉耐材施工效率的几点经验
主要对硅钢退火炉耐材施工进行阐述,对一期工程与二期工程施工经验进行总结,包括设计、施工、耐材生产、人员素质等方面,指出了工程项目所所存在的不足,为同类型炉窑的施工提供借鉴。 This paper describes the construction of silicon steel annealing furnace refractories;and it was summarized the construction experience of phase-Ⅰ and phase-Ⅱ projects,including design,construction,refractory production,the quality of personnel etc,and pointed out the shortcomings of the project,which provided a reference for the construction of the same type of furnaces.
取向硅钢连续退火的工艺与设计
分析了影响脱碳效果和结晶行为的各种要素及其相互制约关系,提出了Hi-B连续退火工艺曲线,总结得出快速加热及合理稳态气氛是实现工艺制度的关键。结合实际工程,介绍了在连续退火炉设计中快速加热和气氛设计的考虑方法,并指出随着Hi-B产品的发展,如何改进这些方法将是连退工程研发的方向之一。 The factors which affect decarbonization and crystallization and the mutual restriction between them were analyzed.A complete continuous annealing process for Hi-B was put forward.As a result,the rapid heating and the proper steady atmosphere were two important factors.According to an actual project,the consider methods for designing rapid heating and proper steady atmosphere were introduced,and it is pointed that with the development of Hi-B technique,how to improve these techniques would be on...
高温卷取的热轧态原料与常化态原料生产高牌号无取向硅钢的比较
研究了采用高温卷取热轧态原料和常化态原料生产高牌号冷轧无取向电工钢组织、织构和磁性能。研究发现钢卷采用750℃高温卷取,下线后立即采用\"保温罩\"对钢卷进行保温,时间96h,然后空冷至100℃时上线生产的工艺可取代常化工艺生产高牌号冷轧无取向电工钢。冷轧上线前,热轧态原料的表层为大量的再结晶组织,这部分组织包括了热轧轧制时保留下来的动态再结晶组织,钢卷本身高温回复后产生再结晶晶粒,以及在保温罩内保温时形成的再结晶组织。高温卷取的热轧态和常化态的热轧卷作为原料时,试样织构类型相似,取向分布密度接近,再结晶后织构类型仍然相似,取向分布密度仍然接近。Goss织构对磁性能增加有促进作用。实验钢中较好的磁性能对应的织构[{100}+Goss]/{111}的比值较高,体现了织构的遗传性。 Microstructure,texture and magnetic properties of high grade cold rolled nonoriented electrical steel which made of hot rolled material with high temperature coiling and with normalization were studied.Steels coiled in high temperature(at 750 ℃),stacked with insulation cover for 96hand air cooled to 100 ℃ were using to manufacture high grade nonoriented electrical steel.The process can replace the normalization process.There are a lot of recrystallized grains in the surface layer of the coil wit...
无取向电工钢RH脱硫渣系的研究
在15 kg真空感应炉上,用CaO-Al2O3-SiO2-MgO渣系进行脱硫试验,探讨了脱硫渣系碱度、MI、Al2O3、CaF2对脱硫效果的影响。研究结果表明,随脱硫渣系碱度、MI、Al2O3和CaF2含量的增加,脱硫率都呈现先增加后减少的趋势。初始硫含量为0.009 33%~0.010 73%,加入脱硫渣系4 min时间内表观脱硫速率为(0.000 96~0.001 49)%/min,平均脱硫率为81.2%,最高达86.8%。当脱硫渣中w(CaO)=58.15%、w(SiO2)=4.85%、w(Al2O3)=25%、w(MgO)=6%、w(CaF2)=6%,脱硫效果最好,此时钢液中硫为0.001 33%。 Experiments on desulfurization of molten steel using CaO-Al2O3-SiO2-MgO based desulfurization slag was carried out in a 15 kg vacuum induction furnace. The effects of desulfurization slag basicity,MI, Al2O3and CaF2on desulfurization of molten steel were studied. The results show that with the increase of basicity,MI,Al2O3or CaF2in desulfurization slag,the desulfurization rate rises initially and then decreases. In addition,as the initial sulfur content is 0. 009 33% ~ 0. 010 73%,the apparent des...
不同牌号无取向硅钢夹杂物定性定量分析
无取向硅钢中夹杂物的存在会抑止晶粒生长,使基体的均匀连续性中断,其在钢中的形态、含量及分布情况都不同程度影响着硅钢的性能,尤其是对磁性能起关键的作用。因此,全尺度分布考察夹杂物对无取向硅钢夹杂物的研究极为重要。本实验确定了适用于不同牌号无取向硅钢夹杂物全尺度分布的分析方法:样品制备—小样电解—过滤喷金—根据不同牌号的要求选择合适的放大倍率扫描观测—夹杂物颗粒的分类统计。通过统计的结果,结合电解的失重量可以得到不同尺度的体积分布数据。实验分析了不同牌号和工艺无取向硅钢夹杂物的种类、形貌、大小和尺度分布,并初步考查了夹杂物与磁性能的关系,对无取向硅钢的工艺研究具有一定参考价值。 Inclusions in non-oriented silica steel could inhibit the growth of grain and cause discontinuity of micro-structure.The configuration,content and size distribution of inclusion have different effects on the performance of silica steel,especially significant on the magnetic property.Therefore,it is very useful to completely characterize inclusions with full size distribution in silica steel.In our research,full size analysis method for inclusion in silica steel had been established as follows: s...
球刻痕法对高磁感取向硅钢磁性的影响
试验研究了球刻痕法对高磁感取向硅钢的铁损、矫顽力、相对磁导率、巴克豪森噪声等磁学性能的影响.研究结果表明:经过球刻痕处理后,高磁感取向硅钢的铁损明显降低,矫顽力下降,8 mm球刻痕过后铁损值与矫顽力分别下降16.2%和14.7%,且铁损和矫顽力均随刻痕间距降低而减少.刻痕后的高磁感取向硅钢磁导率在高磁感应强度下明显上升,刻痕后巴克豪森噪声值明显降低,经过对比分析确定8 mm为球刻痕的最佳刻痕间距.从磁畴观察、细化磁畴的原理等方面解释了细化磁畴对高磁感取向硅钢性能的影响原因. The effects of the ball scribing on magnetic properties of high permeability grain-oriented silicon steels,including the iron loss,coercive force,relative permeability,and Barkhausen noise were investigated. The results showed that the iron loss and coercive force of the high permeability grain-oriented silicon steels apparently decreased 16. 2% and 14. 7% respectively after 8 mm ball scribing and they both decreased with the decrease of the scribing spacing at the same magnetic flux density. At...
无取向硅钢晶粒长大过程中应力对织构和晶界变化的影响
采用EBSD技术研究了有、无拉应力作用下无取向硅钢在晶粒长大过程中织构转变及晶界变化的规律。结果表明:在晶粒生长期间,无应力作用下的硅钢中,{111}〈112〉,{111}〈110〉织构组分强化,而{100}〈001〉织构组分弱化;与无拉应力作用下的情况相比,施加5MPa的拉应力时,{111}〈112〉,{111}〈110〉织构组分强化的速率下降,{100}〈001〉织构组分变化不明显。对于在晶粒生长期间持续变化的{111}〈112〉,{111}〈110〉和{100}〈001〉织构组分而言,虽然有、无拉应力作用下硅钢的{111}〈112〉和{111}〈110〉织构组分的高取向差角度晶界频率均下降,而{100}〈001〉织构组分的高取向差角度晶界频率则上升,但当有拉应力作用后,{111}〈112〉和{111}〈110〉织构组分的高取向差角度晶界频率下降的速率变小,{100}〈001〉织构组分的高取向差角度晶界频率上升的速率稍有变小。通过对无取向硅钢在晶粒长大过程中织构转变及晶界变化规律的研究,分析了合金原子在晶界的偏聚行为。 The rules of texture and grain boundary transformation in the nonoriented silicon steel under applied stress or without applied stress during grain growth were investigated by EBSD.The results show that the {111}〈112〉 and {111}〈110〉 components in the nonoriented silicon steel without stress are strengthened during grain growth whereas {100}〈001〉 component is weakened,but the growth rate of {111}〈112〉 and {111}〈110〉 component decreases,while the area fraction of {100}〈001〉 component doesn’t chang...
