钢厂
无取向电工钢孔洞缺陷控制实践
针对马钢无取向电工钢孔洞缺陷的分布规律及形貌特征,对缺陷样进行了显微分析,并利用生产实绩数据分析了该缺陷产生的原因。结合热轧生产过程,主要通过避免带钢撞击导卫以及降低导卫结瘤的产生等措施,可有效抑制热卷异物压入产生,从而降低冷轧工序孔洞的产生。 In viewing of the distribution and morphology characteristics of the hole defect of non-oriented electrical steel in Maanshan Iron and Steel Co.,Ltd.,the causes of the defect were analyzed by micro analysis of the defect sample and the production data.Combined with the production process of hot rolling,by avoiding the impact of strip steel on the guide and reducing the nodule formation on the guide,the pressing of foreign bodies in hot coiling could be effectively suppressed,thus reducing the fo...
获得抑制剂法生产低温高磁感取向硅钢的抑制剂控制研究进展
综述了国内外大钢铁企业与研究机构采用获得抑制剂法生产低温高磁感取向硅钢的开发及应用情况,分析了以该法生产高磁感取向硅钢过程中抑制剂的控制技术,包括固有抑制剂组成方案、气态渗氮方式与工艺及高温退火工艺的制定.研究表明,固有抑制剂组成方案的设计思路大体一致,化合物抑制剂以AlN为主、硫化物为辅,同时添加少量Sn,Sb等单元素抑制剂,但组成元素含量存在一定差别;在脱碳退火后用NH3进行非平衡渗氮处理已成为气态渗氮的主要方式,但最佳方式仍未明确,具体选择需依据实际生产条件,相应脱碳及渗氮工艺的控制条件差别较大;高温退火工艺中升温制度差别不大,升温阶段退火气氛中N2含量的选择存在差别.此外,分析了抑制剂控制技术目前存在的关键问题,并指出了进一步的研究方向. The current application and exploitation on production of low-temperature high magnetic induction grain-oriented silicon steel with acquired inhibitor method at both iron and steel enterprises and research institutions in the world are reviewed. The control techniques of inhibitors, which include the composition design for inherent inhibitors, nitriding method and process, and secondary recrystallization annealing, are thoroughly analyzed and proposed. It is indicated that the design ideas for i...
晶粒尺寸对无取向硅钢磁性能影响的主成分回归分析
采用电子背散射衍射技术测定50SW1300冷轧无取向硅钢中不同尺寸范围晶粒的含量,利用主成分回归分析法,综合研究不同尺寸范围晶粒的含量对无取向硅钢磁性能的影响。结果表明:通过主成分回归分析法能够从不同尺寸范围晶粒的含量的多个影响因素中获取主要的因素,定量研究它们对无取向硅钢磁性能的影响规律。分析表明,无取向硅钢的铁损与不同尺寸范围晶粒的含量之间存在着可靠的多元线性关系,在一定范围内,较大尺寸晶粒的含量越多,其对铁损优化的作用越明显;而无取向硅钢的磁感与不同尺寸范围晶粒的含量之间并无线性关系。 Distribution of grain size in cold rolled non-oriented silicon steel 50SW1300 was measured by EBSD.The effects of the distribution of grain size on magnetic properties of the non-oriented silicon steel were comprehensively researched by means of principal component regression method.The results indicate that the main factors influencing the magnetic properties in the distribution of grain sizes,which can be used to guantitative study the magnetlic properies of the steel,are obtained by principal...
高温卷取的热轧态原料与常化态原料生产高牌号无取向硅钢的比较
研究了采用高温卷取热轧态原料和常化态原料生产高牌号冷轧无取向电工钢组织、织构和磁性能。研究发现钢卷采用750℃高温卷取,下线后立即采用\"保温罩\"对钢卷进行保温,时间96h,然后空冷至100℃时上线生产的工艺可取代常化工艺生产高牌号冷轧无取向电工钢。冷轧上线前,热轧态原料的表层为大量的再结晶组织,这部分组织包括了热轧轧制时保留下来的动态再结晶组织,钢卷本身高温回复后产生再结晶晶粒,以及在保温罩内保温时形成的再结晶组织。高温卷取的热轧态和常化态的热轧卷作为原料时,试样织构类型相似,取向分布密度接近,再结晶后织构类型仍然相似,取向分布密度仍然接近。Goss织构对磁性能增加有促进作用。实验钢中较好的磁性能对应的织构[{100}+Goss]/{111}的比值较高,体现了织构的遗传性。 Microstructure,texture and magnetic properties of high grade cold rolled nonoriented electrical steel which made of hot rolled material with high temperature coiling and with normalization were studied.Steels coiled in high temperature(at 750 ℃),stacked with insulation cover for 96hand air cooled to 100 ℃ were using to manufacture high grade nonoriented electrical steel.The process can replace the normalization process.There are a lot of recrystallized grains in the surface layer of the coil wit...
锰含量对无取向电工钢组织性能的影响
研究了锰含量对w(Si)=1.8%Si无取向电工钢组织和性能的影响。结果表明,钢中锰含量从0.3%增加到1.2%时,由于α_γ相变的产生,铸坯低倍组织、热轧板金相组织及成品织构等均发生了不同程度的变化,对成品表面质量及磁性能产生了明显的影响。 The effects of manganese content on structure and properties of w(Si)=1.8% non-oriented electrical steels have been studied.Results show that with increasing manganese content to 1.2% from 0.3%,macrostructure of continuous casting slab,hot rolled band metallurgical structure and finished product texture vary in some extent because of the occurrence of α-γ phase transformation,the surface quality and magnetic properties of finished product are affected greatly.
凝固速率对定向凝固50W600无取向硅钢固液界面稳定性和枝晶间距的影响
采用ZMLMC超高梯度定向凝固装置,研究了5种凝固速率(10、35、80、150和450μm/s)对定向凝固50W600无取向硅钢的固液界面稳定性转变规律和一次、二次枝晶间距的影响。研究结果表明,在特定的温度梯度下,随着凝固速率的增加,定向凝固的固液界面由胞状晶转变为胞状枝晶,再转变为细小的树枝晶。随着凝固速率的增加,定向凝固组织的枝晶形貌逐渐细化,一次和二次枝晶间距逐渐减小,且与冷却速率之间都符合指数关系:λ1=151.73×(G L·R)-0.31,λ2=22.07×(G L·R)-0.44。当冷却速率达到4.275℃/s时,一次、二次枝晶间距分别为112μm、14.1μm。 Under the conditions of certain temperature gradient and different solidification rate,the directional solidification experiment of non-oriented electrical steel 50W600 was carried out.The microstructure of 50W600 steel was also analyzed in different solidification rate.The result shows that the solid/liquid interface of the steel undergoes an evolution from cellular,cellular dendrite and finally to fine dendrite morphologies.The dendrite refines gradually and the distance between dendrites decr...
试样剪切应力对冷轧无取向电工钢磁性能的影响
电工钢试样加工产生的剪切应力会恶化钢板的磁性,对不同牌号硅钢片的横向、纵向试样退火前后磁性能的变化进行研究,结果表明:无取向硅钢片在剪切过程中横向、纵向的磁性受到剪切应力影响是不一样的。 The electrical steel sample processing magnetic of electrical steel will worsen due to the shear stress of sample. In this paper,the magnetic change of transverse,longitudinal specimens of different type of silicon steel sheet before and after annealing are studied. The results show that the magnetic of non- oriented silicon steel sheet affected in the process of shear is not the same in horizontal and vertical direction.
取向硅钢超大高斯晶粒取向偏离角的X射线衍射测量
介绍了一种适用于超大晶粒取向硅钢的高斯晶粒取向偏离角的X射线衍射测量方法,提出了将试探法和探测器扫描法相结合的方式进行测量。结果表明:该方法可以同时获得准确的实际衍射角度和取向偏离角度,试样制备方式简单,对设备的要求低且测量结果准确。 This paper introduces a X-ray diffraction measurement method of Gaussian grain orientation deviation angle for ultra-large grain oriented silicon steel, and puts forward a method of combining the test method with the detector scanning. The results show that this method can obtain accurate actual diffraction angle and orientation deviation angle at the same time. The sample preparation method is simple, the requirements for equipment are low, and the measurement results are accurate.
高温退火气氛对硅钢表面硅酸镁底层形貌的影响
对取向硅钢在不同气氛下的高温退火工艺进行实验室模拟,利用X射线衍射仪(XRD)分析了硅钢退火至900℃和1170℃时的样品表面氧化层和底层的物相组成,采用场发射扫描电镜(SEM)观察了样品表面氧化层和底层在截面方向上的微观形貌特征,并计算了高温退火一次升温阶段氧化反应的吉布斯自由能以及900℃时退火气氛的氧分压。结果表明:当退火气氛的露点温度保持一定时,较高的氢气含量有利于生成完整连续的底层;当退火气氛的水氢分压比保持一定时,在露点温度与氢气含量两者较低的条件下,底层附着性不佳易脱落,较高条件下,底层中夹杂着较多的铁单质;当氧化层中无FeO时,底层完整连续但易脱落,当FeO层较薄时,底层下方存在部分未反应的SiO2,当FeO层较厚时,底层不完整连续且有分层。 The high temperature annealing process of grain-oriented silicon steel in different atmospheres was simulated in the laboratory. X-ray diffractometer(XRD) was used to analyze the phase compositions of the surface oxide layer and forsterite film of the silicon steel annealed to 900 ℃ and 1170 ℃. Field-emission scanning electron microscopy(SEM) was used to observe the micro morphology characteristics of the surface oxide layer and forsterite film of the samples in the cross section direction. The ...

