硅钢资料

研究了硼酸对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响。用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同硼酸含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响,同时采用SEM对涂层的表面形貌进行了研究。结果表明,硼酸含量为9.7%时,涂层的耐盐雾性及电化学性能最好;硼酸含量过少或过多时,涂层的耐蚀性和电化学性能都较差。 Influence of boric acid on the performance of chromium-free non-oriented silicon steel insulating coating based on aluminum dihydrogen phosphate was investigated.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of boric acid content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.Surface morphologies of the coatings were tested by SEM.Result shows that when the boric ... 

晶界和{100}柱状晶在硅钢生产过程中对织构的遗传和演变有关键作用,因此本文利用晶体塑性有限元方法进行立方和旋转立方取向双晶在晶界不同位向时晶体取向演变的全场模拟。模拟显示,三种晶界位向下,晶界都具有诱发晶内产生S形状形变不均匀和缓解局部形变不均匀区取向转动的特点,立方和旋转立方取向双晶在带有剪切作用的轧制条件下都显示明显的取向稳定性。GB⊥RD(表示晶界垂直于轧向)晶界位向时,旋转立方取向晶粒优先在晶界中心位置发生取向转动,而立方取向则优先在远离晶界的端部发生取向转动。GB⊥TD(表示晶界垂直于横向)的晶界位向下,其晶界阻碍作用最小,双晶内产生的取向漫散度大,织构强度较低;除绕TD转动外,也具有复杂的绕RD、ND的取向转动。GB⊥ND(表示晶界垂直于法向)的晶界位向下,取向转动与GB⊥RD时相近,但有少量取向绕ND转动。 Grain boundaries and initial{100}columnar grains play a key role in the inheritance and evolution of texture in the production of electrical steels.In this paper,the crystal plasticity finite element method was used to simulate the grain orientation evolution of cube and rotated-cube oriented bicrystals when grain boundary was set to different orientations.It was shown that the grain boundary in three grain boundary orientations demonstrated the characteristics of inducing Sshape deformation inh... 

观察了取向硅钢极薄带经冷轧至不同厚度,并经过不同工艺热处理后的显微组织及亚结构。结果表明:冷轧压下量越大,显微组织中位错密度越高,冷变形组织越多,等轴晶粒越少;增加冷轧压下量可以使试样的再结晶温度降低,当钢带厚度为0.08 mm时,在650℃退火时就能发生明显的再结晶。 Microstructure and substructure of the grain oriented ultra-thin silicon steel sheets is analyzed,which are rolled down to different thickness and treated with different heat treatment process.The result shows that there are higher dislocation density,more cold deformation structure and less equiaxed crystal grain in microstructure of the steel sheets with more cold rolled reduction.Increase of cold rolled reduction will decrease recrystallization temperature,and when thickness of the steel shee... 

【作者】 陈迪安； 李春生； ...

针对传统工艺生产硅钢周期长、能耗大等缺点,采用双辊连铸工艺制备3%Si无取向硅钢连铸薄带,利用MEM,SEM和TEM观察了铸带的组织、织构及析出物,同时对比了Al的质量分数为0.6%和0.9%的连铸薄带在组织、织构及析出物特征方面的异同.结果表明:双辊连铸工艺生产的3%Si无取向硅钢铸带的组织为均匀等轴晶粒,平均晶粒尺寸约为300μm;织构组成随Al质量分数的不同具有明显差别,Al质量分数为0.9%的铸带中{100}织构强度是随机织构的7倍;铸带中的析出物为AlN和MnS,最大尺寸分别为500和50 nm左右. Given the lengthy production cycle,high energy consumption,and other shortcomings of the traditional process for producing silicon steel,a twin-roll casting process was used to produce 3%Si non-oriented silicon steel casting strips. MEM,SEM,and TEM were used to compare micro-structure,texture,and precipitate characteristics of a casting strip containing 0.6%Al with another containing 0.9%Al.The structure of 3%Si non-oriented silicon steel produced by the twin-roll casting process was a uniform i... 

叠片系数是冷轧无取向电工钢的重要质量指标。为了提高叠片系数,必须保证无取向电工钢板形良好以及横向厚差小。针对攀钢冷轧厂4机架HC轧机轧制无取向电工钢的边部减薄问题,以无取向电工钢横向厚差最小作为目标函数,建立了一套针对无取向电工钢边部减薄控制的辊型曲线优化数学模型,开发了无取向电工钢专用辊型曲线,使无取向电工钢横向厚差从25μm降低到10μm以下,取得了良好的控制效果。 The lamination factor is an important quality index of non-oriented silicon steel strip.Considering the lamination factor,the non-oriented silicon steel must have a good shape and a smaller transverse thickness difference.In order to solve the edge thinning of non-oriented silicon steel strip in Panzhihua Steel,a mathematic model for designing the roll shape is built.In the model,the transverse thickness difference of non-oriented silicon steel strip is taken as the objective function.Based on t... 

用还原分离-原子荧光光谱法分析了硅钢中的痕量汞.分析方法的不确定度主要来自测量重复性,样品溶液浓度,工作曲线变动性,标准溶液,移取、配制标准溶液,仪器变动性等.文章分别对上述构成合成不确定度大小的分量进行了计算讨论. Trace mercury in silicon steel and galvanized sheet was analyzed by adopting reduced separation-atomic fluorescence spectrometry.The uncertainty of the analysis method mainly comes from measurement repeatability,sample concentration,working curve volatility,standard solution,pipetting and preparation of standard solution,and instrument variability,etc.The essay conducted all calculations and discussions on the above components that determine uncertainty. 

通过试验确定氩气分析流量为3.5L/min,静态流量为0.75L/min,冲洗时间为3s,预燃时间为12s,积分时间为5s的激发条件,采用火花源原子发射光谱法测定取向硅钢中碳、硅、锰、磷、硫。分别采用铣床铣样、砂轮磨样两种制样方式进行了精密度考察,发现制样方式对结果影响不大;讨论了取向硅钢样品中碳、硅、锰、磷、硫测定时可能存在的共存元素干扰,发现硅对锰元素的干扰不可忽略,采用干扰系数法进行了校正,据此拟合得到各元素校准曲线的相关系数均在0.999 0以上。精密度考察结果表明,碳、硅、锰、磷、硫的相对标准偏差(n=10)在0.71%~9.4%之间。对两块取向硅钢生产样品进行分析,并与钢铁研究总院进行比对分析,结果一致,且偏差均在允许范围内。 Carbon,silicon,manganese,phosphorus and sulfur in oriented silicon steel were determined by spark source atomic emission spectrometry.The selected excitation conditions were as follows:the analytical flow rate of argon was 3.5L/min,the static flow rate was 0.75L/min,the flush time was3s,the precombustion time was 12sand the integration time was 5s.Two sample preparation methods,including milling machine and grinding wheel,were investigated.The precision test results showed that,the determination... 

针对硅钢连续退火机组的主要能源介质消耗现状,对现有生产工艺和设备研究采取机组循环用水、增加清洗段漂洗级数等措施可节约大概27 m3/h的过滤水量,并可减少78%的弱碱处理量;将炉子烟气换热系统增加一级余热回收,每年回收的余热相当于583 t标煤消耗,可节约蒸汽5 368 t。 The present situation of energy consumption for silicon steel annealing line is analyzed in this paper.In existing process and equipment conditions,increasing the number of cleaning series will lead to a saving of about 27 m3/h of filter water and reduce 78 % of weak base processing volume.For the flue gas heat-exchange system,adding a waste heat recovery device will recover waste heat equivalent to 583 tons of standard coal per year,corresponding to a saving of steam 5 368 t per year. 

研究了常化温度、常化时间及常化后冷却速度对Si的质量分数为1.6%的无取向电工钢成品磁性能的影响。结果表明:在850~1 050℃范围内,随着常化温度的升高,成品铁损先减小后增大,成品磁感应强度先增大后减小;当常化温度为1 000℃时,成品平均铁损最低,平均磁感应强度最高;常化时间从3min延长到7min时,成品铁损先减小后增大,成品磁感应强度则呈单调下降趋势;随着常化冷却速度的降低,成品铁损先减小后增大,成品磁感应强度则呈单调增大趋势;对于Si的质量分数为1.6%的无取向电工钢,最佳的常化制度为:在1 000℃进行常化,时间5min,常化后空冷。对热轧板进行常化后,热轧板发生了不同程度的再结晶和晶粒长大。提高常化温度、延长常化时间、降低冷却速度,都能使常化板晶粒粗化,进而粗化成品板晶粒,改善磁性能。通过扫描电镜观察发现,成品板中析出物主要为AlN和MnS的复合析出物,以及少量的单独析出的AlN和MnS,而常化工艺主要是通过粗化析出相,减少细小析出相数量,从而减少对晶界钉扎作用来改善成品磁性能。 The effects of normalizing temperature,normalizing time and cooling rate after normalizing on magnetic properties of non-oriented electrical steel with mass fraction of Si of 1.6% were investigated.The results show that core loss of product decreases first and then increases,while magnetic induction increases first and then decreases with the increase of normalizing temperature from 850 to 1 050℃.Average core loss of product is the lowest and average magnetic induction is the highest when normal... 

主要研究了0.7%Si无取向电工钢退火试样的组织、晶粒尺寸和织构对其磁性能的影响。结果表明,随着退火温度的升高,晶粒尺寸逐渐增大,组织的均匀性得到改善;ɑ取向线上的纤维织构多集中于{114}<110>和{223}<110>附近,再结晶结束后,织构含量变化不大。{111}<110>织构取向密度值随温度升高而下降,{112}<111>织构与{111}<110>织构变化相反。晶粒尺寸增大对磁感强度的影响较小,而对铁损的影响较大。 Influences of microstructure,grain size and texture on the magnetic properties of 0.7% Si non-oriented electrical steels annealed samples were studied.The results show that with annealing temperature increasing the average grain size is increased gradually.Uniformity of the microstructure is improved;the textures of ɑ-fiber gathered in the vicinity of the { 114} < 110 > and { 223 } < 110 > texture.After recrystallization,the volume fraction of texture changes small.{ 111} < 110 &g... 

电工钢反复弯曲次数是电工钢性能检验的重要指标之一,直接影响到用户在使用电工钢过程的机加工性能。主要分析了试样宽度、试样张力、晶粒取向、反复弯曲设备等因素对电工钢反复弯曲试验的影响,并对各个因素的影响程度进行量化以及原因探讨,从而归纳形成各影响因素的基本规律,以便为电工钢实际生产、用户使用提供科学指导。结果表明:试样宽度增加,反复弯曲次数也会不断增加,晶粒位向对取向电工钢的反复弯曲次数影响较大,当支座顶部到拨杆底部的距离减小或拉紧力增加时,反复弯曲次数会不断减小,但当拉紧力达到60N以上时,对反复弯曲次数影响不大,试样经退火后,反复弯曲次数略有上升。 The reverse bend number is an important performance of electrical steels′capabilities,affecting the machining performance directly when the customers used.It investigated some factors,such as sample′s width,sample′s tension load,grain orientation and equipment,how to effect the reverse bend test for electrical steel,measured the influence degree,and discussed the reason,in order to form basic rules which could be guided the manufacturing and using for electrical steel.Results showed that the rev...