硅钢资料

6.5%(质量分数)Si高硅钢具有优异的软磁性能和广阔的应用前景,然而其室温脆性和低的热加工性极大地制约了它的发展。近年来,人们对高硅钢制备技术的研究已经取得了很大的进展,如何通过织构的优化提高高硅钢的磁性能越来越受到人们的关注,归纳和总结了不同工艺制备的高硅钢中的织构演变规律和特点,以及对应的典型磁性能。 6.5wt% Si high silicon steel has excellent soft magnetic properties and wide application prospect.However,the brittleness of room-temperature and poor workability of cold rolling limit its deve-lopment.Recently,the researches of the preparations of high silicon steel have been already made great breakthroughs,and then,more and more attentions are focused on how to optimizing the texture of high silicon steel so as to obtain the best magnetic properties.The evolution of textures of 6.5% Si high s... 

对CSP流程生产的无取向电工钢M50W800不同尺寸样品的磁性能进行了测试和分析,结果表明:采用不同单片检测的磁性能结果与标准的Epstein方圈样品检测对比,存在明显的偏差;且同一尺寸的单片纵横向样品之间相比较,对应的磁性能差异性也较大。几种不同尺寸的单片样品,以320mm×30mm尺寸的纵横向平均值最接近标准Epstein方圈样的性能值,其铁损偏差最小。 The magnetic properties of M50W800 non-oriented electrical steel produced by CSP process were tested and analyzed with samples of different sizes,showing that significant deviation existed compared to that of Epstein square circle sample.In particular,obvious difference in magnetic properties also existed between longitudinal and transverse samples of the same size.For test samples of different sizes,the average magnetic properties of 320mm×30mm samples are the closest to that of Epstein square ... 

利用EBSD技术对CGO硅钢热轧、中间退火、脱碳退火及二次再结晶退火组织及织构进行分析,研究了CGO硅钢各阶段加工制备过程中高斯{110}<001>晶粒的形状、尺寸及分布特点,分析了高斯取向晶粒在各工序过程中的遗传继承性特点。结果表明,CGO硅钢热轧板的次表层存在Goss取向晶粒,历经一次冷轧及中间退火后Goss取向晶粒基本消失,一次再结晶之后Goss织构仍不是主要织构,主要织构为{111}<110>和{111}<112>,说明Goss取向晶粒在二次再结晶退火前数量及尺寸上并不占优势,二次再结晶过程中Goss取向晶粒异常长大形成锋锐Goss织构。{111}<110>和{111}<112>织构组分的强度在一次冷轧中不断增加,{111}<112>织构组分的强度在二次冷轧后达到最大而{111}<110>织构组分是在初次再结晶后变强。 Grain shape,size and distribution of { 110} < 001 > Goss grains in CGO steel and the hereditary characteristics of Goss orientated grains during each processing period were investigated,based on the analysis of the microstructure and texture of the CGO silicon steel during hot rolling,intermediate annealing,decarburizing annealing and secondary recrystallization annealing by means of EBSD. The results show that Goss orientated grains exist in the subsurface of the hot rolled plate,and Goss... 

采用经验设计法初步确定了取向硅钢铸坯感应加热线圈设计参数,应用Ansoft仿真软件分别对36组不同线圈高度、线圈内径的感应加热炉在不同频率下的三维整体磁场和铸坯的温度场进行了数值仿真。通过对比仿真结果,确定电磁场分布最佳的一组感应加热炉设计参数为线圈高度h=1.50 m、线圈内径D1=0.575 m、电流频率f=110 Hz。在该参数下应用Ansoft仿真软件对取向硅钢铸坯感应加热炉的温度场进行了仿真,结果发现温度场分布均匀,可满足取向硅钢铸坯加热要求。 The induction heating coil design parameters for the oriented silicon steel casting blank were determined preliminary by experience design method,and 36 groups three-dimensional electromagnetic field with different height and inside diameter of coil under different frequencies of the induction heating furnace and the temperature field of the casting blank were investigated by numerical simulation using Ansoft simulation software. By comparing the simulation results of electromagnetic field distr... 

结合扫描电镜和大样电解研究了CSP流程W800牌号无取向电工钢表面线状缺陷中夹杂物成分及来源，采用SPSS软件回归分析了生产过程各因素对表面线状缺陷的影响。研究表明：稳态浇铸过程铸坯中大型夹杂物含量为5.39 mg/10 kg。引起无取向电工钢表面线状缺陷的大型夹杂物主要为脱氧产物、镁铝尖晶石和钢包顶渣，主要类型为Al₂O₃、MgO-Al₂O₃、CaO-Al₂O₃-MgO和CaO-Al₂O₃-SiO₂。非稳态浇铸过程钢水洁净度明显降低，热轧板表面线状缺陷比例上升。影响表面线状缺陷的主要因素为RH出站时顶渣的w（CaO）/w（Al₂O₃）、RH脱氧结束氧位及中间包最低吨位。 Combining scanning electron microscopy and large sample electrolysis, the composition and source of inclusions in the surface linear defects of W800 grade non-oriented electrical steel in the CSP process were studied. SPSS software was used to regress and analyze the main factors which affected the surface linear defects in the steelmaking process. Research shows that the content of large inclusions in the steady state casting process is 5.39 mg/10 kg. The large inclusions which cause linear def... 

采用固溶强化、细晶强化和位错强化方法,模拟TSCR流程试开发高强度无取向电工钢,试开发钢的主要合金成分为3%Si、0.83%Al和2.99%Mn。分析热轧、常化、退火后的钢板组织,并针对不同的成品板组织,详尽地分析了相应的力学性能和磁性能。试验电工钢平均晶粒直径为12.37μm时,R p0.2为530 MPa,R m为618 MPa;当退火制度为700℃×4 min,成品组织完全为未再结晶的回复组织时,R p0.2为853.5 MPa,R m为895.5 MPa。该成分的电工钢P15/50或P10/400最小时,对应的平均晶粒直径都大于59.67μm;P10/800或P10/1000最小时,对应的平均晶粒直径都处于12.37~59.67μm尺寸区间。 TSCR was simulated to develop high-strength non-oriented electrical steel with 3% of Si,0.83% of Al and 2.99% of Mn by solution strengthening,grain refinement strengthening and dislocation strengthening.The microstructures of hot rolled plates,normalized plates and annealed plates were analyzed.Furthermore,the mechanical properties and magnetic properties of products with different microstructures were detailedly studied.As the average grain diameter of the steel was 12.37 μm,the yield strength ... 

研究了含铜低碳低硅无取向电工钢中的析出相及其析出机理.由能谱(EDS)及选区电子衍射(SAED)分析可知,铁素体基体上存在的大量弥散分布的等轴状析出相为类B2结构的铜.这些铜析出相的析出机理可以是一般析出、位错析出、台阶机理相间析出和弓出机理相间析出:一般析出在550、650和750℃三个等温温度均可发生;位错析出只发生在较低的等温温度(550℃),此时析出相呈特殊的平行短列状;台阶机理相间析出也可在上述三个等温温度下发生,但650℃等温时最有利于台阶机理相间析出,此时析出相平直列状分布;弓出机理相间析出只发生在较高的等温温度(750℃),析出相弯曲列状分布. Precipitates in low-carbon low-silicon non-oriented electrical steel containing Cu were studied and the precipitation mechanism was analyzed by means of energy dispersive spectrometry(EDS) and selected area electron diffraction(SAED).It is found that the equiaxed precipitates of Cu with B2-like structure distribute dispersively in the non-oriented electrical steel.The precipitation mechanism involves general precipitation,dislocation precipitation,interphase precipitations formed by the ledge me... 

组织和织构是影响无取向硅钢性能的重要因素。为改善产品性能，研究了冷轧压下率（71.7%～87.0%）对高牌号无取向硅钢组织、织构、磁性能和力学性能的影响。结果表明，随冷轧压下率的增加，退火晶粒平均尺寸先减小后增大；高斯和立方织构强度减弱，γ纤维织构增强，α纤维织构转变为较强的α^*（{h, 1, 1}〈1/h, 1, 2〉）织构，并随冷轧压下率的增加而增强，同时其峰值逐渐向{111}面移动；工频铁损P_1.5/50、高频铁损P_1.0/400和磁极化强度J₅₀₀₀同时降低，屈服强度变化不大，表面硬度逐渐增加。当冷轧压下率由84.7%增至87.0%、厚度减至0.30 mm时，高频铁损降幅是工频铁损的11倍，表面硬度增幅变大。以上研究成果对硅钢减薄后织构及组织的优化提供了很好的指导。 Microstructure and texture are critical factors on non-oriented silicon steel properties. In order to improve product properties, this paper studied the effect of cold rolling reduction rate（71.7%-87.0%） on microstructure, texture, magnetic properties and mechanical properties of high-grade non-oriented silicon steel. The results show that with the increase of cold rolling reduction rate, the average size of annealing grain decreases first and then increases. The intensity of Goss and λ fiber te... 

借助OM、激光共聚焦显微镜、质谱仪和电解萃取等设备和方法，研究了添加微量稀土La（质量分数0.001 1%）的取向硅钢在轧制前采用不同加热保温时间对抑制剂固溶行为的影响。结果表明：当稀土取向硅钢在1 250℃分别保温10、20、30 min后，试验钢晶粒尺寸随保温时间延长有先快后慢的长大趋势；三种抑制剂元素Mn、Cu和Al均发生固溶，保温时间对Mn和Cu两种元素的固溶影响明显，固溶量分别由69.8%和43.7%增加至84.2%和85.2%；随着保温时间的延长，稀土取向硅钢中抑制剂的小尺寸未溶物逐渐减少直至消失，较大尺寸未溶物（300～600 nm）逐渐转变为小尺寸未溶物逐步溶入基体中，数量减少且未溶物的类型由复杂逐渐转变为单一。 In this paper the solid solution behavior of the inhibitor under various holding time in 0.001 1 %La oriented silicon steel during reheating had been investigated by using OM, LM, methods of electrolytic extraction and mass spectrometer. The results showed that grain size of the test steel increased significantly with the holding time prolonging when the rare earth oriented silicon steel was heated to1 250 ℃ and held for 10, 20 min and 30 min respectively, and the growth trend slowed down after ... 

采用扫描电镜、原子力显微镜研究了铬酸镁半无机绝缘涂层的微观结构。结果表明,涂层厚度为数微米,涂层中的有机树脂乳液颗粒均匀分布在无机涂层的表面,从而保证了涂层具有良好的冲片性能。采用极化曲线研究了涂层的耐蚀性能,发现铬酸镁与铬酸锌绝缘涂层的耐蚀性能相当。 In this paper,the microstructure and anti-corrosion property of magnesium chromate coating on non-oriented silicon steel were studied.The microstructure was observed by SEM and AFM.The anti-corrosion properties were evaluated by polarization curves.The results show that the thickness of coating is several microns and the polymer particles were scattered on the surface of inorganic coating,which is the guarantee for lamination property.The corrosion resistance of the magnesium chromate film was e... 

针对薄板坯连铸连轧流程结合\"获得抑制剂法\"所制备的低温高磁感取向硅钢,通过热力学计算研究了AlN与MnS在连铸与均热过程中的析出规律与行为。计算结果表明,连铸过程中AlN在凝固后的高温α相中便可能析出,而MnS仅可能在凝固后的α+γ两相区内析出。钢中AlN与MnS在均热过程中均处于部分固溶与部分析出的状态。后续高温渗氮处理后初次晶粒的异常长大并不明显,表明渗氮处理前钢中固有抑制剂的数量相对充足。 The precipitation behavior of MnS and AlN in low-temperature high magnetic induction grain-oriented silicon steel produced by thin slab casting and rolling process with\"acquired inhibitor method\"during continuous casting and soaking was studied by thermodynamic calculation.The calculated results show that AlN is likely to precipitate in ferrite after solidification.However,MnS can precipitate only in the two phase region of ferrite and austenite.Meanwhile,MnS and AlN in the steel can not be comp... 

采用X射线衍射仪分析无取向硅钢冷轧织构和再结晶退火织构的演化,研究了热轧组织对无取向硅钢织构以及磁性能的影响。结果表明,具有均匀、粗大晶粒组织的热轧板,冷轧形成更多的剪切带,导致成品板形成高的高斯织构组分,并提高了{100}织构强度,降低了γ纤维织构,最终导致成品磁感应强度升高,铁损下降。 The texture evolution of non-oriented silicon steel during cold-rolling and recrystallization annealing was investigated by X-ray diffractometer.The effects of hot band microstructure on the texture and magnetic properties of non-oriented silicon steel were analyzed.The results show that more shear bands appear during cold rolling due to homogeneous coarse grain in hot band.So strong{110}<001> texture after recrystallization annealing forms.At the same time,the {100} texture components inc...