硅钢资料

测试了高强无取向电工钢的S-N曲线,并借助光学显微镜、扫描电子显微镜、透射电子显微镜分析了实验钢组织,疲劳断口形貌和位错结构。结果表明:室温条件下,频率为20Hz,应力比R为0.1,循环10~7周次时,实验钢的疲劳强度为360MPa,疲劳裂纹萌生于实验钢的次表面,裂纹萌生点附近有沿晶开裂现象,疲劳裂纹扩展区域有解理台阶与疲劳条纹,瞬间断裂区是韧性断裂,有大量韧窝。实验钢在循环应力作用下基体中产生了大量位错,并有驻留滑移带终止在晶界位置。 The S-N curve of a high strength non-oriented electrical steel was tested.The microstructure and fatigue fracture morphology and dislocation were analyzed by optical microscope,scanning electron microscope,transmission electron microscope.The results showed that:at room temperature and the frequency of 20 Hz and the stress ratio Rof 0.1,the fatigue strength of the experimental steel was 360 MPa when the cycle was 10~7 cycles.The fatigue crack initiation at the surface of the steel and the interg... 

利用光学显微镜、TEM和EBSD研究了退火温度对双辊连铸无取向硅钢再结晶组织的影响。结果表明,900℃退火后组织分布不均匀,有大量带状组织,平均晶粒尺寸29.5μm。提高退火温度,晶粒尺寸增大,组织均匀化程度增加,1050℃退火时,带状组织基本消失,平均晶粒尺寸42.2μm。 Effect of annealing temperature on recrystallization microstructure of non-oriented electrical steel produced by twin-roll casting process was investigated using OM,TEM and EBSD.The results show that the recrystallization microstructure is uneven because of many banded grains existing,average grain size is 29.5 μm.With annealing temperature increasing,the recrystallization grain size increases,microstructure becomes more homogeneous.When 1050 ℃ annealing,the banded structure almost disappear and... 

研究了含铜低碳低硅无取向电工钢中的析出相及其析出机理.由能谱(EDS)及选区电子衍射(SAED)分析可知,铁素体基体上存在的大量弥散分布的等轴状析出相为类B2结构的铜.这些铜析出相的析出机理可以是一般析出、位错析出、台阶机理相间析出和弓出机理相间析出:一般析出在550、650和750℃三个等温温度均可发生;位错析出只发生在较低的等温温度(550℃),此时析出相呈特殊的平行短列状;台阶机理相间析出也可在上述三个等温温度下发生,但650℃等温时最有利于台阶机理相间析出,此时析出相平直列状分布;弓出机理相间析出只发生在较高的等温温度(750℃),析出相弯曲列状分布. Precipitates in low-carbon low-silicon non-oriented electrical steel containing Cu were studied and the precipitation mechanism was analyzed by means of energy dispersive spectrometry(EDS) and selected area electron diffraction(SAED).It is found that the equiaxed precipitates of Cu with B2-like structure distribute dispersively in the non-oriented electrical steel.The precipitation mechanism involves general precipitation,dislocation precipitation,interphase precipitations formed by the ledge me... 

对3层高硅电工钢复合板铸坯进行热轧及温轧变形加工后，采用正火、退火两种热处理方式处理，并观察轧制过程中产生的裂纹，研究不同状态下复合板的磁性能。对不同状态下的试样进行扩散退火处理，研究复合板中裂纹变化及其对磁性能的影响。结果表明：不同热处理工艺下合金内部的裂纹尺寸差异明显，裂纹尺寸对复合板的磁性能影响显著，相对于深裂纹，其他因素的影响较小；温轧变形加工后，复合板内层出现有序组织，但该有序组织在合金存在深裂纹的前提下并不能从本质上提高合金的磁性能；扩散退火工艺可以消除复合板内部的浅裂纹及微裂纹，但不能消除尺寸较大的裂纹，故而不能显著提高存在深裂纹的复合板的磁性能。 After hot rolling and warm rolling deformation processing of casting billet for three-layer high silicon electrical steel composite plate, it was normalized and annealed for heat treatment. Then, the cracks produced during the rolling process were observed, and the magnetic properties of composite plate in different states were also investigated. Furthermore, the samples in different states were subjected to diffusion annealing treatment, and the changes of crack in composite plate and their eff... 

针对不同牌号的无取向硅钢产生结疤缺陷的难易程度和表面结疤缺陷的外形特征及分布规律,分析了该缺陷产生的原因。通过调整剪前导板的对中度,设置精轧侧导板开度余量及短行程数值,及时修补与更换侧导板,减少带坯与侧导板挤撞程度,有效地降低了结疤缺陷发生率。 This article analyses the cause of the scab defects according to the defects appearance characters and distribution law,degree of difficulty to form scar of non-oriented silicon steel. It can effectively decrease the scabs by different methods,such as adjusting the center line of guide plate,setting the opening margin and short stroke value of the side guide on finishing mill,timely repairing and replacing of side guide,decreasing the collision between the strip and side guide. 

利用DSC、XRD,结合热焓分析对硅钢级氧化镁和二氧化硅的固相反应行为进行了研究。比较了不同二氧化硅原料及混合方法对硅钢级氧化镁反应性的影响,找到了一种更为有效的硅钢级氧化镁反应性的评估方法,克服了传统柠檬酸活性法在比较不同厂家生产的氧化镁的反应性上的局限性。进一步研究了Na₂B₄O₇添加剂、TiO₂添加剂对氧化镁和二氧化硅反应行为的影响,结果表明,Na₂B₄O₇添加剂含量的增加对反应有利,而TiO₂添加剂对反应有阻碍作用。 The solid-state reaction behavior between silicon-steel grade MgO and SiO₂ was investigated by DSC and XRD combined with enthalpimetric analysis.The influence of different kinds of SiO₂ and different preparation methods were studied and a specifical measurement that is more reliable was proposed to evaluate reactivity of silicon steel grade MgO.It overcomes the limitation of the traditional citric acid activity（CAA） method,which can not be used to evaluate the reactivity of... 

研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%～100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters... 

针对硅钢连续退火机组的主要能源介质消耗现状,对现有生产工艺和设备研究采取机组循环用水、增加清洗段漂洗级数等措施可节约大概27 m3/h的过滤水量,并可减少78%的弱碱处理量;将炉子烟气换热系统增加一级余热回收,每年回收的余热相当于583 t标煤消耗,可节约蒸汽5 368 t。 The present situation of energy consumption for silicon steel annealing line is analyzed in this paper.In existing process and equipment conditions,increasing the number of cleaning series will lead to a saving of about 27 m3/h of filter water and reduce 78 % of weak base processing volume.For the flue gas heat-exchange system,adding a waste heat recovery device will recover waste heat equivalent to 583 tons of standard coal per year,corresponding to a saving of steam 5 368 t per year. 

针对攀枝花钢钒有限公司难以稳定生产w(S)≤0.006%高级别电工钢的问题,通过开发RH脱硫剂、钢包渣改性及工艺参数控制,形成了RH脱硫系统工艺技术。经工业试验表明,采用该工艺技术后,钢水脱硫率最高达到42%,成品w(S)控制在0.005%以下,全氧、氮含量也得到了较好的控制,且脱硫剂没有引起钢水增碳,满足高级别电工钢的生产要求。 In light of the difficulty of production of high level electrical steel w(S)≤0.006 % steadily in Panzhihua steel & vanadium Co.,Ltd.the process technology of RH desulfurization system has been formed by developing the RH desulfurizer,modifying the ladle slag and controlling the process parameters.Industrial experiments show that the desulfurization rate of hot metal rises to 42 % and the w(S) of the finished products is controlled in below 0.005 % and total oxygen and nitrogen contents are a... 

为提高无取向硅钢导磁性能,研究了不同剪切方式对无取向硅钢剪切处磁畴结构的影响。利用纳米磁流体观测无取向硅钢剪切后边部磁畴结构。结果表明,硅钢无论在机械剪切还是线切割后的边部磁畴都会发生不同程度的改变:线切割对边部磁畴结构改变较小,边部磁畴分布均匀且连续,在距边缘0～20μm范围内出现磁畴宽度变小现象;机械剪切对磁畴的改变较为严重,剪切处磁畴零乱且不连续,在距边缘20μm处仍难以观察到完整的磁畴结构。 The effects of different shearing modes on magnetic domain structure of cold rolled non-oriented silicon steel are studied in this paper.The magnetic domain of cold rolled non-oriented silicon steel is observed by nanometer magnetic fluid pattern method.The results show that the edge magnetic domain structure will be changed by mechanical shear and wire-electrode cutting,the variation of edge magnetic domain structure wire-electrode cutting edge is very small,the magnetic domain structure is wel... 

通过对激光粒度分析仪测量硅钢级氧化镁(MgO)的分析条件进行优化,如分散介质、分散方式、样品预处理、仪器暗淡度等,探讨了硅钢级MgO粒度范围测量重现性较好的试验方法,满足硅钢生产过程控制对MgO粒度的要求。 The analysis condition of the laser particle size analyzer on grain oriented silicon-steel grade magnesium oxide is optimized,including the dispersion medium,dispersion methods,sample preparation,and instrument obscuration,etc.Therefore,particle size measurement with good reproducibility for silicon-steel magnesium oxide is discussed,which may meet the requirement of MgO particle size for silicon-steel process control. 

阐述了电工钢在\"双碳\"中的作用,强调了电工钢的生产工艺技术及在减少碳排放、降低能耗中的作用,对下游能效升级带来明显的节能及降碳成果。同时,分析了2021年电工钢的生产运行情况,介绍了电工钢的未来发展,并针对如何减少碳排放以及生产更多的更低铁损、更高磁感的电工钢谈了几点启示。 The effects of electrical steels on carbon peak and carbon neutralization were expounded,especially on the achievements of obvious energy saving and carbon reduction to the downstream energy efficiency upgrading bringing from the production technology of electrical steels and their effects to reducing carbon emission and energy consumption.Meanwhile the production situation of electrical steels in 2021 was analyzed,and the future development of electrical steels was introduced,and some advices w...