硅钢资料

对1990~2010年在我国申请的冷轧无取向硅钢涂层的专利数量、专利技术领域分布进行了统计,对典型涂层专利技术进行了分析,探讨了无取向硅钢涂层的发展趋势。统计分析结果表明,目前无取向硅钢涂层典型的专利技术主要有自粘结涂层、无铬含稀土元素涂层、含钼酸盐环保涂层及采用有机-无机纳米杂化材料为主成膜物形成的涂层等。无取向硅钢涂层发展的趋势主要是无铬环保的半无机、半有机型涂层。 The patent quantity of cold-rolled non-oriented silicon steel coating and distribution of technology fields applied in China in 1990-2010 were summarized.The analysis results indicate that typical patent technologies include self-adhesion coating,chromium-free and with rare earth element coating,environment-friendly and with molybdate coating,coatings with organic-inorganic hybrid materials as main forming agent and so on.The main development trends of coatings on silicon steel are among semi-in... 

针对硅钢连续退火机组的主要能源介质消耗现状,对现有生产工艺和设备研究采取机组循环用水、增加清洗段漂洗级数等措施可节约大概27 m3/h的过滤水量,并可减少78%的弱碱处理量;将炉子烟气换热系统增加一级余热回收,每年回收的余热相当于583 t标煤消耗,可节约蒸汽5 368 t。 The present situation of energy consumption for silicon steel annealing line is analyzed in this paper.In existing process and equipment conditions,increasing the number of cleaning series will lead to a saving of about 27 m3/h of filter water and reduce 78 % of weak base processing volume.For the flue gas heat-exchange system,adding a waste heat recovery device will recover waste heat equivalent to 583 tons of standard coal per year,corresponding to a saving of steam 5 368 t per year. 

【作者】 胡志强； 张文康； ...

对取向硅钢熔融态钢液进行处理,对比研究了不同脉冲参数的作用效果。结果表明,电脉冲对钢锭晶粒组织具有明显的细化作用,凝固组织等轴晶比例大幅上升。在脉冲电容、频率、处理时间和电压中,影响等轴晶比例的最显著性因素为脉冲频率;最优正交实验参数为:电容1 200μF,脉冲频率1 Hz,处理时间5 s,脉冲电压800 V;随着输入能量的增大,等轴晶率先增大后减小,脉冲输入能量为某值时,等轴晶率最大,通过经典形核理论和热力学对这一现象进行了解释。 Research on the influence of the electric pulse on the solidification structure of oriented silicon steel was preformed.Electric pulses in different parameters were applied to molten steel and results were compared.The result shows that solidification structure of oriented silicon steel can be improved by the electric pulse,and the equiaxed crystal ratio increases obviously.Among the four parameter factors of electric capacity,frequency,applied time and voltage,the most effective factor is frequ... 

将Fe-1.5Si硅钢试样分别在1 000~1 200℃空气条件下氧化30 min,观察发现在1 000℃和1 100℃时,氧化层与基体界面处存在硅酸亚铁,而当温度为1 200℃时,硅酸亚铁不但存在于界面处,同时也存在于氧化层中.将各温度下得到的带有氧化层的试样进行单道次热轧试验,压下率分别为10%和30%,发现1 000℃和1 100℃时,较高的压下率使氧化层破碎更加严重,但是单道次热轧未能改变氧化层的结构;当温度为1 200℃时,由于液态的硅酸亚铁的出现,单道次热轧能够将界面处的液化的硅酸亚铁层挤压到氧化层中,消除了硅酸亚铁层的钉扎基体的效应,改善了氧化层与基体界面的平直度. Specimens of Fe-1.5Si silicon steel were oxidized at 1 000 ~ 1 200 ℃ in air for 30 min.At 1 000 ℃ and 1 100 ℃ fayalite was observed at the scale/substrate interface.While at 1 200 ℃fayalite was found both at the scale/substrate interface and at the outer oxide layer.Then after the single-pass hot rolling process,with the compression ratio of 10% and 30%,it was found that at 1000 ℃ and 1 100 ℃,higher compression rate accelerated the broken of the scale layers,but the scale structure was not affec... 

通过在实验室条件下模拟薄板坯连铸连轧流程,并在以Cu2S为主抑制剂制造普通取向硅钢(CGO)的基础上,加入适量钒钛,研究了钒钛对取向硅钢组织与磁性能的影响。结果表明,适量钒钛使热轧板和脱碳退火板组织更好,尤其使脱碳退火板的晶粒更加细小和均匀;加入适量钒钛不但使热轧板表面高斯织构强度更高,更使脱碳退火板中有利于高斯织构发展的γ织构强度更高;适量钒钛能形成Cu2S+(V,Ti)N等复合析出物,起到辅助抑制剂作用,加强抑制能力。细小均匀的晶粒、强度更高的有利织构和更强的抑制能力使CGO钢磁性能更佳。 Effect of V and Ti on microstructure and magnetic properties of conventional grain-oriented silicon steel(CGO) were investigated under simulated thin slab continuous casting and rolling process in laboratory with Cu2 S as the dominant inhibitor. The results show that appropriate amount V and Ti make the microstructures of the hot rolled sheet and the decarburizing annealed sheet better,especially make the grains of the decarburizing annealed sheet more tiny and uniform. Adding appropriate V and ... 

针对不同牌号的无取向硅钢产生结疤缺陷的难易程度和表面结疤缺陷的外形特征及分布规律,分析了该缺陷产生的原因。通过调整剪前导板的对中度,设置精轧侧导板开度余量及短行程数值,及时修补与更换侧导板,减少带坯与侧导板挤撞程度,有效地降低了结疤缺陷发生率。 This article analyses the cause of the scab defects according to the defects appearance characters and distribution law,degree of difficulty to form scar of non-oriented silicon steel. It can effectively decrease the scabs by different methods,such as adjusting the center line of guide plate,setting the opening margin and short stroke value of the side guide on finishing mill,timely repairing and replacing of side guide,decreasing the collision between the strip and side guide. 

【作者】 陶永根； ...

概述了无抑制剂法生产取向电工钢的特性及其用途;总结无抑制剂生产取向电工钢的原理及工艺方案.重点讨论了成分方案,即元素对磁性能的影响和最终高温退火方案对二次再结晶的影响.研究结果表明,无抑制剂取向硅钢化学成分范围没有普通取向硅钢和高磁感取向硅钢严格,提高了成材率;最终高温退火决定了二次再结晶的好坏,从而最终决定成品磁性能,最佳的高温退火温度在850～950℃之间. This article provides an overview on the characteristics and uses of inhibitorless process producing grain-oriented electrical steels.The mechanism of inhibitorless process and technology programs were discussed.The results show that the chemical composition and final annealing were determined according to magnetic properties.The inhibitor-free grain oriented silicon steel has loose range of chemical composition;Secondary recrystallization occurs mainly in the final annealing and the best anneal... 

简述了无取向硅钢环保涂层发展背景,分析了硅钢环保涂层的特点及国内、外研究进展,提出了硅钢保涂层下一步的发展方向。 The back ground of environmental protection coating of non-oriented silicon steel was described in this paper.The characteristics and study progress in domestic and foreign of environmental protection coating of non-oriented silicon steel were analysised.The next development direction of environmental protection coating of non-oriented silicon steel was put forward. 

研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%～100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters... 

晶界和{100}柱状晶在硅钢生产过程中对织构的遗传和演变有关键作用,因此本文利用晶体塑性有限元方法进行立方和旋转立方取向双晶在晶界不同位向时晶体取向演变的全场模拟。模拟显示,三种晶界位向下,晶界都具有诱发晶内产生S形状形变不均匀和缓解局部形变不均匀区取向转动的特点,立方和旋转立方取向双晶在带有剪切作用的轧制条件下都显示明显的取向稳定性。GB⊥RD(表示晶界垂直于轧向)晶界位向时,旋转立方取向晶粒优先在晶界中心位置发生取向转动,而立方取向则优先在远离晶界的端部发生取向转动。GB⊥TD(表示晶界垂直于横向)的晶界位向下,其晶界阻碍作用最小,双晶内产生的取向漫散度大,织构强度较低;除绕TD转动外,也具有复杂的绕RD、ND的取向转动。GB⊥ND(表示晶界垂直于法向)的晶界位向下,取向转动与GB⊥RD时相近,但有少量取向绕ND转动。 Grain boundaries and initial{100}columnar grains play a key role in the inheritance and evolution of texture in the production of electrical steels.In this paper,the crystal plasticity finite element method was used to simulate the grain orientation evolution of cube and rotated-cube oriented bicrystals when grain boundary was set to different orientations.It was shown that the grain boundary in three grain boundary orientations demonstrated the characteristics of inducing Sshape deformation inh...