硅钢资料

硅钢工业退火炉温度控制具有强耦合、纯滞后、多扰动等特点,它的控制方法代表着一类非线性系统控制的解决方法。以硅钢工业退火炉温度为控制对象,在双交叉限幅控制的基础上引入了智能学习系统,形成了基于智能学习系统的双交叉限幅控制方法来解决此类非线性系统的控制问题,并通过模块化的编程来实现其功能。结果表明:与传统的PID控制相比,该控制方法的控制精度、抗扰性等控制指标有明显提高,是解决此类非线性控制的一种有效方法。 The temperature control of silicon steel industrial annealing furnace has the features of strong coupling,pure lag,multidisturbance. The control method represents the solution of a class of nonlinear control systems. The control object is the temperature control of silicon steel industrial an-nealing furnace, the intelligent learning system based on Double Across Limit Control is introducedand used to solve control problem of this kind of nonlinear system, and the module programming isused to re... 

【作者】 凌健； ...

以青海盐湖水氯镁石为初级原料,采用喷雾热解法制备原料氧化镁,原料氧化镁通过水化制备硅钢级氧化镁前驱体氢氧化镁。原料氧化镁水化实验中对水化剂、水化温度、水化时间、液固比、搅拌速度及陈化时间对水化率、过滤速度和纯度的影响进行系统研究。采用均匀实验设计和DPS数据处理,(依次)通过建模分析、二次多项式模型回归建立数学模型,再通过各因素方差分析和总方差分析,确定了理论最优实验条件,再用理论最优条件作重复实验进行验证,最终确定了原料氧化镁的最佳水化条件。在水化温度60℃,水化时间105 min,液固比4,陈化时间4 h,水化剂1含量4.0%,水化剂2含量3.15%,洗水量4倍,搅拌速度120 r/min时,原料氧化镁的水化率达99.50%以上,得到的硅钢级氧化镁前驱体氢氧化镁纯度高、过滤性能良好。 By spray pyrolysis method,bischofite in Qinghai salt Lake,as primary raw material,was used to prepare precursor raw material MgO for silicon-steel MgO.The precursor raw material MgO was used for preparing Mg(OH)2 which was the precursor of silicon-steel MgO,by hydration method.In the hydration experiment of precursor raw material MgO,some experiment parameters were investigated systematically.such as the hydrated agent,the temperature and time of hydration,liquid/solid ratio that affected the hy... 

采用轧制法制备出具有低铁损高磁感0.23mm厚6.4%(质量分数)Si高硅钢。沿轧制方向的最终磁性能为B8=1.474 T,B50=1.714 T;P10/50=0.30W/kg,P15/50=0.88W/kg。利用X射线衍射及背散射电子衍射(EBSD)技术分析了高硅钢在轧制及退火过程中的织构演变过程。结果表明,通过采用大压下率热轧,确保热轧板次表层中产生更多的高斯织构,随后进行遗传;温轧板中粗大的晶粒有利于冷轧剪切带的形成;冷轧板经脱碳退火后生成强{210}〈001〉织构及次表层较强的高斯织构是在轧向上获得高磁感的原因,归因于其在{111}〈112〉冷轧形变晶粒内的剪切带优先形核并长大;最终退火后虽出现了随机取向,但以{310}〈001〉织构为代表的η织构得以保留并且增强,进一步提高了磁感。随着退火温度的升高及保温时间的延长,高硅钢薄板晶粒尺寸不断增大,铁损明显降低。 6.4wt%Si high silicon steel sheets(0.23mm thick)with low iron loss and high magnetic induction were successfully produced by rolling process.The final magnetic properties along the rolling direction(RD) were:B8=1.474T,B50=1.714T;P10/50=0.30 W/kg,P15/50=0.88 W/kg.The texture evolution during rolling and annealing was investigated by means of X-ray diffraction and electron backscatter diffraction(EBSD).It was found that more Goss textures formed in the subsurface of hot rolled plates by using larg... 

试验研究了退火温度(850~950℃)和时间(5~18 min)对2.3 mm热轧硅钢板(/%:0.036C,3.15Si,0.21Mn,0.005P,0.007S,0.032A1)6道次轧制的0.35 mm冷轧板组织和织构的影响。结果表明,退火温度越高,晶粒平均尺寸越大,900℃5 min退火时平均晶粒尺寸41.39μm,试样织构主要集中在γ取向线上的{111}<112>织构组分和{111}<110>织构组分;900℃18 min退火时平均晶粒尺寸为48.08μm,试样的{111}面织构和{112}面织构密度都明显减弱,{001}面织构增强,磁性能较优。 The effect of annealing temperature(850 ~950 ℃) and holding time(5 ~ 18 min) on structure and texture of 0.35 mm sheet by 6 passes cold-rolling from 2.3 mm hot-rolled plate of silicon steel(/%:0.036 C,3.15 Si,0.21 Mn,0.005 P,0.007 S,0.032A1) has been tested and studied.Results show that the higher the annealing temperature the coarser the average grain size;As annealing at 900 ℃ for 5 min the average grain size of steel sheet is 41.39 μm,and the texture in sample is mainly concentrated in y orie... 

研究了硼酸对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响。用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同硼酸含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响,同时采用SEM对涂层的表面形貌进行了研究。结果表明,硼酸含量为9.7%时,涂层的耐盐雾性及电化学性能最好;硼酸含量过少或过多时,涂层的耐蚀性和电化学性能都较差。 Influence of boric acid on the performance of chromium-free non-oriented silicon steel insulating coating based on aluminum dihydrogen phosphate was investigated.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of boric acid content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.Surface morphologies of the coatings were tested by SEM.Result shows that when the boric ... 

以轻烧氧化镁粉为原料,经消化、碳化制得重镁水,在热解反应前采用络合剂对重镁水中的杂质钙、铁进行络合掩蔽,再经热解得到碱式碳酸镁,碱式碳酸镁经煅烧可制得钙、铁杂质含量较低的氧化镁。在重镁水络合除杂过程中,考察了络合剂三乙醇胺、柠檬酸、草酸单独和复合使用的除铁、除钙效果。以三乙醇胺为络合剂时,在200 mL重镁水中加10 mL三乙醇胺(1∶1),氧化镁产品中w(氧化镁)=99.3%、w(氧化钙)=0.31%、w(氧化铁)=0.042%;使用草酸和柠檬酸作为复合络合剂时,在200 mL重镁水中加入1.0 g柠檬酸和2.0 g草酸,氧化镁产品中w(氧化镁)=98.2%、w(氧化钙)=0.24%、w(氧化铁)=0.030%。 Light-burned magnesia as a raw material was hydrated and carbonated to obtain magnesium bicarbonate liquor.Before the pyrolyzing of magnesium bicarbonate liquor,complexants were used to cover Fe and Ca impurities.Then the treated liquid was pyrolyzed to obtain basic magnesium carbonate which was calcined to magnesium oxide with low calcium and iron content.During the complexing purification of magnesium bicarbonate liquor,the Fe and Ca removing effects of single or compound complexing agents,suc... 

电工钢反复弯曲次数是电工钢性能检验的重要指标之一,直接影响到用户在使用电工钢过程的机加工性能。主要分析了试样宽度、试样张力、晶粒取向、反复弯曲设备等因素对电工钢反复弯曲试验的影响,并对各个因素的影响程度进行量化以及原因探讨,从而归纳形成各影响因素的基本规律,以便为电工钢实际生产、用户使用提供科学指导。结果表明:试样宽度增加,反复弯曲次数也会不断增加,晶粒位向对取向电工钢的反复弯曲次数影响较大,当支座顶部到拨杆底部的距离减小或拉紧力增加时,反复弯曲次数会不断减小,但当拉紧力达到60N以上时,对反复弯曲次数影响不大,试样经退火后,反复弯曲次数略有上升。 The reverse bend number is an important performance of electrical steels′capabilities,affecting the machining performance directly when the customers used.It investigated some factors,such as sample′s width,sample′s tension load,grain orientation and equipment,how to effect the reverse bend test for electrical steel,measured the influence degree,and discussed the reason,in order to form basic rules which could be guided the manufacturing and using for electrical steel.Results showed that the rev... 

在实验室模拟CSP流程制备了不同含量稀土铈(质量分数0~0.018%)的1.2%Si无取向电工钢,并对其进行1 000℃×5min的再结晶退火处理,研究了铈质量分数对无取向电工钢夹杂物、显微组织、再结晶织构和磁性能的影响。结果表明:随着铈质量分数的增加,微细夹杂物数量、再结晶晶粒尺寸、{100}和{110}织构组分、磁感应强度先增后减,{111}织构组分、铁损先减后增;铈的质量分数为0.005 1%时,钢中的夹杂物数量最少,再结晶晶粒尺寸最大,有利织构最多,磁性能最优,铁损P15/50为3.253W·kg-1,磁感应强度B50为1.751T。 Non-oriented electrical steels containing different contents rare earth Ce element(0-0.018wt%) were prepared in the laboratory by simulated CSP(compact strip production)process,and then recrystallization annealing at 1 000 ℃ for 5 min were performed,the effects of Ce content on inclusion,microstructure, recrystallization texture and magnetic properties of non-oriented electrical steels were studied.The results show that with the increase of Ce content,the amounts of fine inclusion,the size of re... 

介绍了重庆钢铁股份有限公司炼钢厂生产低碳低硅钢的脱氧工艺,对连铸过程中水口结瘤的原因进行分析,并提出了优化措施。生产实践表明:钢水中的活性氧质量分数控制在10×10-6～30×10-6时,单中包浇铸炉数由6～7炉提高到11～12炉,同时能保证连铸顺行和减少铸坯气孔。 The deoxidation process of low-carbon and low-silicon steel in steel plant of Chongqing Steel was introduced.The nuzzle clogging was analyzed and some measures were put forward.Production experiments showed that when the active oxygen was controlled between 10×10-6～30×10-6,the amount of furnaces would rise from 6～7 to 11～12,which will make the casting process work well and reduce casting holes. 

针对节能电机对无取向电工钢在磁性能方面的特殊要求,采用普通W600牌号的热轧板为原料,通过大量的现场工艺试验,研究总结出了\"超低张力\"的运行工艺、\"先快后慢\"的加热工艺、\"先湿后干\"的退火脱碳工艺、\"先缓后急\"的冷却工艺,生产出P1.5/50≤4.0 W/kg、B50≥1.70 T的冷轧电工钢产品,满足了节能电机的要求。 Based on the special requirements of no-oriented electrical steel for saving energy motor in magnetic aspects,using common W600 brand of hot rolled plate as raw material,through a large number of real tests,an ultra-low tension process,heating process which was quick at first and then slow,annealing decarburization process which was dry after the first wet,and a cooling technology of \"slow after the first urgent\" were concluded.Electrical steel product with P1.5/50≤4.0W/kg,B50≥1.70T was produced... 

在实验室模拟CSP工艺条件下制备了取向硅钢,研究了二次冷轧中间退火工艺对组织和织构的影响。结果表明,中间退火温度对取向硅钢脱碳,高温退火组织及织构均产生明显影响。经940℃中间退火后,取向硅钢脱碳再结晶晶粒较850℃中间退火的多,且再经高温退火处理后,晶粒粗化,最大晶粒尺寸达4.8 mm;高斯织构组分密度达27.00,较850℃中间退火试样高。 Grain-oriented silicon steel was prepared by simulated CSP technology in laboratory. Effects of secondary cold-rolled intermediate annealing on microstructure and texture were studied. The results show that intermediate annealing has obvious effects on the microstructure and texture of the steels after decarburization annealing and high temperature annealing. After intermediate annealing at 940 ℃,recrystallized grain of decarburization annealed steel is more than that of intermediate annealed at...