硅钢资料

【作者】 凌健； ...

借助电子背散射衍射(EBSD)及ZEISS-200MAT金相显微镜对某钢厂普通取向硅钢(CGO)进行研究,研究结果表明:热轧板组织、织构沿板厚方向存在明显的不均匀性,在热轧板表层及次表层发生再结晶,同时存在强度较高的Goss织构,中心层存在较强的{001}<110>变形织构。冷轧组织均呈纤维状条带组织,一次冷轧后,热轧板中的Goss织构消失,织构主要为α、γ织构,经中间脱碳退火后,α、γ织构强度减弱,并出现一定强度的Goss织构和利于Goss织构发展的{554}<225>、{332}<113>等织构,经二次冷轧后,二次冷轧织构类型与一次冷轧织构一致,但织构强度不同。 The grain-oriented silicon steel produced by a steel factory was investigated by EBSD and ZEISS-200 MAT metallographic microscope.The results show that the textures and microstructures along thickness of hot rolled slab are inhomogeneous.The surface layer and the layer near that are recrystallized structure which has a high Goss texture,but there is deformation texture{001}<110>in the central layer.The structure after cold rolling is a structure like fiber strip.After the first cold rollin... 

通过对取向硅钢进行脉冲磁场退火实验,发现在相同的退火时间(6.0 min)内,低于1 T的脉冲磁场可以在一定程度上提高取向硅钢的磁感(B8),而高于1 T的脉冲磁场则会使取向硅钢的磁性能急剧恶化.同时发现,脉冲直流电加热方式会使取向硅钢的磁性能恶化.研究表明,脉冲磁场退火有望成为一种调控材料微观结构的有效手段. We have carried out experiments of annealing by pulse magnetic field.The results show that a pulse magnetic field with intensity lower than 1 T can promote magnetic induction density(B8) of grain-oriented silicon steel,while the magnetic properties deteriorate sharply when intensity is higher than 1 T.It has also been found that heating by using pulse direct current can cause the magnetic properties to deteriorate,in contrast to the traditional heating using resistance furnace.Our research shows... 

采用火花源原子发射光谱分析测定电工钢中超低C,研究试样制备方法、Ar纯度和压力等条件对分析结果的影响,并对工作曲线进行了优化,实现了一次分析同时测定电工钢的多种元素,满足炉前和精炼在线分析的要求。 Ultra-low carbon in electrical steel is determined with spark-source atom emission spectrum.It is researched the influence of sample making method,purity of Ar,and pressure on analysis result.The work curve is optimized.The determination of many elements in electrical steel only in one analysis is realized.It meets demands of on-line analysis for blast furnace and refining. 

本文介绍了无取向硅钢C6涂液的性能,研究了配水量、固化程度和涂层厚度等因素对无取向硅钢C6涂层性能的影响。结果表明,随着配水量的增加,完全固化所需的时间增加,涂液固体含量降低,涂层厚度减小;随着固化程度的提高,涂层硬度先增大然后趋于恒定,而柔韧性逐渐变差,在过固化后急剧恶化;涂层厚度对涂层的表面外观、附着性和绝缘层间电阻均有显著影响。 Based on the introduction about the performance of C6 varnish for non-oriented silicon steel sheets,effects of water amount,curing degree and coating thickness are discussed. Results show that with the increase of water amount,the time required to cure completely extends,and both the solid content of C6 varnish and the coating thickness decrease. As the curing degree increases,the hardness of the coating increases first and then tends to be constant,however the flexibility degenerates,especially... 

对硅钢板材分别进行异步和同步轧制,研究了轧制参数包括速比、压下量和道次对板材表面显微组织的演变的作用.结果表明,异步轧制硅钢板材表面形成了晶粒尺寸为10~50 nm,取向接近随机分布的纳米晶,而同步轧制板材的表面只形成了位错胞,证明异步轧制可以诱发表面纳米化.异步轧制板材表面纳米晶的形成过程为:在剪切力的反复作用下,高密度位错形成、滑移、湮灭和重组形成亚微米尺度的亚微晶/位错胞.随着压下量和轧制道次增加,高密度位错重复以上过程使晶粒尺寸减小、取向差增大,最终形成取向接近随机分布的纳米晶组织.大压下量和多道次是异步轧制诱发板材表面纳米化的关键,而速比的增加可以加快纳米化进程. Surface nanocrystallization(SNC) can effectively enhance the surface and global properties of the metallic materials,such as microhardness,intensity,fatigue,wear and corrosion resistances,therefore provides more promising practical industrial applicability.Up to now,several SNC treatment methods were developed based either on the principles of ball impactions or friction sliding,however,difficulty still exists for the surface treatment of large-dimensional samples with high efficiency.Recently,m... 

本文研究了丙烯酸树脂含量对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同树脂含量对硅钢绝缘涂层的耐盐雾性能和电化学行为的影响,同时采用SEM对涂层的表面形貌和附着性进行研究.结果表明,树脂含量为19.9~29.4%时,涂层的耐蚀性和附着性最好;树脂含量过多时,涂层的耐蚀性和附着性均较差. This paper studies the influence of acrylic resin on the performance of insulating coating of aluminum dihydrogen phosphate on chromium-free non-oriented silicon steel.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of acrylic resin content on the salt spray resistance and electrochemical behavior of the insulation coating of nonoriented silicon steel.The surface morphologys and adhesion of coating were tested by SEM.... 

以青海盐湖氯化镁为初级原料,采用喷雾热解法制备原料氧化镁。原料氧化镁通过水化制备氢氧化镁。将氢氧化镁过滤、洗涤、烘干、粉碎、煅烧,制备硅钢级氧化镁。本文重点考察煅烧温度、煅烧时间、料层厚度等因素对氧化镁水化率的影响,采用均匀实验设计和DPS数据处理,确定最优煅烧实验条件为:煅烧温度1250℃,煅烧保温时间4小时,料层厚度0.5cm。在此条件下得到的硅钢级氧化镁完全满足硅钢及氧化镁的行业标准。 The magnesium oxide is prepared by Spray pyrolysis process,which magnesium chloride from Qinghai Salt Lake is used as primary raw material,and hydrated to magnesium hydroxide,then obtained silicon steel magnesia through filtering,washing,drying,crushing and calcinations.In this paper,influences of some factors on magnesia hydration rate are studied,such as calcination temperature,calcination time and material thickness.After average experimental design and DPS data processing,optimal calcination... 

针对川威950的工艺现状,结合无取向低硅钢SGG生产的工艺特点,主要从控制其钢坯加热和轧制以及终轧温度和卷曲温度几方面入手,进行无取向低硅钢生产的工艺控制研究。同时根据近6000吨的生产实践表明,该工艺措施能很好的满足该钢种的需要。 950 process Chuanwei status quo,with non-oriented silicon steel production process features low,mainly from the control of billet heating and rolling and finish rolling temperature and coiling temperature of several aspects,for non-oriented silicon steel production process of low control at the same time According to nearly 6,000 tons of production practice shows that the process measures could well meet the needs of the steel. 

研究二次冷轧压下率对于硅的质量分数为3.0%的无取向硅钢组织结构和磁性能的影响。结果表明:当第二次冷轧压下率从0变化至16.7%时,铁损逐渐增加,磁感逐渐降低。当第二次冷轧压下率大于16.7%时,随压下率的增加,铁损逐渐减小,磁感逐渐增加。当第二次冷轧压下率大于38%时,二次冷轧法所能获得的磁性能明显优于一次冷轧法。 Effect of double cold reduction on magnetic,microstructure and texture of 3.0% Si non-oriented silicon steel sheets was investigated.The results show that the iron loss increases and magnetic induction reduces as the percentage redcution in secondary cold rolling changes from 0 to 16.7%.The core loss can be reduced remarkably,and magnetic induction can get a little benefit if the percentage redcution in double cold reduction is higher 16.7%.In case of higher than 38% of the percentage redcution ... 

以不断增长的薄板坯流程为背景,与传统流程对比分析了薄板坯流程无取向电工钢热轧晶粒组织特征;以50W800和50W1300钢为典型实例,探讨了两种流程下成品板晶粒组织、织构、磁性能及其磁时效行为的基体差异和相关原理。研究表明,薄板坯流程热轧板组织较粗大,有利于在成品板中获得粗大的晶粒和有利的织构,从而得到较低的铁损和较高的磁感。然而,薄板坯流程会造成第二相粒子的细小弥散分布与不充分析出,容易因磁时效而使磁性能恶化。 Based on the rapid development of compact strip production(CSP) processing,the characteristics of hot band grain structure produced by CSP processing were analyzed in comparison with those of conventional technology.The basic differences in grain size,texture,magnetic properties and the magnetic aging behaviors of the final sheet products produced by the two processing technologies and the corresponding principles were discussed,while steel 50W800 and 50W1300 were taken as examples.It is indicat... 

以轻烧氧化镁粉为原料,经消化、碳化制得重镁水,在热解反应前采用络合剂对重镁水中的杂质钙、铁进行络合掩蔽,再经热解得到碱式碳酸镁,碱式碳酸镁经煅烧可制得钙、铁杂质含量较低的氧化镁。在重镁水络合除杂过程中,考察了络合剂三乙醇胺、柠檬酸、草酸单独和复合使用的除铁、除钙效果。以三乙醇胺为络合剂时,在200 mL重镁水中加10 mL三乙醇胺(1∶1),氧化镁产品中w(氧化镁)=99.3%、w(氧化钙)=0.31%、w(氧化铁)=0.042%;使用草酸和柠檬酸作为复合络合剂时,在200 mL重镁水中加入1.0 g柠檬酸和2.0 g草酸,氧化镁产品中w(氧化镁)=98.2%、w(氧化钙)=0.24%、w(氧化铁)=0.030%。 Light-burned magnesia as a raw material was hydrated and carbonated to obtain magnesium bicarbonate liquor.Before the pyrolyzing of magnesium bicarbonate liquor,complexants were used to cover Fe and Ca impurities.Then the treated liquid was pyrolyzed to obtain basic magnesium carbonate which was calcined to magnesium oxide with low calcium and iron content.During the complexing purification of magnesium bicarbonate liquor,the Fe and Ca removing effects of single or compound complexing agents,suc...