硅钢资料

以质量分数为25%的丙烯酸乳液MC-102、15%Al(H2PO4)3溶液、0.01%H3BO3、0.01%Zn(Ac)2·2H2O和2%二乙二醇丁醚组分,在不同固化工艺下制备涂层。极化曲线和电导率测试发现300℃处理60 s得到的涂层具有良好的耐腐蚀性和绝缘性;水煮实验证明该涂层具有良好的耐水性;断口线扫描发现涂层具有良好的附着性。 A formula comprising MC-102 acrylic emulsion 25%,aluminium dihydrogen phosphate15%,boric acid 0. 01%,zinc acetate dihydrate 0. 01% and diethylene glycol monobutyl ether 2% was used to prepare coatings via different treatment process. The conductivity test and polarization curves revealed that a coating cured at 300 ℃ for 60 s showed good insulative and anticorrosive properties. The water boiling test indicated that the said coating had good water resistance. A cross section of the coating was in... 

以一种新的Fe-Si合金制备工艺为出发点,研究了不同放电等离子体快速烧结工艺(SPS)和Si含量变化对Fe-Si合金材料显微组织与磁性能的影响。结果表明,在烧结温度为1 000℃时制备的Fe-6.5%Si合金(质量分数,下同)的综合磁性能较好,其在50Hz下的铁损为0.549W/kg,最大磁感应强度为0.124 3T,矫顽力245.6 A/m,磁导率0.338mH/m。另外,材料的最大磁感应强度随Si含量的增加显著增长,1 000Hz下,Fe-10.0%Si的最大磁感应强度可达到Fe-6.5%Si合金的5倍左右。 The effects of Si content and SPS technology on microstructure and magnetic properties of Fe-Si alloy material were studied in the paper.It shows that the magnetic properties are the best when the content of Si is 6.5wt% and the sintering temperature is 1 000℃,the iron loss is 0.549W / kg in 50Hz,maximum magnetic induction is 0.124 3T,coercive force is 245.6A / m and permeability is 0.338mH / m。And,the maximum magnetic induction increases significantly with the increase of Si.The maximum magneti... 

研究了取向硅钢制备过程中常见的两种冷轧工艺,主要研究了一阶段冷轧与两阶段冷轧+中间退火工艺对初次再结晶组织及织构的影响.结果表明:采用两阶段冷轧+中间退火工艺制备以Cu2S为主抑制剂的取向硅钢,其初次再结晶平均晶粒尺寸为18.1μm,高斯晶粒的体积分数为0.6%,迁移性强的重位点阵晶界(Σ5+Σ9)和高能晶界(20°~45°取向偏差角)所占比例分别为1.8%和50.4%.与一阶段冷轧工艺相比,其初次再结晶晶粒较细,且高斯晶核与特征晶界所占的比例较高,有利于高斯晶粒发生二次再结晶. Two common cold-rolling processes of grain oriented silicon steel and the effects of the single stage cold rolling and tw o-stage cold rolling w ith intermediate annealing processes on the primary recrystallization microstructure and texture w ere investigated. The results revealed that for the grain oriented silicon steel prepared under the tw o-stage cold rolling process w ith intermediate annealing w ith Cu 2 S as the main inhibitor,the average grain size of the primary recrystallization micr... 

通过对35W300高牌号0.35 mm冷轧无取向电工钢卷(/%:0.002C、2.71Si、0.22Mn、0.015P、0.003S、0.0020N、0.55Als)头、中、尾组织、织构及对应的磁性能的试验研究,发现因热轧时12 MPa高压水连续冷却造成接触轧辊的钢卷头、中、尾在不同温度下轧制,卷取后钢卷头部处于卷心、温度略高而冷却速度略低于钢卷尾部,致使钢卷纵向组织、织构不同,成品卷头、尾各250 m内磁感逐渐增加,铁损逐渐降低,250 m外至钢卷中部磁性能稳定。通过将热轧辊的冷却方式改为周期冷却和卷取后的层流冷却改为钢卷70 m后开始冷却,至钢卷尾部70 m前停止冷却的方式使得钢卷纵向铁损差异明显减小,磁感差异略有改善。 According to the test research on structure and texture of head,meddle and end of 35W300 high grade 0.35 mm cold rolled non-oriented electrical steel strip coil(/%:0.002C,2.71Si,0.22Mn,0.015P,0.003S,0.002 0 N,0.55Als) and corresponding magnetic properties,It is found that due to 12 MPa high pressure water continuous cooling the roller in hot rolling process led to head,middle and tail of strip rolling at different temperature and after coiling the head of strip coil being in center of coil led t... 

采用经验设计法初步确定了取向硅钢铸坯感应加热线圈设计参数,应用Ansoft仿真软件分别对36组不同线圈高度、线圈内径的感应加热炉在不同频率下的三维整体磁场和铸坯的温度场进行了数值仿真。通过对比仿真结果,确定电磁场分布最佳的一组感应加热炉设计参数为线圈高度h=1.50 m、线圈内径D1=0.575 m、电流频率f=110 Hz。在该参数下应用Ansoft仿真软件对取向硅钢铸坯感应加热炉的温度场进行了仿真,结果发现温度场分布均匀,可满足取向硅钢铸坯加热要求。 The induction heating coil design parameters for the oriented silicon steel casting blank were determined preliminary by experience design method,and 36 groups three-dimensional electromagnetic field with different height and inside diameter of coil under different frequencies of the induction heating furnace and the temperature field of the casting blank were investigated by numerical simulation using Ansoft simulation software. By comparing the simulation results of electromagnetic field distr... 

利用EBSD技术对CGO硅钢热轧、中间退火、脱碳退火及二次再结晶退火组织及织构进行分析,研究了CGO硅钢各阶段加工制备过程中高斯{110}<001>晶粒的形状、尺寸及分布特点,分析了高斯取向晶粒在各工序过程中的遗传继承性特点。结果表明,CGO硅钢热轧板的次表层存在Goss取向晶粒,历经一次冷轧及中间退火后Goss取向晶粒基本消失,一次再结晶之后Goss织构仍不是主要织构,主要织构为{111}<110>和{111}<112>,说明Goss取向晶粒在二次再结晶退火前数量及尺寸上并不占优势,二次再结晶过程中Goss取向晶粒异常长大形成锋锐Goss织构。{111}<110>和{111}<112>织构组分的强度在一次冷轧中不断增加,{111}<112>织构组分的强度在二次冷轧后达到最大而{111}<110>织构组分是在初次再结晶后变强。 Grain shape,size and distribution of { 110} < 001 > Goss grains in CGO steel and the hereditary characteristics of Goss orientated grains during each processing period were investigated,based on the analysis of the microstructure and texture of the CGO silicon steel during hot rolling,intermediate annealing,decarburizing annealing and secondary recrystallization annealing by means of EBSD. The results show that Goss orientated grains exist in the subsurface of the hot rolled plate,and Goss... 

针对攀枝花钢钒有限公司难以稳定生产w(S)≤0.006%高级别电工钢的问题,通过开发RH脱硫剂、钢包渣改性及工艺参数控制,形成了RH脱硫系统工艺技术。经工业试验表明,采用该工艺技术后,钢水脱硫率最高达到42%,成品w(S)控制在0.005%以下,全氧、氮含量也得到了较好的控制,且脱硫剂没有引起钢水增碳,满足高级别电工钢的生产要求。 In light of the difficulty of production of high level electrical steel w(S)≤0.006 % steadily in Panzhihua steel & vanadium Co.,Ltd.the process technology of RH desulfurization system has been formed by developing the RH desulfurizer,modifying the ladle slag and controlling the process parameters.Industrial experiments show that the desulfurization rate of hot metal rises to 42 % and the w(S) of the finished products is controlled in below 0.005 % and total oxygen and nitrogen contents are a... 

利用EBSD技术研究了电工钢中长轴平行于轧向的柱状晶样品在热轧和退火过程中组织和取向的演变规律,并与长轴平行于板法向的样品的已有研究结果进行对比。结果表明,无论柱状晶按何种方向排列,只要表面存在剪切力,热轧后都可形成剪切织构,同时中心形成轧制织构,主要包括旋转立方织构和{112}<1-10>。柱状晶造成的影响主要体现在板中心层,长轴平行于轧向排列的样品热轧时形成的粗大旋转立方晶粒要到脱碳退火后才能完全消除,但破坏了正常的不同取向晶粒间的取向差分布及尺寸均匀性,导致二次再结晶不完全及磁性能降低。 The evolution of microstructure and grain orientation in an electrical steel containing columnar grains with its long axis being parallel to the rolling direction of sheet was studied during hot rolling and annealing by EBSD technique.The results are compared with those of samples containing columnar grains being parallel to normal direction of sheet reported in the reference [3].It was shown that,whether the long axis of columnar grains was arranged in RD or ND,shear textures can be formed in t... 

选取了三种50W 800无取向电工钢,分析了化学成分、晶粒尺寸、织构、以及200℃时效处理48 h前后的磁性能和第二相粒子析出状态的变化。结果表明,钢板中第二相粒子的分布密度对钢板铁损有最重要的影响。降低钢中C、N元素含量,或改进钢板热加工参数以降低成品钢板中第二相粒子形成元素的过饱和度均有利于明显降低钢板磁时效过程中的铁损增幅。钢板中对磁性能有利的织构也有利于降低钢板铁损的时效幅度。 The evolution of chemical composition,grain size,texture,as well as magnetic property after aging treatment at 200 ℃ for 48 h and distribution of second phase particles precipitation in three selected 50W800 non-oriented electrical steels were analyzed.The results show that the distribution density of second phase particles has great influence on core loss.Reducing C and N content,or improving hot-working parameters to reduce the supersaturation of elements forming second phase particles in prod... 

针对宝钢硅钢常化退火过程中产生的退火炉辊印缺陷问题,通过实际生产的大数据与产品质量问题相结合,将数据挖掘、数据分析方法应用到实际,一定程度上解决了现场实际生产中的痛点,为现场生产提供决策支撑,避免了以前通过人工识别判定存在疏漏和无法定量判断的问题,形成了一套具有鲁棒性和可操作性的钢铁生产过程数据分析方法。通过智慧决策系统平台获取实际生产和表检仪数据,基于Pearson相关系数算法进行变量挑选和特征工程,并应用随机森林算法对数据建立分类预测模型,实现了质量问题的溯源和监控,通过数据量化预测了炉辊印缺陷是否可通过轧制消除的质量问题,识别准确率达到96.43%。 In views of the normalizing annealing furnace roll marks problem occurred in the process of normalizing annealing of silicon steel in Baosteel,by combining big data from actual production with product quality problems,data mining and data analysis methods were applied to actual production to solve the pain points and provide decision support,a robust and practical data analysis method for the steel production process has been developed,which avoided the previous problems of omission and non-quan... 

针对薄板坯连铸连轧流程结合\"获得抑制剂法\"所制备的低温高磁感取向硅钢,通过热力学计算研究了AlN与MnS在连铸与均热过程中的析出规律与行为。计算结果表明,连铸过程中AlN在凝固后的高温α相中便可能析出,而MnS仅可能在凝固后的α+γ两相区内析出。钢中AlN与MnS在均热过程中均处于部分固溶与部分析出的状态。后续高温渗氮处理后初次晶粒的异常长大并不明显,表明渗氮处理前钢中固有抑制剂的数量相对充足。 The precipitation behavior of MnS and AlN in low-temperature high magnetic induction grain-oriented silicon steel produced by thin slab casting and rolling process with\"acquired inhibitor method\"during continuous casting and soaking was studied by thermodynamic calculation.The calculated results show that AlN is likely to precipitate in ferrite after solidification.However,MnS can precipitate only in the two phase region of ferrite and austenite.Meanwhile,MnS and AlN in the steel can not be comp... 

通过对湿H2气氛下,相同退火温度、不同退火时间的CGO硅钢初次再结晶样品进行金相组织观察,并进行了EBSD微观织构分析,研究了CGO硅钢初次再结晶过程中的组织及再结晶织构演变行为。结果表明,在湿H2气氛下,820℃保温,CGO硅钢初次再结晶过程约在120 s时完成。随着退火时间的延长,γ面上{111}<112>织构含量逐渐减少,{111}<110>织构先减少后增多,随着再结晶的完成,部分{111}<112>取向晶粒向高斯{110}<001>取向转化的同时,也向{111}<110>取向转化,高斯{110}<001>织构含量逐渐增多。高斯取向晶粒较多是由{111}<112>取向晶粒转化而来,同时也证明了CGO硅钢高斯取向晶粒的二次再结晶异常长大生长机制为择优形核。 Microstructure development and texture evolution of conventional grain oriented silicon steel,which were annealed at same annealing temperature and different annealing time under wet H2 atmosphere,were investigated through metallographic observation and electron backscattered diffraction analyzing.The results show that the primary recrystallization finishes in 120 s at 820 ℃ under wet H2 atmosphere.With the extending of annealing time,{111}<112> texture decreases,{111}<110> texture d...