硅钢资料

【作者】 张煜； 朱国辉； ...

运用电子背散射衍射(EBSD)和X射线衍射(XRD)技术对硅钢热轧板的织构在板厚方向的分布进行了研究,并分析了两种织构测量方法的特点。EBSD技术能直观给出板厚方向的微观织构,XRD能得到钢板的宏观统计织构信息,结合两种技术的分析,能更直观更精确的研究不同织构在板厚方向的分布。 The texture distribution along the thickness of the silicon steel has been investigated by electron backscatter diffraction(EBSD) and X-ray diffraction(XRD) technique.The characteristics of two technique of texture analysis have been investigated.Combined the two techniques,the texture distribution along the thickness of the silicon steel could be realized distinctly and accurately. 

借助于EBSD对比研究了常化退火对高牌号无取向电工钢热轧组织和织构演变的影响,分析了常化退火对热轧板各厚度层织构的演变规律。结果表明,常化退火改善了热轧组织的均匀性,并弱化了热轧变形的γ纤维织构。升高常化退火温度,可增大热轧板的晶粒尺寸,提高{100}和{110}织构组分占有率,有利于提高无取向电工钢成品板的磁性能。 Effects of normalizing annealing on microstructure and texture of high-grade non-oriented electrical steel hot-rolled sheet were investigated by EBSD. Emphasis was put on the effects of normalizing annealing on texture evolution in the sheet thickness. The results show that the hot-rolled microstructure homogeneity is improved and the γ-fiber texture is weakened by normalizing annealing treatment. The grain size of hot-rolled sheet and intensity of the {100} and {110} favorable texture can be in... 

对两种硅钢水溶性极厚绝缘涂层进行了不同温度的热老化实验。通过TG-DTA,GDS,FT-IR,SEM和光泽度仪等测试方法对老化的涂层进行分析表征,提出了评估硅钢水溶性极厚绝缘涂层热老化性能的合理温度区间,探讨了涂层热老化行为,并分析了两种涂层热老化性能的差异。结果表明,涂层附着性随着老化时间的延长逐渐下降。FT-IR表征结果显示,热老化过程中,涂料交联形成的化学键未发生断裂,交联剂氨基树脂的三嗪环被破坏是聚合物三维网络结构坍塌的主要原因。 Thermal aging expriments at different temperature were carried out on two types of water-soluble and extra-thick insulation coatings for non-oriented silicon steel,and a series of test methods such as glossmeters,TG-DTA,FT-IR,GDS,SEM were applied in analysis.For evaluating the thermal aging effect of this kind of insulation coating,the proper temperature range was proposed.The difference of aging performance between two coatings was been investigated and the related behaviors were been discussed... 

针对新日铁公开的相关专利,总结日本高强度无取向电工钢的研究进展,分析了各专利化学成分、生产工艺及产品性能的特点,指出固溶强化、细晶强化、析出强化、位错强化都有可能被用来提高无取向电工钢的强度。在高强度无取向电工钢的研发过程中,需要根据其具体用途确定目标性能,再采用合适的强化手段,从而实现力学性能、磁性能和生产性能之间的平衡。 Authors summarize the research progress of high strength non-oriented electrical steel in Japan by learning related patents brought into the public by Nippon Steel. Authors also analyze the characteristics of the chemical composition, production technology and properties of products in the patents and point out that any ones of solution strengthening method, fine-grain strengthening method, precipitation strengthening method or dislocations strengthening method may be used to improve the strengt... 

取向硅钢常化工序主要采用现场实测带钢温度的方式测定冷却速率，并通过稳定冷却水温、调整冷却水量及喷梁运行数量等方式保证合理的冷却速率，给常化工艺设计和生产带来诸多不便。通过对常化工艺水冷过程带钢的传热分析求解，在建立带钢水冷温度模型的基础上，研究了不同冷却工艺参数对带钢温度及冷却速率的影响规律以及冷却工艺的交互作用结果。结果表明：模型计算结果能够较好地反映取向硅钢在常化水冷过程中的温度及冷却速率的变化，其计算误差为0.80%～4.11%;在特定取向硅钢厚度规格和常化工艺下，随着常化冷却水量及有效冷却长度的增加，带钢水冷温度及冷却速率与呈非线性变化；常化水冷工艺主要通过调控带钢与冷却水之间热交换量和交换时间实现对带钢温度的控制，实际生产中需综合考虑机组速度、冷却水量及有效冷却长度之间的交互作用，选定喷梁投入数量和冷却水量以获得稳定的冷却速率。 The cooling rate of normalization process mainly determined by measuring the grain oriented silicon steel strip temperature on site, and ensures the cooling rate by stabilizing the cooling water temperature, adjusting the cooling water volume and the operation quantity of spray beam, which brings inconvenience to the normalization process design and production. Based on the heat transfer of strip in the water cooling section of normalization process, the water cooling temperature model for the n... 

利用FE-SEM、EDS分析了含不同抑制剂成分的成品取向硅钢中夹杂物的组成和形貌,统计其尺寸及数量分布;结合对磁性能测试的结果,分析了Sn、Cu、Nb和Cr对取向硅钢磁性能影响的机理。结果表明:含Sn的取向硅钢试样中夹杂物主要为块状的微米级Al-Ti-C-N-O复合物,还有少量的球形Al-N-O颗粒和块状Ti-C-N-O颗粒,棒状夹杂物较少;含Cr的取向硅钢试样中夹杂物主要为球形的微米级Al2O3,还有少量Cu-Al-N-O-S复合物,棒状夹杂物和不规则夹杂物均较少;含Cr试样中1~3μm夹杂物的平均尺寸较含Sn试样小,但数量多,而大于3μm夹杂物的平均尺寸较含Sn试样大,但数量很少。磁性能测试结果表明,外场为800A/m和2500A/m时,含Cr试样磁感应强度偏低,铁损值P1.7/50较含Sn试样高,为1.171W/kg。 The composition and morphology of inclusions in the finished grain-oriented silicon steels are analyzed by using FE-SEM and EDS, and the number density and size distribution of the inclusions are counted. The influence mechanism of Sn, Cu, Nb, and Cr on the magnetic properties of the steel is also discussed. Results show that the inclusions composition in the grain-oriented silicon steel samples containing Sn is mainly block Al-Ti-C-N-O, compounding with a few spherical Al-N-O and block Ti-C-N-O... 

借助实验室设备研究了B元素对高牌号无取向硅钢热轧板组织和磁性能的影响。结果表明,与无硼钢相比,含硼钢的热轧板晶粒尺寸略小,析出物的类型和尺寸没有区别,主要是AlN和(AlN+MnS)复合析出物,少量的MnS析出物,尺寸集中在1.0～2.5μm范围内。未发现BN析出物。在力学性能方面,B对钢的软化作用不明显。在磁性能方面,含硼钢的铁损为3.215W/kg,磁感为1.710T,综合磁性能比无硼钢差。 Influences of boron on microstructure and properties of hot rolled band in high-grade non-oriented silicon steel are researched in this paper by experimental equipments.Compared with boron-free steel,the result shows that boron-bearing steel has smaller grain size,but the type and size of precipitations have no differences.The main precipitates are AlN,(MnS + AlN) composite precipitate and few MnS,the range of which are between 1.0 μm and 2.5 μm.BN precipitation is not found.With reward to mecha... 

通过对激光粒度分析仪测量硅钢级氧化镁(MgO)的分析条件进行优化,如分散介质、分散方式、样品预处理、仪器暗淡度等,探讨了硅钢级MgO粒度范围测量重现性较好的试验方法,满足硅钢生产过程控制对MgO粒度的要求。 The analysis condition of the laser particle size analyzer on grain oriented silicon-steel grade magnesium oxide is optimized,including the dispersion medium,dispersion methods,sample preparation,and instrument obscuration,etc.Therefore,particle size measurement with good reproducibility for silicon-steel magnesium oxide is discussed,which may meet the requirement of MgO particle size for silicon-steel process control. 

利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1～2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,... 

对欧盟市场汽车压缩机专用产品进行技术解析,对比分析了其电磁性能、退火和发蓝处理、物理性能、化学成分、应用特点等参数。探讨国内外电工钢产品应用方式的不同特点,并结合鞍钢自身工艺装备和炼钢、热轧、冷轧工艺参数介绍了其生产可行性。提供了冶金工艺流程下,后工序电工钢专业生产线及传统冷轧系统生产线两种生产方式,均能满足用户最终使用要求。 The technology of automotive compressor accommodation manufacture of European Economic and Monetary Union market was described.The magnetic properties,annealing bluing,physical properties,chemical composition,application parameters were analysed.The different characteristics of the application of electrical steel products,the feasibility of manufacture on the existing technology and equipment,steelmaking,hot rolled,cold rolled technical parameters were discussed.The professional product line of ... 

借助高温激光共聚焦显微镜,在线观察了不同Mn含量的无取向硅钢中夹杂物的尺寸、类型、数量变化。结果表明,Mn含量(质量分数)为0.77%、0.32%时,试样中的夹杂物数量分别约为1000万个/mm3、1600万个/mm3。Mn含量较高的钢种,会优先析出球形、椭球形MnS夹杂物,其析出数量较少,尺寸相对较大,可以有效抑制AlN、CuxS夹杂物析出;Mn含量较低的钢种,会在试样再加热后冷却过程中,先析出相当数量MnS夹杂物,并作为AlN夹杂物析出核心,形成MnS+AlN复合夹杂物。这种复合夹杂物数量较多,尺寸也较大。 Based on the high temperature confocal microscope, the chage of size, type, and quantity of inclusions in non-oriented silicon steels with different Mn content were observed by in-situ SEM. Results show that the inclusion quantities are 10 million per mm3 and 16 million per mm3,while the mass fractions of Mn are 0.77% and 0.32%, respectively. In the silicon steel with higher Mn content, the spherical and ellipsoidal MnS inclusion will precipitate first, which can retard the precipitation of AlN ...