钢厂
CSP流程生产高磁感无取向电工钢磁各向异性研究
对CSP流程生产的高磁感无取向电工钢50W1300在偏离轧制方向不同角度处的磁性能进行了测试和分析。结果表明:在偏离轧向不同角度处,磁性能差异显著,尤其在α=60°时磁感最低;偏离轧制方向不同角度处的磁性能大小取决于织构类型、强度及分布状态;增强{100}<0vw>和α、η取向的有利织构组分,降低不利的γ取向织构组分,且使有利织构组分分布越漫散,磁各向异性越小。 Magnetic properties of high magnetic induction non-oriented electrical steel 50W1300 produced by CSP processes were investigated with different direction in relation to the rolling direction.The result shows that magnetic properties are significantly different in relation to the rolling direction,in particular,the minimum magnetic induction occurs at 60° in relation to the rolling direction.Magnetic properties of different directions in relation to rolling direction depend on type and distributi...
电感耦合等离子体质谱法测定硅钢中痕量铜和镍
研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%~100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters...
50W600无取向硅钢钙处理的热力学分析及实验研究
通过热力学计算及实验室研究,对钙处理前后50W600无取向硅钢退火冷轧板中夹杂物的类型、数量及尺寸进行了系统分析。结果表明,50W600无取向硅钢经钙处理后(w(Ca)=0.002 6%),钙在1 600℃的钢液中主要以固态的CaO·2Al2O3、CaO·6Al2O3及溶解钙的形式存在。在钢液的凝固过程中,钢中的溶解钙和硫反应生成了CaS和CaS-MnS复合夹杂,有效抑制了MnS的弥散析出,减少了钢中微细夹杂物的数量。同时钙处理促进了钢中微细夹杂物的聚合长大,导致显微夹杂物的数量增加。 Based on thermodynamic calculation and laboratory experiment,the type,quantity and size of inclusions in annealed cold-rolled steel sheets of 50W600 non-oriented silicon steel before and after calcium treatment were systematically studied.Results showed that after calcium treatment(w(Ca) = 0.002 6%),calcium was mainly in the form of CaO·2Al2O3,CaO·6Al2O3 and dissolved calcium in steel at 1 600 ℃.Dissolved calcium could combine with sulfur to form CaS inclusions and compound CaS-MnS inclusions du...
氢氧化镁煅烧制备硅钢级氧化镁的研究
以青海盐湖氯化镁为初级原料,采用喷雾热解法制备原料氧化镁。原料氧化镁通过水化制备氢氧化镁。将氢氧化镁过滤、洗涤、烘干、粉碎、煅烧,制备硅钢级氧化镁。本文重点考察煅烧温度、煅烧时间、料层厚度等因素对氧化镁水化率的影响,采用均匀实验设计和DPS数据处理,确定最优煅烧实验条件为:煅烧温度1250℃,煅烧保温时间4小时,料层厚度0.5cm。在此条件下得到的硅钢级氧化镁完全满足硅钢及氧化镁的行业标准。 The magnesium oxide is prepared by Spray pyrolysis process,which magnesium chloride from Qinghai Salt Lake is used as primary raw material,and hydrated to magnesium hydroxide,then obtained silicon steel magnesia through filtering,washing,drying,crushing and calcinations.In this paper,influences of some factors on magnesia hydration rate are studied,such as calcination temperature,calcination time and material thickness.After average experimental design and DPS data processing,optimal calcination...
热轧组织对无取向硅钢织构的影响
采用X射线衍射仪分析无取向硅钢冷轧织构和再结晶退火织构的演化,研究了热轧组织对无取向硅钢织构以及磁性能的影响。结果表明,具有均匀、粗大晶粒组织的热轧板,冷轧形成更多的剪切带,导致成品板形成高的高斯织构组分,并提高了{100}织构强度,降低了γ纤维织构,最终导致成品磁感应强度升高,铁损下降。 The texture evolution of non-oriented silicon steel during cold-rolling and recrystallization annealing was investigated by X-ray diffractometer.The effects of hot band microstructure on the texture and magnetic properties of non-oriented silicon steel were analyzed.The results show that more shear bands appear during cold rolling due to homogeneous coarse grain in hot band.So strong{110}<001> texture after recrystallization annealing forms.At the same time,the {100} texture components inc...
取向硅钢生产工艺技术分析和发展趋势
介绍了普通取向硅钢(CGO)和高磁感取向硅钢(Hi-B)铸坯高温加热两次冷轧、一次冷轧和铸坯低温加热两次冷轧、一次冷轧法4种成熟生产工艺的主要技术参数,取向硅钢理论研究(Goss晶核和抑制剂)和生产技术现状。取向钢的发展趋势为:提高(110)[001]晶粒取向度,降低取向硅钢铁损,发展铸坯低温加热(≤1 300℃)和薄板坯连铸连轧流程生产取向硅钢工艺。 Main technology parameters of four developed process:cast bloom higher temperature heating-double cold rolling or single cold rolling,lower temperature heating-double cold rolling or single rolling process for production of common grain oriented silicon steel(CGO) and high magnetic induction grain oriented silicon steel(Hi-B),theory research on grain oriented steel(Goss nucleus and inhibitor) and present situation of process are summarized in this paper.The development trend of grain oriented si...
硅钢常化退火炉辊印缺陷预测分类预警方法研究
针对宝钢硅钢常化退火过程中产生的退火炉辊印缺陷问题,通过实际生产的大数据与产品质量问题相结合,将数据挖掘、数据分析方法应用到实际,一定程度上解决了现场实际生产中的痛点,为现场生产提供决策支撑,避免了以前通过人工识别判定存在疏漏和无法定量判断的问题,形成了一套具有鲁棒性和可操作性的钢铁生产过程数据分析方法。通过智慧决策系统平台获取实际生产和表检仪数据,基于Pearson相关系数算法进行变量挑选和特征工程,并应用随机森林算法对数据建立分类预测模型,实现了质量问题的溯源和监控,通过数据量化预测了炉辊印缺陷是否可通过轧制消除的质量问题,识别准确率达到96.43%。 In views of the normalizing annealing furnace roll marks problem occurred in the process of normalizing annealing of silicon steel in Baosteel,by combining big data from actual production with product quality problems,data mining and data analysis methods were applied to actual production to solve the pain points and provide decision support,a robust and practical data analysis method for the steel production process has been developed,which avoided the previous problems of omission and non-quan...
硅钢RH处理过程碳和硫行为分析
分析了太原钢铁(集团)有限公司第二炼钢厂80 t RH生产冷轧硅钢脱碳、脱硫原理及影响因素,认为通过合理控制RH到站钢水碳和氧含量、加大插入管内径、采用快速抽真空度等可提高脱碳效果。降低顶渣中FeO和MnO含量,保证脱硫剂加入后的循环时间可以提高RH脱硫率。 The present article analyzes the principle of decarburization and desulfurization in refining the cold rolled silicon steel in the 80 t RH in No.2 Steelmaking Plant of Taiyuan Iron & Steel(Group) Corp.,and its influencing factors.It’s determined that the decarburization effect can be achieved by properly controlling the cabon and oxygen contents in the hot metal coming into the RH station,enlarging the inner diameter of snorkel and adopting the fast evacuation method.In the meanwhile the des...
ZnO对无铬无取向硅钢绝缘涂层性能的影响研究
主要研究了氧化锌对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验和动电位极化研究了不同氧化锌含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响.采用SEM和体视显微镜对涂层的表面形貌和附着性能进行研究.结果表明,氧化锌含量为4.0%时,氧化锌能完全中和涂层表面的游离磷酸,涂层的耐蚀性和附着性最好;氧化锌含量过少或过多时,涂层的耐蚀性和附着性都较差. This paper studies the influence of zinc oxide on the performance of chromium-free non-oriented silicon steel insulating coating which based on aluminum dihydrogen phosphate.Salt spray experiment and potentiodynamic polarization were used to study the influence of zinc oxide content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.The surface morphology and adhesion of coating were tested by SEM and stereo microscope.The results show that when t...
低铁损高磁通密度无取向硅钢的应用与生产技术进展
分析了高转矩和高转速条件下高效驱动马达铁芯材料对无取向硅钢磁性能要求,讨论了无取向硅钢的高磁通密度和低铁损对电机转矩和效率的影响,介绍了国内外高磁感无取向硅钢发展情况。在生产工艺上,提高钢质纯净度,弱化夹杂物和第二相粒子对畴壁移动和再结晶晶粒长大的钉扎作用,添加微量晶界和带钢表面的偏析元素促使有利织构发展等技术可提高无取向硅钢的磁通密度。 The requirements of high efficient drive motor core materials under the conditions of high torque and high speed were analyzed.The effects of high magnetic flux density of non-oriented silicon steel on the torque and efficiency of the motor were discussed.The development of non-oriented silicon steel with high magnetic was introduced.The magnetic flux density of non-oriented silicon steel sheet can be obviously improved by some production technologies,such as purification steel,weakening the pin...
树脂含量对半无机型无铬无取向硅钢涂层性能的影响
本文研究了丙烯酸树脂含量对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同树脂含量对硅钢绝缘涂层的耐盐雾性能和电化学行为的影响,同时采用SEM对涂层的表面形貌和附着性进行研究.结果表明,树脂含量为19.9~29.4%时,涂层的耐蚀性和附着性最好;树脂含量过多时,涂层的耐蚀性和附着性均较差. This paper studies the influence of acrylic resin on the performance of insulating coating of aluminum dihydrogen phosphate on chromium-free non-oriented silicon steel.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of acrylic resin content on the salt spray resistance and electrochemical behavior of the insulation coating of nonoriented silicon steel.The surface morphologys and adhesion of coating were tested by SEM....

