钢厂
表面机械研磨/异步轧制无取向硅钢薄带的渗硅行为
对w(Si)=3%无取向硅钢进行表面机械研磨处理(SMAT)和异步轧制(CSR),获得表面纳米结构,再进行550～650℃、4 h固体粉末渗硅处理,用透射电镜(TEM)、扫描电镜(SEM)和X射线衍射仪(XRD)研究表层组织演变。结果表明:经过SMAT后,w(Si)=3%无取向硅钢表面形成了等轴状、取向呈随机分布的、晶粒尺寸为10 nm的纳米晶组织;异步轧制后,表面纳米晶组织保持不变;550～650℃、4 h渗硅处理后,SMAT+CSR样品表面形成化合物层,其厚度随着温度的升高由17μm增加到52μm;化合物层由Fe3Si和FeSi相组成. Nanostructured surface layer was fabricated on a 3%(mass fraction) non-grain oriented silicon steel by means of surface mechanical attrition treatment(SMAT) and cross-shear rolling(CSR),and then a solid powder siliconizing treatment was carried out for the SMAT+CSR sample at 550~650 ℃ for 4 h.The microstructural evolution was examined by using transmission electron microscopy(TEM),scanning electron microscopy(SEM) and X-ray diffraction(XRD).Experimental results show that: equiaxed nanocrystallin...
硅钢连续退火炉无氧化加热段辐射换热研究
以能量平衡和辐射换热理论为基础,通过合理假定,建立了硅钢无氧化加热炉数学模型。采用数值计算的方法,通过自编程序,完成对带钢加热过程温度场的仿真。结果显示:数学模型能够反映带钢在无氧化炉内的加热过程,其升温曲线能够与工艺曲线相吻合;现行炉温分布并非最优,数学模型能够为炉温分布的优化、炉段的设计提供理论依据。 Mathematical model of NOF Section of Continuous Annealing Furnace is established based on energy balance and radiation heat exchange. The temperature field of steel is simulated by mathematical computation. The simulating results show that the mathematical model can reflect the heating process of silicon steel in NOF section, and the heat-up curve is coincide with the processing curve. From the results,it is known that the current furnace temperature gradient is not the best, and the mathematica...
湿H_2气氛下CGO硅钢初次再结晶织构演变行为
通过对湿H2气氛下,相同退火温度、不同退火时间的CGO硅钢初次再结晶样品进行金相组织观察,并进行了EBSD微观织构分析,研究了CGO硅钢初次再结晶过程中的组织及再结晶织构演变行为。结果表明,在湿H2气氛下,820℃保温,CGO硅钢初次再结晶过程约在120 s时完成。随着退火时间的延长,γ面上{111}<112>织构含量逐渐减少,{111}<110>织构先减少后增多,随着再结晶的完成,部分{111}<112>取向晶粒向高斯{110}<001>取向转化的同时,也向{111}<110>取向转化,高斯{110}<001>织构含量逐渐增多。高斯取向晶粒较多是由{111}<112>取向晶粒转化而来,同时也证明了CGO硅钢高斯取向晶粒的二次再结晶异常长大生长机制为择优形核。 Microstructure development and texture evolution of conventional grain oriented silicon steel,which were annealed at same annealing temperature and different annealing time under wet H2 atmosphere,were investigated through metallographic observation and electron backscattered diffraction analyzing.The results show that the primary recrystallization finishes in 120 s at 820 ℃ under wet H2 atmosphere.With the extending of annealing time,{111}<112> texture decreases,{111}<110> texture d...
资源节约型高强度电工钢SXRC的开发
日本住友金属成功地开发了一种资源节约型高强度无取向电工钢SXRC,这种电工钢是通过固溶铌适度抑制位错的合并对消而得到一种特殊的微观组织,因此兼具很高的力学性能和磁性,特别适用于HEV、EV驱动电机转子。而且,不使用昂贵的镍就可以达到期望的强度,合金成本可控,是一种优越的资源节约型产品。 Sumitomo metal industries ltd of Japan successfully developed a type of high strength non-orientation electrical steel SXRC of resources-saving.The steel has both high mechanical performance and good magnetic property thanks to the special microstructure produced by the formation of Nb solid solution serving to appropriately inhibit the combination and cancellation of dislocations.The material is,in particular,suitable for manufacturing rotors of HEV and EV driving motors.Besides,expected streng...
异步轧制硅钢的表面纳米化及轧制参数的影响
对硅钢板材分别进行异步和同步轧制,研究了轧制参数包括速比、压下量和道次对板材表面显微组织的演变的作用.结果表明,异步轧制硅钢板材表面形成了晶粒尺寸为10~50 nm,取向接近随机分布的纳米晶,而同步轧制板材的表面只形成了位错胞,证明异步轧制可以诱发表面纳米化.异步轧制板材表面纳米晶的形成过程为:在剪切力的反复作用下,高密度位错形成、滑移、湮灭和重组形成亚微米尺度的亚微晶/位错胞.随着压下量和轧制道次增加,高密度位错重复以上过程使晶粒尺寸减小、取向差增大,最终形成取向接近随机分布的纳米晶组织.大压下量和多道次是异步轧制诱发板材表面纳米化的关键,而速比的增加可以加快纳米化进程. Surface nanocrystallization(SNC) can effectively enhance the surface and global properties of the metallic materials,such as microhardness,intensity,fatigue,wear and corrosion resistances,therefore provides more promising practical industrial applicability.Up to now,several SNC treatment methods were developed based either on the principles of ball impactions or friction sliding,however,difficulty still exists for the surface treatment of large-dimensional samples with high efficiency.Recently,m...
Nb微合金化Fe14Si2高硅钢温轧板织构演变规律
采用Nb对Fe-6.5%Si(质量分数)高硅钢进行微合金化处理,结果表明:Nb在高硅钢薄板制备过程中细晶效果明显.铸态、锻态和热轧态组织的晶粒分别细化了17.50%,24.51%和30.13%.铸态样品压缩强度由1365 MPa提高至1520 MPa,延伸率提高77.78%;温轧板试样室温拉伸强度由573 MPa提高至621 MPa,延伸率提高44.44%.利用XRD对厚度为0.30—1.68 mm的温轧板的板面织构演变过程进行跟踪测量,结果发现:初始织构以(011)〈100〉Goss织构为主,单道次变形量为26.2%的情况下,Goss织构完全转化为(100)〈011〉旋转立方织构,随后,在单道次变形为22.6%的情况下,旋转立方织构完全转化为{111}面织构,即纤维织构,并稳定保持至0.30 mm. Fe-6.5%Si（mass fraction） alloy possess perfect magnetic properties,though intermetallics of Fe14Si2 phase brought 6.5%Si leads to room temperature brittleness and hinder this significant materials industrialization.Nb was adopted into micro-alloying of Fe-6.5%Si high silicon steel. OM,thermal simulated test machine and XRD were employed to study the influence of Nb on high silicon steel in processing stages.Textures of warm-rolled high silicon steel strips were determined b...
优化脱氧工艺改善低碳低硅钢钢水可浇性
介绍了重庆钢铁股份有限公司炼钢厂生产低碳低硅钢的脱氧工艺,对连铸过程中水口结瘤的原因进行分析,并提出了优化措施。生产实践表明:钢水中的活性氧质量分数控制在10×10-6～30×10-6时,单中包浇铸炉数由6～7炉提高到11～12炉,同时能保证连铸顺行和减少铸坯气孔。 The deoxidation process of low-carbon and low-silicon steel in steel plant of Chongqing Steel was introduced.The nuzzle clogging was analyzed and some measures were put forward.Production experiments showed that when the active oxygen was controlled between 10×10-6～30×10-6,the amount of furnaces would rise from 6～7 to 11～12,which will make the casting process work well and reduce casting holes.
“双碳”大背景下的中国电工钢走势
阐述了电工钢在\"双碳\"中的作用,强调了电工钢的生产工艺技术及在减少碳排放、降低能耗中的作用,对下游能效升级带来明显的节能及降碳成果。同时,分析了2021年电工钢的生产运行情况,介绍了电工钢的未来发展,并针对如何减少碳排放以及生产更多的更低铁损、更高磁感的电工钢谈了几点启示。 The effects of electrical steels on carbon peak and carbon neutralization were expounded,especially on the achievements of obvious energy saving and carbon reduction to the downstream energy efficiency upgrading bringing from the production technology of electrical steels and their effects to reducing carbon emission and energy consumption.Meanwhile the production situation of electrical steels in 2021 was analyzed,and the future development of electrical steels was introduced,and some advices w...
低温高磁感取向硅钢高温退火过程高斯晶粒的演变
对低温加热工艺生产的以AlN为主抑制剂的高磁感取向硅钢高温退火过程进行中断实验,借助电子背散射衍射技术对高温退火过程中高斯晶粒的演变进行了研究.在升温过程中高斯晶粒平均尺寸先减小再增大.800℃时取向分布函数图出现高斯织构组分,但强度很弱,高斯晶粒偏离角在10°以上;900℃时高斯晶粒平均生长速率超过其他晶粒;950~1000℃时高斯晶粒异常长大,偏离角3°~6°;在1000℃之前高斯取向晶粒相比于其他晶粒没有尺寸优势. The high-temperature annealing process of high permeability grain-oriented silicon steel with AlN as an inhibitor was studied by interrupting test.The evolution of Goss texture in this process was analyzed by electron back-scattered diffraction.It is found that the Goss grain size first decreases and then increases with the rise of temperature.Goss texture appears in the orientation distribution function at 800 ℃,but the intensity is very weak and the deviation angle is more than 10°.The average...
